We investigate the statistical equilibrium of Co in the atmospheres of cool stars, and the influence of NLTE and HFS (hyperfine splitting) on the formation of Co lines and abundances. Significant departures from LTE level populations are found for Co I, also number densities of excited states in Co II differ from LTE at low metallicity. The NLTE abundance of Co in solar photosphere is 4.95 +/- 0.04 dex, which is in agreement with that in C I meteorites within the combined uncertainties. The spectral lines of Co I were calculated using the results of recent measurements of hyperfine interaction constants by UV Fourier transform spectrometry. For Co II, the first laboratory measurements of hyperfine structure splitting A and B factors were performed. A differential abundance analysis of Co is carried out for 18 stars in the metallicity range -3.12 < [Fe/H] < 0. The abundances are derived by method of spectrum synthesis. At low [Fe/H], NLTE abundance corrections for Co I lines are as large as +0.6 >... +0.8 dex. Thus, LTE abundances of Co in metal-poor stars are severely underestimated. The stellar NLTE abundances determined from the single UV line of Co II are lower by ~0.5-0.6 dex. The discrepancy might be attributed to possible blends that have not been accounted for in the solar Co II line and its erroneous oscillator strength. The increasing [Co/Fe] trend in metal-poor stars, as calculated from the Co I lines under NLTE, can be explained if Co is overproduced relative to Fe in massive stars. The models of galactic chemical evolution are wholly inadequate to describe this trend suggesting that the problem is in SN yields.
We present a grid of computed non-local thermodynamic equilibrium (NLTE) equivalent widths (EW) and NLTE abundance corrections for four Ba II lines: 4554, 5853, 6141, and 6496 A. The grid can be useful in deriving the NLTE barium abundance in stars having parameters in the following ranges: effective temperature from 4000 K to 6500 K, surface gravity log g from 0 to 5, microturbulent velocity 0 km s^-1 to 3 km s^-1, metallicity [Fe/H] from -2 to +0.5, and [Ba/Fe] from -0.4 to +0.6. The NLTE abundance can be either derived by EW interpolation (using the observed Ba II line EW) or by using the N…
Non-local thermodynamic equilibrium (NLTE) line formation for neutral and singly-ionized iron is considered through a range of stellar parameters characteristic of cool stars. A comprehensive model atom for Fe I and Fe II is presented. Our NLTE calculations support the earlier conclusions that the statistical equilibrium (SE) of Fe I shows an underpopulation of Fe I terms. However, the inclusion of the predicted high-excitation levels of Fe I in our model atom leads to a substantial decrease in the departures from LTE. As a test and first application of the Fe I/II model atom, iron abundances …
For the well studied halo star HD 122563 and the four stars in the globular cluster NGC 6397, we determine NLTE abundances of iron using classical plane-parallel model atmospheres. Each star reveals a discrepancy in abundances between the Fe I lines arising from the ground state and the other Fe I lines, in qualitative agreement with the 3D-LTE line formation predictions, however, the magnitude of the observed effect is a factor of 2 smaller compared with the predicted one. When ignoring the Fe I low-excitation lines, the NLTE abundances from the two ionization stages, Fe I and Fe II, are cons…
Observational constraints on the origin of the elements. VII. NLTE analysis of Y II lines in spectra of cool stars and implications for Y as a Galactic chemical clock
The new version of TLUSTY allows for the calculation of restricted NLTE in cool stars using pre-calculated opacity tables. We demonstrate that TLUSTY gives consistent results with MULTI, a well-tested code for NLTE in cool stars. We use TLUSTY to perform LTE and a series of NLTE calculations of Na, Mg, K and Ca using all combinations of 1, 2, 3 and the 4 elements mentioned above simultaneously in NLTE. In this work we take into account how departures from LTE in one element can affect others through changes in the opacities due to NLTE. We find that atomic Mg, which provides strong UV opacity,…
We study the influence of X-rays on the wind structure of selected O stars. For this purpose we use our non-local thermodynamic equilibrium (NLTE) wind code with inclusion of additional artificial source of X-rays, assumed to originate in the wind shocks. We show that the influence of shock X-ray emission on wind mass-loss rate is relatively small. Wind terminal velocity may be slightly influenced by the presence of strong X-ray sources, especially for stars cooler than Teff < 35 000 K. We discuss the origin of the Lx/L \sim 10^-7 relation. For stars with thick wind this relation can be explai…
We construct a comprehensive model atom for TiI-II using more than 3600 measured and predicted energy levels of TiI and 1800 energy levels of TiII, and quantum mechanical photoionisation cross-sections. Non-local thermodynamical equilibrium (NLTE) line formation for the two ions of titanium is treated through a wide range of spectral types from A to K, including metal-poor stars with [Fe/H] down to -2.6 dex. NLTE leads to systematically depleted total absorption in the TiI lines and to positive abundance corrections. The magnitude of NLTE abundance corrections is smaller compared to the availa…
The interpretation of water lines in red supergiant stellar atmospheres has been much debated over the past decade. The introduction of the so-called MOLspheres to account for near-infrared "extra" absorption has been controversial. We propose that non-LTE effects should be taken into account before considering any extra-photospheric contribution. After a brief introduction on the radiative transfer treatment and the inadequacy of classical treatments in the case of large-scale systems such as molecules, we present a new code, based on preconditioned Krylov subspace methods. Preliminary result…
X-rays/EUV radiation emitted from wind-embedded shocks in hot, massive stars can affect the ionization balance in their outer atmospheres, and can be the mechanism responsible for the production of highly ionized species. To allow for these processes in the context of spectral analysis, we have implemented such emission into our unified, NLTE model atmosphere/spectrum synthesis code FASTWIND. The shock structure and corresponding emission is calculated as a function of user-supplied parameters. We account for a temperature and density stratification inside the post-shock cooling zones, calcula…
It is generally accepted that the atmospheres of cool/lukewarm stars of spectral types A and later are described well by LTE model atmospheres, while the O-type stars require a detailed treatment of NLTE effects. Here model atmosphere structures, spectral energy distributions and synthetic spectra computed with ATLAS9/SYNTHE and TLUSTY/SYNSPEC, and results from a hybrid method combining LTE atmospheres and NLTE line-formation with DETAIL/SURFACE are compared. Their ability to reproduce observations for effective temperatures between 15000 and 35000 K are verified. Strengths and weaknesses of t…
Aiming at testing the validity of our magnesium atomic model and investigating the effects of non-local thermodynamical equilibrium (NLTE) on the formation of the H-band neutral magnesium lines, we derive the differential Mg abundances from selected transitions for 13 stars either adopting or relaxing the assumption of local thermodynamical equilibrium (LTE). Our analysis is based on high-resolution and high signal-to-noise ratio H-band spectra from the Apache Point Observatory Galactic Evolution Experiment (APOGEE) and optical spectra from several instruments. The absolute differences between…
Context. Obtaining precise stellar and wind properties and abundance patterns of massive stars is crucial to understanding their nature and interactions with their environments, as well as to constrain their evolutionary paths and end-products. Aims. To enable higher versatility and precision of the complete UV to optical range, we improve our NLTE atmosphere and spectrum synthesis code FASTWIND. We also aim to obtain an advanced description of X-ray emission from wind-embedded shocks. Methods. We include a detailed comoving frame radiative transfer for the essential frequency range, but still…
A comprehensive model atom was developed for Si I-II-III using the most up-to-date atomic data available so far. Based on the non-local thermodynamic equilibrium (non-LTE = NLTE) line formation for Si I, Si II, and Si III and high-resolution observed spectra, we determined the NLTE abundances for a sample of nine unevolved A9 to B3-type stars with well determined atmospheric parameters. For each star, NLTE reduces substantially the line-to-line scatter for Si II compared with the LTE case and leads to consistent mean abundances from lines of different ionisation stages. In the hottest star of …
(Abridged) We characterize a series of neutral vanadium atomic absorption lines in the 800--910nm wavelength region of high signal-to-noise, high-resolution, telluric-corrected M-dwarf spectra from the CARMENES survey. Many of these lines are prominent and exhibit a distinctive broad and flat-bottom shape, which is a result of hyperfine structure (HFS). We investigate the potential and implications of these HFS split lines for abundance analysis of cool stars. With standard spectral synthesis routines, as provided by the spectroscopy software iSpec and the latest atomic data (including HFS) av…
One of the most important factors in determining the stellar lithium abundance is the effective temperature. In a previous study by the authors, new effective temperatures Teff for sixteen metal-poor halo dwarfs were derived using a local thermodynamic equilibrium (LTE) description of the formation of Fe lines. This new Teff scale reinforced the discrepancy. For six of the stars from our previous study we calculate revised temperatures using a non-local thermodynamic equilibrium (NLTE) approach. These are then used to derive a new mean primordial lithium abundance in an attempt to solve the li…
The non-local thermodynamic equilibrium (NLTE) line formation of neutral boron in the atmospheres of cool stars are investigated. Our results confirm that NLTE effects for the B I resonance lines, which are due to a combination of overionization and optical pumping effects, are most important for hot, metalpoor, and low-gravity stars; however, the amplitude of departures from LTE found by this work are smaller than that of previous studies. In addition, our calculation shows that the line formation of B I will get closer to LTE if the strength of collisions with neutral hydrogen increases, whi…
Current three-dimensional (3D) hydrodynamical model atmospheres together with NLTE spectrum synthesis, permit to derive reliable atomic and isotopic chemical abundances from high-resolution stellar spectra. Not much is known about the presence of the fragile 6Li isotope in evolved solar-metallicity RGB stars, not to mention its production in magnetically active targets like HD123351. From fits of the observed CFHT spectrum with synthetic line profiles based on 1D and 3D model atmospheres, we seek to estimate the abundance of the 6Li isotope and to place constraints on its origin. We derive A(L…
Accurate spectroscopic lithium abundances are essential in addressing a variety of open questions, such as the origin of a uniform lithium content in the atmospheres of metal-poor stars (Spite plateau) or the existence of a correlation between the properties of extra-solar planetary systems and the lithium abundance of their host stars. We have developed a tool that allows the user to improve the accuracy of standard lithium abundance determinations based on 1D model atmospheres and the assumption of Local Thermodynamic Equilibrium (LTE) by applying corrections that account for hydrodynamic (3…
We investigate departures from LTE in the line formation of Fe for a number of well-studied late-type stars in different evolutionary stages. A new model of Fe atom was constructed from the most up-to-date theoretical and experimental atomic data available so far. Non-local thermodynamic equilibrium (NLTE) line formation calculations for Fe were performed using 1D hydrostatic MARCS and MAFAGS-OS model atmospheres, as well as the spatial and temporal average stratifications from full 3D hydrodynamical simulations of stellar convection computed using the Stagger code. It is shown that the Fe I/F…
An analysis of the CH molecule in non-local thermodynamic equilibrium (NLTE) is performed for the physical conditions of cool stellar atmospheres typical of red giants (log g = 2.0, Teff = 4500 K) and the Sun. The aim of the present work is to explore whether the G-band of the CH molecule, which is commonly used in abundance diagnostics of Carbon-Enhanced Metal-Poor (CEMP) stars, is sensitive to NLTE effects. LTE and NLTE theoretical spectra are computed with the MULTI code. We use one-dimensional (1D) LTE hydrostatic MARCS model atmospheres with parameters representing eleven red giant stars …
Non-local thermodynamic equilibrium (NLTE) effects in diagnostically important solar Fe I lines are important due to the strong sensitivity of Fe I to ionizing UV radiation, which may lead to a considerable under-population of the Fe I levels in the solar atmosphere and, therefore, to a sizeable weakening of Fe I lines. Such NLTE effects may be intensified or weakened by horizontal radiative transfer (RT) in a three-dimensionally (3-D) structured atmosphere. We analyze the influence of horizontal RT on commonly used Fe I lines in a snapshot of a 3-D radiation magneto-hydrodynamic (MHD) simulat…
The present work proposes a self-consistent reduced-order NLTE kinetic model for radiating plasmas such as are found in the outer layers of stellar atmospheres. Starting from the most up-to-date set of ab-initio and experimental data, the highly complex collisional-radiative kinetic mechanism is simplified by lumping the bound energy states in groups. Different grouping strategies are investigated, such as uniform and Maxwell-Boltzmann. The reduced set of governing equations for the material gas and the radiation field is obtained based on a moment method. Applications consider the steady flow…
It is well known that cool star atmospheres depart from local thermodynamic equilibrium (LTE). Accurate abundance determination requires taking those effects into account, but the necessary non-LTE calculations are often lacking. Our goal is to provide detailed estimates of NLTE effects for FGK type stars for all spectral lines from the ultraviolet to the infrared that are potentially useful as abundance diagnostics. The first paper in this series focusses on the light elements Na, Mg and Al. The code PySME is used to compute curves-of-growth for 2158 MARCS model atmospheres in a wide paramete…
Non-local thermodynamic equilibrium (non-LTE) line formation for Ca I-Ca II, Ti I-Ti II, and Fe I-Fe II is considered in model atmospheres of giant stars with an effective temperature of 4000 K $\le$ Teff $\le$ 5000 K and a metal abundance of -4 $\le$ [Fe/H] $\le$ 0. The departures from LTE are analyzed depending on atmospheric parameters. We present the non-LTE abundance corrections for 28 lines of Ca I, 42 lines of Ti I, 54 lines of Ti II, and 262 lines of Fe I and a three-dimensional interpolation code to obtain the non-LTE correction online (http://spectrum.inasan.ru/nLTE/) for an individu…
Magnesium abundances of cool stars with different metallicities are important for understanding the galactic chemical evolution. This study tests atomic data used in stellar magnesium abundance analyses. We evaluate non-local thermodynamical equilibrium (NLTE) line formation for Mg I using the most up-to-date theoretical and experimental atomic data available so far and check the Mg abundances from individual lines in the Sun, four well studied A-type stars, and three reference metal-poor stars. With the adopted gf-values, NLTE abundances derived from the Mg I 4703 A, 5528 A, and Mg Ib lines a…
Aluminium plays a key role in studies of the chemical enrichment of the Galaxy and of globular clusters. However, strong deviations from LTE (non-LTE) are known to significantly affect the inferred abundances in giant and metal-poor stars. We present NLTE modeling of aluminium using recent and accurate atomic data, in particular utilizing new transition rates for collisions with hydrogen atoms, without the need for any astrophysically calibrated parameters. For the first time, we perform 3D NLTE modeling of aluminium lines in the solar spectrum. We also compute and make available extensive gri…
We investigate the role of hydrogen collisions in NLTE spectral line synthesis, and introduce a new general empirical recipe to determine inelastic charge transfer (CT) and bound-bound hydrogen collisional rates. This recipe is based on fitting the energy functional dependence of published quantum collisional rate coefficients of several neutral elements (BeI, NaI, MgI, AlI, SiI and CaI) using simple polynomial equations. We perform thorough NLTE abundance calculation tests using our method for four different atoms, Na, Mg, Al and Si, for a broad range of stellar parameters. We then compare th…
Iron plays a crucial role in studies of late-type stars. In their atmospheres, Fe I is the minority species and its lines are subject to the departures from LTE. In contrast, one believes that LTE is a realistic approximation for Fe II lines. The main source of the uncertainties in the non-LTE (NLTE) calculations for cool atmospheres is a treatment of inelastic collisions with hydrogen atoms. We investigate the effect of Fe I + H I and Fe II + H I collisions and their different treatment on the Fe I/Fe II ionisation equilibrium and Fe abundance determinations for Galactic halo benchmark stars …
The Space Telescope Imaging Spectrograph (STIS) has measured the spectral energy distributions (SEDs) for several stars of types O, B, A, F, and G. These absolute fluxes from the CALSPEC database are fit with a new spectral grid computed from the ATLAS-APOGEE ATLAS9 model atmosphere database using a chi-square minimization technique in four parameters. The quality of the fits are compared for complete LTE grids by Castelli & Kurucz (CK04) and our new comprehensive LTE grid (BOSZ). For the cooler stars, the fits with the MARCS LTE grid are also evaluated, while the hottest stars are also fit wi…
For studies of Galactic evolution, the accurate characterization of stars in terms of their evolutionary stage and population membership is of fundamental importance. A standard approach relies on extracting this information from stellar evolution models but requires the effective temperature, surface gravity, and metallicity of a star obtained by independent means. In previous work, we determined accurate effective temperatures and non-LTE logg and [Fe/H] (NLTE-Opt) for a large sample of metal-poor stars, -3<[Fe/H]<-0.5, selected from the RAVE survey. As a continuation of that work, we derive…
In this paper, we aim to derive high-precision alpha-element abundances using CRIRES high-resolution IR spectra of 72 cool M giants of the inner Galactic bulge. Silicon, magnesium, and calcium abundances were determined by fitting a synthetic spectrum for each star. We also incorporated recent theoretical data into our spectroscopic analysis (i.e. updated K-band line list, better broadening parameter estimation, non-local thermodynamic equilibrium (NLTE) corrections). We compare these inner bulge alpha abundance trends with those of solar neighbourhood stars observed with IGRINS using the same…
We redetermine the abundances of all iron group nuclei in the Sun, based on neutral and singly-ionised lines of Sc, Ti, V, Mn, Fe, Co and Ni in the solar spectrum. We employ a realistic 3D hydrodynamic model solar atmosphere, corrections for departures from local thermodynamic equilibrium (NLTE), stringent line selection procedures and high quality observational data. We have scoured the literature for the best quality oscillator strengths, hyperfine constants and isotopic separations available for our chosen lines. We find $\log ε_\mathrm{Sc}=3.16\pm0.04$, $\log ε_\mathrm{Ti}=4.93\pm0.04$, $\…
OH is an important molecule in the H2O chemistry and the cooling budget of star-forming regions. The goal of the Herschel key program `Water in Star-forming regions with Herschel' (WISH) is to study H2O and related species during protostellar evolution. Our aim in this letter is to assess the origin of the OH emission from star-forming regions and constrain the properties of the emitting gas. High-resolution observations of the OH 2Pi1/2 J = 3/2-1/2 triplet at 1837.8 GHz (163.1 micron) towards the high-mass star-forming region W3 IRS 5 with the Heterodyne Instrument for the Far-Infrared (HIFI)…
