我们报道了磁热FeMnP $_{0.75}$ Si $_{0.25}$化合物的合成和结构表征。合成了两种类型的样品（淬火和退火）并进行了结构和磁性表征。我们已经发现，晶体有序度的微小变化会引起磁性的巨大变化。退火后的样品有序度较高，是反铁磁的，净磁矩为零。淬灭态样品的净矩为1.26 $μ_B$ /f. u。和类亚铁磁性的行为。理论计算给出相当大的值的Fe和Mn的磁矩，无论是在四面体和金字塔晶格网站上占领。最大的是金字塔形位点的Mn矩达到高达2.8 $μ_B$ /原子的值。
英文摘要：
We report on the synthesis and structural characterization of the magnetocaloric FeMnP$_{0.75}$Si$_{0.25}$ compound. Two types of samples (as quenched and annealed) were synthesized and characterized structurally and magnetically. We have found that minute changes in the degree of crystallographic order causes a large change in the magnetic properties. The annealed sample, with higher degree of order is antiferromagnetic with a zero net moment. The as-quenched sample has a net moment of 1.26 $μ_B$/f.u. and ferrimagnetic-like behavior. Theoretical calculations give rather large values for the Fe and Mn magnetic moments, both when occupied on the tetrahedral and pyramidal lattice site. The largest being the Mn moment for the pyramidal site reaches values as high as 2.8 $μ_B$/atom.
We predict a transition to metallicity when a sufficient amount of disorder is induced in graphene. Calculations were performed by means of a first principles stochastic quench method. The resulting amorphous graphene can be seen as nanopatches of graphene that are connected by a network of disordered small and large carbon rings. The buckling is minimal and we believe that it is a result of averaging of counteracting random in-plane stress forces. The linear response conductance is obtained by a model theory as function of lattice distortions. Such metallic behaviour is a much desired propert…
Mastery of order-disorder processes in highly non-equilibrium nanostructured oxides has significant implications for the development of emerging energy technologies. However, we are presently limited in our ability to quantify and harness these processes at high spatial, chemical, and temporal resolution, particularly in extreme environments. Here we describe the percolation of disorder at the model oxide interface LaMnO$_3$ / SrTiO$_3$, which we visualize during in situ ion irradiation in the transmission electron microscope. We observe the formation of a network of disorder during the initia…
We study the effect of strong disorder on topology and entanglement in quench dynamics. Although disorder-induced topological phases have been well studied in equilibrium, the disorder-induced topology in quench dynamics has not been explored. In this work, we predict a disorder-induced topology of post-quench states characterized by the quantized dynamical Chern number and the crossings in the entanglement spectrum in $(1+1)$ dimensions. The dynamical Chern number undergoes transitions from zero to unity, and back to zero when increasing the disorder strength. The boundaries between different…
In this work the conducting properties of graphene lattice with a particular concentration of defect (5\% and 10\%) has been studied. The real space block recursion method introduced by Haydock et al. has been used in presence of the random distribution of defects in graphene. This Green function based method is found more powerful than the usual reciprocal based methods which need artificial periodicity. Different resonant states appear because of the presence of topological and local defects are studied within the framework of Green function.
Given the consensus that pressure improves cation order in most of known materials, a discovery of pressure-induced disorder could require reconsideration of order-disorder transition in solid state physics/chemistry and geophysics. Double perovskites Y2CoIrO6 and Y2CoRuO6 synthesized at ambient pressure show B-site order, while the polymorphs synthesized at 6 and 15 GPa are partially-ordered and disordered respectively. With the decrease of ordering degrees, the lattices are shrunken and the crystal structures alter from monoclinic to orthorhombic symmetry. Correspondingly, long-range ferrima…
We study disorder induced topological phase transitions in magnetically doped (Bi, Sb)$_2$Te$_3$ thin films, by using large scale transport simulations of the conductance through a disordered region coupled to reservoirs in the quantum spin Hall regime. Besides the disorder strength, the rich phase diagram also strongly depends on the magnetic exchange field, the Fermi level, and the initial topological state in the undoped and clean limit of the films. In an initially trivial system at non-zero exchange field, varying the disorder strength can induce a sequence of transitions from a normal in…
Polymorphs are common in nature and can be stabilized by applying external pressure in materials. The pressure/strain can also be induced by the gradually accumulated radiation disorder. However, in semiconductors, the radiation disorder accumulation typically results in the amorphization instead of engaging polymorphism. By studying these phenomena in gallium oxide we found that the amorphization may be prominently suppressed by the monoclinic to orthorhombic phase transition. Utilizing this discovery, a highly oriented single-phase orthorhombic film on the top of the monoclinic gallium oxide…
Non-Hermiticity in Weyl Hamiltonian leads to the realization of Weyl exceptional rings and flat bands inside the Weyl exceptional rings. Recently, the platform of non-Hermitian physics is extended to many-body or disordered systems where quasiparticles possess finite lifetime. Here, we clarify that the deviation from unitarity limit in a disordered Weyl semimetal leads to the generation of Weyl exceptional rings regardless of the detail of the scattering potential. In the case of topological Dirac semimetals, hybrid rings and flat bands without vorticity of complex-energy eigenvalues are reali…
The translational symmetry of solids gives rise to the existence of low-frequency phonons. In ordered systems, some phonons characterized by different wavevectors are degenerate, i.e. they share the same frequency $ω$; in finite-size systems, phonons form a discrete set of bands with $n_q(ω)$-fold degeneracy. Here we focus on understanding how this degeneracy is lifted in the presence of disorder, and its physical implications. Using standard degenerate perturbation theory and simple statistical considerations, we predict the dependence of the disorder-induced frequency width of phonon bands t…
