We introduce a fundamental theory for the kinetics of systems of classical particles. The theory represents a unification of kinetic theory, Brownian motion and field theory. It is self-consistent and is the dynamic generalization of the functional theory of static equilibrium fluids. This gives one a powerful tool for investigating the existence of ergodic-nonergodic transitions near the liquid-glass transition.
A critical examination of some basic conceptual issues in classical statistical mechanics is attempted, with a view to understanding the origins, structure and statuts of that discipline. Due attention is given to the interplay between physical and mathematical aspects, particularly regarding the role of probability theory. The focus is on the equilibrium case, which is currently better understood, serving also as a prelude for a further discussion of non-equilibrium statistical mechanics.
Assuming a classical statistical system of point particles the fundamental equations of continuum thermomechanics (continuity equation, equation of motion, and energy equation) shall be derived exactly. The macroscopic state functions (density, velocity, stress, energy density, heat flux) are interpreted as expected values.
A time-dependent statistical description of multiple particle breakage is presented. The approach combines the Tsallis non-extensive entropy with a fractal kinetic equation for the time variation of the number of fragments. The obtained fragment size distribution function is tested by fitting some experimental reports.
The exact equations of motion for microscopic density of classical particles number with account of inter-particle interactions and external field in closed form are derived. An integral equation for equilibrium distributions of the particles is deduced. No statistical or probabilistic hypotheses and assumption in these deductions have been used. Some well known results of equilibrium statistical mechanics are deduced from the obtained equations as simple limiting cases. The wave equation for almost homogeneous systems with inter-particle interactions are obtained. Connection between inter-par…
The s=1/2 Ising chain with uniform nearest-neighbor and next-nearest-neighbor coupling is used to construct a system of floating particles characterized by motifs of up to six consecutive local spins. The spin couplings cause the assembly of particles which, in turn, remain free of interaction energies even at high density. All microstates are configurations of particles from one of three different sets, excited from pseudo-vacua associated with ground states of periodicities one, two, and four. The motifs of particles and elements of pseudo-vacuum interlink in two shared site variables. The s…
Within the theory of statistical ensemble, the so-called $μPT$ ensemble describes equilibrium systems that exchange energy, particles, and volume with the surrounding. General, model-independent features of volume and particle number statistics are derived. Non-analytic points of the partition function are discussed in connection with divergent fluctuations and ensemble equivalence. Quantum and classical ideal gases, and a model of Bose gas with mean-field interactions are discussed as examples of the above considerations.
We present predictions for the statistical error due to finite sampling in the presence of thermal fluctuations in molecular simulation algorithms. Specifically, we establish how these errors depend on Mach number, Knudsen number, number of particles, etc. Expressions for the common hydrodynamic variables of interest such as flow velocity, temperature, density, pressure, shear stress and heat flux are derived using equilibrium statistical mechanics. Both volume-averaged and surface-averaged quantities are considered. Comparisons between theory and computations using direct simulation Monte Car…
For open quantum systems, the Gaussian environmental dissipative effect can be represented by statistical quasi-particles, namely, dissipatons. We exploit this fact to establish the dissipaton thermofield theory. The resulting generalized Langevin dynamics of absorptive and emissive thermofield operators are effectively noise-resolved. The system-bath entanglement theorem is then readily followed between an important class of nonequilibrium steady-state correlation functions. All these relations are validated numerically. A simple corollary is the transport current expression, which exactly re…
We use the non-equilibrium statistical field theory for classical particles recently developed by Mazenko and Das and Mazenko, together with the free generating functional for particles initially correlated in phase space derived in Bartelmann et al. to study the impact of initial correlations on the equation of state of real gases. We first show that we can reproduce the well known van der Waals equation of state for uncorrelated initial conditions using this approach. We then impose correlated initial conditions and study their qualitative and quantitative effect on the equation of state of …
We argue that a particle language provides a conceptually simple framework for the description of anomalous equilibration in isolated quantum systems. We address this paradigm in the context of integrable models, which are those with particles that are stable against decay. In particular, we demonstrate that a complete description of equilibrium ensembles for interacting integrable models requires a formulation built from the mode occupation numbers of the underlying particle content, mirroring the case of non-interacting particles. This yields an intuitive physical interpretation of generaliz…
A classical particle system coupled with a thermostat driven by an external constant force reaches its steady state when the ensemble-averaged drift velocity does not vary with time. The statistical mechanics of such a system is derived merely based on the equal probability and ergodicity principles, free from any conclusions drawn on equilibrium statistical mechanics or local equilibrium hypothesis. The momentum space distribution is determined by a random walk argument, and the position space distribution is determined by employing the equal probability and ergodicity principles. The express…
A chain of kinetic equations for non-equilibrium one-particle, two-particle and $ s $-particle distribution functions of particles which take into account nonlinear hydrodynamic fluctuations is proposed. The method of Zubarev non-equilibrium statistical operator with projection is used. Nonlinear hydrodynamic fluctuations are described with non-equilibrium distribution function of collective variables that satisfies generalized Fokker-Planck equation. On the basis of the method of collective variables, a scheme of calculation of non-equilibrium structural distribution function of collective va…
In this paper we presented an overview on our works. More than ten years ago, we proposed a new fundamental equation of nonequilibrium statistical physics in place of the present Liouville equation. That is the stochastic velocity type's Langevin equation in 6N dimensional phase space or its equivalent Liouville diffusion equation. This equation is time-reversed asymmetrical. It shows that the form of motion of particles in statistical thermodynamic systems has the drift-diffusion duality, and the law of motion of statistical thermodynamics is expressed by a superposition of both the law of dy…
We show that extremely simple systems of a not too large number of particles can be simultane- ously thermally stable and complex. To such an end, we extend the statistical complexity's notion to simple configurations of non-interacting particles, without appeal to probabilities, and discuss configurational properties.
Introducing the Boltzmann distribution very early in a statistical thermodynamics course (in the spirit of Feynmann) has many didactic advantages, in particular that of easily deriving the Gibbs entropy formula. In this note, a short derivation is proposed from the fundamental postulate of statistical mechanics and basics calculations accessible to undergraduate students.
Appealing to the 1902 Gibbs' formalism for classical statistical mechanics (SM), the first SM axiomatic theory ever that successfully explained equilibrium thermodynamics, we will here show that already at the classical level there is a strong correlation between the Renyi's exponent $α$ and the number of particles for very simple systems. No reference to heat baths is needed for such a purpose.
It was recently shown by Bartelmann et al. how correlated initial conditions can be introduced into the statistical field theory for classical particles pioneered by Das and Mazenko. In this paper we extend this development from the canonical to the grand canonical ensemble for a system satisfying statistical homogeneity and isotropy. We do this by translating the probability distribution for the initial phase space coordinates of the particles into an easy diagrammatic representation and then using a variant of the Mayer cluster expansion to sum over particle numbers. The grand canonical gene…
The equations of evolutionary change by natural selection are commonly expressed in statistical terms. Fisher's fundamental theorem emphasizes the variance in fitness. Quantitative genetics expresses selection with covariances and regressions. Population genetic equations depend on genetic variances. How can we read those statistical expressions with respect to the meaning of natural selection? One possibility is to relate the statistical expressions to the amount of information that populations accumulate by selection. However, the connection between selection and information theory has never…
We present a formalism for obtaining the statistical properties of functionals and inverse functionals of the paths of a particle diffusing in a one-dimensional quenched random potential. We demonstrate the implementation of the formalism in two specific examples: (1) where the functional corresponds to the local time spent by the particle around the origin and (2) where the functional corresponds to the occupation time spent by the particle on the positive side of the origin, within an observation time window of size $t$. We compute the disorder average distributions of the local time, the in…
Consistent statistical physical description is given for systems where the elementary excitations are composite objects. Explicit calculational scheme is constructed for the energy density and the total number of thermodynamical degrees of freedom, based on the spectral function of the system. One demonstrates through characteristic examples that single quasiparticle contributions combine non-linearly in these quantities. Relation to the Gibbs paradox is also discussed.
As a rough model for the collective motions of cells and organisms we develop here the statistical mechanics of swarms of self-propelled particles. Our approach is closely related to the recently developed theory of active Brownian motion and the theory of canonical-dissipative systems. Free motion and motion of a swarms confined in an external field is studied. Briefly the case of particles confined on a ring and interacting by repulsive forces is studied. In more detail we investigate self-confinement by Morse-type attracting forces. We begin with pairs N = 2; the attractors and distribution…
A statistical approach to a self-consistent description of kinetic and hydrodynamic processes in systems of interacting particles is formulated on the basis of the nonequilibrium statistical operator method by D.N.Zubarev. It is shown how to obtain the kinetic equation of the revised Enskog theory for a hard sphere model, the kinetic equations for multistep potentials of interaction and the Enskog-Landau kinetic equation for a system of charged hard spheres. The BBGKY hierarchy is analyzed on the basis of modified group expansions. Generalized transport equations are obtained in view of a self…
We discuss recent results of the replica approach to statistical mechanics of a single classical particle placed in a random N(>>1)-dimensional Gaussian landscape. The particular attention is paid to the case of landscapes with logarithmically growing correlations and to its recent generalisations. Those landscapes give rise to a rich multifractal spatial structure of the associated Boltzmann-Gibbs measure. We also briefly mention related results on counting stationary points of random Gaussian surfaces, as well as ongoing research on statistical mechanics in a random landscape constructed loc…
Recently Mazenko and Das and Mazenko introduced a non-equilibrium field theoretical approach to describe the statistical properties of a classical particle ensemble starting from the microscopic equations of motion of each individual particle. We use this theory to investigate the transition from those microscopic degrees of freedom to the evolution equations of the macroscopic observables of the ensemble. For the free theory, we recover the continuity and Jeans equations of a collisionless gas. For a theory containing two-particle interactions in a canonical perturbation series, we find the m…
Quantum statistical mechanics is formulated as an integral over classical phase space. Some details of the commutation function for averages are discussed, as is the factorization of the symmetrization function used for the grand potential and for the multi-particle density. Three binary choices (eight routes) for the average energy are shown to be mutually consistent. An expression for the phase space function that gives the average virial pressure is derived.
Chern-Simons gauge field theory has provided a natural framework to gain deep insight about many novel phenomena in two-dimensional condensed matter. We investigate the nonequilibrium thermodynamics properties of a (two-dimensional) dissipative harmonic particle when the Abelian topological gauge action and the (linear) Brownian motion dynamics are treated on an equal footing. We find out that the particle exhibits remarkable magneticlike features in the quantum domain that are beyond the celebrated Landau diamagnetism: this could be viewed as the non-relativistic Brownian counterpart of the c…
The vacuum is full of virtual particles which exist for short moments of time. In this paper we construct a chaotic model of vacuum fluctuations associated with a fundamental entropic field that generates an arrow of time. The dynamics can be physically interpreted in terms of fluctuating virtual momenta. This model leads to a generalized statistical mechanics that distinguishes fundamental constants of nature.
Random packings of objects of a particular shape are ubiquitous in science and engineering. However, such jammed matter states have eluded any systematic theoretical treatment due to the strong positional and orientational correlations involved. In recent years progress on a fundamental description of jammed matter could be made by starting from a constant volume ensemble in the spirit of conventional statistical mechanics. Recent work has shown that this approach, first introduced by S. F. Edwards more than two decades ago, can be cast into a predictive framework to calculate the packing frac…
Basing on main principles of statistical mechanics only, an exact virial expansion for path probability distribution of molecular Brownian particle in a fluid is derived which connects response of the distribution to perturbations of the fluid and statistical correlations of its molecules with Brownian particle. The expansion implies that (i) spatial spread of these correlations is finite, (ii) this is inconsistent with Gaussian distribution involved by the ``molecular chaos'' hypothesis, and (iii) real path distribution possesses power-law long tails. This means that actual Brownian path neve…
A fundamental pillar of quantum mechanics concerns indistinguishable quantum particles. In three dimensions they may be classified into fermions or bosons, having, respectively, antisymmetric or symmetric wave functions under particle exchange. One of numerous manifestations of this quantum statistics is the tendency of fermions (bosons) to anti-bunch (bunch). In a two-particle scattering experiment with two possible outgoing channels, the probability of the two particles to arrive each at a different terminal is enhanced (with respect to classical particles) for fermions, and reduced for boso…
We propose a new look at the heat bath for two Brownian particles, in which the heat bath as a `system' is both perturbed and sensed by the Brownian particles. Non-local thermal fluctuation give rise to bath-mediated static forces between the particles. Based on the general sum-rule of the linear response theory, we derive an explicit relation linking these forces to the friction kernel describing the particles' dynamics. The relation is analytically confirmed in the case of two solvable models and could be experimentally challenged. Our results point out that the inclusion of the environment …
We propose a method to study the transition to chaos in isolated quantum systems of interacting particles. It is based on the concept of delocalization of eigenstates in the energy shell, controlled by the Gaussian form of the strength function. We show that although the fluctuations of energy levels in integrable and non-integrable systems are principally different, global properties of the eigenstates may be quite similar, provided the interaction between particles exceeds some critical value. In this case the quench dynamics can be described analytically, demonstrating the universal statist…
We discuss a particle system of 5 neighbors with two independent conserved densities. The mean momentum uniquely depends on a pair of the densities and a three-dimensional fundamental diagram is obtained. It shows the phase transition of behavior of asymptotic solution to the system. Moreover, we propose two other systems which have the similar unique dependency obtained numerically.
The Lorentz covariant classical and quantum statistical mechanics and thermodynamics of an ideal relativistic gas of bradyons (particles slower than light), luxons (particles moving with the speed of light) and tachyons (hypothetical particles faster than light) is discussed. The Lorentz covariant formulation is based on the preferred frame approach which among others enables consistent, free of paradoxes description of tachyons. The thermodynamic functions within the covariant approach are obtained both in classical and quantum case.
We model a quantum walk of identical particles that can change their exchange statistics by hopping across a domain wall in a 1D lattice. Such a "statistical boundary" is transparent to single particles and affects the dynamics only by swapping multiple particles arriving together. We find that the two-particle interference is dramatically altered by reflections of these bunched waves at the interface, producing strong measurable asymmetries. Depending on the phases on the two sides, a bunched wavepacket can get completely reflected or split into a superposition of a reflected wave and an anti…
We propose a unified framework to study the turbulent transport problem from the perspective of nonequilibrium statistical mechanics. By combining Krarichnan's turbulence thermalization assumption and Ruelle's recent work on nonequilibrium statistical mechanics settings for fluids, we show that the equation for viscous fluid can be viewed as the non-canonical Hamiltonian system perturbed by different thermostats. This allows an analogy between the viscous fluid and the nonequilibrium heat conduction model where the Fourier modes can be regarded as the ''particles''. With this framework, we ref…
A new class of identical particles which may exhibit both Bose and Fermi statistics with respective probabilities $p_b$ and $p_f$ is introduced. Such an uncertainity may be either an intrinsic property of a particle or can be viewed as an ``experimental uncertainity''. Statistical equivalence of such particles and particles obeying parastatistics of infinite order is shown. Generalized statistical distributions are derived and statistical and thermodynamical properties of an ideal gas of the particles are investigated. The physical nature of such particles and the implications of this investig…
The deep connection between thermodynamics, computation, and information is now well established both theoretically and experimentally. Here, we extend these ideas to show that thermodynamics also places fundamental constraints on statistical estimation and learning. To do so, we investigate the constraints placed by (nonequilibrium) thermodynamics on the ability of biochemical signaling networks within cells to estimate the concentration of an external signal. We show that accuracy is limited by energy consumption, suggesting that there are fundamental thermodynamic constraints on statistical…
