The Kondo effect has been observed in a single gate-tunable atom. The measurement device consists of a single As dopant incorporated in a Silicon nanostructure. The atomic orbitals of the dopant are tunable by the gate electric field. When they are tuned such that the ground state of the atomic system becomes a (nearly) degenerate superposition of two of the Silicon valleys, an exotic and hitherto unobserved valley Kondo effect appears. Together with the regular spin Kondo, the tunable valley Kondo effect allows for reversible electrical control over the symmetry of the Kondo ground state from an SU(2)- to an SU(4) -configuration.
We propose a mechanism to directly measure the chiral anomaly in disorder Weyl semimetals (WSMs) by the Kondo effect. We find that in a magnetic and electric field driven WSM, the locations of the Kondo peaks can be modulated by the chiral chemical potential, which is proportional to $\mathbf{E}\cdot \mathbf{B}$. The Kondo peaks come from spin fluctuations within the impurities, which apart from the temperature, relate closely to the host's Fermi level. In WSMs, the chiral-anomaly-induced chirality population imbalance will shift the local Fermi levels of the paired Weyl valleys toward opposit…
Determination of the molecular Kondo temperature $T_K$ poses a challenge in most cases when the experimental temperature cannot be tuned to a sufficient extent. We show how this ambiguity can be resolved if additional control parameters are present, such as magnetic field and mechanical gating. We record the evolution of the differential conductance by lifting an individual molecule from the metal surface with the tip of a scanning tunneling microscope. By fitting the measured conductance spectra with the single impurity Anderson model we are able to demonstrate that the lifting tunes the junc…
With recent advances in the areas of nanostructure fabrication and molecular spintronics the idea of using single molecule magnets as building blocks for the next generation electronic devices becomes viable. A particular example represents a metal-organic complex in which organic ligands surround a rare-earth element or transition metal. Recently, it was explicitly shown that the relative position of the ligands with respect to each other can be reversibly changed by the external voltage without any need of the chemical modification of the sample. This opens a way of the electrical tuning of …
We propose a realization of Kondo-lattice physics in moiré superlattices at the interface between a WX$_2$ homobilayer and MoX$_2$ monolayer (where X=S,Se). Under appropriate gating conditions, the interface-WX$_2$-layer forms a triangular lattice of local moments that couple to itinerant electrons in the other WX$_2$-layer via a gate-tunable Kondo exchange interaction. Using a parton mean-field approach we identify a range of twist-angles which support a gate-tuned quantum phase transition between a heavy-fermion liquid with large anomalous Hall conductance and a fractionalized chiral spin-li…
Thermoelectric Signatures of Kondo Physics in Geometry-Tunable Double Quantum Dots
Gerencia de Investigación y Aplicaciones, GAIDI, CNEA（应用研究管理部，GAIDI，CNEA）；Consejo Nacional de Investigaciones Científicas y Técnicas（国家科学研究委员会）；Centro Atómico Bariloche, GAIDI（巴里洛切原子中心，GAIDI）
Proximity of two different materials leads to an intricate coupling of quasiparticles so that an unprecedented electronic state is often realized at the interface. Here, we demonstrate a resonance-type many-body ground state in graphene, a non-magnetic two-dimensional Dirac semimetal, when grown on SmB6, a Kondo insulator, via thermal decomposition of fullerene molecules. This ground state is typically observed in three-dimensional magnetic materials with correlated electrons. Above the characteristic Kondo temperature of the substrate, the electron band structure of pristine graphene remains …
A Kondo resonance has been observed on purely organic molecules in several combinations of charge transfer complexes on a metal surface. It has been regarded as a fingerprint of the transfer of one electron from the donor to the extended $π$ orbital of the acceptor's LUMO. Here, we investigate the stoichiometric checkerboard structure of tetrathiafulvalene (TTF) and tetracyanoethylene (TCNE) on a Au(111) surface using scanning tunneling and atomic force microscopy at 4.8 K. We find a bistable state of the TCNE molecules with distinct structural and electronic properties. The two states represe…
Realization of Kondo lattice in superconducting van der Waals materials not only provides a unique opportunity for tuning the Kondo lattice behavior by electrical gating or intercalation, but also is helpful for further understanding the heavy fermion superconductivity. Here we report a low-temperature and vector-magnetic-field scanning tunneling microscopy and spectroscopy study on a superconducting compound (4Hb-TaS2) with alternate stacking of 1T-TaS2 and 1H-TaS2 layers. We observe the quasi-two-dimensional superconductivity in the 1H-TaS2 layer with anisotropic response to the in-plane and…
We elaborate on the recently introduced concept of reentrant Kondo effect in quantum impurities/dots coupled to hybrid metal-semiconductor contacts [G.~Diniz {\em et al.}, Phys. Rev. B {\bf 101}, 125115 (2020)]. By noticing the equivalence of the originally suggested semiconducting arrangement to an analogous three-terminal quantum dot setup with a normal and two phase-biased superconducting leads introduced in our recent work [Phys. Rev. B {\bf 103}, 035419 (2021)], we put this effect into a new physical context, which enables us a fresh look on the problem. First, we identify the superconduc…
Quantum phase transitions are ubiquitous in many exotic behaviors of strongly-correlated materials. However the microscopic complexity impedes their quantitative understanding. Here, we observe thoroughly and comprehend the rich strongly-correlated physics in two profoundly dissimilar regimes of quantum criticality. With a circuit implementing a quantum simulator for the three-channel Kondo model, we reveal the universal scalings toward different low-temperature fixed points and along the multiple crossovers from quantum criticality. Notably, an unanticipated violation of the maximum conductan…
The gating effect achieved by an ionic liquid and its electric double layer allows for charge transfer which can be an order of magnitude larger than with conventional dielectrics. However, the large charged ions also causes inevitable Coulomb scattering in the conducting channel formed at the interface, which can limit the carrier mobility enhancement. In this work, we study the effect of the LaAlO3 thickness on the transport properties in LaAlO3/SrTiO3 heterostructures by ionic liquid gating. We find that the transport properties of the LaAlO3/SrTiO3 interface are dominated by the intrinsic …
We investigate the electrical control of the exchange coupling (J) between donor bound electrons in silicon with a detuning gate bias, crucial for the implementation of the two-qubit gate in a silicon quantum computer. We find the asymmetric 2P-1P system provides a highly tunable exchange-curve with mitigated J-oscillation, in which 5 orders of magnitude change in the exchange energy can be achieved using a modest range of electric field for 15 nm qubit separation. Compared to the barrier gate control of exchange in the Kane qubit, the detuning gate design reduces the demanding constraints of …
Strong electron correlations and interference effects are discussed in parallel-coupled single-level and orbitally doubly degenerate quantum dots. The finite-U mean-field slave boson approach is used to study many-body effects. The analysis is carried out in a wide range of parameter space including both atomic-like and molecular-like Kondo regimes and taking into account various perturbations, like interdot tunneling, interdot interaction, mixing of the electrode channels and exchange interaction. We also discuss the influence of singularities of electronic structure and the impact of polariz…
Molecular electronics offers unique scientific and technological possibilities, resulting from both the nanometre scale of the devices and their reproducible chemical complexity. Two fundamental yet different effects, with no classical analogue, have been demonstrated experimentally in single-molecule junctions: quantum interference due to competing electron transport pathways, and the Kondo effect due to entanglement from strong electronic interactions. Here we unify these phenomena, showing that transport through a spin-degenerate molecule can be either enhanced or blocked by Kondo correlati…
We report on the first measurement of the Seebeck coefficient in a tunnel-contacted and gate-tunable individual single-quantum dot junction in the Kondo regime, fabricated using the electromigration technique. This fundamental thermoelectric parameter is obtained by directly monitoring the magnitude of the voltage induced in response to a temperature difference across the junction, while keeping a zero net tunneling current through the device. In contrast to bulk materials and single molecules probed in a scanning tunneling microscopy (STM) configuration, investigating the thermopower in nanos…
Many-body correlations and macroscopic quantum behaviors are fascinating condensed matter problems. A powerful test-bed for the many-body concepts and methods is the Kondo model which entails the coupling of a quantum impurity to a continuum of states. It is central in highly correlated systems and can be explored with tunable nanostructures. Although Kondo physics is usually associated with the hybridization of itinerant electrons with microscopic magnetic moments, theory predicts that it can arise whenever degenerate quantum states are coupled to a continuum. Here we demonstrate the previous…
We consider a model describing a spin field-effect transistor based on a quantum nanowire with a tunable spin-orbit interaction embedded between two ferromagnetic leads with anticollinear magnetization. We investigate a regime of a strong interplay between resonance Kondo scattering and interference associated with the Aharonov-Casher effect. Using the Keldysh technique at weak coupling regime we calculate perturbatively the charge current. It is predicted that the effects of the spin-orbit interaction result in a non-vanishing current for any spin polarization of the leads including the case …
Controlling electronic transport through a single-molecule junction is crucial for molecular electronics or spintronics. In magnetic molecular devices, the spin degree-of-freedom can be used to this end since the magnetic properties of the magnetic ion centers fundamentally impact the transport through the molecules. Here we demonstrate that the electron pathway in a single-molecule device can be selected between two molecular orbitals by varying a magnetic field, giving rise to a tunable anisotropic magnetoresistance up to 93%. The unique tunability of the electron pathways is due to the magn…
Observation of Kondo Effect in Rhombohedral Graphene Superlattices
State Key Laboratory for Mesoscopic Physics and Frontiers Science Center for Nano-optoelectronics, School of Physics, Peking University（北京大学物理学院介观物理国家重点实验室和纳米光电前沿科学中心）；Centre for Quantum Physics, Key Laboratory of Advanced Optoelectronic Quantum Architecture and Measurement (MOE), School of Physics, Beijing Institute of Technology（北京理工大学物理学院量子物理中心、先进光电子量子架构与测量教育部重点实验室）；Research Center for Electronic and Optical Materials, National Institute for Material Sciences（物质材料研究机构电子与光学材料研究中心）；Research Center for Materials Nanoarchitectonics, National Institute for Material Sciences（物质材料研究机构材料纳米结构研究中心）；Hefei National Laboratory（合肥国家实验室）
We report scanning tunneling microscopy studies of individual adatoms deposited on an InSb(110) surface. The adatoms can be reproducibly dropped off from the STM tip by voltage pulses, and impact tunneling into the surface by up to ~100x. The spatial extent and magnitude of the tunneling effect are widely tunable by imaging conditions such as bias voltage, set current and photoillumination. We attribute the effect to occupation of a (+/0) charge transition level, and switching of the associated adatom-induced band bending. The effect in STM topographic images is well reproduced by transport mo…
Cooper pair charge Kondo effect in a hybrid quantum dot - superconductor device
SISSA（的里雅斯特国际高等研究学院）；INFN Sezione di Trieste（意大利国家核物理研究所的里雅斯特分部）；Dipartimento di Fisica e Astronomia “G. Galilei”, Università degli Studi di Padova（帕多瓦大学伽利略物理与天文系）；Istituto Nazionale di Fisica Nucleare (INFN), Sezione di Padova（意大利国家核物理研究所帕多瓦分部）；Dipartimento di Fisica dell’Università di Pisa and INFN, sezione di Pisa（比萨大学物理系及意大利国家核物理研究所比萨分部）
Whether a quantum bath can be approximated as classical noise is a fundamental issue in central spin decoherence and also of practical importance in designing noise-resilient quantum control. Spin qubits based on bismuth donors in silicon have tunable interactions with nuclear spin baths and are first-order insensitive to magnetic noise at so-called clock-transitions (CTs). This system is therefore ideal for studying the quantum/classical nature of nuclear spin baths since the qubit-bath interaction strength determines the back-action on the baths and hence the adequacy of a classical noise mo…
The ability to control single dopants in solid-state devices has opened the way towards reliable quantum computation schemes. In this perspective it is essential to understand the impact of interfaces and electric fields, inherent to address coherent electronic manipulation, on the dopants atomic scale properties. This requires both fine energetic and spatial resolution of the energy spectrum and wave-function, respectively. Here we present an experiment fulfilling both conditions: we perform transport on single donors in silicon close to a vacuum interface using a scanning tunneling microscop…
