It is shown that in adiabatic approximation for nuclei the many-component Coulomb system cannot be described on the basis of the grand canonical ensemble. Using the variational Bogolyubov's procedure for the free energy, the Hohenberg-Kohn theorem is proved in the canonical ensemble for inhomogeneous electron gas at finite temperature. The principal difference between consideration in the framework of quantum statistics in the canonical ensemble and quantum-mechanical consideration of a finite number of particles in infinite volume is established. The problem of universality of the density functional for describing the inhomogeneous electron density in a disordered nuclei field is considered.
We extend a recently introduced free-energy formalism for homogeneous Fokker-Planck equations to a wide, and physically appealing, class of inhomogeneous nonlinear Fokker-Planck equations. In our approach, the free-energy functional is expressed in terms of an entropic functional and an auxiliary potential, both derived from the coefficients of the equation. With reference to the introduced entropic functional, we discuss the entropy production in a relaxation process towards equilibrium. The properties of the stationary solutions of the considered Fokker-Planck equations are also discussed.
We present a derivation of the kinetic equation describing the secular evolution of spatially inhomogeneous systems with long-range interactions, the so-called inhomogeneous Landau equation, by relying on a functional integral formalism. We start from the BBGKY hierarchy derived from the Liouville equation. At the order ${1/N}$, where $N$ is the number of particles, the evolution of the system is characterised by its 1-body distribution function and its 2-body correlation function. Introducing associated auxiliary fields, the evolution of these quantities may be rewritten as a traditional func…
The inhomogeneous cooling state describing the hydrodynamic behavior of a freely evolving granular gas strongly confined between two parallel plates is studied, using a Boltzmann kinetic equation derived recently. By extending the idea of the homogeneous cooling state, we propose a scaling distribution in which all the time dependence occurs through the granular temperature of the system, while there is a dependence on the distance to the confining walls through the density. It is obtained that the velocity distribution is not isotropic, and it has two different granular temperature parameters…
A unified formulation of the density functional theory is constructed on the foundations of entropic inference in both the classical and the quantum regimes. The theory is introduced as an application of entropic inference for inhomogeneous fluids in thermal equilibrium. It is shown that entropic inference reproduces the variational principle of DFT when information about expected density of particles is imposed. In the classical regime, this process introduces a family of trial density-parametrized probability distributions, and consequently a trial entropy, from which the preferred one is fo…
We investigate some aspects of the Bose-Einstein condensation (BEC) of quantum gases in the presence of inhomogeneous conditions. We consider three-dimensional (3D) quantum gases trapped by an external potential when the temperature is sufficiently low to show a BEC phase region around the center of the trap. If the trap is sufficiently large, different phases may coexist in different space regions, when moving from the center of the trap. We show that the quantum gas develops a peculiar critical behavior at the boundary of the BEC region, whose scaling behavior is controlled by the universali…
Conformal field theory (CFT) has been extremely successful in describing large-scale universal effects in one-dimensional (1D) systems at quantum critical points. Unfortunately, its applicability in condensed matter physics has been limited to situations in which the bulk is uniform because CFT describes low-energy excitations around some energy scale, taken to be constant throughout the system. However, in many experimental contexts, such as quantum gases in trapping potentials and in several out-of-equilibrium situations, systems are strongly inhomogeneous. We show here that the powerful CFT…
Using the adiabatic connection, we formulate the free energy in terms of the correlation function of a fictitious system, $h_λ({\bf r},{\bf r}')$, where $λ$ determines the interaction strength. To obtain $h_λ({\bf r},{\bf r}')$ we use the Ornstein-Zernike equation, and the two equations constitute a general liquid-state framework for treating inhomogeneous fluids. As the two equations do not form a closed set, an approximate closure relation is required and it determines a type of an approximation. In the present work we investigate the random phase approximation (RPA) closure. We determine th…
Density Functional Theory of Inhomogeneous Liquids IV. Squared-gradient approximation and Classical Nucleation Theory
发展了修正核Van der Waals密度泛函理论模型的平方梯度近似。一个简单的，明确的SGA系数的表达式只涉及体状态方程和相互作用势。该模型解决了平面界面和球形集群，并被证明是定量准确的计算机模拟比较。介绍了一种基于分段线性密度分布求解SGA的近似技术，并给出了合理的零阶近似模型的数值解。球形团簇的分段线性模型被证明是经典成核理论的自然延伸，并用于澄清以前在液-汽成核中观察到的一些非经典效应。成核途径进行了研究，使用约束能量最小化和最速下降技术。
Motivated by the calculation of correlation functions in inhomogeneous one-dimensional (1d) quantum systems, the 2d Inhomogeneous Gaussian Free Field (IGFF) is studied and solved. The IGFF is defined in a domain $Ω\subset \mathbb{R}^2$ equipped with a conformal class of metrics $[{\rm g}]$ and with a real positive coupling constant $K: Ω\rightarrow \mathbb{R}_{>0}$ by the action $\mathcal{S}[h] = \frac{1}{8π} \int_Ω\frac{\sqrt{\rm g} d^2 {\rm x}}{K({\rm x})} \, {\rm g}^{i j} (\partial_i h)(\partial_j h)$. All correlations functions of the IGFF are expressible in terms of the Green's functions …
When a fluid is subject to an external field, as is the case near an interface or under spatial confinement, then the density becomes spatially inhomogeneous. Although the one-body density provides much useful information, a higher level of resolution is provided by the two-body correlations. These give a statistical description of the internal microstructure of the fluid and enable calculation of the average interparticle force, which plays an essential role in determining both the equilibrium and dynamic properties of interacting fluids. We present a theoretical framework for the description…
Density Functional Theory relies on universal functionals characteristic of a given system. Those functionals in general are different for the electron gas and for jellium (electron gas with uniform background). However, jellium is frequently used to construct approximate functionals for the electron gas (e.g., local density approximation, gradient expansions). The precise relationship of the exact functionals for the two systems is addressed here. In particular, it is shown that the exchange - correlation functionals for the inhomogeneous electron gas and inhomogeneous jellium are the same. T…
Conformal field theories in curved backgrounds have been used to describe inhomogeneous one-dimensional systems, such as quantum gases in trapping potentials and non-equilibrium spin chains. This approach provided, in a elegant and simple fashion, non-trivial analytic predictions for quantities, such as the entanglement entropy, that are not accessible through other methods. Here, we generalise this approach to low-lying excited states, focusing on the entanglement and relative entropies in an inhomogeneous free-fermionic system. Our most important finding is that the universal scaling functio…
