In the presence of a neighboring atom, electron-ion recombination can proceed resonantly via excitation of an electron in the atom, with subsequent relaxation through radiative decay. It is shown that this two-center dielectronic process can largely dominate over single-center radiative recombination at internuclear distances as large as several nanometers. The relevance of the predicted process is demonstrated by using examples of water-dissolved alkali cations and warm dense matter.
Calculation of the differential cross section for the dielectronic recombination with two-electron uranium within the framework of QED is presented. The polarization of the emitted photon is investigated. The contributions of the Breit interaction and the interference of the photon multipoles are studied.
The recombination of an electron with an (initially) hydrogen-like ion is investigated. The effect of the electron-electron interaction is treated rigorously to the first order in the parameter 1/Z and within the screening-potential approximation to higher orders in 1/Z, with Z being the nuclear charge number. The two-electron correction contains the dielectronic-recombination part, which contributes to the process not only under the resonance condition for the projectile energy but also in the regions far from resonances. The mechanism of the off-resonant dielectronic recombination is studied…
Electron scattering and dielectronic recombination with an ion in the presence of a neighboring atom is studied. The incident electron is assumed to be captured by the ion, leading to resonant excitation of the atom which afterwards may stabilize either by electron re-emission or radiative decay. We show that the participation of the atom can strongly affect, both quantitatively and qualitatively, the corresponding processes of electron scattering and recombination. Various ion-atom systems and electronic transitions are considered. In particular we show that electron scattering under backward…
Dielectronic recombination (DR) of Na-like Fe$^{15+}$ forming Mg-like Fe$^{14+}$ via excitation of a $2l$ core electron has been investigated. We find that configuration interaction (CI) between DR resonances with different captured electron principal quantum numbers $n$ can lead to a significant reduction in resonance strengths for $n \geq 5$. Previous theoretical work for this system has not considered this form of CI. Including it accounts for most of the discrepancy between previous theoretical and experimental results.
We report a measurement of $KLL$ dielectronic recombination in charge states from Kr$^{+34}$ through Kr$^{+28}$, in order to investigate the contribution of Breit interaction for a wide range of resonant states. Highly charged Kr ions were produced in an electron beam ion trap, while the electron-ion collision energy was scanned over a range of dielectronic recombination resonances. The subsequent $Kα$ x rays were recorded both along and perpendicular to the electron beam axis, which allowed the observation of the influence of Breit interaction on the angular distribution of the x rays. Experi…
We aim to present a comprehensive theoretical investigation of dielectronic recombination (DR) of the silicon-like isoelectronic sequence and provide DR and radiative recombination (RR) data that can be used within a generalized collisional-radiative modelling framework. Total and final-state level-resolved DR and RR rate coefficients for the ground and metastable initial levels of 16 ions between $\rm{P^{+}}$ and $\rm{Zn^{16+}}$ are determined. We carried out multi-configurational Breit-Pauli (MCBP) DR calculations for silicon-like ions in the independent processes, isolated resonance, distor…
The recombination of a free electron into a bound state of bare, heavy nucleus under simultaneous production of bound-electron--free-positron pair is studied within the framework of relativistic first--order perturbation theory. This process, denoted as "negative-continuum dielectronic recombination" leads to a formation of not only the ground but also the singly- and doubly-excited states of the residual helium-like ion. The contributions from such an excited--state capture to the total as well as angle-differential cross-sections are studied in detail. Calculations are performed for the reco…
We present improved fits to our treatment of suppression of dielectronic recombination at intermediate densities. At low densities, most recombined excited states eventually decay to the ground state, and therefore the total dielectronic recombination rate to all levels is preserved. At intermediate densities, on the other hand, collisions can lead to ionization of higher-lying excited states, thereby suppressing the dielectronic recombination rate. The improved suppression factors presented here, although highly approximate, allow summed recombination rate coefficients to be used to intermedi…
We discuss a parity nonconserving (PNC) asymmetry in the cross section of dielectronic recombination of polarized electrons on multiply charged ions with Z>40. This effect is strongly enhanced for close doubly-excited states of opposite parity in the intermediate compound ion. Such states are known for He-like ions. However, these levels have large energy and large radiative widths which hampers observation of the PNC asymmetry. We argue that accidentally degenerate states of the more complex ions may be more suitable for the corresponding experiment.
A free electron can form a bound state with an atomic center $A$ upon photo emission (radiative recombination). In the presence of a neighboring atom $B$, such a bound state can, under certain conditions, be also formed via resonant transfer of energy to $B$, with its subsequent relaxation through radiative decay (two-center dielectronic recombination). This two-center process is very efficient in the 'static' case where $A$ and $B$ form a weakly bound system, dominating over single-center radiative recombination up to internuclear distances as large as several nanometers. Here we study its dy…
We investigate the parity nonconservation (PNC) effect in the dielectronic recombination (DR) of a polarized electron with a heavy He-like ion into doubly-excited $((1s 2p_{1/2})_{0} nκ)_{1/2}$ and $\left(\left(1s 2s\right)_{0} nκ\right)_{1/2}$ states of Li-like ion. We determine the nuclear charge number $Z$ for which these opposite-parity levels are near to cross and, therefore, the PNC effect will be significantly enhanced. Calculations are performed for quantum numbers $n \geq 4$ and $κ= \pm 1$.
In this work we introduce a new expression of the plasma Dielecronic Recombination (DR) rate as a function of the temperature, derived assuming a small deformation of the Maxwell-Boltzmann distribution and containing corrective factors, in addition to the usual exponential behaviour, caused by non-linear effects in slightly non ideal plasmas. We then compare the calculated DR rates with the experimental DR fits in the low temperature region.
The process of recombination of a quasi-free electron into a bound state of an initially bare nucleus with the simultaneous creation of a bound-electron--free-positron pair is investigated. This process is called the negative-continuum assisted dielectronic recombination (NCDR). In a typical experimental setup, the initial electron is not free but bound in a light atomic target. In the present work, we study the effects of the atomic target on the single and double-differential cross sections of the positron production in the NCDR process. The calculations are performed within the relativistic…
Tungsten is an important metal in nuclear fusion reactors. It will be used in the divertor component of ITER (Latin for 'the way'). The Tungsten Project aims to calculate partial and total DR rate coefficients for the isonuclear sequence of Tungsten. The calculated data will be made available as and when they are produced via the open access database OPEN- ADAS in the standard adf09 and adf48 file formats. We present our progress thus far, detailing calculational methods, and showing comparisons with other available data. We conclude with plans for the future.
A recent measurement of the dielectronic recombination (DR) of W^20+ [Schippers et al Phys. Rev. A83, 012711 (2011)] found an exceptionally large contribution from near threshold resonances (<1eV). This still affected the Maxwellian rate coefficient at much higher temperatures. The experimental result was found to be a factor 4 or more than that currently in use in the 100-300eV range which is of relevance for modeling magnetic fusion plasmas. We have carried-out DR calculations with AUTOSTRUCTURE which include all significant single electron promotions. Our intermediate coupling (IC) results …
Isotope shifts in dielectronic recombination spectra were studied for Li-like ^{A}Nd^{57+} ions with A=142 and A=150. From the displacement of resonance positions energy shifts δE^{142,150}(2s-2p_1/2)= 40.2(3)(6) meV (stat)(sys)) and δE^{142,150}(2s-2p_3/2) = 42.3(12)(20) meV of 2s-2p_j transitions were deduced. An evaluation of these values within a full QED treatment yields a change in the mean-square charge radius of ^{142,150}δ<r^2> = -1.36(1)(3) fm^2. The approach is conceptually new and combines the advantage of a simple atomic structure with high sensitivity to nuclear size.
A general expression for the differential cross section of dielectronic recombination (DR) of polarized electrons and polarized ions is derived by using usual atomic theory methods and is represented in the form of multiple expansions over spherical tensors. The ways of the application of the general expressions suitable for the specific experimental conditions are outlined by deriving asymmetry parameters of angular distribution of DR radiation in the case of nonpolarized and polarized ions and electrons.
The current paper presents atomic data generated to investigate the recombination lines of C II in the spectra of planetary nebulae. These data include energies of bound and autoionizing states, oscillator strengths and radiative transition probabilities, autoionization probabilities, and recombination coefficients. The R-matrix method of electron scattering theory was used to describe the C2+ plus electron system.
Dielectronic recombination has been investigated for Delta-n = 1 resonances of ground-state Li+(1s^2) and for Delta-n = 0 resonances of metastable Li+(1s2s ^3S). The ground-state spectrum shows three prominent transitions between 53 and 64 eV, while the metastable spectrum exhibits many transitions with energies < 3.2 eV. Reasonably good agreement of R-matrix, LS coupling calculations with the measured recombination rate coefficient is obtained. The time dependence of the recombination rate yields a radiative lifetime of 52.2 +- 5.0 s for the 2 ^3S level of Li+.
The accuracy of dielectronic recombination (DR) data for astrophysics related ions plays a key role in astrophysical plasma modeling. The measurement of the absolute DR rate coefficient of Fe17+ ions was performed at the main cooler storage ring at Institute of Modern Physics, Lanzhou, China. The experimental electron-ion collision energy range covers first Rydberg series up to n = 24 for the DR resonances associated with the 2P1/2--2P3/2 dn = 0 core excitations. A theoretical calculation was performed by using FAC code and compared with the measured DR rate coefficient. Overall reasonable agr…
Tungsten is an important element for magnetically confined fusion plasmas but has the potential to cool, or even quench the plasma due to it being an efficient radiator. Total and level-resolved dielectronic recombination (DR) rate coefficients, for all ionization stages, are essential to model tungsten. We describe a set calculations performed using the distorted wave code AUTOSTRUCTURE for the tungsten ions W$^{37+}$ to W$^{28+}$. We demonstrate the importance of relativistic configuration mixing in such calculations. In particular, we show that the partial DR rate coefficients calculated in…
The photorecombination spectrum of 48Ti18+ was measured employing the merged electron-ion beams technique at a heavy-ion storage ring. The experimental electron-ion collision energy range 0-80 eV comprises all dielectronic recombination (DR) resonances associated with 2s->2p (Delta N =0) core excitations as well as trielectronic recombination (TR) resonances that involve 2s2->2p2 core double-excitations. At low collision energies DR resonances are observed that are associated with the excitation of metastable 2s2p 3P0 primary ions with nearly infinite lifetime for the isotope 48Ti with zero nu…
Dielectronic recombination (DR) of xenonlike W20+ forming W19+ has been studied experimentally at a heavy-ion storage-ring. A merged-beams method has been employed for obtaining absolute rate coefficients for electron-ion recombination in the collision energy range 0-140 eV. The measured rate coefficient is dominated by strong DR resonances even at the lowest experimental energies. At plasma temperatures where the fractional abundance of W20+ is expected to peak in a fusion plasma, the experimentally derived plasma recombination rate coefficient is over a factor of 4 larger than the theoretica…
We performed an extensive study of configuration mixing between the doubly excited (doorway) states and complex multiply excited states of U$^{28+}$ near its ionization threshold. The detailed investigation of complex spectrum and analysis of the statistics of eigenstate components show that the dielectronic (doorway) states weakly mixed with each other. However, they show substantial mixing with the complex multiply excited states. This situation explains the mechanism of low energy electron recombination with U$^{28+}$. We calculated the energy averaged capture cross sections as a sum over d…
Highly excited eigenstates of atoms and ions with open f shell are chaotic superpositions of thousands, or even millions of Hartree-Fock determinant states. The interaction between dielectronic and multielectronic configurations leads to the broadening of dielectronic recombination resonances and relative enhancement of photon emission due to opening of thousands of radiative decay channels. The radiative yield is close to 100% for electron energy . 1 eV and rapidly decreases for higher energies due to opening of many autoionization channels. The same mechanism predicts suppression of photoion…
We apply relativistic configuration-interaction method coupled with many-body perturbation theory (CI+MBPT) to describe low-energy dielectronic recombination. We combine the CI+MBPT approach with the complex rotation method (CRM) and compute the dielectronic recombination spectrum for Li-like carbon recombining into Be-like carbon. We demonstrate the utility and evaluate the accuracy of this newly-developed CI+MBPT+CRM approach by comparing our results with the results of the previous high-precision study of the CIII system [Mannervik et al., Phys. Rev. Lett. 81, 313 (1998)].
Theoretical and experimental resonance strengths for KLL dielectronic recombination (DR) into He-, Li-, Be-, and B-like mercury ions are presented, based on state-resolved DR x-ray spectra recorded at the Heidelberg electron beam ion trap. The DR resonance strengths were experimentally extracted by normalizing them to simultaneously recorded radiative recombination signals. The results are compared to state-of-the-art atomic calculations that include relativistic electron-electron correlation and configuration mixing effects. Combining the present data with other existing ones, we derive an im…
Dielectronic recombination (DR) is a key atomic process which affects the spectroscopic diagnostic modelling of tungsten, most of whose ionization stages will be found somewhere in the ITER fusion reactor: in the edge, divertor, or core plasma. Accurate DR data is sparse while complete DR coverage is unsophisticated (e.g. average-atom or Burgess General Formula) as illustrated by the large uncertainties which currently exist in the tungsten ionization balance. To this end, we present a series of partial final state-resolved and total DR rate coefficients for W73+ to W56+ Tungsten ions. This is…
We present a systematic measurement of the X-ray emission asymmetries in the K-shell dielectronic, trielectronic, and quadruelectronic recombination of free electrons into highly charged ions. Iron ions in He-like through O-like charge states were produced in an electron beam ion trap, and the electron-ion collision energy was scanned over the recombination resonances. Two identical X-ray detectors mounted head-on and side-on with respect to the electron beam propagation recorded X-rays emitted in the decay of resonantly populated states. The degrees of linear polarization of X-rays inferred f…
We report linear polarization measurements of x rays emitted due to dielectronic recombination into highly charged krypton ions. The ions in the He-like through O-like charge states were populated in an electron beam ion trap with the electron beam energy adjusted to recombination resonances in order to produce $Kα$ x rays. The x rays were detected with a newly developed Compton polarimeter using a beryllium scattering target and 12 silicon x-ray detector diodes sampling the azimuthal distribution of the scattered x rays. The extracted degrees of linear polarization of several dielectronic rec…
A recently generated theoretical line list of C II dielectronic recombination lines together with observational data gathered from the literature is used to investigate the electron temperature in a range of astronomical objects, mainly planetary nebulae. The electron temperature is obtained by a least-squares optimisation using all the reliable observed lines in each object. In addition, the subset of lines arising directly from autoionising states is used to directly determine the free-electron energy distribution which is then compared with various theoretical possibilities. The method desc…
Rate coefficients for dielectronic recombination of N-like Ne
GSI Helmholtzzentrum für Schwerionenforschung GmbH（吉西亥尔姆霍兹重离子研究中心有限公司）；Helmholtz-Institut Jena（耶拿亥尔姆霍兹研究所）；Institut für Kernphysik, Goethe Universität（歌德大学核物理研究所）；Institut für Kernphysik, Universität zu Köln（科隆大学核物理研究所）；I. Physikalisches Institut, Justus-Liebig-Universität（吉森大学第一物理研究所）；Helmholtz Forschungsakedemie Hessen für FAIR (HFHF)（黑森亥尔姆霍兹FAIR研究学院）；Physics Department, Auburn University（奥本大学物理系）
We present a theoretical investigation of dielectronic recombination (DR) of Ar-like ions that sheds new light on the behavior of the rate coefficient at low-temperatures where these ions form in photoionized plasmas. We provide results for the total and partial Maxwellian-averaged DR rate coefficients from the initial ground level of K II -- Zn XIII ions. It is expected that these new results will advance the accuracy of the ionization balance for Ar-like M-shell ions and pave the way towards a detailed modeling of astrophysically relevant X-ray absorption features. We utilize the AUTOSTRUCTU…
Dielectronic recombination (DR) is the dominant mode of recombination in magnetically confined fusion plasmas for intermediate to low-charged ions of W. Complete, final-state resolved partial isonuclear W DR rate coefficient data is required for detailed collisional-radiative modelling for such plasmas in preparation for the upcoming fusion experiment ITER. To realize this requirement, we continue {\it The Tungsten Project} by presenting our calculations for tungsten ions W$^{55+}$ to W$^{38+}$. As per our prior calculations for W$^{73+}$ to W$^{56+}$, we use the collision package {\sc autostr…
The experimental thermonuclear reactor, ITER, is currently being constructed in Cadarache, France. The reactor vessel will be constructred with a beryllium coated wall, and a tungsten coated divertor. As a plasma-facing component, the divertor will be under conditions of extreme temperature, resulting in the sputtering of tungsten impurities into the main body plasma. Modelling and understanding the potential cooling effects of these impurities requires detailed collisional-radiative modelling. These models require a wealth of atomic data for the various atomic species in the plasma. In partic…
Dielectronic recombination data for astrophysical applications: Plasma rate-coefficients for Fe^q+ (q=7-10, 13-22) and Ni^25+ ions from storage-ring experiments
We investigated experimentally and theoretically dielectronic recombination (DR) populating doubly excited configurations $3l3l'$ (LMM) in Fe XVII, the strongest channel for soft X-ray line formation in this ubiquitous species. We used two different electron beam ion traps and two complementary measurement schemes for preparing the Fe XVII samples and evaluating their purity, observing negligible contamination effects. This allowed us to diagnose the electron density in both EBITs. We compared our experimental resonant energies and strengths with those of previous independent work at a storage…
Longstanding problems in the comparison of very accurate hyperfine-shift measurements to theory were partly overcome by precise measurements on few-electron highly-charged ions. Still the agreement between theory and experiment is unsatisfactory. In this paper, we present a radically new way of precisely measuring hyperfine shifts, and demonstrate its effectiveness in the case of the hyperfine shift of $4s\_{1/2}$ and $4p\_{1/2}$ in $^{207}\mathrm{Pb}^{53+}$. It is based on the precise detection of dielectronic resonances that occur in electron-ion recombination at very low energy. This allows…
Dielectronic and higher-order resonant electron recombination processes including a K-shell excitation were systematically measured at high resolution in electron beam ion traps. Storing highly charged Ar, Fe, and Kr ions, the dependence on atomic number Z of the contribution of these processes to the total recombination cross section was studied and compared with theoretical calculations. Large higher-order resonant recombination contributions are found, especially for systems with 10<Z<36. In some cases, they even surpass the strength of the dielectronic channel, which was hitherto presumed …
Dielectronic recombination(DR) of lithium-like Ti19+(1s2 2s) ions via 2s->2p core excitations has been measured at the Heidelberg heavy ion storage ring TSR. We find that not only external electric fields (0 <= Ey <= 280 V/cm) but also crossed magnetic fields (30 mT <= Bz <= 80 mT) influence the DR via high-n (2p_j nl)-Rydberg resonances. This result confirms our previous finding for isoelectronic Cl14+ ions [Bartsch T et al, PRL 82, 3779 (1999)] that experimentally established the sensitivity of DR to ExB fields. In the present investigation the larger 2p_{1/2}-2p_{3/2} fine structure splitti…
We calculate the electron recombination rates with target ions W$^{q+}$, $q = 18$ -- $25$, as functions of electron energy and electron temperature (i.e. the rates integrated over the Maxwellian velocity distribution). Comparison with available experimental data for W$^{18+}$, W$^{19+}$, and W$^{20+}$ is used as a test of our calculations. Our predictions for W$^{21+}$, W$^{22+}$, W$^{23+}$, W$^{24+}$, and W$^{25+}$ (where the experimental data are not available) may be used for plasma modelling in thermonuclear reactors. The results for the temperature dependent rates for each ion are fitted …
We have developed a general model for determining density-dependent effective dielectronic recombination (DR) rate coefficients in order to explore finite-density effects on the ionization balance of plasmas. Our model consists of multiplying by a suppression factor those highly-accurate total zero-density DR rate coefficients which have been produced from state-of-the-art theoretical calculations and which have been benchmarked by experiment. The suppression factor is based-upon earlier detailed collision-radiative calculations which were made for a wide range of ions at various densities and…
Motivated by possible atomic origins of the unidentified emission line detected at 3.55 keV to 3.57 keV in a stacked spectrum of galaxy clusters (Bulbul et al. 2014), an electron beam ion trap (EBIT) was used to investigate the resonant dielectronic recombination (DR) process in highly-charged argon ions as a possible contributor to the emission feature. The He-like Ar DR-induced transition 1s$^2$2l - 1s2l3l$^\prime$ was suggested to produce a 3.62 keV photon (Bulbul et al. 2014) near the unidentified line at 3.57 keV and was the starting point of our investigation. The collisional-radiative m…
Past and ongoing research activities at the Heidelberg heavy-ion storage-ring TSR are reviewed which aim at providing accurate absolute rate coefficients and cross sections of atomic collision processes for applications in astrophysics and magnetically confined fusion. In particular, dielectronic recombination and electron impact ionization of iron ions are discussed as well as dielectronic recombination of tungsten ions.
Absolute dielectronic recombination (DR) rates for lithium-like Ni$^{25+}$($1s^2 2s$) ions were measured at high-energy resolution at the Heidelberg heavy-ion storage ring TSR. We studied the center-of-mass energy range 0--130 eV which covers all $Δn$=0 core excitations. The influence of external crossed electric (0--300 V/cm) and magnetic (41.8--80.1 mT) fields was investigated. For the measurement at near-zero electric field resonance energies and strengths are given for Rydberg levels up to n$=$32; also Maxwellian plasma rate coefficients for the $Δn$=0 DR at electron temperatures between 0…
The low energy C IV dielectronic recombination (DR) rate coefficient associated with 2s-2p Delta n=0 excitations of this lithiumlike ion has been measured with high energy-resolution at the heavy-ion storage-ring TSR of the Max-Planck-Institut fuer Kernphysik in Heidelberg, Germany. The experimental procedure and especially the experimental detection probabilities for the high Rydberg states produced by the recombination of this ion are discussed in detail. From the experimental data a Maxwellian plasma rate coefficient is derived with 15% systematic uncertainty and parameterized for ready use…
The resonant process of nuclear excitation by electron transition (NEET) in highly charged ions is investigated. In NEET, a bound electronic decay transition occurs with the simultaneous excitation of the nucleus, provided that the energies of the atomic and nuclear transition match. By varying the atomic charge state, the atomic transition energy can be tuned to a better match of the nuclear transition energy. We propose a new way to create the atomic hole in highly charged ions by dielectronic capture of a free electron. In order to derive the cross section for the three-step process compose…
We performed an overview of the inner shell excitation phenomena in the study of electron recombination with multiply charged complex ions such as Au$^{q+}$ (q=49-52) and Pb$^{53+}$. It is found the the inner shell excitations play a significant role in the low energy electron recombination. Taking into account these inner shell excitations we have calculated the energy avaraged capture cross sections. The dielectronic rate coefficients are found to be in good agreement with the experiment. We show that the contribution from the inner-shell enhances the recombinmation rate by an order of magit…
A statistical theory of resonant multielectron recombination based on properties of chaotic eigenstates is developed. The level density of many-body states increases exponentially with the number of excited electrons. When the residual electron-electron interaction exceeds the interval between these levels, the eigenstates (called compound states or compound resonances if these states are in the continuum) become "chaotic" superpositions of large numbers of Hartree-Fock configurational basis states. This situation takes place in some rare-earth atoms and many open-shell multiply charged ions e…
We discuss a parity nonconserving asymmetry in the cross section of KLL dielectronic recombination of polarized electrons on the hydrogen-like ions with $Z \lesssim 60$. This effect is strongly enhanced because of the near-degeneracy of doubly-excited $2l2l'$ states of opposite parity in He-like ions. For ions with $Z \sim 30$ the asymmetry is of the order of $10^{-9}$. For $Z \approx 48$ a level crossing takes place, leading to the PNC asymmetry of $\pm 5\times 10^{-9}$, which is $10^8$ times greater than the basic strength of the weak interaction in atoms.
We present the first detailed ab initio quantum mechanical calculations for total and state-specific recombination rate coefficients for e + Ni III --> Ni II. These rates are obtained using a unified treatment for total electron-ion recombination that treats the nonresonant radiative recombination and the resonant dielectronic recombination in a self-consistent unified manner in the close coupling approximation. Large-scale calculations are carried out using a 49-state wavefunction expansion from core configurations 3d^8, 3d^74s, and 3d^64p that permits the inclusion of prominent dipole allowe…
Dielectronic recombination (DR) of few-electron ions has evolved into a sensitive spectroscopic tool for highly charged ions. This is due to technological advances in electron-beam preparation and ion-beam cooling techniques at heavy-ion storage rings. Recent experiments prove unambiguously that DR collision spectroscopy has become sensitive to 2nd order QED and to nuclear effects. This review discusses the most recent developments in high-resolution spectroscopy of low-energy DR resonances, experimental studies of KLL DR of very heavy hydrogenlike ions, isotope shift measurements of DR resona…
We present new experimentally measured and theoretically calculated rate coefficients for the electron-ion recombination of W$^{18+}$([Kr] $4d^{10}$ $4f^{10}$) forming W$^{17+}$. At low electron-ion collision energies, the merged-beam rate coefficient is dominated by strong, mutually overlapping, recombination resonances. In the temperature range where the fractional abundance of W$^{18+}$ is expected to peak in a fusion plasma, the experimentally derived Maxwellian recombination rate coefficient is 5 to 10 times larger than that which is currently recommended for plasma modeling. The complexi…
Relativistic close coupling calculations are reported for unified electronic recombination of (e + C IV) including non-resonant and resonant recombination processes, radiative and dielectronic recombination (RR and DR). Detailed comparison of the theoretical unified results with two recent experiments on ion storage rings (Mannervik etal. [1] and Schippers etal. [2]) shows very good agreement in the entire measured energy region 2s -- 2p with 2pnl resonances. The results benchmark theory and experiments to uncertainties of ~15%, and show that the resonant and the background cross sections are …
