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arXiv 0912.4201cond-mat.supr-concond-mat.str-el
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磷属元素化物超导体的展望

A perspective on pnictide superconductors

John A. Wilson

摘要:

以FeSe为参考材料,研究了层状铁磷属元素化物的高温超导行为。结构和随后的半金属带结构形式在这里是相当不寻常的,与所得的基态的细节非常敏感的精确形状的Fe-X配位单元。超导电性是由共振价键(RVB)和激子绝缘体物理学的结合,并结合玻色子-费米子简并。虽然来源于一个非常不同的方式,后者导致一些similarites与高温超导(HTSC)铜酸盐。激子绝缘体行为看到SDW、CDW/PLD和双稳态不稳定性都争夺基态状态。这种冲突导致了一系列非常敏感和复杂的性质,经常反映出HTSC铜氧化物的行为。基态之间的微妙平衡,由于它所能产生的结构形式的微观不均匀性而变得特别难以解开。据指出,其他几个值得注意的超导体,层状形式,半金属与间接重叠,并拥有单极键,看起来属于相同的一般类别,β-ZrNCl和MgB 2和高压形式的几个元素,如硫,磷,锂和钙,是适当的情况。

英文摘要:

FeSe is employed as reference material to elucidate the observed high Tc superconducting behaviour of the related layered iron pnictides. The structural and ensuing semimetallic band structural forms are here rather unusual, with the resulting ground state details extremely sensitive to the precise shape of the Fe-X coordination unit. The superconductivity is presented as coming from a combination of Resonant Valence Bond (RVB) and Excitonic Insulator physics, and incorporating Boson-Fermion degeneracy. Although sourced in a very different fashion the latter leads to some similarites with the high temperature superconducting (HTSC) cuprates. The Excitonic Insulator behaviour sees SDW, CDW/PLD and superconductive instabilities all vie for ground state status. The conflict leads to a very sensitive and complex set of properties, frequently mirroring HTSC cuprate behaviour. The delicate balance between ground states is made particularly difficult to unravel by the micro-inhomogeneity of structural form which it can engender. It is pointed out that several other notable superconductors, layered in form, semimetallic with indirect overlap and possessing homopolar bonding, would look to fall into the same general category, beta-ZrNCl and MgB2 and the high-pressure forms of several elements, like sulphur, phosphorus, lithium and calcium, being cases in point.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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