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arXiv 1001.4844quant-ph
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定态开放系统的熵和specific heat

Entropy and specific heat for open systems in steady states

X. L. Huang, B. Cui, X. X. Yi

摘要:

统计力学的基本假设是,系统处于任何可达微观状态的可能性相等。在此基础上,导出了玻尔兹曼分布,建立了完整的统计热力学理论。本文证明了一般的玻尔兹曼分布不能描述开放系统的定态。基于有效哈密顿量方法,计算了一个开放系统的定态比热、自由能和熵。举例说明和讨论。

英文摘要:

The fundamental assumption of statistical mechanics is that the system is equally likely in any of the accessible microstates. Based on this assumption, the Boltzmann distribution is derived and the full theory of statistical thermodynamics can be built. In this paper, we show that the Boltzmann distribution in general can not describe the steady state of open system. Based on the effective Hamiltonian approach, we calculate the specific heat, the free energy and the entropy for an open system in steady states. Examples are illustrated and discussed.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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