We use linear-response theory to evaluate the frequency-dependent conductivity of a system subject to a continuous quantum measurement of the current. Application of this formalism to graphene yields a consistent framework for discussing nonuniversal values of its minimal conductivity.
The thermal conductivity of graphene nanoribbons (layer from 1 to 8 atomic planes) is investigated by using the nonequilibrium molecular dynamics method. We present that the room-temperature thermal conductivity decays monotonically with the number of the layers in few-layer graphene. The superiority of zigzag graphene in thermal conductivity is only available in high temperature region and disappears in multi-layer case. It is explained that the phonon spectral shrink in high frequency induces the change of thermal conductivity. It is also reported that single-layer graphene has better ballis…
We consider the tight-binding approximation for the description of energy bands of graphene, together with the standard Boltzmann's transport equation and constant relaxation time, an expression for the conductivity was obtained. We predicted strong nonlinear effects in graphene which may be useful for high frequency generation.
The analysis of Current-voltage characteristic and Ampere-Gauss characteristic for graphene with Hubbard interaction was carried out depending on frequency of external variable field and magnetic field. The regions of the absolute negative conductivity were found.
Transport properties of irradiated graphene (electrical conductivity and mobility) are numerically investigated using the real-space Kubo formalism. A micrometer-sized system consisting of millions of atoms with nanopores of various sizes and concentrations is described. Electrical conductivity and mobility as a function of carrier (hole) density are calculated to provide possible comparisons with experiments.
Disordered Fermi-Dirac distributions are used to model, within a straightforward and essentially phenomenological Boltzmann equation approach, the electron/hole transport across graphene puddles. We establish, with striking experimental support, a functional relationship between the graphene minimum conductivity, the mobility in the Boltzmann regime, and the steepness of the conductivity parabolic profile usually observed through gate-voltage scanning around the charge neutral point.
Using the Landauer formula approach, it is proven that minimal conductivity of order of $e^{2}/h$ found experimentally in bilayer graphene is its intrinsic property. For the case of ideal crystals, the conductivity turns our to be equal to $e^{2}/2h$ per valley per spin. A zero-temperature shot noise in bilayer graphene is considered and the Fano factor is calculated. Its value $1-2/π$ is close to the value 1/3 found earlier for the single-layer graphene.
We study thermal transport in folded graphene nanoribbons using molecular dynamics simulations and the non-equilibrium Green's function method. It is found that the thermal conductivity of flat graphene nanoribbons can be modulated by folding and changing interlayer couplings. The analysis of transmission reveals that the reduction of thermal conductivity is due to scattering of low frequency phonons by the folds. Our results suggest that folding can be utilized in the modulation of thermal transport properties in graphene and other two dimensional materials.
Using non-equilibrium molecular dynamics method(NEMD), we have found that the thermal conductivity of multilayer graphene nanoribbons monotonously decreases with the increase of the number of layers, such behavior can be attributed to the phonon resonance effect of out-of-plane phonon modes. The reduction of thermal conductivity is found to be proportional to the layer size, which is caused by the increase of phonon resonance. Our results are in agreement with recent experiment on dimensional evolution of thermal conductivity in few layer graphene.
In this study, the Optical conductivity of substitutionary doped graphene is investigated in presence of the Rashba spin orbit coupling (RSOC). Calculations have been performed within the coherent potential approximation (CPA) beyond the Dirac cone approximation. Results of the current study demonstrate that the optical conductivity is increased by increasing the RSOC strength. Meanwhile it was observed that the anisotropy of the band energy results in a considerable anisotropic optical conductivity (AOC) in monolayer graphene. The sign and magnitude of this anisotropic conductivity was shown …
The minimum conductivity value as well as the linear dependence of conductivity on the charge density near the Dirac point in single and doublelayer graphene is derived from the energy-time uncertainty principle applied to ballistic charge carriers.
We address the tunneling current in a graphene-hBN-graphene heterostructure as function of the twisting between the crystals. The twisting induces a modulation of the hopping amplitude between the graphene layers, that provides the extra momentum necessary to satisfy momentum and energy conservation and to activate coherent tunneling between the graphene electrodes. Conservation rules limit the tunneling to states with wavevectors lying at the conic curves defined by the intersection of two Dirac cones shifted in momentum and energy. There is a critical voltage where the intersection is a stra…
Conductivity of monolayer and two-layer graphene is considered with due regard for mutual drag of band electrons and holes. Search of contribution of the drag in conductivity shows that this effect can sufficiently influence on mobility of carriers, which belong to different groups and have different drift velocities. In two-layer system the mutual drag can even change the di-rection of partial current in separate layer.
In the recent paper [arXiv:0802.2216, 15 Feb 2008], Kashuba argued that the intrinsic conductivity of graphene independent of temperature originated in strong electron-hole scattering. We propose a much more explicit derivation based on a scaling theory approach. We also give an explanation of a rapid increase in graphene conductivity caused by applied gate voltage.
Using the linearized Boltzmann transport equation and perturbation theory, we analyze the reduction in the intrinsic thermal conductivity of few-layer graphene sheets accounting for all possible three-phonon scattering events. Even with weak coupling between layers, a significant reduction in the thermal conductivity of the out-of-plane acoustic modes is apparent. The main effect of this weak coupling is to open many new three-phonon scattering channels that are otherwise absent in graphene. However, reflection symmetry is only weakly broken with the addition of multiple layers, and ZA phonons…
We theoretically study the population inversion and negative dynamic conductivity in intrinsic graphene in the terahertz (THz) frequency range upon pulse photoexcitation with near-/mid-infrared wavelength. The threshold pulse energy required for the population inversion and negative dynamic conductivity can be orders-of-magnitude lower when the pulse photon energy is lower, due to the inverse proportionality of the photoexcited carrier concentration to the pulse photon energy and to the weaker carrier heating. We also investigate the dependence of the dynamic conductivity on the momentum relax…
The thermal conductivity of doped graphene flake of finite size is investigated with emphasis on the influence of mass of substituting atoms on this property. It is shown that the graphene doping by small concentrations of relatively heavy atoms results in a disproportionately impressive drop of lattice thermal conductivity.
We develop the theory of heat conductivity in supported graphene, accounting for coherent phonon scattering on disorder induced by an amorphous substrate. We derive spectra for in-plane and out-of-plane phonons in the framework of Green's function approach. The energetic parameters of the theory are obtained using the molecular dynamics simulations for graphene on SiO$_2$ substrate. The heat conductivity is calculated by the Boltzmann transport equation. We find that the interaction with the substrate drastically reduces the phonon lifetime and completely suppresses the contribution of ZA phon…
We analyze numerically the thermal conductivity of carbon nanoribbons with ideal and rough edges. We demonstrate that edge disorder can lead to a suppression of thermal conductivity by several orders of magnitude. This effect is associated with the edge-induced Anderson localization and suppression of the phonon transport, and it becomes more pronounced for longer nanoribbons and low temperatures.
We study the effect of electron-electron interactions in the optical conductivity of graphene under applied bias and derive a generalization of Elliot's formula, commonly used for semiconductors, for the optical intensity. We show that {\it excitonic resonances} are responsible for several features of the experimentally measured mid-infrared response of graphene such as the increase of the conductivity beyond the "universal" value above the Fermi blocked regime, the broadening of the absorption at the threshold, and the decrease of the optical conductivity at higher frequencies. Our results ar…
We study the effect of disordered ripples on the conductivity of monolayer graphene flakes. We calculate the relaxation times and the Boltzmann conductivities associated with two mechanisms. First, we study the conductivity correction due to an external in-plane magnetic field $B_\parallel$. Due to the irregular local curvature found at graphene sheets deposited over a substrate, $B_\parallel$ can be mapped into an effective random magnetic field perpendicular to the graphene surface. Second, we study the electron momentum relaxation due to intrinsic pseudo magnetic fields originated from defo…
By using non-equilibrium molecular dynamics simulations(NEMD), the modulation on temperature dependence of thermal conductivity of graphene phononic crystals (GPnCs) are investigated. It is found that the temperature dependence of thermal conductivity of GPnCs follows $T^{-α}$ behavior. The power exponents ($α$) can be efficiently tuned by changing the characteristic size of GPnCs. The phonon participation ratio spectra and dispersion relation reveal that the long-range phonon modes are more affected in GPnCs with larger size of holes ($L_0$). Our results suggest that constructing GPnCs is an …
We investigate optical transitions of non-interacting electron systems consisting of two symmetric energy bands touching each other at the Fermi energy (e.g. graphene at half filling). Optical conductivity is obtained using Kubo formula at zero temperature. We show that for particles whose pseudospin direction is determined solely by the direction of their momentum, the optical conductivity has power law frequency dependence with the exponent $(d-2)/z$ where $d$ is the dimension of the system and $z$ is the dynamical exponent. According to our result two-dimensional systems with the above pseu…
Graphene has a high intrinsic thermal conductivity and a high electron mobility. The thermal conductivity of graphene can be significantly reduced when different carbon isotopes are mixed, which can enhance the performance of thermoelectric devices. Here we compare the thermal conductivities of isotopic c12/c13 random mixes with isotope superlattices with periods ranging from 46 to 225 nm. Raman Opto-Thermal conductivity measurements of these superlattice structures show an approximately 50% reduction in thermal conductivity compared to pristine c12 graphene. This average reduction is similar …
Synthesis of multilayer graphene on copper wires by a chemical vapor deposition method is reported. After copper etching, the multilayer tube collapses forming stripes of graphitic films, their electrical conductance as a function of temperature indicate a semiconductor-like behavior. Using the multilayer graphene stripes, a cross junction is built and owing to its electrical behavior we propose that a tunneling process exists in the device.
An exact solution is obtained for the electromagnetic field due to an electric current in the presence of a surface conductivity model of graphene. The graphene is represented by an infinitesimally-thin, local and isotropic two-sided conductivity surface. The field is obtained in terms of dyadic Green's functions represented as Sommerfeld integrals. The solution of plane-wave reflection and transmission is presented, and surface wave propagation along graphene is studied via the poles of the Sommerfeld integrals. For isolated graphene characterized by complex surface conductivity, a proper tra…
We study the effect of SiC substrate on thermal conductivity of epitaxial graphene nanoribbons (GNRs) using the nonequilibrium molecular dynamics method. We show that the substrate has strong interaction with single-layer GNRs during the thermal transport, which largely reduces the thermal conductivity. The thermal conductivity characteristics of suspended GNRs are well preserved in the second GNR layers of bilayer GNR, which has a weak van der Waals interaction with the underlying structures. The out-of-plane phonon mode is found to play a critical role on the thermal conductivity variation o…
We theoretically reveal a new mechanism of light amplification in graphene under the conditions of interband population inversion. It is enabled by the indirect interband transitions, with the photon emission preceded or followed by the scattering on disorder. The emerging contribution to the optical conductivity, which we call the interband Drude conductivity, appears to be negative for the photon energies below the double quasi-Fermi energy of pumped electrons and holes. We find that for the Gaussian correlated distribution of scattering centers, the real part of the net Drude conductivity (…
Observations of terahertz loss to gain switching in transmission through gates on biased graphene sandwiches are explained by response under electron streaming in graphene. Basing on this consideration the terahertz source is proposed consisting of silicon resonator placed on the sandwich with current flow in graphene. It should provide tunable by bias emission in wide terahertz band. The source is direct terahertz analog of tunable microwave laser demonstrated.
We study the conductivity of a graphene strip taking into account electrostatically-induced charge accumulation on its edges. Using a local dependency of the conductivity on the carrier concentration we find that the electrostatic size effect in doped graphene strip of the width of 0.5 - 3 $% μ$m can result in a significant (about 40%) enhancement of the effective conductivity in comparison to the infinitely wide samples. This effect should be taken into account both in the device simulation as well as for verification of scattering mechanisms in graphene.
We present an analytic calculation of the conductivity of pure graphene as a function of frequency $ω$, wave-vector $k$, and temperature for the range where the energies related to all these parameters are small in comparison with the band parameter $γ=3$ eV. The simple asymptotic expressions are given in various limiting cases. For instance, the conductivity for $kv_{0}\ll T\ll ω$ is equal to $σ(ω, k)=e^{2}/4\hbar $ and independent of the band structure parameters $γ$ and $v_{0}$. Our results are also used to explain the known dependence of the graphite conductivity on temperature and pressur…
We present a theory of the influence of band renormalization and excitonic electron-electron interaction effects on the optical conductivity $σ(ω)$ of doped bilayer graphene. Using the Keldysh formalism, we derive a kinetic equation from which we extract numerical and approximate analytic results for $σ(ω)$. Our calculations reveal a previously unrecognized mechanism which couples the Drude and interband response and renormalizes the plasmon frequency, and suggest that screening must play an essential role in explaining the weakly renormalized conductivity seen in recent experiments.
It has been recently demonstrated experimentally that graphene, or single-layer carbon, is a gapless semiconductor with massless Dirac energy spectrum. A finite conductivity per channel of order of $e^{2}/h$ in the limit of zero temperature and zero charge carrier density is one of the striking features of this system. Here we analyze this peculiarity based on the Kubo and Landauer formulas. The appearance of a finite conductivity without scattering is shown to be a characteristic property of Dirac chiral fermions in two dimensions.
We compute the optical conductivity of graphene beyond the usual Dirac cone approximation, giving results that are valid in the visible region of the conductivity spectrum. The effect of next nearest neighbor hoping is also discussed. Using the full expression for the optical conductivity, the transmission and reflection coefficients are given. We find that even in the optical regime the corrections to the Dirac cone approximation are surprisingly small (a few percent). Our results help in the interpretation of the experimental results reported by Nair {\it et al.} [Science {\bf 320}, 1308 (20…
The gapless energy band spectra make the structures based on graphene and graphene bilayers with the population inversion created by optical or injection pumping to be promising media for the interband terahertz (THz) lasing. However, a strong intraband absorption at THz frequencies still poses a challenge for efficient THz lasing. In this paper, we show that in the pumped graphene bilayer structures, the indirect interband radiative transitions accompanied by scattering of carriers caused by disorder can provide a substantial negative contribution to the THz conductivity (together with the di…
The in-plane DC conductivity of twisted bilayer graphene (TBLG) is calculated using an expansion of the real-space Kubo-Bastin conductivity in terms of Chebyshev polynomials. We investigate within a tight-binding (TB) approach the transport properties as a function of rotation angle, applied perpendicular electric field and vacancy disorder. We find that for high-angle twists, the two layers are effectively decoupled, and the minimum conductivity at the Dirac point corresponds to double the value observed in monolayer graphene. This remains valid even in the presence of vacancies, hinting that…
We observe conductivity oscillations with aperiodic spacing to only one side of the tunneling current in a dual-gated graphene field effect transistor with an n-p-n type potential barrier. The spacing and width of these oscillatoins were found to be inconsistent with pure Farbry-Perot-type interferences, but are in quantitative agreement with theoretical predictions that attribute them to resonant tunneling through quasi-bound impurity states. This observation may be understood as another signature of Klein tunneling in graphene heterojunctions and is of importance for future development and m…
We have calculated the optical conductivity of a disorder-free single graphene sheet in the presence of spin-orbit coupling, using the Kubo formalism. Both intrinsic and structural-inversion-asymmetry induced types of spin splitting are considered within a low-energy continuum theory. Analytical results are obtained that allow us to identify distinct features arising from spin-orbit couplings. We point out how optical-conductivity measurements could offer a way to determine the strengths of spin splitting due to various origins in graphene.
Graphene has been proposed as a promising material for future nanoelectronics because of its unique electronic properties. Understanding the scaling behavior of this new nanomaterial under common experimental conditions is of critical importance for developing graphene-based nanoscale devices. We present a comprehensive experimental and theoretical study on the influence of edge disorder and bulk disorder on the minimum conductivity of graphene ribbons. For the first time, we discovered a strong non-monotonic size scaling behavior featuring a peak and saturation minimum conductivity. Through e…
Non-equilibrium molecular dynamics is used to investigate the heat current due to the atomic lattice vibrations in graphene nanoribbons and nanorings under a thermal gradient. We consider a wide range of temperature, nanoribbon widths up to 6nm and the effect of moderate edge disorder. We find that narrow graphene nanorings can efficiently suppress the lattice thermal conductivity at low temperatures (~100K), as compared to nanoribbons of the same width. Remarkably, rough edges do not appear to have a large impact on lattice energy transport through graphene nanorings while nanoribbons seem mo…
We show that the optical transparency of suspended graphene is defined by the fine structure constant, alpha, the parameter that describes coupling between light and relativistic electrons and is traditionally associated with quantum electrodynamics rather than condensed matter physics. Despite being only one atom thick, graphene is found to absorb a significant (pi times alpha=2.3%) fraction of incident white light, which is a consequence of graphene's unique electronic structure. This value translates into universal dynamic conductivity G =e^2/4h_bar within a few percent accuracy.
We theoretically study current dynamics of graphene nanoribbons subject to bias dc and ac driven fields. We showed that graphene nanoribbons exhibit negative high-harmonic differential conductivity. Negative differential conductivity appears when bias electric filed is in the neighborhood of applied ac filed amplitude. We also observe both even and odd high-harmonic negative differential conductivity at wave mixing of two commensurate frequencies. The even harmonics are more pronounced than the odd harmonics. A possible use of the present method for generating terahertz frequencies at even har…
We investigate electronic transport in the nitrogen-doped graphene containing different configurations of point defects: singly or doubly substituting N atoms and nitrogen-vacancy complexes. The results are numerically obtained using the quantum-mechanical Kubo-Greenwood formalism. Nitrogen substitutions in graphene lattice are modelled by the scattering potential adopted from the independent self-consistent ab initio calculations. Variety of quantitative and qualitative changes in the conductivity behaviour are revealed for both graphite- and pyridine-type N defects in graphene. For the most …
We investigate the conductivity of doped graphene in the semiclassical Boltzmann limit, as well as the conductivity minimum within the self-consistent transport theory. Using the hard-disk model for a two-dimensional distribution of impurities gives rise to both strong increase in the slope of conductivity at low charge carrier densities in graphene and a strongly sub-linear behavior of the conductivity at high charge carrier densities when the correlation distance between the impurities is large. On the other hand, we find that a super-linear dependence of the conductivity on charge carrier d…
Applying a quasiclassical equation to carriers in graphene we found a way how to distinguish between samples with the domination of short and long range scatterers from the conductivity measurements. The model proposed explains recent transport experiments with chemically doped as well as suspended graphene.
We report our theoretical calculations on the temperature and energy dependent electrical conductivity of gapped graphene within the framework of Boltzmann transport formalism. Since screening effects have known to be of vital importance in explaining the conductivity of gapless graphene therefore we first worked out the behaviour of the temperature dependent polarization function for gapped graphene as a function of wave vector and band gap, respectively. Polarization of gapped graphene has been compared with that of gapless graphene, bilayer graphene and 2DEG to see the effects of gap. It is…
The conductivity of doped graphene is considered taking into account scattering by short-range nonsymmetric defects, when the longitudinal and transverse components of conductivity tensor appear to be different. The calculations of the anisotropic conductivity tensor are based on the quasiclassical kinetic equation for the case of monopolar transport at low temperatures. The effective longitudinal conductivity and the transverse voltage, which are controlled by orientation of sample and by gate voltage (i.e. doping level), are presented.
Graphene has an unusual low-energy band structure with four chiral bands and half-quantized and quantized Hall effects that have recently attracted theoretical and experimental attention. We study the Fermi energy and disorder dependence of its spin Hall conductivity. In the metallic regime we find that vertex corrections enhance the intrinsic spin Hall conductivity and that skew scattering can lead to its values that exceed the quantized ones expected when the chemical potential is inside the spin-orbit induced energy gap. We predict that large spin Hall conductivities will be observable in g…
We take a wide-angle view of the problem of monolayer graphene where the valley-mixing and the spin-degeneracy lifting are assumed to be possible by wedging in the requisite ingredients, viz. the atomically sharp scatterers and the strong Rashba coupling dominating over the intrinsic spin-orbit coupling. This leads to eight Majorana-like modes (quasi-particles which are self-conjugate) close to the experimentally inaccessible Dirac points. Using Kubo formula we also show that the semi-classical diffusive (longitudinal) conductivity is nearly (2.018 e2/h) at room temperature for the disordered …
Using the Kubo linear response formalism, we study the effects of intrinsic graphene optical and surface polar phonons (SPPs) on the optical conductivity of doped graphene. We find that inelastic electron-phonon scattering contributes significantly to the phonon-assisted absorption in the optical gap. At room temperature, this midgap absorption can be as large as 20-25% of the universal ac conductivity for graphene on polar substrates due to strong electron-SPP coupling. The midgap absorption, moreover, strongly depends on the substrates and doping levels used. With increasing temperature, the…
Utilizing a complete Lorentz-covariant and local-gauge-invariant formulation, we discuss graphene response to arbitrary external electric field. The relation, which is called as Kramers-Kr(\ddot{o})nig relation in the paper, between imaginary part and real part of ac conductivity is given. We point out there exists an ambiguity in the conductivity computing, attributed to the wick behavior at ultraviolet vicinity. We argue that to study electrical response of graphene completely, non-perturbational contribution should be considered.
We have investigated thermal conductivity of graphene laminate films deposited on polyethylene terephthalate substrates. Two types of graphene laminate were studied - as deposited and compressed - in order to determine the physical parameters affecting the heat conduction the most. The measurements were performed using the optothermal Raman technique and a set of suspended samples with the graphene laminate thickness from 9 to 44 micrometers. The thermal conductivity of graphene laminate was found to be in the range from 40 W/mK to 90 W/mK at room temperature. It was found unexpectedly that th…
A Drude-Boltzmann theory is used to calculate the transport properties of bilayer graphene. We find that for typical carrier densities accessible in graphene experiments, the dominant scattering mechanism is overscreened Coulomb impurities that behave like short-range scatterers. We anticipate that the conductivity $σ(n)$ is linear in $n$ at high density and has a plateau at low density corresponding to a residual density of $n^* = \sqrt{n_{\rm imp} {\tilde n}}$, where ${\tilde n}$ is a constant which we estimate using a self-consistent Thomas-Fermi screening approximation to be ${\tilde n} \a…
The quantum corrections to the conductivity and the thermopower in monolayer graphene are studied. We use the recursive Green's function method to calculate numerically the conductivity and the thermopower of graphene. We then analyze these weak localization corrections by fitting with the analytical theory as function of the impurity parameters and the gate potential. As a result of the quantum corrections to the thermopower, we find large magnetothermopower which is shown to provide a very sensitive measure of the size and strength of the impurities. We compare these analytical and numerical…
The band structure and the optical conductivity of an ABA (Bernal-type) stacked graphene trilayer are calculated. It is shown that, under appropriate doping, a strong resonant peak develops in the optical conductivity, located at the frequency corresponding to approximately 1.4 times the interlayer hopping energy and caused by the 'nesting' of two nearly parabolic bands in the electronic spectrum. The intensity of this resonant absorption can be controlled by adjusting the gate voltage. The effect is robust with respect to increasing temperature.
Minimal conductivity of a single undoped graphene layer is known to be of the order of the conductance quantum, independent of the electron velocity. We show that this universality does not survive electron-electron interaction which results in the non-trivial frequency dependence. We begin with analyzing the perturbation theory in the interaction parameter 'g' for the electron self-energy and observe the failure of the random-phase approximation. The optical conductivity is then derived from the quantum kinetic equation and the exact result is obtained in the limit when g << 1 << g lnω.
The next-nearest neighbor interaction (NNN) is included in a tight-binding calculation of the electronic spectrum and conductivity of doped graphene. As a result, we observe a wide variation of the conductivity behavior, since the Fermi energy and the resonance peak are not shifted by the same amount. Such effect can have a profound effect in the idea of explaining the minimal conductivity of graphene as a consequence of impurities or defects. Finally, we also estimate the mean free path and relaxation time due to resonant impurity scattering.
It is a fact that the minimal conductivity $σ_0$ of most graphene samples is larger than the well-established universal value for ideal graphene $4e^2/πh$; in particular, larger by a factor $\gtrsimπ$. Despite intense theoretical activity, this fundamental issue has eluded an explanation so far. Here we present fully atomistic quantum mechanical estimates of the graphene minimal conductivity where electron-electron interactions are considered in the framework of density functional theory. We show the first conclusive evidence of the dominant role on the minimal conductivity of charged impuriti…
We calculate the conductivity of a clean graphene sheet at finite temperatures starting from the tight-binding model. We obtain a finite value for the dc-conductivity at zero temperature. For finite temperature, the spontaneous electron-hole creation, responsible for the finite conductivity at zero temperature, is washed out and the dc-conductivity yields zero. Our results are in agreement with calculations based on the field-theoretical model for graphene.
A model for the rival mechanisms of hysteresis in graphene channel resistivity on a substrate of different nature dependence on a gate voltage - a direct one (caused by adsorbates with dipole moment on surface and interface) and an inverse one (caused by capture of free carriers from graphene onto localized states on graphene-substrate interface) is proposed. Possible discrimination of these two channels by variation of the gate voltage sweep rate is discussed. Our theory predictions are in good correlation with experimental data, available in literature.