We use a mean-field (Hartree-like) approach to study the conductance of a strongly localized electron system in two dimensions. We find a crossover between a regime where Coulomb interactions modify the conductance significantly to a regime where they are negligible. We show that under rather general conditions the conduction obeys a scaling relation which we verify using numerical simulations. The use of a Hartree self-consistent approach gives a clear physical picture, and removes the ambiguity of the use of single-particle tunneling density-of-states (DOS) in the calculation of the conductance. Furthermore, the theory contains interaction-induced correlations between the on site energy of the localized states and distances, as well as finite temperature corrections of the DOS.
We study electronic transport in Anderson insulators with strong Coulomb interactions in dimensions d>=2. Close to the metal insulator transition where the single particle localization length is much larger than interparticle-distance, the interactions lead to a strongly correlated quantum glass phase. Even though single particle excitations are localized and the system is insulating, there are collective electronic modes which remain delocalized down to parametrically small energies. These collective excitations serve as a continuous bath which can provide the activation energy for variable r…
We establish the connection between the presence of a glass phase and the appearance of a Coulomb gap in disordered materials with strongly interacting electrons. Treating multiparticle correlations in a systematic way, we show that in the case of strong disorder a continuous glass transition takes place whose Landau expansion is identical to that of the Sherrington-Kirkpatrick spin glass. We show that the marginal stability of the glass phase controls the physics of these systems: it results in slow dynamics and leads to the formation of a Coulomb gap.
We derive a microscopic expression for the dielectric susceptibility $χ$ of a Coulomb glass, which corresponds to the definition used in classical electrodynamics, the derivative of the polarization with respect to the electric field. The fluctuation-dissipation theorem tells us that $χ$ is a function of the thermal fluctuations of the dipole moment of the system. We calculate $χ$ numerically for three-dimensional Coulomb glasses as a function of temperature and frequency.
We study the influence of electron-electron interactions on the electronic properties of disordered materials. In particular, we consider the insulating side of a metal-insulator transition where screening breaks down and the electron-electron interaction remains long-ranged. The investigations are based on the quantum Coulomb glass, a generalization of the classical Coulomb glass model of disordered insulators. The quantum Coulomb glass is studied by decoupling the Coulomb interaction by means of a Hartree-Fock approximation and exactly diagonalizing the remaining localization problem. We inv…
A nonlinear screening theory is formulated to study the problem of gap formation and its relation to glassy freezing in classical Coulomb glasses. We find that a pseudo-gap ("plasma dip") in a single-particle density of states begins to open already at temperatures comparable to the Coulomb energy. This phenomenon is shown to reflect the emergence of short range correlations in a liquid (plasma) phase, a process which occurs even in the absence of disorder. Glassy ordering emerges when disorder is present, but this occurs only at temperatures more then an order of magnitude lower, which is sho…
The relaxation of the specific heat and the entropy to their equilibrium values is investigated numerically for the three-dimensional Coulomb glass at very low temperatures. The long time relaxation follows a stretched exponential function, $f(t)=f_0\exp[-(t/τ)^β]$, with the exponent $β$ increasing with the temperature. The relaxation time follows an Arrhenius behavior divergence when $T\to 0$. A relation between the specific heat and the entropy in the long time regime is found.
The quantum Coulomb glass model describes disordered interacting electrons on the insulating side of a metal-insulator transition. By taking quantum fluctuations into account it can describe not only the localized limit but also the weakly localized regime. We discuss several possibilities to generalize the concept of Anderson localization to interacting electron systems such as the quantum Coulomb glass and define criteria for localization. The corresponding physical quantities are calculated by numerically exact diagonalization. The results indicate that single-particle excitations close to …
We show that introducing long-range Coulomb interactions immediately lifts the massive ground state degeneracy induced by geometric frustration for electrons on quarter-filled triangular lattices in the classical limit. Important consequences include the stabilization of a stripe-ordered crystalline (global) ground state, but also the emergence of very many low-lying metastable states with amorphous "stripe-glass" spatial structures. Melting of the stripe order thus leads to a frustrated Coulomb liquid at intermediate temperatures, showing remarkably slow (viscous) dynamics, with very long rel…
We investigate the behavior of disordered interacting electrons in the insulating regime. Our study is based on the quantum Coulomb glass model which is obtained from the classical Coulomb glass by adding hopping matrix elements between neighboring sites. We use two different numerical methods, viz. a Hartree-Fock approximation and an exact diagonalization and compare the results for the tunneling density of states and the localization properties in order to determine the range of validity of the Hartree-Fock method. We find that the Hartree-Fock method gives a good approximation for the densi…
Optical measurements of the real and imaginary frequency dependent conductivity of uncompensated n-type silicon are reported. The experiments are done in the quantum limit, $ \hbarω> k_{B}T$, across a broad doping range on the insulating side of the Metal-Insulator transition (MIT). The observed low energy linear frequency dependence shows characteristics consistent with theories of a Coulomb glass, but discrepancies exist in the relative magnitudes of the real and imaginary components. At higher energies we observe a crossover to a quadratic frequency dependence that is sharper than expected …
We study the low temperature phase of the 3D Coulomb glass within a mean field approach which reduces the full problem to an effective single site model with a non-trivial replica structure. We predict a finite glass transition temperature $T_c$, and a glassy low temperature phase characterized by permanent criticality. The latter is shown to assure the saturation of the Efros-Shklovskii Coulomb gap in the density of states. We find this pseudogap to be universal due to a fixed point in Parisi's flow equations. The latter is given a physical interpretation in terms of a dynamical self-similari…
We investigate the lattice Coulomb glass model in three dimensions via Monte Carlo simulations. No evidence for an equilibrium glass phase is found down to very low temperatures, although the correlation length increases rapidly near T=0. A charge-ordered phase (COP) exists at low disorder. The transition to this phase is consistent with the Random Field Ising universality class, which shows that the interaction is effectively screened at moderate temperature. For large disorder, the single-particle density of states near the Coulomb gap satisfies the scaling relation g(e,T)=T^δf(|e|/T) with δ…
The relaxations of conductivity have been studied in the glassy regime of a strongly disordered two-dimensional electron system in Si after a temporary change of carrier density during the waiting time t_w. Two types of response have been observed: a) monotonic, where relaxations exhibit aging, i.e. dependence on history, determined by t_w and temperature; b) nonmonotonic, where a memory of the sample history is lost. The conditions that separate the two regimes have been also determined.
The dynamics of many glassy systems are known to exhibit string-like hopping motions each consisting of a line of particles displacing one and other. By using molecular dynamics simulations of glassy polymers, we show that these motions become highly repetitive back-and-forth motions as temperature decreases and do not necessarily contribute to net displacements. Particle hops which constitute string-like motions are reversed with a high probability, reaching 73% and beyond at low temperature. Structural relaxation rate is then dictated not by a simple particle hopping rate but instead by the …
The phononless hopping conductivity of a disordered system with localized states is studied in a broad range of frequencies by straightforward computer simulations taking into account Coulomb interactions. At sufficiently low temperatures, the conductivity is determined by the zero-phonon absorption of the photon by pairs of states. The laser frequency dependence of the conductivity is examined and compared with the analytical model of Efros and Shklovskii and with recent experimental data obtained on Si:P. The range of parameters is determined, for which the conductivity dependence on photon …
One of the most actively debated issues in the study of the glass transition is whether a mean-field description is a reasonable starting point for understanding experimental glass formers. Although the mean-field theory of the glass transition -- like that of other statistical systems -- is exact when the spatial dimension $d\rightarrow\infty$, the evolution of systems properties with $d$ may not be smooth. Finite-dimensional effects could dramatically change what happens in physical dimensions, $d=2,3$. For standard phase transitions finite-dimensional effects are typically captured by renor…
We show that 1/f noise is produced in a 3D electron glass by charge fluctuations due to electrons hopping between isolated sites and a percolating network at low temperatures. The low frequency noise spectrum goes as ω^{-α} with αslightly larger than 1. This result together with the temperature dependence of αand the noise amplitude are in good agreement with the recent experiments. These results hold true both with a flat, noninteracting density of states and with a density of states that includes Coulomb interactions. In the latter case, the density of states has a Coulomb gap that fills in …
We have implemented a new numerical method to obtain the low-energy many-particle states of the Coulomb glass. First, this method creates an initial set of low-energy states by a hybrid of local search and simulated annealing approaches. Then, systematically investigating the surroundings of the states found, this set is completed. The transition rates between these states are calculated. The connectivity of the corresponding graph is analysed in dependence on temperature and duration of measurement. We study how the formation of clusters is reflected in the specific heat as non-ergodic effect…
We study exchange coupling due to the interelectron Coulomb interaction between two ferromagnetic grains embedded into insulating matrix. This contribution to the exchange interaction complements the contribution due to virtual electron hopping between the grains. We show that the Coulomb and the hopping based exchange interactions are comparable. However, for most system parameters these contributions have opposite signs and compete with each other. In contrast to the hopping based exchange interaction the Coulomb based exchange is inversely proportional to the dielectric constant of the insu…
The existence of an equilibrium glassy phase for charges in a disordered potential with long-range electrostatic interactions has remained controversial for many years. Here we conduct an extensive numerical study of the disorder-temperature phase diagram of the three-dimensional Coulomb glass model using population annealing Monte Carlo to thermalize the system down to extremely low temperatures. Our results strongly suggest that, in addition to a charge order phase, a transition to a glassy phase can be observed, consistent with previous analytical and experimental studies.
We employ Monte Carlo simulations to investigate the two-time density autocorrelation function for the two-dimensional Coulomb glass. We find that the nonequilibrium relaxation properties of this highly correlated disordered system can be described by a full aging scaling ansatz. The scaling exponents are non-universal, and depend on temperature and charge density.
We employ Monte Carlo simulations to study the relaxation properties of the two-dimensional Coulomb glass in disordered semiconductors and the three-dimensional Bose glass in type-II superconductors in the presence of extended linear defects. We investigate the effects of adding non-zero random on-site energies from different distributions on the properties of the correlation-induced Coulomb gap in the density of states (DOS) and on the non-equilibrium aging kinetics highlighted by the density autocorrelation functions. We also probe the sensitivity of the system's equilibrium and non-equilibr…
We reply to the Comment by Mobius and Richter [arXiv:0908.3092, Phys. Rev. Lett. 105, 039701 (2010)] on "Density of States and Critical Behavior of the Coulomb Glass" [arXiv:0805.4640, Phys. Rev. Lett. 102, 067205 (2009)] and address the issues raised with our results on the density of states. In addition, we correct our statements about the random displacement version of the Coulomb glass model where the Wigner crystal is not as robust to disorder as stated. Still, our main result of a lack of a finite-temperature transition in the Coulomb glass remains unchallenged.
We show that the time development of the Coulomb gap in a Coulomb glass can involve very long relaxation times due to electron rearrangement and hopping. We find that an applied magnetic field reduces the rate of electron hopping and, hence, Coulomb gap formation. These results are consistent with recent conductance experiments on thin semiconducting and metallic films.
The dynamics of the 2D Coulomb glass model is investigated by kinetic Monte Carlo simulation. An exponential divergence of the relaxation time signals a zero-temperature freezing transition. At low temperatures the dynamics of the system is glassy. The local charge correlations and the response to perturbations of the local potential show aging. The dynamics of formation of the Coulomb gap is slow and the density of states at the Fermi level decays in time as a power law. The relevance of these findings for recent transport experiments in Anderson-insulating films is pointed out.
Two models involving particles moving by ``hopping'' in disordered media are investigated: I) A model glass-forming liquid is investigated by molecular dynamics under (pseudo-) equilibrium conditions. ``Standard'' results such as mean square displacements, intermediate scattering functions, etc. are reported. At low temperatures hopping is present in the system as indicated by a secondary peak in the distribution of particle displacements during a time interval 't'. The dynamics of the model is analyzed in terms of its potential energy landscape (potential energy as function of the 3N particle…
Aging dynamics in glassy systems is investigated by considering the hopping motion in a rugged energy landscape whose deep minima are characterized by an exponential density of states. In particular we explore the behavior of a generic two-time correlation function Pi(t_w+t,t_w) below the glass transition temperature T_g when both the observation time t and the waiting time t_w become large. We show the occurrence of ordinary scaling behavior, which includes normal aging and subaging, and the possible simultaneous occurrence of generalized scaling behavior. Which situation occurs depends on th…
We have annealed two dimensional lattice model of Coulomb glass using Monte Carlo simulations to obtain the ground state. We have shown that the energy required to create a domain of linear size L in d dimensions is proportional to $L^{d-1}$. Using Imry-Ma arguments given for RFIM, one gets $d_{c}\geq 2$ for Coulomb glass. The investigations in the transition region shows that the domain wall of the metastable state in the charge-ordered phase shifts as disorder is increased to give disordered ground state at higher disorder strength indicating phase coexistence. This coupled with discontinuit…
We present zero-temperature simulations for the single-particle density of states of the Coulomb glass. Our results in three dimensions are consistent with the Efros and Shklovskii prediction for the density of states. Finite-temperature Monte Carlo simulations show no sign of a thermodynamic glass transition down to low temperatures, in disagreement with mean-field theory. Furthermore, the random-displacement formulation of the model undergoes a transition into a distorted Wigner crystal for a surprisingly broad range of the disorder strength.
At low temperatures electron hopping in a three dimensional Coulomb glass produces fluctuations in the single particle density of states and hence in the resistivity. This results in a low frequency resisitivity noise spectrum which goes as (1/f)^(alpha) where alpha is very close to 1. This holds down to extremely low frequencies.
We develop a numerical method, which allows to find pairs of metastable states differing by transition of several electrons. We show that at low temperature these pairs can be treated as local metastable systems that determine low-frequency properties of Coulomb Glass with low external disorder. The contribution of these pairs to low-frequency properties is suppressed when the strength of the external disorder becomes comparable with interaction between neighboring electrons.
We show that the non-equilibrium dynamic in two-dimensional electron glasses close to metal-dielectric transition is dramatically sensitive to electric fields confinement inside the sample, which leads to a nearly thermally activated conductance behavior and a strong non-equilibrium conductance response to the gate voltage, i. e. memory dip in a field dependence of conductance. Theory accounts qualitatively and quantitatively for the universal temperature and field dependencies of memory dip.
We have studied the ground states of two dimensional lattice model of Coulomb Glass via Monte Carlo annealing. Our results show a possibility of existence of a critical disorder (Wc) below which the system is in the charge ordered phase and above it the system is in the disordered phase. We have used finite size scaling to calculate Wc = 0.2413, the critical exponent of magnetization β = 0 indicating discontinuity in magnetization and the critical exponent of correlation length ν = 1.0. The distribution of staggered magnetization for different disorder strengths shows a three peak structure. W…
We explore the stability of far-from-equilibrium metastable states of a three-dimensional Coulomb glass at zero temperature by studying charge avalanches triggered by a slowly varying external electric field. Surprisingly, we identify a sharply defined dynamical ("depinning") phase transition from stationary to nonstationary charge displacement at a critical value of the external electric field. Using particle-conserving dynamics, scale-free system-spanning avalanches are observed only at the critical field. We show that the qualitative features of this depinning transition are completely diff…
We study the hopping conduction in a composite made of straight metallic nanowires randomly and isotropically suspended in an insulator. Uncontrolled donors and acceptors in the insulator lead to random charging of wires and hence finite bare density of states at the Fermi level. Then the Coulomb interactions between electrons of distant wires result in the soft Coulomb gap. At low temperatures the conductivity is due to variable range hopping of electrons between wires and obeys the Efros-Shklovskii (ES) law $\lnσ\propto -(T_{ES}/T)^{1/2}$. We show that $T_{ES} \propto 1/(nL^3)^2$, where $n$ …
We report measurements of the real and imaginary parts of the AC conductivity in the quantum limit, \hbar ω> k_B T of insulating nominally uncompensated n-type silicon. The observed frequency dependence shows evidence for a crossover from interacting Coulomb glass-like behavior at lower energies to non-interacting Fermi glass-like behavior at higher energies across a broad doping range. The crossover is sharper than predicted and cannot be described by any existing theories. Despite this, the measured crossover energy can be compared to the theoretically predicted Coulomb interaction energy an…
In a recent numerical investigation of the Coulomb glass, Surer et al. [Phys. Rev. Lett. 102, 067205 (2009)] concluded that their simulation results are consistent with the Efros Shklovskii prediction for the density of states in the three-dimensional case. Here, we show that this statement has no relevance concerning the problem of the asymptotic behavior in the Coulomb gap since it is based on unjustified assumptions. Moreover, for the random-displacement Coulomb glass model, we demonstrate that a part of the density of states data by Surer et al. erroneously exhibit a broad gap. This is rel…
In granular superconductors, individual grains can contain bound Cooper pairs while the system as a whole is strongly insulating. In such cases the conductivity is determined by electron hopping between localized states in individual grains. Here we examine a model of hopping conductivity in such an insulating granular superconductor, where disorder is assumed to be provided by random charges embedded in the insulating gaps between grains. We use computer simulations to calculate the single-electron and electron pair density of states at different values of the superconducting gap $Δ$, and we …
We study an experimentally feasible system of strongly correlated bosons with random hoppings, described by the infinite-range Bose-Hubbard model on a lattice with hopping integrals given by independent random variables of Gaussian distribution with non-zero mean. We solve this quantum model in the thermodynamic limit, employing the replica method and the Trotter-Suzuki formula. We find and describe a superglass phase that emerges at the interface between glass and superfluid phases. Both glassy and long-range orderings are present in the superglass and compete with each other, as revealed by …
We study the hopping conductivity in a composite made of Gaussian coils of flexible metallic wires randomly and isotropically suspended in an insulator at such concentrations that the spheres containing each wire overlap. Uncontrolled donors and acceptors in the insulator lead to random charging of wires and, hence, to a finite density of states (DOS) at the Fermi level. Then the Coulomb interactions between electrons of distant wires result in the soft Coulomb gap. At low temperatures the conductivity is due to variable range hopping of electrons between wires and obeys the Efros-Shklovskii (…
We consider the combined influence of disorder, electron-electron interactions and quantum hopping on the properties of electronic systems in a localized phase, approaching an insulator-metal transition. The generic models in this regime are the quantum Coulomb glass and its generalization to electrons with spin. After introducing these models we explain our computational method, the Hartree-Fock based diagonalization. We then discuss the conductance and compare spinless fermions and electrons. It turns out that spin degrees of freedom do not play an essential role in the systems considered. F…
We study numerically the configuration space at low energy of electron glasses. We consider systems with Coulomb interactions, short-range interactions and no interactions. First, we calculate the integrated density of configurations as a function of energy. At a given energy, this density is smaller for Coulomb glasses than for short-range systems, which in turn is smaller than for non-interacting systems. We analyze how the site occupancy varies with the number of configurations. Through this study we estimate the number of particles involved in a typical low-energy transition between config…
The temperature dependence of the electrical resistivity in insulator systems with a Coulomb gap in the density of states is expressed by a very simple function which coincides with the Efros-Shklovskii T^(-1/2)result, at temperatures lower than some value Tlim. Above this limit it consists of the product of the Mott T^(-1/4) exponential with another one like a simply thermally activation process. It fits well several experimental results reported as having a crossover between the Efros-Shklovskii and Mott regimes, and allows the determination of the gap parameters even in experiments that do …
In this work we report on a loss of ergodicity in a simple hopping model, motivated by the Hubbard Hamiltonian, of a many body quantum system at zero temperature, quantized in Euclidean time. We show that this quantum system may lose ergodicity at high densities on a large lattice, as a result of both Pauli exclusion and strong Coulomb repulsion. In particular we study particle hopping susceptibilities and the tendency towards particle localization. It is found that the appearance and existence of quantum phase transitions in this model, in the case of high density and strong Coulomb repulsion…
We vary the amplitude of the long-range Coulomb forces within a classical potential describing a model silica glass and study the consequences on the structure and dynamics of the glass, via molecular dynamics simulations. This model allows us to follow the variation of specific features such as the First Sharp Diffraction Peak and the Boson Peak in a system going continuously from a fragile (no Coulomb forces) to a strong (with Coulomb forces) glass. In particular we show that the characteristic features of a strong glass (existence of medium range order, bell-shaped ring size distribution, s…
We have extended our supercomputer-enabled Monte Carlo simulations of hopping transport in completely disordered 2D conductors to the case of substantial electron-electron Coulomb interaction. Such interaction may not only suppress the average value of hopping current, but also affect its fluctuations rather substantially. In particular, the spectral density $S_I (f)$ of current fluctuations exhibits, at sufficiently low frequencies, a $1/f$-like increase which approximately follows the Hooge scaling, even at vanishing temperature. At higher $f$, there is a crossover to a broad range of freque…
In a film with large dielectric constant $κ$ the electric field of an electron spreads inside the film before exiting the film at large distances of order of $κd$ ($d$ is the film width). This leads to the logarithmic Coulomb repulsion between electrons and modifies the shape of the Coulomb gap in the density of localized states in a doped film. As a result the variable range hopping conductivity in such a film has a peculiar temperature dependence, where the domain of the $\ln σ(T) \propto (T_0/T)^{p}$ dependence, with the index $p \simeq 0.7$, is sandwiched between the two domains with $p = …
We present numerical evidence using Monte Carlo simulations of finite-temperature phase transition in two dimensional Coulomb Glass lattice model with random site energies at half-filling. For the disorder strengths ($W$) studied in this paper, we find the existence of charge-ordered phase (COP) below the critical temperature ($T_{c}(W)$). Also, the probability distribution of staggered magnetization calculated at each W shows a two-peak structure at their respective critical temperature. Thus the phase transition from fluid to COP as a function of temperature is second order for all $W$. We f…
Qualitatively new transport mechanism is suggested for hopping of carriers according to which the variable-range hopping (VRH) arises from the resonant tunneling between transport states brought into resonance by Coulomb potentials produced by surrounding sites with fluctuating occupations. A semiquantitative description of the hopping transport is given based on the assumption that fluctuations of energies of hopping sites have spectral density 1/f.
We study spin glass behavior in a random Ising Coulomb antiferromagnet in two and three dimensions using Monte Carlo simulations. In two dimensions, we find a transition at zero temperature with critical exponents consistent with those of the Edwards Anderson model, though with large uncertainties. In three dimensions, evidence for a finite-temperature transition, as occurs in the Edwards-Anderson model, is rather weak. This may indicate that the sizes are too small to probe the asymptotic critical behavior, or possibly that the universality class is different from that of the Edwards-Anderson…
We present an alternate solution of a Gaussian spin-glass model with infinite ranged interactions and a global spherical constraint at zero magnetic field. The replicated spin-glass Hamiltonian is mapped onto a Coulomb gas of logarithmically interacting particles confined by a logarithmic single particle potential. The precise free energy is obtained by analyzing the Painlevé $τ^{IV} [n]$ function in the $n\to 0$ limit. The large $N$ thermodynamics exactly recovers that of Kosterlitz, Thouless and Jones \cite{ktjonesPRL}. It is hoped that the approach here can be extended to apply to systems b…
Motivated by evidence of local electron-electron attraction in experiments on disordered insulating films, we propose a new two-component Coulomb glass model that combines strong disorder and long-range Coulomb repulsion with the additional possibility of local pockets of a short-range inter-electron attraction. This model hosts a variety of interesting phenomena, in particular a crucial modification of the Coulomb gap previously believed to be universal. Tuning the short-range interaction to be repulsive, we find non-monotonic humps in the density of states within the Coulomb gap. We further …
In this paper, we analyze the dynamics of the Coulomb Glass lattice model in three dimensions near a local equilibrium state by using mean-field approximations. We specifically focus on understanding the role of localization length ($ξ$) and the temperature ($T$) in the regime where the system is not far from equilibrium. We use the eigenvalue distribution of the dynamical matrix to characterize relaxation laws as a function of localization length at low temperatures. The variation of the minimum eigenvalue of the dynamical matrix with temperature and localization length is discussed numerical…
In this paper, we have studied the three dimensional Coulomb glass lattice model at half-filling using Monte Carlo Simulations. Annealing of the system shows a second-order transition from paramagnetic to charge-ordered phase for zero as well as small disorders. We have also calculated the critical exponents and transition temperature using a finite sizing scaling approach. The Monte Carlo simulation is done using the Metropolis algorithm, which allowed us to study larger lattice sizes. The transition temperature and the critical exponents at zero disorder matched the previous studies within n…
We consider an electron system under conditions of strong Anderson localization, taking into account interelectron long-range Coulomb repulsion. We have established that with the electron density going to zero the Coulomb interaction brings the arrangement of the Anderson localized electrons closer and closer to an ideal (Wigner) crystal lattice, provided the temperature is sufficiently low and the dimension of the system is > 1. The ordering occurs despite the fact that a random spread of the energy levels of the localized one-electron states, exceeding the mean Coulomb energy per electron, r…
