We calculate the absorption efficiency of the composite grains, made up of host silicate spheroids and inclusions of ices/graphites/or voids, in the spectral region $7.0-14.0μ$m The absorption efficiencies of the composite spheroidal grains for three axial ratios are computed using the discrete dipole approximation (DDA) as well as using the effective medium approximation & T-Matrix (EMT-Tmatrix) ap proach. We study the absorption as a function of the volume fraction of the inclusions and porosity. In particular, we study the variation in the $10.0μ$m feature with the volume fraction of the inclusions and porosity. We then calculate the infrared fluxes for these composite grains and compare the model curves with the average observed IRAS-LRS curve, obtained for several circumstellar dust shells around stars. These results on the composite grains show that the wavelength of the peak absorption shifts and the width of the $10.0μ$m feature varies with the variation in the volume fraction of the inclusions. The model curves for composite grains with axial ratios not very large (AR$\sim$1.3) and volume fractions of inclusions with f=0.20, and dust temperature of about 250-300$^{\circ}$K, fit the observed emission curves reasonably well.
The properties of interstellar grains, such as grain size distribution and grain porosity, are affected by interstellar processing, in particular, coagulation and shattering, which take place in the dense and diffuse interstellar medium (ISM), respectively. In this paper, we formulate and calculate the evolution of grain size distribution and grain porosity through shattering and coagulation. For coagulation, we treat the grain evolution depending on the collision energy. Shattering is treated as a mechanism of forming small compact fragments. The balance between these processes are determined…
The radiative properties of interstellar dust are affected not only by the grain size distribution but also by the grain porosity. We develop a model for the evolution of size-dependent grain porosity and grain size distribution over the entire history of galaxy evolution. We include stellar dust production, supernova dust destruction, shattering, coagulation, and accretion. Coagulation is {assumed to be} the source of grain porosity. We use a one-zone model with a constant dense gas fraction ($η_\mathrm{dense}$), which regulates the balance between shattering and coagulation. We find that por…
It is generally agreed that interstellar dust grains consist of two main components, namely, silicates and graphites. Some models, like MRN model, assume these grains to be homogeneous spheres following a power law size distribution. This paper presents, in the framework of Mie theory, a parametrization of extinction spectrum curves of the silicates and the graphites separately in terms of frequency and the minimum and maximum of sizes in the distribution. Analytic expressions in ultraviolet and far-ultraviolet are presented for both types of grains.The values of maximum and minimum sizes for …
The depletion of iron and sulphur into dust in the interstellar medium and the exact nature of interstellar amorphous silicate grains is still an open question. We study the incorporation of iron and sulphur into amorphous silicates of olivine- and pyroxene-type and their effects on the dust spectroscopy and thermal emission. We used the Maxwell-Garnett effective-medium theory to construct the optical constants for a mixture of silicates, metallic iron, and iron sulphide. We also studied the effects of iron and iron sulphide in aggregate grains. Iron sulphide inclusions within amorphous silica…
Absorption lines in the spectra of distant quasars whose sightlines pass through foreground galaxies provide a valuable tool to probe the dust and gas compositions of the interstellar medium (ISM) in galaxies. The first evidence of silicate dust in a quasar absorption system (QAS) was provided through our detection of the 10 micron silicate feature in the z=0.52 absorber toward the quasar AO 0235+164. We present results from 2 follow-up programs using archival Spitzer Space Telescope infrared spectra to study the interstellar silicate dust grain properties in a total of 13 QASs at 0.1<z<1.4. W…
Understanding the history and evolution of small bodies, such as dust grains and comets, in planet-forming disks is very important to reveal the architectural laws responsible for the creation of planetary systems. These small bodies in cold regions of the disks are typically considered as mixtures of dust particles with molecular ices, where ices cover the surface of a dust core or are actually physically mixed with dust. Whilst the first case, ice-on-dust, has been intensively studied in the laboratory in recent decades, the second case, ice-mixed-with-dust, present uncharted territory. This…
When Two Worlds Collide: How Collisions Between Silicate and Carbonaceous Nanograins can Drive Complex Chemistry
Universitat Autònoma de Barcelona（巴塞罗那自治大学）；Universitat de Barcelona（巴塞罗那大学）；Accademia delle Scienze di Torino（都灵科学院）；Institució Catalana de Recerca i Estudis Avançats (ICREA)（加泰罗尼亚研究与高级研究所）
The degree of porosity in interstellar dust-grain material is poorly defined, although recent work has suggested that the grains could be highly porous. Aside from influencing the optical properties of the dust, porosity has the potential to affect the chemistry occurring on dust-grain surfaces, via increased surface area, enhanced local binding energies, and the possibility of trapping of molecules within the pores as ice mantles build up on the grains. Through computational kinetics simulations, we investigate how interstellar grain-surface chemistry and ice composition are affected by the p…
Thermally irreversible sulfur chemisorption on silicate grains as a major sulfur reservoir in molecular clouds
Institute of Low Temperature Science, Hokkaido University（北海道大学低温科学研究所）；Department of Chemistry, Hiroshima University（广岛大学化学系）；Departamento de Astrofísica Molecular, Instituto de Física Fundamental, CSIC（西班牙国家研究委员会基础物理研究所分子天体物理学部）；RIKEN Pioneering Research Institute（理研先锋研究机构）
Two different silicate/water ice mixtures representing laboratory analogues of interstellar and circumstellar icy grains were produced in the laboratory. For the first time, optical constants, the real and imaginary parts of the complex refractive index, of such silicate/water ice mixtures were experimentally determined in the mid-infrared spectral region at low temperatures. In addition, optical constants of pure water ice and pure silicates were derived in the laboratory. Two sets of constants were compared, namely, measured constants calculated from the transmission spectra of silicate/wate…
While it is well recognized that interstellar grains are made of amorphous silicates and some form of carbonaceous materials, it remains debated regarding what exact chemical and physical form the carbonaceous component takes. Contemporary grain models assume that the silicate and carbon components are either physically separated, or they form a core-mantle structure, or they agglomerate to form porous composites. The core-mantle model posits that the mantle is made of some sort of aliphatic hydrocarbon materials and is responsible for the 3.4 micrometer absorption feature ubiquitously seen in…
We interpret the interstellar extinction observed towards the Galactic Center (GC) in the wavelength range $λ= 1 - 20\,\mkm$. Its main feature is the flat extinction at $3 - 8\,\mkm$ whose explanation is still a problem for the cosmic dust models. We search for structure and chemical composition of dust grains that could explain the observed extinction. In contrast to earlier works we use laboratory measured optical constants and consider particles of different structure. We show that a mixture of compact grains of aromatic carbon and of some silicate is better suited for reproducing the flat …
Whether ice in cold cosmic environments is physically separated from the silicate dust or mixed with individual silicate moieties is not known. However, different grain models give very different compositions and temperatures of grains. The aim of the present study is a comparison of the mid-IR spectra of laboratory silicate-grains/water-ice mixtures with astronomical observations to evaluate the presence of dust/ice mixtures in interstellar and circumstellar environments. The laboratory data can explain the observations assuming reasonable mass-averaged temperatures for the protostellar envel…
The 9.7-micron silicate absorption profile in the interstellar medium provides important information on the physical and chemical composition of interstellar dust grains. Measurements in the Milky Way have shown that the profile in the diffuse interstellar medium is very similar to the amorphous silicate profiles found in circumstellar dust shells around late M stars, and narrower than the silicate profile in denser star-forming regions. Here, we investigate the silicate absorption profile towards the very heavily obscured nucleus of NGC 4418, the galaxy with the deepest known silicate absorpt…
In dense molecular clouds, interstellar grains are covered by mantles of iced molecules. The formation of the grain mantles has two important consequences: it removes species from the gas phase and promotes the synthesis of new molecules on the grain surfaces. The composition of the mantle is a strong function of the environment which the cloud belongs to. Therefore, clouds in high-zeta galaxies, where conditions -like temperature, metallicity and cosmic rays flux- are different from those in the Milky Way, will have different grain mantles. In the last years, several authors have suggested th…
The composition of silicate dust in the diffuse interstellar medium and in protoplanetary disks around young stars informs our understanding of the processing and evolution of the dust grains leading up to planet formation. Analysis of the well-known 9.7μm feature indicates that small amorphous silicate grains represent a significant fraction of interstellar dust and are also major components of protoplanetary disks. However, this feature is typically modelled assuming amorphous silicate dust of olivine and pyroxene stoichiometries. Here, we analyze interstellar dust with models of silicate du…
The formation and growth of refractory matter on pre-existing interstellar dust grain surfaces was studied experimentally by annealing neon-ice matrices in which potential precursors of silicate grains (Mg and Fe atoms, SiO and SiO$_2$ molecules) and of solid carbon (C$_n$ molecules, $n$ = 2-10) were initially isolated. Other molecules, mainly O$_3$, CO, CO$_2$, C$_3$O, and H$_2$O, were embedded at the same time in the matrices. The annealing procedure caused the cold dopants to diffuse and interact in the neon ice. Monitoring the procedure in situ with infrared spectroscopy revealed the disap…
Spinning small silicate grains were recently invoked to account for the Galactic foreground anomalous microwave emission. These grains, if present, will absorb starlight in the far ultraviolet (UV). There is also renewed interest in attributing the enigmatic 2175 Angstrom interstellar extinction bump to small silicates. To probe the role of silicon in the UV extinction, we explore the relations between the amount of silicon required to be locked up in silicates [Si/H]_{dust} and the 2175 Angstrom bump or the far-UV extinction rise, based on an analysis of the extinction curves along 46 Galacti…
The motion of diamagnetic dust particles in interstellar magnetic fields is studied numerically with several different sets of parameters. Two types of behavior are observed, depending on the value of the critical number $R$, which is a function of the grain inertia, the magnetic susceptibility of the material and of the strength of rotation braking. If $R\leq10$, the grain ends up in a static state and perfectly aligned with the magnetic field, after a few braking times. If not, it goes on precessing and nutating about the field vector for a much longer time. Usual parameters are such that th…
Recent space missions have provided information on the physical and chemical properties of interstellar grains such as the ratio $β$ of radiation pressure to gravity acting on the grains in addition to the composition, structure, and size distribution of the grains. Numerical simulation on the trajectories of interstellar grains captured by Stardust and returned to Earth constrained the $β$ ratio for the Stardust samples of interstellar origin. However, recent accurate calculations of radiation pressure cross sections for model dust grains have given conflicting stories in the $β$ ratio of int…
Recent mid-infrared high spatial resolution observations have revealed that active galactic nuclei (AGNs) may host a polar dust region with the size of several pc, and such dust may be carried by radiation from the central engine. The polar dust emission often exhibits very weak or absence of the silicate 10-$μ$m emission feature. A possible explanation is that the polar dust is dominated by micron-sized large grains because these grains do not show the silicate feature, while it remains unclear how large grains are preferentially supplied to the polar region. We here propose a new scenario de…
Cosmic dust models are key ingredients in advancing our understanding of astronomical environments as diverse as interstellar clouds in galaxies, circumstellar envelopes around evolved and young stars, and protoplanetary disks. Such models consist of several dust populations, each with different compositions and size distributions. They may also consider different grain shapes, although most models assume spherical grains. All include a component of silicate dust. The absorption and emission properties of these dust components are calculated from the optical constants of each dust material whi…
Supernova remnants (SNRs) are well-recognised dust producers, but their net dust production rate remains elusive due to uncertainties in grain properties that propagate into observed dust mass uncertainties, and determine how efficiently these grains are processed by reverse shocks. In this paper, we present a detection of polarised dust emission in the Crab pulsar wind nebula, the second SNR with confirmed polarised dust emission after Cassiopeia A. We constrain the bulk composition of the dust with new SOFIA/HAWC+ polarimetric data in band C 89 um and band D 154 um. After correcting for sync…
Core-collapse supernovae can condense large masses of dust post-explosion. However, sputtering and grain-grain collisions during the subsequent passage of the dust through the reverse shock can potentially destroy a significant fraction of the newly formed dust before it can reach the interstellar medium. Here we show that in oxygen-rich supernova remnants like Cassiopeia A the penetration and trapping within silicate grains of the same impinging ions of oxygen, silicon and magnesium that are responsible for grain surface sputtering can significantly reduce the net loss of grain material. We m…
Anomalous microwave emission (AME) is an important Galactic foreground of Cosmic Microwave Background (CMB) radiation. It is believed that the AME arises from rotational emission by spinning polycyclic aromatic hydrocarbons (PAHs) in the interstellar medium (ISM). In this paper, we assume that a population of ultrasmall silicate grains may exist in the ISM, and quantify rotational emissivity from these tiny particles and its polarization spectrum. We found that spinning silicate nanoparticles can produce strong rotational emission when those small grains follow a log-normal size distribution. …
6-14 micron Spitzer spectra obtained at 6 epochs between April 2005 and October 2008 are used to determine temporal changes in dust features associated with Sakurai's Object (V4334 Sgr), a low mass post-AGB star that has been forming dust in an eruptive event since 1996. The obscured carbon-rich photosphere is surrounded by a 40-milliarcsec torus and 32 arcsec PN. An initially rapid mid-infrared flux decrease stalled after 21 April 2008. Optically-thin emission due to nanometre-sized SiC grains reached a minimum in October 2007, increased rapidly between 21-30 April 2008 and more slowly to Oct…
We compiled the polarimetric data for a sample of lines of sight with known abundances of Mg, Si, and Fe. We correlated the degree of interstellar polarization $P$ and polarization efficiency (the ratio of $P$ to the colour excess $E(B-V)$ or extinction $A_V$) with dust phase abundances. We detect an anticorrelation between $P$ and the dust phase abundance of iron in non silicate - containing grains $< [\rm Fe(rest)/H > ]_\rm d$, a correlation between $P$ and the abundance of Si, and no correlation between $P/E(B-V)$ or $P/A_V$ and dust phase abundances. These findings can be explained if main…
We present infrared (IR) and submillimeter observations of the Crab-like supernova remnant (SNR) G54.1+0.3 including 350 micron (SHARC-II), 870 micron (LABOCA), 70, 100, 160, 250, 350, 500 micron (Herschel) and 3-40 micron (Spitzer). We detect dust features at 9, 11 and 21 micron and a long wavelength continuum dust component. The 21 micron dust coincides with [Ar II] ejecta emission, and the feature is remarkably similar to that in Cas A. The IRAC 8 micron image including Ar ejecta is distributed in a shell-like morphology which is coincident with dust features, suggesting that dust has forme…
Dust plays a central role in the unification theory of active galactic nuclei (AGNs). Whether the dust that forms the torus around an AGN is tenth-$μ$m-sized like interstellar grains or much larger has a profound impact on correcting for the obscuration of the dust torus to recover the intrinsic spectrum and luminosity of the AGN. Here we show that the ratio of the optical extinction in the visual band ($A_V$) to the optical depth of the 9.7 $μ$m silicate absorption feature ($Δτ_{9.7}$) could potentially be an effective probe of the dust size. The anomalously lower ratio of $A_V/Δτ_{9.7} \appr…
We study the light scattering properties of random ballistic aggregates constructed in Shen et al. (Paper I). Using the discrete-dipole-approximation, we compute the scattering phase function and linear polarization for random aggregates with various sizes and porosities, and with two different compositions: 100% silicate and 50% silicate-50% graphite. We investigate the dependence of light scattering properties on wavelength, cluster size and porosity using these aggregate models. We find that while the shape of the phase function depends mainly on the size parameter of the aggregates, the li…
We investigate the abundance and properties (especially, grain size) of dust in galaxy halos using available observational data in the literature. There are two major sets of data. One is (i) the reddening curves at redshifts $z\sim 1$ and 2 derived for Mg II absorbers, which are assumed to trace the medium in galaxy halos. The other is (ii) the cosmic extinction up to $z\sim 2$ mainly traced by distant background quasars. For (i), the observed reddening curves favor a grain radius of $a\sim 0.03~μ$m for silicate, while graphite is not supported because of its strong 2175 Å bump. Using amorpho…
Context. Excess microwave emission, commonly known as anomalous microwave emission (AME), is now routinely detected in the Milky Way. Although its link with the rotation of interstellar (carbonaceous) nano-grains seems to be relatively well established at cloud scales, large-scale observations show a lack of correlation between the different tracers of nano-carbons and AME, which has led the community to question the viability of this link. Aims. Using ancillary data and spinning dust models for nano-carbons and nano-silicates, we explore the extent to which the AME that come out of the Galact…
To model the cold dust emission observed in the diffuse interstellar medium, in dense molecular clouds or in cold clumps that could eventually form new stars, it is mandatory to know the physical and spectroscopic properties of this dust and to understand its emission. This work is a continuation of previous studies aiming at providing astronomers with spectroscopic data of realistic cosmic dust analogues for the interpretation of observations. Ferromagnesium amorphous silicate dust analogues were produced with a mean composition close to $\mathrm{Mg_{1-x}Fe_{x}SiO_3}$ with x = 0.1, 0.2, 0.3, …
In a series of two recent papers, the frequency and size distribution dependence of extinction spectra for astronomical silicate and graphite grains was analyzed by us in the context of MRN type interstellar dust models. These grains were taken to be homogeneous spheres following the power law $(a^{-3.5})$ size distribution which is very much in use. The analytic formulas were obtained for the graphite and silicate grains in wavelength range 1000Å- 22,500Åand their utility was demonstrated. In this paper of the series, we present analytic formulas for the scattering and absorption spectrum of …
We modelled dust grain-size distributions for carbonaceous and silicates dust, as well as for free-flying iron nanoparticles in the environment of a $γ$-ray burst (GRB) afterglow, GRB 180325A. This GRB, at $z=2.2486$, has an unambiguous detection of the 2175 Å extinction feature with $R_V=4.58$ and $A_V=1.58$. In addition to silicates, polycyclic aromatic hydrocarbons (PAH), and graphite, we used iron nanoparticles grain-size distributions for the first time to model the observed extinction curve of GRB 180325A. We fit the observed extinction for four model permutations, using 232 sets of sili…
Cold dust grains emission in the FIR/submm is usually expressed as a modified black body law in which the dust mass absorption coefficient (MAC), is described with a temperature- and wavelength-independent emissivity spectral index, beta. However, numerous data from space and balloon-born missions and recently from Herschel and Planck show that dust emission is not well understood, as revealed by the observed anti-correlation of beta with the grain temperature. In order to give astronomers the necessary data to interpret FIR/submm observations, we synthesised analogues of interstellar amorphou…
FU Orionis-type stars are young stellar objects showing large outbursts due to highly enhanced accretion from the circumstellar disk onto the protostar. FUor-type outbursts happen in a wide variety of sources from the very embedded ones to those with almost no sign of extended emission beyond the disk. The subsequent eruptions might gradually clear up the obscuring envelope material and drive the protostar on its way to become a disk-only T Tauri star. We used VLT/VISIR to obtain the first spectra that cover the 8-13 $μ$m mid-infrared wavelength range in low-resolution of five recently discove…
We calculate the absorption efficiencies of composite silicate grains with inclusions of graphite and silicon carbide in the spectral range 5--25$\rm μm$. We study the variation in absorption profiles with volume fractions of inclusions. In particular we study the variation in the wavelength of peak absorption at 10 and 18$\rm μm$. We also study the variation of the absorption of porous silicate grains. We use the absorption efficiencies to calculate the infrared flux at various dust temperatures and compare with the observed infrared emission flux from the circumstellar dust around some M-Typ…
Depletion studies provide a way to understand the chemical composition of interstellar dust grains. We here examine 23 gamma-ray bursts (GRB) optical afterglow spectra (spanning 0.6<z<5.0) and compare their silicon and iron dust-phase column densities with different extinction curve parameters to study the composition of the interstellar dust grains in these high-redshift GRB host galaxies. The majority of our sample (87%) show featureless extinction curves and only vary in shape. We observe strong correlations (with >96% significance) between the total-to-selective extinction, R_V, and the du…
Context. A porous and/or fractal description can generally be applied where particles have undergone coagulation into aggregates. Aims. To characterise finite-sized, porous and fractal particles and to understand the possible limitations of these descriptions. Methods. We use simple structure, lattice and network considerations to determine the structural properties of irregular particles. Results. We find that, for finite-sized aggregates, the terms porosity and fractal dimension may be of limited usefulness and show with some critical and limiting assumptions, that highly-porous aggregates (…
We report a NanoSIMS search for presolar grains in the CM chondrites Asuka (A) 12169 and A12236. We found 90 presolar O-rich grains and 25 SiC grains in A12169, giving matrix-normalized abundances of 275 (+55/-50, 1$σ$) ppm or, excluding an unusually large grain, 236 (+37/-34) ppm for O-rich grains and 62 (+15/-12) ppm for SiC grains. For A12236, 18 presolar silicates and 6 SiCs indicate abundances of 58 (+18/-12) and 20 (+12/-8) ppm, respectively. The SiC abundances are in the typical range of primitive chondrites. The abundance of presolar O-rich grains in A12169 is essentially identical to …
In protoplanetary discs, the coagulation of dust grains into large aggregates still remains poorly understood. Grain porosity appears to be a promising solution to allow the grains to survive and form planetesimals. Furthermore, dust shattering has generally been considered to come only from collisional fragmentation; however, a new process was recently introduced, rotational disruption. We wrote a one-dimensional code that models the growth and porosity evolution of grains as they drift to study their final outcome when the two shattering processes are included. When simulating the evolution …
