We analyse observational correlations for three elements entering into the composition of interstellar silicate and oxide grains. Using current solar abundances (Asplund et al. 2009), we convert the gas-phase abundances into dust-phase abundances for 196 sightlines. We deduce a sharp difference in abundances for sightlines located at low ($|b|<30\degr$) and high ($|b|>30\degr$) galactic latitudes. For high-latitude stars the ratios Mg/Si and Fe/Si in dust are close to 1.5. For disk stars they are reduced to ${\rm Mg/Si} \sim 1.2$ and ${\rm Fe/Si} \sim 1.05$. The derived numbers indicate that 1) the dust grains cannot be the mixture of silicates with olivine and pyroxene composition only and some amount of magnesium or iron (or both) should be in another population and 2) the destruction of Mg-rich grains in the warm medium is more effective than of Fe-rich grains. We reveal a decrease of dust-phase abundances and correspondingly an increase of gas-phase abundances with distance $D$ for stars with $D\ga 400$\,pc. We attribute this fact to an observational selection effect: a systematic trend toward smaller observed hydrogen column density for distant stars. We find differences in abundances for disk stars with low ($E({\rm B-V}) \la 0.2$) and high ($E({\rm B-V}) \ga 0.2$) reddenings which reflect the distinction between the sightlines passing through diffuse and translucent interstellar clouds. For Scorpius-Ophiuchus we detect an uniform increase of dust-phase abundances of Mg and Si with an increase of the ratio of total to selective extinction $R_{\rm V}$ and a decrease of the strength of the far-UV extinction. This is the first evidence for a growth of Mg-Si grains due to accretion in the interstellar medium.
In this brief review of recent work relating the DIBs to other gas-phase constituents of the ISM, we explore correlations between DIB equivalent widths and the column densities of various atomic and molecular species, drawn from a large database constructed for that purpose. The tightness and slopes of the correlations can provide information on how the DIBs might be related to those species (physically, chemically, spatially) and on various properties of the DIB carriers. Deviations from the mean relationships can reveal dependences of DIB strengths on other parameters, regional variations in…
A model of key processes influencing the evolution of a hydrocarbon grain of an arbitrary size under astrophysical conditions corresponding to ionized hydrogen regions (HII regions) and supernova remnants is presented. The considered processes include aromatization and photodestruction, sputtering by electrons and ions, and shattering due to collisions between grains. The model can be used to simulate the grain size distribution and the aromatization degree during the evolution of HII regions and supernova remnants for a specified radiation field, relative velocity of gas and dust, etc. The co…
Some very large (>0.1 um) presolar grains are sampled in meteorites. We reconsider the lifetime of very large grains (VLGs) in the interstellar medium focusing on interstellar shattering caused by turbulence-induced large velocity dispersions. This path has never been noted as a dominant mechanism of destruction. We show that, if interstellar shattering is the main mechanism of destruction of VLGs, their lifetime is estimated to be $\gtrsim 10^8$ yr; in particular, very large SiC grains can survive cosmic-ray exposure time. However, most presolar SiC grains show residence times significantly s…
Quantifying the efficiency of dust destruction in the interstellar medium (ISM) due to supernovae (SNe) is crucial for the understanding of galactic dust evolution. We present 3D hydrodynamic simulations of an SN blast wave propagating through the ISM. The interaction between the forward shock of the remnant and the surrounding ISM leads to destruction of ISM dust by the shock heated gas. We consider the dust processing due to ion sputtering, accretion of atoms/molecules and grain-grain collisions. Using 2D slices from the simulation timeseries, we apply post-processing calculations using the …
The low density interstellar medium (ISM) close to the Sun and inside of the heliosphere provides a unique laboratory for studying interstellar dust grains. Grain characteristics in the nearby ISM are obtained from observations of interstellar gas and dust inside of the heliosphere and the interstellar gas towards nearby stars. Comparison between the gas composition and solar abundances suggests that grains are dominated by olivines and possibly some form of iron oxide. Measurements of the interstellar Ne/O ratio by the Interstellar Boundary Explorer spacecraft indicate that a high fraction of…
We study the extinction properties of the composite dust grains, consisting of host silicate spheroids and graphite as inclusions, using discrete dipole approximation (DDA). We calculate the extinction cross sections of the composite grains in the ultraviolet spectral region, 1200Å-3200Åand study the variation in extinction as a function of the volume fraction of the inclusions. We compare the model extinction curves with the observed interstellar extinction curves obtained from the data given by the International Ultraviolet Explorer (IUE) satellite. Our results for the composite grains show …
Cosmic-ray (CR) induced heating of whole interstellar grains is an important desorption mechanism for grain surface molecules in interstellar molecular clouds. This study aims to provide a detailed temperature spectra for such CR-induced heating. For this, olivine grains with radius of 0.05, 0.1 and 0.2 microns shielded by interstellar gas with isotropic column densities characteristic to dark cores were considered. The accumulation of an ice mantle of increasing thickness was taken into account. The CR energy spectra was obtained for these column densities for 32 cosmic-ray constituents. We c…
The composition of silicate dust in the diffuse interstellar medium and in protoplanetary disks around young stars informs our understanding of the processing and evolution of the dust grains leading up to planet formation. Analysis of the well-known 9.7μm feature indicates that small amorphous silicate grains represent a significant fraction of interstellar dust and are also major components of protoplanetary disks. However, this feature is typically modelled assuming amorphous silicate dust of olivine and pyroxene stoichiometries. Here, we analyze interstellar dust with models of silicate du…
The degree to which interstellar grains align with respect to the interstellar magnetic field depends on disaligning as well as aligning mechanisms. For decades, it was assumed that disalignment was due primarily to the random angular impulses a grain receives when colliding with gas-phase atoms. Recently, a new disalignment mechanism has been considered, which may be very potent for a grain that has a time-varying electric dipole moment and drifts across the magnetic field. We provide quantitative estimates of the disalignment times for silicate grains with size > approximately 0.1 micron. Th…
Clustering and dynamics of nano-sized particles (nano dust) is investigated using high-resolution ($1024^3$) simulations of compressible isothermal hydrodynamic turbulence, intended to mimic the conditions inside cold molecular clouds in the interstellar medium. Nano-sized grains may cluster in a turbulent flow (small-scale clustering), which increases the local grain density significantly. Together with the increased interaction rate due to turbulent motions, aggregation of interstellar nano-dust may be plausible.
Recent space missions have provided information on the physical and chemical properties of interstellar grains such as the ratio $β$ of radiation pressure to gravity acting on the grains in addition to the composition, structure, and size distribution of the grains. Numerical simulation on the trajectories of interstellar grains captured by Stardust and returned to Earth constrained the $β$ ratio for the Stardust samples of interstellar origin. However, recent accurate calculations of radiation pressure cross sections for model dust grains have given conflicting stories in the $β$ ratio of int…
A quantitative interpretation of the observed relation between the interstellar linear polarization curve parameters $K$ and $λ_{\max}$ characterizing the width and the wavelength of a polarization maximum, respectively, is given. The observational data available for 57 stars located in the dark clouds in Taurus, Chamaeleon, around the stars $ρ$ Oph and R CrA are considered. The spheroidal particle model of interstellar dust grains earlier applied to simultaneously interpret the interstellar extinction and polarization curves in a wide spectral range is utilized. The observed trend $K \approx …
A recently discovered filament of polarized starlight that traces a coherent magnetic field is shown to have several properties that are consistent with an origin in the outer heliosheath of the heliosphere: (1) The magnetic field that provides the best fit to the polarization position angles is directed within 6.7+-11 degrees of the observed upwind direction of the flow of interstellar neutral helium gas through the heliosphere. (2) The magnetic field is ordered; the component of the variation of the polarization position angles that can be attributed to magnetic turbulence is small. (3) The …
Interstellar dust is a significant component of matter in the galaxies. The dust owns its origin and reprocessing in a wide range of astrophysical environments. In order to understand the origin and evolution of the distinct types of interstellar dust grains, we have attempted a comprehensive correlated study of the thermodynamics condensation of dust grains in distinct stellar environments with the Galactic chemical evolution of the Milky Way Galaxy. The Galaxy is evolved in terms of elemental evolution resulting from stellar nucleosynthetic contributions of several generations of stars. Base…
Interstellar dust spans a wide range in size distribution, ranging from ultrasmall grains of a few Angstroms to micrometer-size grains. While the presence of nanometer-size dust grains in the Galactic interstellar medium was speculated six decades ago and was previously suggested based on early infrared observations, systematic and direct analysis of their properties over a wide range of environments has been lacking. Here we report the detection of nanometer-size dust grains that appear to be universally present in a wide variety of astronomical environments, from Galactic high-latitude cloud…
We compiled the polarimetric data for a sample of lines of sight with known abundances of Mg, Si, and Fe. We correlated the degree of interstellar polarization $P$ and polarization efficiency (the ratio of $P$ to the colour excess $E(B-V)$ or extinction $A_V$) with dust phase abundances. We detect an anticorrelation between $P$ and the dust phase abundance of iron in non silicate - containing grains $< [\rm Fe(rest)/H > ]_\rm d$, a correlation between $P$ and the abundance of Si, and no correlation between $P/E(B-V)$ or $P/A_V$ and dust phase abundances. These findings can be explained if main…
The properties of interstellar grains, such as grain size distribution and grain porosity, are affected by interstellar processing, in particular, coagulation and shattering, which take place in the dense and diffuse interstellar medium (ISM), respectively. In this paper, we formulate and calculate the evolution of grain size distribution and grain porosity through shattering and coagulation. For coagulation, we treat the grain evolution depending on the collision energy. Shattering is treated as a mechanism of forming small compact fragments. The balance between these processes are determined…
Collisions of gas particles with a drifting grain give rise to a mechanical torque on the grain. Recent work by Lazarian & Hoang showed that mechanical torques might play a significant role in aligning helical grains along the interstellar magnetic field direction, even in the case of subsonic drift. We compute the mechanical torques on 13 different irregular grains and examine their resulting rotational dynamics, assuming steady rotation about the principal axis of greatest moment of inertia. We find that the alignment efficiency in the subsonic drift regime depends sensitively on the grain s…
We examine a synthetic way of constructing the grain size distribution in the interstellar medium (ISM). First we formulate a synthetic grain size distribution composed of three grain size distributions processed with the following mechanisms that govern the grain size distribution in the Milky Way: (i) grain growth by accretion and coagulation in dense clouds, (ii) supernova shock destruction by sputtering in diffuse ISM, and (iii) shattering driven by turbulence in diffuse ISM. Then, we examine if the observational grain size distribution in the Milky Way (called MRN) is successfully synthes…
The methodology for modeling grain-surface chemistry has been greatly improved by taking into account the grain size and fluctuation effects. However, the reaction rate coefficients currently used in all practical models of gas-grain chemistry are inaccurate by a significant amount. We provide expressions for these crucial rate coefficients that are both accurate and easy to incorporate into gas-grain models. We use exact results obtained in earlier work, where the reaction rate coefficient was defined by a first-passage problem, which was solved using random walk theory. The approximate react…
Icy grains in the interstellar medium and star-formation regions consist of a variety of materials. Such composite grains interact differently with cosmic-ray (CR) particles compared to simple single-material grains. We aim to calculate the spectra of energies and temperatures of mixed-composition grains undergoing whole-grain heating by CRs. The grains were assumed to consist of a mixture of carbon and olivine, covered by ices consisting of carbon oxides and water. The energy and temperature spectra for grains with radii 0.05; 0.1, and 0.2 microns impacted by CRs were calculated for eight val…
Interstellar space hosts nanometre- to micron-sized dust grains. The carbonaceous-rich component of these grain populations emits in infrared bands, observed remotely for decades with telescopes and satellites. They are a key ingredient of astrochemical dust evolution. The precise carriers for most of these bands are still unknown and not well reproduced in the laboratory. In this work, we show the high-energy mechanochemical synthesis of disordered aromatic and aliphatic analogues provides interstellar relevant dust particles. The mechanochemical milling of carbon-based solids under a hydroge…
Interstellar abundance determinations from fits to X-ray absorption edges often rely on the incorrect assumption that scattering is insignificant and can be ignored. We show instead that scattering contributes significantly to the attenuation of X-rays for realistic dust grain size distributions and substantially modifies the spectrum near absorption edges of elements present in grains. The dust attenuation modules used in major X-ray spectral fitting programs do not take this into account. We show that the consequences of neglecting scattering on the determination of interstellar elemental ab…
We extend and investigate the spheroidal model of interstellar dust grains used to simultaneously interpret the observed interstellar extinction and polarization curves. We compare our model with similar models recently suggested by other authors, study its properties and apply it to fit the normalized extinction $A(λ)/A_{\rm V}$ and the polarizing efficiency $P(λ)/A(λ)$ measured in the near IR to far UV region for several stars seen through one large cloud. We conclude that the model parameter $Ω$ being the angle between the line of sight and the magnetic field direction can be more or less r…
Molecular hydrogen is the most abundant molecule in the universe. It is the first one to form and survive photo-dissociation in tenuous environments. Its formation involves catalytic reactions on the surface of interstellar grains. The micro-physics of the formation process has been investigated intensively in the last 20 years, in parallel of new astrophysical observational and modeling progresses. In the perspectives of the probable revolution brought by the future satellite JWST, this article has been written to present what we think we know about the H$_2$ formation in a variety of interst…
Theoretical studies have revealed that dust grains are usually moving fast through the turbulent interstellar gas, which could have significant effects upon interstellar chemistry by modifying grain accretion. This effect is investigated in this work on the basis of numerical gas-grain chemical modeling. Major features of the grain motion effect in the typical environment of dark clouds (DC) can be summarised as follows: 1) decrease of gas-phase (both neutral and ionic) abundances and increase of surface abundances by up to 2-3 orders of magnitude; 2) shifts of the existing chemical jumps to e…
Context. Hydrogenated amorphous carbons, a-C:H, can incorporate a variety of heteroatoms, which can lead to interesting effects. Aims. To investigate the doping of interstellar a-C:H grains with, principally, Si, O, N and S atoms within the astrophysical context. Methods. A search of the literature on doped a-C:H reveals a number of interesting phenomena of relevance to astrophysics. Results. X dopants in a-C:H:X materials can affect the sp3/sp2 ratio (X = Si, O and N), lead to blue photoluminescence (undoped or X = N), induce ferromagnetic-like behaviour (X = N and S) or simply be incorporate…
We present theoretical calculations of the X-ray scattering properties of porous grain aggregates with olivine monomers. The small and large angle scattering properties of these aggregates are governed by the global structure and substructure of the grain, respectively. We construct two diagnostics, R_X and T_X, based on the optical and X-ray properties of the aggregates, and apply them to a Chandra measurement of the dust halo around the Galactic binary GX13+1. Grain aggregates with porosities higher than about 0.55 are ruled out. Future high-precision observations of X-ray dust haloes togeth…
The distribution of interstellar dust grains (ISDG) observed in the Solar System depends on the nature of the interstellar medium-solar wind interaction. The charge of the grains couples them to the interstellar magnetic field (ISMF) resulting in some fraction of grains being excluded from the heliosphere while grains on the larger end of the size distribution, with gyroradii comparable to the size of the heliosphere, penetrate the termination shock. This results in a skewing the size distribution detected in the Solar System. We present new calculations of grain trajectories and the resultant…
Computational models of interstellar gas-grain chemistry have historically adopted a single dust-grain size of 0.1 micron, assumed to be representative of the size distribution present in the interstellar medium. Here, we investigate the effects of a broad grain-size distribution on the chemistry on dust-grain surfaces and the subsequent build-up of molecular ices on the grains, using a three-phase gas-grain chemical model of a quiescent dark cloud. We include an explicit treatment of the grain temperatures, governed both by the visual extinction of the cloud and the size of each individual gr…
We present a new method for using the observed starlight polarization and polarized submm emission to constrain the shapes and porosities of interstellar grains. We present the modified picket fence approximation (MPFA), and verify that it is sufficiently accurate for modeling starlight polarization. We introduce the starlight polarization integral $Π_{\rm obs}$ as a measure of overall strength of the observed polarization of starlight, and the starlight polarization efficiency integral $Φ$ to characterize the effectiveness of different grain types for producing polarization of starlight. The …
Interstellar ices are layers of molecules deposited on !ne dust grains in dark and dense molecular cloud cores. Subsurface ice has been considered in a few astrochemical models, which have shown that it can be of great importance. The aim of this work is to introduce an established subsurface ice description into the state-of-the-art astrochemical model ALCHEMIC. The model has been developed by the Heidelberg astrochemistry group. The result is an up-to-date model for interstellar molecular cloud research with possible application for protoplanetary disks.
Interstellar polarization in the optical/infrared has long been known to be due to asymmetrical dust grains aligned with the magnetic field and can potentially provide a resource effective way to probe both the topology and strength of the magnetic field. However, to do so with confidence, the physics and variability of the alignment mechanisms must be quantitatively understood. The last 15 years has seen major advancements in both the theoretical and observational understanding of this problem. I here review the current state of the observational constraints on the grain alignment physics. Wh…
The form of depleted sulphur in dense clouds is still unknown. Until now, only two molecules, OCS and SO2, have been detected in interstellar ices but cannot account for the elemental abundance of sulphur observed in diffuse medium. Chemical models suggest that solid H2S is the main form of sulphur in denser sources but observational constraints exist that infirm this hypothesis. We have used the Nautilus gas-grain code in which new chemical reactions have been added, based on recent experiments of H2S ice irradiation with UV photons and high energy protons. In particular, we included the new …
Interstellar dust grains are non-spherical and, in some environments, partially aligned along the direction of the interstellar magnetic field. Numerous alignment theories have been proposed, all of which examine the grain rotational dynamics. In 1999, Lazarian & Draine introduced the important concept of thermal flipping, in which internal relaxation processes induce the grain body to flip while its angular momentum remains fixed. Through detailed numerical simulations, we study the role of thermal flipping on the grain dynamics during periods of relatively slow rotation, known as `crossovers…
The sizes of interstellar grains are widely distributed, ranging from a few angstroms to a few micrometers. The ultraviolet (UV) and optical extinction constrains the dust in the size range of a couple hundredth micrometers to several submicrometers. The near and mid infrared (IR) emission constrains the nanometer-sized grains and angstrom-sized very large molecules. However, the quantity and size distribution of micrometer-sized grains remain unknown as they are gray in the UV/optical extinction and they are too cold and emit too little in the IR to be detected by IRAS, Spitzer, or Herschel. …
Whether ice in cold cosmic environments is physically separated from the silicate dust or mixed with individual silicate moieties is not known. However, different grain models give very different compositions and temperatures of grains. The aim of the present study is a comparison of the mid-IR spectra of laboratory silicate-grains/water-ice mixtures with astronomical observations to evaluate the presence of dust/ice mixtures in interstellar and circumstellar environments. The laboratory data can explain the observations assuming reasonable mass-averaged temperatures for the protostellar envel…
In this paper we consider the implications of the distributions of dust and metals in the disc of M31. We derive mean radial dust distributions using a dust map created from Herschel images of M31 sampling the entire far-infrared (FIR) peak. Modified blackbodies are fit to approximately 4000 pixels with a varying, as well as a fixed, dust emissivity index (beta). An overall metal distribution is also derived using data collected from the literature. We use a simple analytical model of the evolution of the dust in a galaxy with dust contributed by stellar sources and interstellar grain growth, …
Cold molecular clouds are the birthplaces of stars and planets, where dense cores of gas collapse to form protostars. The dust mixed in these clouds is thought to be made of grains of an average size of 0.1 micrometer. We report the widespread detection of the coreshine effect as a direct sign of the existence of grown, micrometer-sized dust grains. This effect is seen in half of the cores we have analyzed in our survey, spanning all Galactic longitudes, and is dominated by changes in the internal properties and local environment of the cores, implying that the coreshine effect can be used to …
In this paper, we present a new gas-grain chemical code for interstellar clouds written in pure Python (GGCHEMPY). By combining with the high-performance Python compiler Numba, GGCHEMPY is as efficient as the Fortran-based version. With the Python features, flexible computational workflows and extensions become possible. As a showcase, GGCHEMPY is applied to study the general effects of three-dimensional projection on molecular distributions using a two-core system which can be easily extended for more complex cases. By comparing the molecular distribution differences between two overlapping c…
Interstellar iron in the form of metallic iron nanoparticles may constitute a component of the interstellar dust. We compute the stability of iron nanoparticles to sublimation in the interstellar radiation field, finding that iron clusters can persist down to a radius of $\simeq 4.5\,$Å, and perhaps smaller. We employ laboratory data on small iron clusters to compute the photoelectric yields as a function of grain size and the resulting grain charge distribution in various interstellar environments, finding that iron nanoparticles can acquire negative charges particularly in regions with high …
In this work we investigate the effects of ion accretion and size-dependent dust temperatures on the abundances of both gas-phase and grain-surface species. While past work has assumed a constant areal density for icy species, we show that this assumption is invalid and the chemical differentiation over grain sizes are significant. We use a gas-grain chemical code to numerically demonstrate this in two typical interstellar conditions: dark cloud (DC) and cold neutral medium (CNM). It is shown that, although the grain size distribution variation (but with the total grain surface area unchanged)…
Grain growth by the accretion of metals in interstellar clouds (called `grain growth') could be one of the dominant processes that determine the dust content in galaxies. The importance of grain size distribution for the grain growth is demonstrated in this paper. First, we derive an analytical formula that gives the grain size distribution after the grain growth in individual clouds for any initial grain size distribution. The time-scale of the grain growth is very sensitive to grain size distribution, since the grain growth is mainly regulated by the surface to volume ratio of grains. Next, …
Grain growth by accretion of gas-phase metals is a common assumption in models of dust evolution, but in dense gas, where the timescale is short enough for accretion to be effective, material is accreted in the form of ice mantles rather than adding to the refractory grain mass. It has been suggested that negatively-charged small grains in the diffuse interstellar medium (ISM) can accrete efficiently due to the Coulomb attraction of positively-charged ions, avoiding this issue. We show that this inevitably results in the growth of the small-grain radii until they become positively charged, at …
In the interstellar medium (ISM), the formation of complex organic molecules (COMs) is largely facilitated by surface reactions. However, in cold dark clouds, thermal desorption of COMs is inefficient because of the lack of thermal energy to overcome binding energies to the grain surface. Non-thermal desorption methods are therefore important explanations for the gas-phase detection of many COMs that are primarily formed on grains. Here we present a new non-thermal desorption process: cosmic ray sputtering of grain ice surfaces based on water, carbon dioxide, and a simple mixed ice. Our model …
The study of the chemical evolution of glycine in the interstellar medium is one of challenging topics in astrochemistry. Here, we present the chemical modeling of glycine in hot cores using the state-of-the-art three-phase chemical model NAUTILUS, which is focused on the latest glycine chemistry. For the formation process of glycine on the grain surface, we obtained consistent results with previous studies that glycine would be formed via the reactions of COOH with CH$_2$NH$_2$. However, we will report three important findings regarding the chemical evolution and the detectability of interste…
The solar wind carves a bubble in the surrounding interstellar medium (ISM), known as the heliosphere. Charged interstellar dust grains (ISDG) encountering the heliosphere may be diverted around the heliopause or penetrate it depending on their charge-to-mass ratio. We present new calculations of trajectories of ISDG in the heliosphere, and the dust density distributions that result. We include up-to-date grain charging calculations using a realistic UV radiation field and full 3-D magnetohydrodynamic fluid + kinetic models for the heliosphere. Models with two different (constant) polarities f…
We present a novel method to measure the strength of interstellar magnetic fields based on ultraviolet (UV) polarization of starlight, which is in part produced by weakly aligned, small interstellar grains. We begin with calculating degrees of alignment of small (size $a\sim 0.01μ$m) and very small ($a\sim 0.001μ$m) grains in the interstellar magnetic field due to the Davis-Greenstein paramagnetic relaxation and resonance paramagnetic relaxation. We compute the degrees of paramagnetic alignment with the ambient magnetic field $B$ using Langevin equations. In this paper, we take into account va…
Context. Evaporative (sublimation) cooling of icy interstellar grains occurs when the grains have been suddenly heated by a cosmic-ray (CR) particle or other process. It results in thermal desorption of icy species, affecting the chemical composition of interstellar clouds. Aims. We investigate details on sublimation cooling, obtaining necessary knowledge before this process is considered in astrochemical models. Methods. We employed a numerical code that describes the sublimation of molecules from an icy grain, layer by layer, also considering a limited diffusion of bulk-ice molecules toward …
We investigate the composition of interstellar grains along the line of sight toward Zeta Ophiuchi, a well-studied environment near the diffuse-dense cloud transition. A spectral decomposition analysis of the solid-state absorbers is performed using archival spectroscopic observations from the Spitzer Space Telescope and Infrared Space Observatory. We find strong evidence for the presence of sub-micron-sized amorphous silicate grains, principally comprised of olivine-like composition, with no convincing evidence of H2O ice mantles. However, tentative evidence for thick H2O ice mantles on large…
Recent photometric and polarimetric observations of type Ia supernovae (SNe Ia) show unusually low total-to-selective extinction ratio ($R_{V}<2$) and wavelength of maximum polarization ($λ_{max}<0.4μm$) for several SNe Ia, which indicates peculiar properties of interstellar (IS) dust in the SN hosted galaxies and/or the presence of circumstellar (CS) dust. In this paper, we use inversion technique to infer best-fit grain size distribution and alignment function of interstellar grains along the lines of sight toward four SNe Ia with anomalous extinction and polarization data (SNe 1986G, 2006X,…
Interstellar grain alignment studies are currently experiencing a renaissance due to the development of a new quantitative theory based on Radiative Alignment Torques (RAT). One of the distinguishing predictions of this theory is a dependence of the grain alignment efficiency on the relative angle ($Ψ$) between the magnetic field and the anisotropy direction of the radiation field. In an earlier study we found observational evidence for such an effect from observations of the polarization around the star HD 97300 in the Chamaeleon I cloud. However, due to the large uncertainties in the measure…
Within the framework of The Heterogeneous dust Evolution Model at the IaS (THEMIS) this work investigates in detail the surface processes and chemistry relating to core/mantle interstellar and cometary grain structures and its influence on the nature of these fascinating particles. It appears that a realistic consideration of the nature and chemical reactivity of interstellar grain surfaces could self-consistently and within a coherent framework explain: the anomalous oxygen depletion, the nature of the CO dark gas, the formation of 'polar ice' mantles, the red wing on the 3 um water ice band,…
The first off-lattice Monte Carlo kinetics model of interstellar dust-grain surface chemistry is presented. The positions of all surface particles are determined explicitly, according to the local potential minima resulting from the pair-wise interactions of contiguous atoms and molecules, rather than by a pre-defined lattice structure. The model is capable of simulating chemical kinetics on any arbitrary dust-grain morphology, as determined by the user-defined positions of each individual dust-grain atom. A simple method is devised for the determination of the most likely diffusion pathways a…
For the first time, we report a unified microscopic-macroscopic Monte Carlo simulation of gas-grain chemistry in cold interstellar clouds in which both the gas-phase and the grain surface chemistry are simulated by a stochastic technique. The surface chemistry is simulated with a microscopic Monte Carlo method in which the chemistry occurs on an initially flat surface. The surface chemical network consists of 29 reactions initiated by the accreting species H, O, C, and CO. Four different models are run with diverse but homogeneous physical conditions including temperature, gas density, and dif…
Observations of gaseous complex organic molecules (COMs) in cold starless and prestellar cloud cores require efficient desorption of the COMs and their parent species from icy mantles on interstellar grains. With a simple astrochemical model, we investigate if mechanical removal of ice fragments in oblique collisions between grains in two size bins (0.01 and 0.1 micron) can substantially affect COM abundances. Two grain collision velocities were considered - 10 and 50 meters per second, corresponding to realistic grain relative speeds arising from ambipolar diffusion and turbulence, respective…
