arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 0906.0400cond-mat.supr-concond-mat.str-el
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用~(59)Co核磁共振和核四极共振技术测量LixCoO2(x=0.0 - 0.35)中的电子关联

Measurement of electron correlations in LixCoO2 (x=0.0 - 0.35) using 59Co nuclear magnetic resonance and nuclear quadrupole resonance techniques

S. Kawasaki, T. Motohashi, K. Shimada, T. Ono, R. Kanno, M. Karppinen, H. Yamauchi, Guo-qing Zheng

摘要:

CoO 2是超导体NaxCoO 2 \cdot 1.3H2O的母体化合物,并且被广泛认为是莫特绝缘体。我们进行了59钴核磁共振(NMR)和核四极共振(NQR)的研究LixCoO 2(x = 0.35,0.25,0.12,和0.0),以揭示电子状态和自旋的相关性在这一系列的化合物,最近获得的锂从原始LiCoO 2的电化学脱嵌。我们发现,虽然反铁磁自旋相关性系统地增加与减少锂含量(x),端员,CoO 2是一个非相关的金属,以及满足柯林加关系的费米液体。因此,对于AxCoO 2(A = Li,Na)化合物,CoO 2不是简单地位于x->0的极限。CoO 2中电子相关性的消失是由于化合物的三维性,这与AxCoO 2的高度二维结构相反。

英文摘要:

CoO2 is the parent compound for the superconductor NaxCoO2\cdot1.3H2O and was widely believed to be a Mott insulator. We performed 59Co nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) studies on LixCoO2 (x = 0.35, 0.25, 0.12, and 0.0) to uncover the electronic state and spin correlations in this series of compounds which was recently obtained through electrochemical de-intercalation of Li from pristine LiCoO2. We find that although the antiferromagnetic spin correlations systematically increase with decreasing Li-content (x), the end member, CoO2 is a non-correlated metal that well satisfies the Korringa relation for a Fermi liquid. Thus, CoO2 is not simply located at the limit of x->0 for AxCoO2 (A = Li, Na) compounds. The disappearance of the electron correlations in CoO2 is due to the three dimensionality of the compound which is in contrast to the highly two dimensional structure of AxCoO2.

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