We present an analysis of interstellar H2 toward HD 37903, which is a hot, B 1.5 V star located in the NGC 2023 reflection nebula. Meyer et al. (2001) have used a rich spectrum of vibrationally excited H2 observed by the HST to calculate a model of the interstellar cloud toward HD 37903. We extend Mayer's analysis by including the v"=0 vibrational level observed by the FUSE satellite.
The T01 temperature should not be interpreted as a rotational temperature, but rather as a temperature of thermal equilibrium between the ortho and para H2. The ortho to para H2 ratio is lower for collisionally populated levels than for the levels populated by fluorescence.
The PDR model of the cloud located in front of HD 37903 points to a gas temperature Tkin=110-377 K, hydrogen density nH=1874-544 cm^-3 and the star-cloud distance of 0.45 pc.
Interstellar dark clouds are the sites of star formation. Their main component, dihydrogen, exists under two states, ortho and para. H2 is supposed to form in the ortho:para ratio (OPR) of 3:1 and to subsequently decay to almost pure para-H2 (OPR <= 0.001). Only if the H2 OPR is low enough, will deuteration enrichment, as observed in the cores of these clouds, be efficient. The second condition for strong deuteration enrichment is the local disappearance of CO, which freezes out onto grains in the core formation process. We show that this latter condition does not apply to DCO+, which, therefo…
Context: Fast surface conversion between ortho- and para-H2 has been observed in laboratory studies, and this mechanism has been proposed to play a role in the control of the ortho-para ratio in the interstellar medium. Observations of rotational lines of H2 in Photo-Dissociation Regions (PDRs) have indeed found significantly lower ortho-para ratios than expected at equilibrium. The mechanisms controlling the balance of the ortho-para ratio in the interstellar medium thus remain incompletely understood, while this ratio can affect the thermodynamical properties of the gas (equation of state, c…
The chemistry in the diffuse interstellar medium initiates the gradual increase of molecular complexity during the life cycle of matter. A key molecule that enables build-up of new molecular bonds and new molecules via proton-donation is H3+. Its evolution is tightly related to molecular hydrogen and thought to be well understood. However, recent observations of ortho and para lines of H2 and H3+ in the diffuse ISM showed a puzzling discrepancy in nuclear spin excitation temperatures and populations between these two key species. H3+, unlike H2, seems to be out of thermal equilibrium, contrary…
The ultraviolet and far--ultraviolet spectra of HD 147888 allows to access the v=0 as well as higher vibrational levels of the ground H2 electronic level. We have determined column densities of the H2 molecule on vibrational levels v=0-5 and rotational levels J=0-6. The ortho to para H2 ratio for the excited vibrational states equals to 1.2. For the lowest vibrational state v=0 and rotational level J=1 the ortho to para H2 ratio is only 0.16. The temperature of ortho-para thermodynamical equilibrium is T_OP=43+-3 K. The large number of H2 absorption lines in the HST spectra allows to determine…
We report on the detection of the ground-state rotational line of ortho-D2H+ at 1.477 THz (203 micron) using the German REceiver for Astronomy at Terahertz frequencies (GREAT) onboard the Stratospheric Observatory For Infrared Astronomy (SOFIA). The line is seen in absorption against far-infrared continuum from the protostellar binary IRAS 16293-2422 in Ophiuchus. The para-D2H+ line at 691.7 GHz was not detected with the APEX telescope toward this position. These D2H+ observations complement our previous detections of para-H2D+ and ortho-H2D+ using SOFIA and APEX. By modeling chemistry and rad…
We report additional detections of the chloronium molecular ion, H$_2$Cl$^+$, toward four bright submillimeter continuum sources: G29.96, W49N, W51, and W3(OH). With the use of the HIFI instrument on the Herschel Space Observatory, we observed the $2_{12}-1_{01}$ transition of ortho-H$_2^{35}$Cl$^+$ at 781.627 GHz in absorption toward all four sources. Much of the detected absorption arises in diffuse foreground clouds that are unassociated with the background continuum sources and in which our best estimates of the $N({\rm H_2Cl^+})/N({\rm H})$ ratio lie in the range $(0.9 - 4.8) \times 10^{-…
We present a list of interstellar absorption lines in the direction of HD 37061 in the M 43 nebula. Some of the absorption lines arise from atomic excited levels that are uncommon in interstellar clouds. The excited levels of Fe II are populated by fluorescence. We found a large number of H2 molecular absorption lines arising from vibrationally excited levels. The ortho/para H2 ratio is equal to 2.7. The H2 rotational temperature of vibrational levels 1 - 5 exceeds 2000 K.
Based on recent $Herschel$ results, the ortho-to-para ratio (OPR) of NH$_2$ has been measured towards the following high-mass star-forming regions: W31C (G10.6-0.4), W49N (G43.2-0.1), W51 (G49.5-0.4), and G34.3+0.1. The OPR at thermal equilibrium ranges from the statistical limit of three at high temperatures to infinity as the temperature tends toward zero, unlike the case of H$_{2}$. Depending on the position observed along the lines-of-sight, the OPR was found to lie either slightly below the high temperature limit of three (in the range $2.2-2.9$) or above this limit ($\sim3.5$, $\gtrsim 4…
The nuclear-spin chemistry of interstellar water is investigated using the University of Grenoble Alpes Astrochemical Network (UGAN). This network includes reactions involving the different nuclear-spin states of the hydrides of carbon, nitrogen, oxygen and sulphur, as well as their deuterated forms. Nuclear-spin selection rules are implemented within the scrambling hypothesis for reactions involving up to seven protons. The abundances and ortho-to-para ratios (OPRs) of gas-phase water and water ions (H$_2$O$^+$ and H$_3$O$^+$) are computed under the steady-state conditions representative of a…
A quantitative interpretation of the observed relation between the interstellar linear polarization curve parameters $K$ and $λ_{\max}$ characterizing the width and the wavelength of a polarization maximum, respectively, is given. The observational data available for 57 stars located in the dark clouds in Taurus, Chamaeleon, around the stars $ρ$ Oph and R CrA are considered. The spheroidal particle model of interstellar dust grains earlier applied to simultaneously interpret the interstellar extinction and polarization curves in a wide spectral range is utilized. The observed trend $K \approx …
Using integral field data we extract the optical spectra of shocked interstellar clouds in Kepler's supernova remnant located in the inner regions of our Galaxy, as well as in the Large Magellanic Cloud (LMC), the Small Magellanic Cloud (SMC), NGC6822 and IC 1613. Using self-consistent shock modelling, we make a new determination of the chemical composition of the interstellar medium (ISM) in N, O, Ne, S, Cl and Ar in these galaxies and obtain accurate estimates of the fraction of refractory grains destroyed in the shock. By comparing our derived abundances with those obtained in recent works …
A continuous supersonic flow reactor has been used to measure rate constants for the C + NH3 reaction over the temperature range 50 to 296 K. C atoms were created by the pulsed laser photolysis of CBr4. The kinetics of the title reaction were followed directly by vacuum ultra-violet laser induced fluorescence (VUV LIF) of C loss and through H formation. The experiments show unambiguously that the reaction is rapid at 296 K, becoming faster at lower temperatures, reaching a value of 1.8 10-10 cm3 molecule-1 s-1 at 50 K. As this reaction is not currently included in astrochemical networks, its i…
We perform a multiwavelength study toward the SNR G18.1-0.1 and nearby several HII regions (infrared dust bubbles N21 and N22, and the HII regions G018.149-00.283 and G18.197-00.181). Our goal is to provide observational evidence supporting that massive stars usually born in clusters from the same molecular cloud, which then produce, along their evolution, different neighboring objects such as HII regions, interstellar bubbles and supernova remnants. We suggest that the objects analysed in this work belong to a same complex located at the distance of about 4 kpc. Using molecular data we inspec…
We report the first detection in interstellar space of the 3-cyano propargyl radical (CH2C3N). This species was observed in the cold dark cloud TMC-1 using the Yebes 40m telescope. A total of seven rotational transitions for both ortho- and para-CH2C3N species were observed in the 31.0-50.4 GHz range. We derive a total column density of (1.6 +/- 0.4)e11 cm-2 and an ortho/para ratio of 2.4 +/- 1.2, which implies an abundance ratio CH2C3N/CH3C3N around 0.1, in sharp contrast with the smaller analogues, in which case CH2CN/CH3CN = 3. This indicates that the chemistry of the cyanides CH2C3N and CH…
The slopes of interstellar reddening lines in the 2MASS J-H versus H-Ks diagrams for 26 areas in the inner Galaxy (from Vulpecula to Centaurus) are determined. For this aim we use the red-clump giants located inside and behind spiral arms, or behind dense dust clouds of the Local arm. In most of the investigated directions the ratio E(J-H)/E(H-K_s) is found to be between 1.9 and 2.0, taking the stars with the visual extinction less than 12 mag. The stars with larger extinction deviate down from the reddening lines corresponding to less reddened stars. Probably, this is related to the curvature…
Spectral line surveys reveal rich molecular reservoirs in G331.512-0.103, a compact radio source in the center of an energetic molecular outflow. In this first work, we analyse the physical conditions of the source by means of CH$_3$OH and CH$_3$CN. The observations were performed with the APEX telescope. Six different system configurations were defined to cover most of the band within (292-356) GHz; as a consequence we detected a forest of lines towards the central core. A total of 70 lines of $A/E$-CH$_3$OH and $A/E$-CH$_3$CN were analysed, including torsionally excited transitions of CH$_3$…
The detection of CF$^+$ in interstellar clouds potentially allows astronomers to infer the elemental fluorine abundance and the ionization fraction in ultraviolet-illuminated molecular gas. Because local thermodynamic equilibrium (LTE) conditions are hardly fulfilled in the interstellar medium (ISM), the accurate determination of the CF$^+$ abundance requires one to model its non-LTE excitation via both radiative and collisional processes. Here, we report quantum calculations of rate coefficients for the rotational excitation of CF$^+$ in collisions with para- and ortho-H2 (for temperatures up…
Using the Herschel Space Observatory's Heterodyne Instrument for the Far-Infrared (HIFI), we have observed para-chloronium (H2Cl+) toward six sources in the Galaxy. We detected interstellar chloronium absorption in foreground molecular clouds along the sight-lines to the bright submillimeter continuum sources Sgr A (+50 km/s cloud) and W31C. Both the para-H2-35Cl+ and para-H2-37Cl+ isotopologues were detected, through observations of their 1(11)-0(00) transitions at rest frequencies of 485.42 and 484.23 GHz, respectively. For an assumed ortho-to-para ratio of 3, the observed optical depths imp…
We report the detection of absorption from interstellar C_2 and C_3 toward the moderately reddened star Sk 143, located in the near 'wing' region of the SMC, in optical spectra obtained with the ESO VLT/UVES. These detections of C_2 (rotational levels J=0-8) and C_3 (J=0-12) absorption in the SMC are the first beyond our Galaxy. The total abundances of C_2 and C_3 (relative to H_2) are similar to those found in diffuse Galactic molecular clouds -- as previously found for CH and CN -- despite the significantly lower average metallicity of the SMC. Analysis of the rotational excitation of C_2 yi…
We carry out a multiwavelength study to characterize the HI supershell designated GS 118+01-44, and to analyse its possible origin. A multiwavlength study has been carried out to study the supershell and its environs. We performed an analysis of the HI, CO, radio continuum, and infrared emission distributions. The Canadian Galactic Plane Survey (CGPS) HI data reveals that GS 118+01-44 is centred at (l, b) = (117.7, 1.4) with a systemic velocity of -44.3 km/s. According to Galactic rotation models this structure is located at 3.0 +- 0.6 kpc from the Sun. There are several HII regions and three …
The HIFI instrument on board the Herschel Space Observatory has been used to observe interstellar nitrogen hydrides along the sight-line towards G10.6-0.4 in order to improve our understanding of the interstellar chemistry of nitrogen. We report observations of absorption in NH N=1-0, J=2-1 and ortho-NH2 1_1,1-0_0,0. We also observed ortho-NH3 1_0-0_0, and 2_0-1_0, para-NH3 2_1-1_1, and searched unsuccessfully for NH+. All detections show emission and absorption associated directly with the hot-core source itself as well as absorption by foreground material over a wide range of velocities. All…
The aim of the present work is to perform a comprehensive analysis of the interstellar chemistry of nitrogen, focussing on the gas-phase formation of the smallest polyatomic species and in particular nitrogen hydrides. We present a new chemical network in which the kinetic rates of critical reactions have been updated based on recent experimental and theoretical studies, including nuclear spin branching ratios. Our network thus treats the different spin symmetries of the nitrogen hydrides self-consistently together with the ortho and para forms of molecular hydrogen. This new network is used t…
We report the detection of absorption by interstellar hydroxyl cations and water cations, along the sight-line to the bright continuum source W49N. We have used Herschel's HIFI instrument, in dual beam switch mode, to observe the 972 GHz N = 1 - 0 transition of OH+ and the 1115 GHz 1(11) - 0(00) transition of ortho-H2O+. The resultant spectra show absorption by ortho-H2O+, and strong absorption by OH+, in foreground material at velocities in the range 0 to 70 km/s with respect to the local standard of rest. The inferred OH+/H2O+ abundance ratio ranges from ~ 3 to ~ 15, implying that the observ…
We investigate the distribution of the interstellar dust towards six small volumes of the sky in the region of the Gum nebula. New high-quality four-colour uvby and Hβ Strömgren photometry obtained for 352 stars in six selected areas of Kapteyn, complemented with data obtained in a previous investigation for two of these areas, were used to estimate the colour excess and distance to these objects. The obtained colour excess versus distance diagrams, complemented with other information, when available, were analysed in order to infer the properties of the interstellar medium permeating the obse…
We aim to make use of the measurements from the Giraffe Inner Bulge Survey (GIBS) and the Gaia$-$ESO survey (GES) to study the kinematics and distance of the carrier of DIB$\,λ$8620, as well as other properties. We successfully detected and measured DIB$\,λ$8620 in 760 of 4117 GES spectra. Combined with the DIBs measured in GIBS spectra, we confirmed a tight relation between EW and $E(J-K_{\rm S})$ as well as $A_{\rm V}$, with similar fitting coefficients to those found by previous works. With a more accurate sample and the consideration of the solar motion, the rest-frame wavelength of DIB$\,…
Hydronium (H$_3$O$^+$) was first detected in 1986 in interstellar molecular clouds. It was reported in many galactic diffuse and dense regions, as well as in extragalactic sources. H$_3$O$^+$ plays a major role both in interstellar oxygen and water chemistry. However, despite the large number of H$_3$O$^+$ observations, its collisional excitation was investigated only partially. In the present work we study the state-to-state rotational de-excitation of $ortho$- and $para$-H$_3$O$^+$ in collisions both with $ortho$- and $para$-H$_2$. The cross sections are calculated within the close-coupling …
Evidence of triggered star formation at large spatial scales involving stellar clusters is scarce. We investigate a Galactic region (l=130.0, b=0.35) populated by several open stellar clusters that according to the last GAIA data release, are located at a distance of about 2.9 kpc. By analyzing the interstellar medium (ISM) at infrared, centimeter, and millimeter wavelengths towards this group of clusters we discovered a shell of material of about 2 degree in size at the same distance. We suggest that the shell, mainly observed at 12 um and in the Hi emission at 21 cm, was generated by the act…
We present new observations with the Atacama Large Millimeter/sub-millimeter Array of the 122um and 205um fine-structure line emission of singly-ionised nitrogen in a strongly lensed starburst galaxy at z=2.6. The 122/205um [NII] line ratio is sensitive to electron density, n_e, in the ionised interstellar medium, and we use this to measure n_e~300cm^-3 averaged across the galaxy. This is over an order of magnitude higher than the Milky Way average, but comparable to localised Galactic star-forming regions. Combined with observations of the atomic carbon (CI(1-0)) and carbon monoxide (CO(4-3))…
Diffuse interstellar bands (DIBs) are absorption features commonly observed in optical/near-infrared spectra of stars and thought to be associated with polyatomic molecules that comprise a significant reservoir of organic material in the universe. However, the central wavelengths of almost all DIBs do not correspond with electronic transitions of known atomic or molecular species and the specific physical nature of their carriers remains inconclusive despite decades of observational, theoretical, and experimental research. It is well established that DIB carriers are located in the interstella…
On its journey through the Galaxy, the Sun passes through diverse regions of the interstellar medium. High-resolution spectroscopic measurements of interstellar absorption lines in spectra of nearby stars show absorption components from more than a dozen warm partially ionized clouds within 15 pc of the Sun. The two nearest clouds - the Local Interstellar Cloud (LIC) and Galactic (G) cloud - move toward each other. Their bulk heliocentric velocities can be compared with the interstellar neutral helium flow velocity obtained from space-based experiments. We combine recent results from Ulysses, …
We analyze high-resolution ultraviolet spectra of three nearby exoplanet host stars (HD 192310, HD 9826, and HD 206860) to study interstellar properties along their lines of sight and to search for the presence of astrospheric absorption. Using HST/STIS spectra of the Lyman-alpha, Mg II, and Fe II lines, we identify three interstellar velocity components in the lines of sight to each star. We can reliably assign eight of the nine components to partially ionized clouds found by Redfield & Linsky (2008) on the basis of the star's location in Galactic coordinates and agreement of measured radial …
We present high resolution (R = 114,000) ultraviolet measurements of the interstellar absorption line profiles of the CIV (1550 A) high ionization doublet recorded towards the nearby B2Ve star HD 158427 (d~74pc). These data, which were recorded with the recently re-furbished STIS instrument on the HST, represent the most convincing detection yet of highly ionized CIV absorption that can be associated with interstellar gas located within the boundary of the Local Cavity. Two highly ionized gas clouds at V1 = -24.3 km/s and V2 = -41.3 km/s are revealed in both CIV absorption lines, with the V1 c…
We present a new database of 5780.5 and 6283.8 Å DIB measurements and also study their correlation with the reddening. The database is based on high-resolution, high-quality spectra of early-type nearby stars located in the southern hemisphere at an average distance of 300 pc. Equivalent widths of the two DIBs were determined by means of a realistic continuum fitting and synthetic atmospheric transmissions. For all stars that possess a precise measurement of their color excess, we compare the DIBs and the extinction. We find average linear relationships of the DIBS and the color excess that ag…
The excitation temperature T_01 derived from the relative intensities of the J = 0 (para) and J = 1 (ortho) rotational levels of H2 has been assumed to be an accurate measure of the kinetic temperature in interstellar environments. In diffuse molecular clouds, the average value of T_01 is ~70 K. However, the excitation temperature T(H3+) derived from the (J,K) = (1,1) (para) and (1,0) (ortho) rotational levels of H3+ has been observed to be ~30 K in the same types of environments. In this work, we present observations of H3+ in three additional diffuse cloud sight lines for which H2 measuremen…
We report the first detection of chloronium, H$_2$Cl$^+$, in the interstellar medium, using the HIFI instrument aboard the \emph{Herschel} Space Observatory. The $2_{12}-1_{01}$ lines of ortho-H$_2^{35}$Cl$^+$ and ortho-H$_2^{37}$Cl$^+$ are detected in absorption towards NGC~6334I, and the $1_{11}-0_{00}$ transition of para-H$_2^{35}$Cl$^+$ is detected in absorption towards NGC~6334I and Sgr~B2(S). The H$_2$Cl$^+$ column densities are compared to those of the chemically-related species HCl. The derived HCl/H$_2$Cl$^+$ column density ratios, $\sim$1--10, are within the range predicted by models…
Some observations of warm carbon chain chemistry (WCCC) cores indicate that they are often located near the edges of molecular clouds. This finding may suggest that WCCC is promoted in star-forming cores exposed to radiation from the interstellar medium. We aim to investigate the chemistry of carbon chains in such a core. A chemical simulation of a gas parcel in a low-mass star-forming core with a full level of irradiation by interstellar photons and cosmic rays was compared to a simulation of a core receiving only one-tenth of such irradiation. In the full irradiation model, the abundances of…
We carried out synthetic observations of a theoretical model of interstellar carbon in CO, C I and C II including H2 formation. The theoretical model based on numerical simulations of H I gas converging at a velocity of 20 km/s by Inoue & Inutsuka (2012) is employed in the present study. The gas model, which is fairy realistic and consistent with the observations of the local gas located at high b, is turbulent and inhomogeneous with magnetic field. We focus on the evolution of the rare species, CO, C I and C II from 0.3 Myr to 9 Myr since the converging flows collided. In the early phase with…
This study aims to determine the main physical parameters (N(H2) hydrogen column density and Td dust temperature) of the Interstellar medium, and their distribution in the extended star-forming region, which includes IRAS 05156+3643, 05162+3639, 05168+3634, 05177+3636, and 05184+3635 sources. We also provide a comparative analysis of the properties of the Interstellar medium and young stellar objects. Analysis of the results revealed that Interstellar medium forms relativity dense condensations around IRAS sources, which are interconnected by a filament structure. In general, in sub-regions Td…
Until recently, the strong interstellar scattering observed towards the Galactic center (GC) black hole, Sgr A*, was thought to come from dense gas within the GC region. The pulse broadening towards the transient magnetar SGR J1745-2900 near Sgr A* has shown that the source of the scattering is instead located much closer to Earth, possibly in a nearby spiral arm. We show that a single HII region along the line of sight, 1.5-4.8 kpc away from Earth with density $n_e$ of a few 100 cm$^{-3}$ and radius R = 1.8-3.2 pc can explain the observed angular broadening of Sgr A*. Clouds closer to the GC …
The properties of the interstellar medium (ISM) surrounding a planetary system can impact planetary climate through a number of mechanisms, including changing the size of the astrosphere (one of the major shields for cosmic rays) as well as direct deposition of material into planetary atmospheres. In order to constrain the ambient ISM conditions for exoplanetary systems, we present observations of interstellar Na I and K I absorption towards seventeen early-type stars in the Kepler prime mission field of view. We identify 39 Na I and 8 K I velocity components, and attribute these to eleven ISM…
We analyse observational correlations for three elements entering into the composition of interstellar silicate and oxide grains. Using current solar abundances (Asplund et al. 2009), we convert the gas-phase abundances into dust-phase abundances for 196 sightlines. We deduce a sharp difference in abundances for sightlines located at low ($|b|<30\degr$) and high ($|b|>30\degr$) galactic latitudes. For high-latitude stars the ratios Mg/Si and Fe/Si in dust are close to 1.5. For disk stars they are reduced to ${\rm Mg/Si} \sim 1.2$ and ${\rm Fe/Si} \sim 1.05$. The derived numbers indicate that 1…
High sensitivity interstellar scintillation and polarization observations of PSR~B0656+14 made at three epochs over a year using the Five-hundred-meter Aperture Spherical radio Telescope (FAST) show that the scattering is dominated by two different compact regions. We identify the one nearer to the pulsar with the shell of the Monogem Ring, thereby confirming the association. The other is probably associated with the Local Bubble. We find that the observed position angles of the pulsar spin axis and the space velocity are significantly different, with a separation of $19\fdg3\pm$0\fdg8, incons…
The HI line at 21 cm is a tracer of circumstellar matter around AGB stars, and especially of the matter located at large distances (0.1-1 pc) from the central stars. It can give unique information on the kinematics and on the physical conditions in the outer parts of circumstellar shells and in the regions where stellar matter is injected into the interstellar medium. However this tracer has not been much used up to now, due to the difficulty of separating the genuine circumstellar emission from the interstellar one. With the Nancay Radiotelescope we are carrying out a survey of the HI emissio…
We investigate metal pollution onto the surface of low-mass population III stars (Pop. III survivors) via interstellar objects floating in the Galactic interstellar medium. Only recently, Tanikawa et al. analytically estimated how much metal should collide to an orbiting Pop. III survivor encouraged by the recent discovery of 'Oumuamua and suggested that ISOs are the most dominant contributor of metal enrichment of Pop. III survivors. When we consider a distribution of interstellar objects in the Galactic disc, Pop. III survivors' orbits are significant properties to estimate the accretion rat…
