Electronic and Magnetic Properties of the Interface between a doped cuprate Y0.6Pr0.4Ba2Cu3O7 and a colossal-magnetoresistance manganite La2/3Ca1/3MnO3
Jian Liu, B. J. Kirby, M. Kareev, J. W. Freeland, H. -U. Habermeier, G. Cristiani, B. Keimer, J. Chakhalian
The interfacial properties of Y0.6Pr0.4Ba2Cu3O7/La2/3Ca1/3MnO3 superlattices have been studied by resonant soft x-rays and diffuse scattered neutrons. Linearly polarized X-ray absorption at Cu L3 -edge reveals dramatic interfacial changes from the bulk including charge transfer between LCMO and YPBCO and an orbital reconstruction in the interface CuO2 plane. The similarities to the case of zero Pr-doping are due to the strongly hybridized covalent bond between Cu and Mn. However, reduced charge transfer and a more bulk-like interfacial orbital occupation are observed and related to the effect of Pr-doping. Neutron reflectometry measurements reveal a drastic increase in diffuse scattering with decreasing temperature, likely due to buckling caused by the structural phase transition of the SrTiO3 substrate. We observe no evidence that this diffuse scattering is related to the superconducting transition.
Giant oxygen isotope effects observed in colossal magnetoresistance manganites are investigated by employing the combined model of the double exchange and interacting lattice polaron mechanism. We have shown that the isotope effects on $ T_C$ in the metallic phase and $ T_{CO}$ in the charge ordered phase of manganites can be explained well in terms of the double exchange and polaron narrowing factors with reasonable physical parameters.
We present a small-but-sizeable magnetic polaron picture where transport at high temperatures is activated while at low temperatures it is band-like. We show that both double exchange and finite bandwidth effects are important to understand colossal magnetoresistance as well as the coincidence of the metal-insulator and the ferromagnetic transitions in manganites. The magnetic transition is explained using band-like motion of the polarons.
Based on the combined model of the double exchange and the polaron, we have studied the small-to-large polaron crossover transition and explored its effects on the magnetic and transport properties in colossal magnetoresistance (CMR) manganites. We have used the variational Lang-Firsov canonical transformation, and shown that the magnetic and transport properties of both high and low $T_C$ manganites are well described in terms of a single formalism. We have reproduced the rapid resistivity drop below $T_C$, a realistic CMR ratio, and the {\it first-order-like} sharp magnetic phase transition,…
The metallic or insulating nature of the paramagnetic phase of the colossal-magnetoresistance manganites is investigated via a double exchange Hamiltonian with diagonal disorder. Mobility edge trajectory is determined with the transfer matrix method. Density of states calculations indicate that random hopping alone is not sufficient to induce Anderson localization at the Fermi level with 20-30% doping. We argue that the metal-insulator transtion is likely due to the formation of localized polarons from nonuniform extended states as the effective band width is reduced by random hoppings and ele…
The persistent proximity of insulating and metallic phases, a puzzling characterestic of manganites, is argued to arise from the self organization of the twofold degenerate e_g orbitals of Mn into localized Jahn-Teller(JT) polaronic levels and broad band states due to the large electron - JT phonon coupling present in them. We describe a new two band model with strong correlations and a dynamical mean-field theory calculation of equilibrium and transport properties. These explain the insulator metal transition and colossal magnetoresistance quantitatively, as well as other consequences of two …
The colossal magnetoresistance in manganites AMnO_3 is studied from the viewpoint of multicritical phenomena. To understand the complicated interplay of various phases, we study the Ginzburg-Landau theory in terms of both the mean-field approximation and the renormalization-group analysis to compare with the observed phase diagram. Several novel features, such as the first-order ferromagnetic transition, and the dip in the transition temperature near the multicritical point, can be understood as driven by enhanced fluctuations near the multicritical point. Furthermore, we obtain a universal sc…
Extensive experimental results are presented on the multi-scale phase modulation phenomena observed in colossal magnetoresistance manganites. Two key types of phase inhomogeneities directly relevant to the colossal magnetoresistance (CMR) are discussed. The first type involves micrometer-scale coexistence of structurally and electronically different phases. We present extensive experimental data for a prototypical system exhibiting such a phase coexistence, (La,Pr)$_{5/8}$Ca$_{3/8}$MnO$_{3}$. These data reveal that percolative transport phenomena play the key role in the metal-insulator transi…
It has been observed that the low temperature magnetoresistance behaviour in polycrystalline colossal magnetoresistive (CMR) manganites differ significantly from the single crystals. The polycrystalline samples show large magnetoresistance at temperatures much below the ferromagnetic transition temperature where the magnetoresistance of single crystals is very small. This has conventionally been attributed to spin polarised tunnelling at the grain boundaries in polycrystalline samples. In this paper we show the existence of a variable range hopping behaviour in resistivity at low temperatures …
The sensitivity of transport in CMR manganite to external fields is examined using a PZT-based field effect configuration with a La0.7Ca0.3MnO3 channel subjected to electric and magnetic fields, separately and in conjugation. We not only find a colossal electroresistance (CER) of ~76% at 4X10^5 V/cm, but also a remarkable complimentarity of this CER with the widely studied CMR. Specifically, the ERmax (MRmax) of the system is largely independent of the magnetic (electric) field biasing, and for equal conductivity values, the ER (MR) is lower (higher) for T<Tp than that for T>Tp. The size and s…
Taking into account both the Jahn-Teller lattice distortion and the on-site electronic potential fluctuations in the orbital-degenerated double-exchange model, in which both the core-spin and the lattice distortion are treated classically, we investigate theoretically the metal-insulator transition (MIT) in manganites by considering the electronic localization effect. An inverse matrix method is developed for calculation in which we use the inverse of the transfer matrix to obtain the localization length. We find that within reasonable range of parameters, both the lattice effect and the poten…
The temperature dependence of the electronic and atomic structure of the colossal magnetoresistive oxides $La_{1-x}Sr_{x}MnO_{3}$ (x = 0.3, 0.4) has been studied using core and valence level photoemission, x-ray absorption and emission, and extended x-ray absorption fine structure spectroscopy. A dramatic and reversible change of the electronic structure is observed on crossing the Curie temperature, including charge localization and spin moment increase of Mn, together with Jahn-Teller distortions, both signatures of polaron formation. Our data are also consistent with a phase-separation scen…
We have studied the low-frequency dielectric properties of the phase-separated manganite Pr0.7Ca0.3MnO3 as a function of applied magnetic field in the low temperature phase-separated state. The dielectric constant is strongly field dependent and also depends on the magnetic field history of the sample. The dielectric behavior appears to be associated with the hopping of polaronic charge carriers, and we can derive the field dependent hopping energy barrier from the frequency dependence of the dielectric constant. This analysis allows us to associate the metal-insulator transition observed in t…
We derive a realistic microscopic model for doped colossal magnetoresistance manganites, which includes the dynamics of charge, spin, orbital and lattice degrees of freedom on a quantum mechanical level. The model respects the SU(2) spin symmetry and the full multiplet structure of the manganese ions within the cubic lattice. Concentrating on the hole doped domain ($0\le x\le 0.5$) we study the influence of the electron-lattice interaction on spin and orbital correlations by means of exact diagonalisation techniques. We find that the lattice can cause a considerable suppression of the coupling…
In view of recent experiments, indicating the spatial coexistence of conducting and insulating regions in the ferromagnetic metallic phase of doped manganites, we propose a refined mixed-phase description. The model is based on the competition of a double-exchange driven metallic component and a polaronic insulating component, whose volume fractions and carrier concentrations are determined self-consistently by requiring equal pressure and chemical potential. The resulting phase diagram as well as the order of the phase transition are in very good agreement with measured data. In addition, mod…
We show that the Anomalous Hall Effect (AHE) observed in Colossal Magnetoresistance Manganites is a manifestation of Berry phase effects caused by carrier hopping in a non-trivial spin background. We determine the magnitude and temperature dependence of the Berry phase contribution to the AHE, finding that it increases rapidly in magnitude as the temperature is raised from zero through the magnetic transition temperature T_c, peaks at a temperature $T_{max} > T_c$ and decays as a power of T, in agreement with experimental data. We suggest that our theory may be relevant to the anomalous hall e…
We review colossal magnetoresistance in single phase manganites, as related to the field sensitive spin charge interactions and phase separation; the rectifying property and negative/positive magnetoresistance in manganite/Nb:SrTiO3 pn junctions in relation to the special interface electronic structure; magnetoelectric coupling in manganite/ferroelectric structures that takes advantage of strain, carrier density, and magnetic field sensitivity; tunneling magnetoresistance in tunnel junctions with dielectric, ferroelectric, and organic semiconductor spacers using the fully spin polarized nature…
Colossal magnetoresistance (CMR) and electroresistance (CER) induced by the electric field in spinel multiferroic CdCr2S4 are reported. It is found that a metal-insulator transition (MIT) in CdCr2S4 is triggered by the electrical field. In magnetic fields, the resistivity of CdCr2S4 responds similarly to that of CMR manganites. Combing previous reports, these findings make CdCr2S4 the unique compound to possess all four properties of the colossal magnetocapacitive (CMC), colossal electrocapacitive (CEC), CER, and CMR. The present results open a new venue for searching new materials to show CMR…
In order to study the magnetic excitation behaviors in colossal magnetoresistance manganites, a magnon-phonon interacting system is investigated. Sudden broadening of magnon linewidth is obtained when a magnon branch crosses over an optical phonon branch. Onset of the broadening is approximately determined by the magnon density of states. Anomalous magnon damping at the brillouine zone boundary observed in low Curie temperature manganites is explained.
We have studied the bandwidth-temperature-magnetic field phase diagram of RE(0.55)Sr(0.45)MnO(3) colossal magnetoresistance manganites with ferromagnetic metallic (FM) ground state. The bandwidth (or equivalently the double exchange interaction) was controlled both via chemical substitution and hydrostatic pressure with a focus on the vicinity of the critical pressure p* where the character of the zero-field FM transition changes from first to second order. Below p* the first-order FM transition extends up to a critical magnetic field, H_cr. It is suppressed by pressure and approaches zero on …
High resolution topographic images obtained by scanning tunneling microscope in the insulating state of Pr0.68Pb0.32MnO3 single crystals showed regular stripe-like or zigzag patterns on a width scale of 0.4 - 0.5 nm confirming a high temperature polaronic state. Spectroscopic studies revealed inhomogeneous maps of zero-bias conductance with small patches of metallic clusters on length scale of 2 - 3 nm only within a narrow temperature range close to the metal-insulator transition. The results give a direct observation of polarons in the insulating state, phase separation of nanometer-scale met…
We propose a dielectrophoresis model for phase-separated manganites. Without increase of the fraction of metallic phase, an insulator-metal transition occurs when a uniform electric field applied across the system exceeds a threshold value. Driven by the dielectrophoretic force, the metallic clusters reconfigure themselves into stripes along the direction of electric field, leading to the filamentous percolation. This process, which is time-dependent, irreversible and anisotropic, is a probable origin of the colossal electroresistance in manganites.
Using a two-band double-exchange model with Jahn-Teller lattice distortions and super-exchange interactions, supplemented by quenched disorder, at electron density $n=0.65$, we explicitly demonstrate the coexistence of the $n$ = 1/2-type ($π, π$) charge-ordered and the ferromagnetic nanoclusters above the ferromagnetic transition temperature $T_{\rm c}$ in colossal magnetoresistive (CMR) manganites. The resistivity increases due to the enhancement of the volume fraction of the charge-ordered and the ferromagnetic nanoclusters with decreasing the temperature down to $T_{\rm c}$. The ferromagnet…
We show that the current carrier density collapse in doped manganites, which results from bipolaron formation in the paramagnetic phase, leads to a colossal change of the optical conductivity in an external magnetic field at temperatures close to the ferromagnetic transition. As with the colossal magnetoresistance (CMR) itself, the corresponding magnetooptical effect is explained by the dissociation of localized bipolarons into mobile polarons owing to the exchange interaction with the localized Mn spins in the ferromagnetic phase. The effect is positive at low frequencies and negative in the …
At low temperatures, EuTiO$_3$ system has very large resistivities and exhibits colossal magnetoresistance. Based on a first principle calculation and the dynamical mean-field theory for small polaron we have calculated the transport properties of EuTiO$_3$. It is found that due to electron-phonon interaction the conduction band may form a tiny subband which is close to the Fermi level. The tiny subband is responsible for the large resistivity. Besides, EuTiO$_3$ is a weak antiferromagnetic material and its magnetization would slightly shift the subband via exchange interaction between conduct…
Critical phenomena of ferromagnetic transition in colossal magnetoresistance manganites are theoretically studied. Concerning the critical exponents for this transition, there still remains controversy among experimental results. In order to clarify intrinsic physics of the manganites through a comparison with theoretical prediction, we investigate the critical phenomena of double-exchange models by using finite-size scaling analysis on unbiased numerical results. As a result, we show that the critical exponents of the ferromagnetic transition of the three-dimensional double-exchange model is …
Materials that exhibit colossal magnetoresistance (CMR) are currently the focus of an intense research effort, driven by the technological applications that their sensitivity lends them to. Using the angular correlation of photons from electron-positron annihilation, we present a first glimpse of the Fermi surface of a material that exhibits CMR, supported by ``virtual crystal'' electronic structure calculations. The Fermi surface is shown to be sufficiently cubic in nature that it is likely to support nesting.
We present a small polaron picture and show that finite bandwidth effects are important to understand colossal magnetoresistance. Besides the polaron size parameter, we show that there is another parameter (adiabaticity parameter) that is relevant to studying magnetoresistance. We find that for fixed values of the polaron size parameter an increase in the adiabaticity parameter increases the magnetoresistance. The magnetic transition is studied within a mean field approach. We point out important oversights in the literature. We find that for the reported values of the bandwidth (based on band…
We address the issue of massive phase separation (PS) in manganite family of doped Mott insulators through ac conductivity measurements on La$_{0.625-y}$Pr$_{y}$Ca$_{0.375}$MnO$_{3}$ (0.375 $\leq$ y $\leq$ 0.275), and establish applicability of the scaling theory of percolation in the critical regime of the PS. Measurements of dc resistivity, magnetization (M(T)) and electron diffraction show incomplete growth of a ferromagnetic (FM) metallic component on cooling the high temperature charge ordered (CO) phase well below Curie temperature. The impedance $\mid$Z(T,f)$\mid$ measured over a freque…
In addition to mechanisms already proposed to account for the formation in manganites of a small-polaron superlattice above the Curie temperature Tc and to a metallic-like sea of large polarons below Tc, we now consider other observed colossal-resistance inducing fields, such as magnetic, electric, photon, or strain fields. We attribute the charge-ordered phase formation to the occurrence of strong dipolar binding of vibronic small polarons arising from the phonon coupling of highly polarizable two-level orbital systems. These species having associated inherent electric and magnetic off-center…
We give an overview on several recent topics of colossal magnetoresistive manganites in both experiments and theories, focusing on the effect of quenched disorder. The disorder is intrinsically involved since the compounds are solid solutions, and its importance has been pointed out in several experiments of transport and magnetic properties. Recent progress in the experimental control of the strength of disorder is also reviewed. Theoretically, the effect of the disorder has been explored within the framework of the double-exchange mechanism. Several efforts to understand the phase diagram an…
We report a significant decrease in the low-temperature resistance induced by the application of an electric current on the $ab$-plane in the paramagnetic insulating (PMI) state of (La$_{0.4}$Pr$_{0.6}$)$_{1.2}$Sr$_{1.8}$Mn$_{2}$O$_{7}$. A colossal electroresistance effect attaining -95% is observed at lower temperatures. A colossal magnetoresistive step appears near 5T at low temperatures below 10K, accompanied by an ultrasharp width of the insulator-metal transition. Injection of higher currents to the crystal causes a disappearance of the steplike transition. These findings have a close rel…
Colossal magnetoresistance is of great fundamental and technological significance and exists mostly in the manganites and a few other materials. Here we report colossal magnetoresistance that is starkly different from that in all other materials. The stoichiometric Mn3Si2Te6 is an insulator featuring a ferrimagnetic transition at 78 K. The resistivity drops by 7 orders of magnitude with an applied magnetic field above 9 Tesla, leading to an insulator-metal transition at up to 130 K. However, the colossal magnetoresistance occurs only when the magnetic field is applied along the magnetic hard a…
We present a detailed study of the polycrystalline perovskite manganites La0.67Ca0.33AlxMn1-xO3 (x = 0, 0.1, 0.15, 0.5) at low temperatures and high magnetic fields, including electrical resistance, magnetization, ac susceptibility. The static magnetic susceptibility was also measured up to 1000 K. All the samples show colossal magnetoresistance behavior and the Curie temperatures decrease with Al doping. The data suggest the presence of correlated magnetic clusters near by the ferromagnetic transition. This appears to be a consequence of the structural and magnetic disorder created by the ran…
The electronic properties of many transition metal oxide systems require new ideas concerning the behaviour of electrons in solids for their explanation. A recent example, subsequent to that of cuprate superconductors, is of rare earth manganites doped with alkaline earths, namely $Re_{1-x}A_x MnO_3$, which exhibit colossal magnetoresistance, metal insulator transition and many other poorly understood phenomena. Here we show that the strong Jahn Teller coupling between the twofold degenerate ($d_{x^2 -y^2}$ and $d_{3z^2 -r^2}$) $e_g$ orbitals of $Mn$ and lattice modes of vibration (of the oxyg…
Ca3Ru2O7 with a Mott-like transition at 48 K features different in-plane anisotropies of magnetization and magnetoresistance. Applying magnetic field along the magnetic easy-axis precipitates a spin-polarized state via a first-order metamagnetic transition, but does not lead to a full suppression of the Mott state, whereas applying magnetic field along the magnetic hard axis does, causing a resistivity reduction of three orders of magnitude. The colossal magnetoresistivity is attributed to the collapse of the orbital ordered and spin-polarized state. Evidence for a density wave is also present…
Recently we have reported the observation of colossal magnetostriction effect in HoMn2O5 single crystals. Besides we have made the supposition for possible correlation between the peculiarities, observed in the field depended polarization measurements, and the colossal magnetostriction effect at a 4.2 K temperature. In this article we present our results received by polarization and magnetostriction measurements on HoMn2O5 and TbMn2O5 single crystals and the strong correlation between magnetostriction and polarization phase transition for these two compounds. The origin of this correlation is …
Transport and magnetic studies of Ca3Ru2O7 for temperatures ranging from 0.4 K to 56 K and magnetic fields, B, up to 45 T leads to strikingly different behavior when the field is applied along the different crystal axes. A ferromagnetic (FM) state with full spin polarization is achieved for B||a-axis, but colossal magnetoresistance is realized only for B||b-axis. For B||c-axis, Shubnikov-de Haas oscillations are observed and followed by a less resistive state than for B||a. Hence, in contrast to standard colossal magnetoresistive materials, the FM phase is the least favorable for electron hopp…
Manganites are famous mostly for the colossal magnetoresistive effect, which involves the phase separation between ferromagnetic phase and charge-ordered CE-type antiferromagnetic phases. Furthermore, manganites contain some typical magnetic ferroelectrics, e.g. E-type antiferromagnetic $o$-HoMnO$_3$. Here we re-examined these zigzag-winding antiferromagnetic phases (CE-type and E-type antiferromagnets) from the topological perspective. Our theoretical analysis proved that the E-type phase is a weak topological insulator belonging to the $\mathbb{Z}$ class. In momentum space, we classify the s…
We report magnetic and inter-plane transport properties of Ca3Ru2O7 at high magnetic fields and low temperatures. Ca3Ru2O7 with a bilayered orthorhombic structure is a Mott-like system with a narrow charge gap of 0.1eV. Of a host of unusual physical phenomena revealed in this study, a few are particularly intriguing: (1) a collapse of the c-axis lattice parameter at a metal-nonmetal transition, TMI (=48 K), and a rapid increase of TMI with low uniaxial pressure applied along the c-axis; (2) quantum oscillations in the gapped, nonmetallic state for 20 mK<T<6.5 K; (3) tunneling colossal magnetor…
A novel ferromagnetic transition, accompanied by carrier density collapse, is found in doped charge-transfer insulators with strong electron-phonon coupling. The transition is driven by an exchange interaction of polaronic carriers with localized spins; the strength of the interaction determines whether the transition is first or second order. A giant drop in the number of current carriers during the transition, which is a consequence of bound pairs formation in the paramagnetic phase close to the transition, is extremely sensitive to an external magnetic field. This carrier density collapse d…
We report recent transport and thermodynamic experiments over a wide range of temperatures for the Mott-like system Ca3Ru2O7 at high magnetic fields, B, up to 30 T. This work reveals a rich and highly anisotropic phase diagram, where applying B along the a-, b-, and c-axis leads to vastly different behavior. A fully spin-polarized state via a first order metamagnetic transition is obtained for B||a, and colossal magnetoresistance is seen for B||b, and quantum oscillations in the resistivity are observed for B||c, respectively. The interplay of the lattice, orbital and spin degrees of freedom a…
A field-induced crossover is observed in the resistivity and magnetization (M) of a La(0.7)Pb(0.3)MnO(3) single crystal. The field-dependence of the resistivity and M suggests that a small spin-canted species with mean-field-like interactions dominates at low fields (H), whereas, individual spins and 3D Ising/Heisenberg models describe the high-H behavior rather well. Around the ferromagnetic transition, an H-induced destruction of the small spin-canted magnetic polarons is accompanied by large magnetoresistance.
Angle-resolved photoemission spectroscopy data for the bilayer manganite La1.2Sr1.8Mn2O7 show that, upon lowering the temperature below the Curie point, a coherent polaronic metallic groundstate emerges very rapidly with well defined quasiparticles which track remarkably well the electrical conductivity, consistent with macroscopic transport properties. Our data suggest that the mechanism leading to the insulator-to-metal transition in La1.2Sr1.8Mn2O7 can be regarded as a polaron coherence condensation process acting in concert with the Double Exchange interaction.
The electronic structure of La0.7Ce0.3MnO3 (LCeMO) thin film has been investigated using photoemission spectroscopy (PES) and x-ray absorption spectroscopy (XAS). The Ce 3d core-level PES and XAS spectra of LCeMO are very similar to those of CeO2, indicating that Ce ions are far from being trivalent. A very weak 4f resonance is observed around the Ce 4d $\to$ 4f absorption edge, suggesting that the localized Ce 4f states are almost empty in the ground state. The Mn 2p XAS spectrum reveals the existence of the Mn(2+) multiplet feature, confirming the Mn(2+)-Mn(3+) mixed-valent states of Mn ions…
We present a systematic optical study for a bandwidth-controlled series of nearly half doped colossal magnetoresistive manganites RE$_{0.55}$AE$_{0.45}$MnO$_3$ (RE and AE being rare earth and alkaline earth ions, respectively) under the presence of quenched disorder over a broad temperature region $T=10-800$ K. The ground state of the compounds ranges from the charge and orbital ordered insulator through the spin glass to the ferromagnetic metal. The enhanced phase fluctuations, namely the short-range charge and orbital correlations dominate the paramagnetic region of the phase diagram above a…
By performing angle-resolved photoemission spectroscopy of the bilayer colossal magnetoresistive (CMR) manganite, $La_{2-2x}Sr_{1+2x}Mn_{2}O_{7}$, we provide the complete mapping of the Fermi level spectral weight topology. Clear and unambiguous bilayer splitting of the in-plane 3d$_{x^2-y^2}$ band, mapped throughout the Brillouin zone, and the full mapping of the 3d$_{3z^2-r^2}$ band are reported. Peculiar doping and temperature dependencies of these bands imply that as transition from the ferromagnetic metallic phase approaches, either as a function of doping or temperature, coherence along …
Colossal electroresistance (CER) has been observed in the ferromagnetic insulating (FMI) state of a manganite. Notably, the CER in the FMI state occurs in the absence of magnetoresistance (MR). Measurements of electroresistance (ER) and current induced resistivity switching have been performed in the ferromagnetic insulating state of a single crystal manganite of composition Nd$_0.7$Pb$_0.3$MnO$_3$ (NPMO30). The sample has a paramagnetic to ferromagnetic (Curie) transition temperature, Tc = 150 K and the ferromagnetic insulating state is realized for temperatures, T <~ 130 K. The colossal elec…
We report occurrence of large magnetoresistance in lightly doped antiferromagnetic paraelectric EuTiO3. Reports of magnetoresistance in rare-earth titanates (RTiO3 oxides) are very scarce because they are highly insulating at low temperatures. EuTiO3 is an insulator at 2.5 K and 1% La3+ substitution for Eu2+ lowers the resistivity over five orders of magnitude at 2.5 K. It is shown that Eu0.99La0.01TiO3 which is antiferromagnetic below T= 5.43 K shows large magnetoresistance over a wide temperature. At 2.5 K, magnetoresistance is -42 % for H = 6 kOe and it increases to -75 % for H = 7 T. Even …
Mixed-valence perovskite manganites (Re$_{1-x}$A$_{x}$MnO$_{3}$ where Re=rare earth, A=alkaline earth) provide a unique opportunity to study the relationships between the structure and the magnetotransport properties due to an interplay among charge carriers, magnetic coupling, orbital ordering and structural distortion. This makes these compounds very exciting from both the basic research and from the technological view point. As the technology pursued with these materials requires film growth, extensive studies have been made on materials synthesis, structural and physical characterization a…
We present a new type of colossal magnetoresistance (CMR) arising from an anomalous collapse of the Mott insulating state via a modest magnetic field in a bilayer ruthenate, Ti-doped Ca$_3$Ru$_2$O$_7$. Such an insulator-metal transition is accompanied by changes in both lattice and magnetic structures. Our findings have important implications because a magnetic field usually stabilizes the insulating ground state in a Mott-Hubbard system, thus calling for a deeper theoretical study to reexamine the magnetic field tuning of Mott systems with magnetic and electronic instabilities and spin-lattic…
Current theoretical approaches to manganites mainly stem from magnetic framework, in which the electronic transport is thought to be spin-dependent and the double exchange mechanism plays a core role. However, quite a number of experimental observations can yet not be reasonably explained. For example, multiplicate insulator-metal transitions and resistivity reduction induced by perturbations other than magnetic field, such as electric current, are not well understood. A comprehensive analysis on earlier extensive studies is performed and two types of origins for resistivity change are highlig…
Inspired by the strong experimental evidence for the coexistence of localized and itinerant charge carriers close to the metal-insulator transition in the ferromagnetic phase of colossal magnetoresistive manganese perovskites, for a theoretical description of the CMR transition we propose a two-phase scenario with percolative characteristics between equal-density polaron and Zener band-electron states. We find that the subtle balance between these two states with distinctly different electronic properties can be readily influenced by varying physical parameters, producing various ``colossal'' …
We present a rectifying manganite-titanate heterojunction exhibiting a magnetic field tunable depletion layer. This creates a large positive magnetocapacitance, a direct measure of the field-induced reduction of the effective depletion width across the junction. Furthermore, the reduction of the junction barrier shifts the forward bias characteristics, giving exponentially-enhanced differential magnetoresistance, occurring despite the absence of a spin filter. These results provide a unique probe of a Mott insulator/band insulator interface, and further suggest new electronic devices incorpora…
Spatially resolved tunneling spectroscopic studies of colossal magnetoresistive (CMR) manganite $\rm La_{0.7}Ca_{0.3}MnO_3$ (LCMO) epitaxial films on $\rm (LaAlO_3)_{0.3}(Sr_2AlTaO_6)_{0.7}$ substrate are investigated as functions of temperature, magnetic field and spin polarization by means of scanning tunneling spectroscopy. Systematic surveys of the tunneling spectra taken with Pt/Ir tips reveal spatial variations on the length scale of a few hundred nanometers in the ferromagnetic state, which may be attributed to the intrinsic heterogeneity of the manganites due to their tendency towards …
We present temperature-dependent scanning tunneling spectroscopy measurements on $La_{1-x}Ca_{x}MO_{3}$ ($x\sim0.33$) films with different degrees of biaxial strain. A depletion in normalized conductance around the Fermi level is observed both above and below the insulator-to-metal transition temperature $T_{MI}$, for weakly as well as highly-strained films. This pseudogap-like depletion globally narrows on cooling. The zero-bias conductance decreases on cooling in the insulating phase, reaches a minimum close to $T_{MI}$ and increases on cooling in the metallic phase, following the trend of m…
In the present work we reply to the Comment by Catalan and Scott (cond-mat/0607500) on two of our papers. This Comment has been rejected from publication in Physical Review Letters and, hence, our Reply is based on the cond-mat version.
An effective one-band Hamiltonian for colossal-magnetoresistance (CMR) manganites is constructed and the spin excitations are determined. Fitting the experimental data by the derived spin-wave dispersion gives an e_g -electron hopping amplitude of about 0.2 eV in agreement with LDA band calculations.
Temperature- and magnetic field-dependent electrical noise and electrical resistivity measurements were carried out on epitaxial thin films of a large bandwidth La0.7Sr0.3MnO3 and a disordered intermediate bandwidth (La0.5Pr0.2)Ba0.3MnO3 manganite system. The power spectraldensity was dominated by 1/f-noise. This 1/f-noise was observed to follow the overall temperature dependence of the resistivity. Moreover, in these compounds the magneto-noise effect was found to be of nearly the same magnitude as the magnetoresistance. This direct correlation between magneto-noise and magnetoresistance sugg…
The Monte Carlo Ferromagnetic Ising model was used to study the electrical properties of manganese oxides due to the charge ordering phase occurring at doping, x = 0.5. The half-doped manganites have an insulator antiferromagnetic ground state. We calculated the internal energy, specific heat, resistivity and the magneto-resistance, MR, with parallel and anti-parallel applied magnetic fields. Our simulation reveals that the resistivity decreases exponentially and the electric current increases with increasing temperature according the free charge increase, to transport from an insulator to con…
