We show that some composite pulses widely employed in NMR experiments are regarded as non-adiabatic geometric quantum gates with Aharanov-Anandan phases. Thus, we reveal the presence of a fundamental issue on quantum mechanics behind the traditional technique of the composite pulses. To examine the robustness of such composite pulses against fluctuations, we present a practical noise model in a two-level system. Then, we find that the composite pulses possesses purely geometrical nature even under a specific type of fluctuations.
A geometrical approach to non-adiabatic transitions in quantum theory: applications to NMR, over-barrier reflection and parametric excitation of quantum oscillator
High performance quantum information processing requires efficient control of undesired decohering effects, which are present in realistic quantum dynamics. To deal with this issue, a powerful strategy is to employ transitionless quantum driving (TQD), where additional fields are added to speed up the evolution of the quantum system, achieving a desired state in a short time in comparison with the natural decoherence time scales. In this paper, we provide an experimental investigation of the performance of a generalized approach for TQD to implement shortcuts to adiabaticity in nuclear magneti…
We experimentally demonstrate composite stimulated Raman adiabatic passage (CSTIRAP), which combines the concepts of composite pulse sequences and adiabatic passage. The technique is applied for population transfer in a rare-earth doped solid. We compare the performance of CSTIRAP with conventional single and repeated STIRAP, either in the resonant or the highly detuned regime. In the latter case, CSTIRAP improves the peak transfer efficiency and robustness, boosting the transfer efficiency substantially compared to repeated STIRAP. We also propose and demonstrate a universal version of CSTIRA…
The error-robust and short composite operations named ConCatenated Composite Pulses (CCCPs), developed as high-precision unitary operations in quantum information processing (QIP), are derived from composite pulses widely employed in nuclear magnetic resonance (NMR). CCCPs simultaneously compensate for two types of systematic errors, which was not possible with the known composite pulses in NMR. Our experiments demonstrate that CCCPs are powerful and versatile tools not only in QIP but also in NMR.
Geometric quantum gates in liquid-state NMR based on a cancellation of dynamical phases
将非绝热几何相位应用于量子计算的建议称为双环方法[S.- L. Zhu和Z. D. Wang，Phys.Rev.A { \bf 67}，022319（2003）]在液态NMR量子计算机中得到证明。使用自旋回波技术，原来的方法进行修改，使量子门实现在一个标准的高精度NMR系统的化学分析。我们证明了动力学相位被成功地消除，实现了一个单量子比特的量子门，虽然保真度不是很高。
This paper presents a systematic study of applying composite method approximations with locally dense basis sets (LDBS) to efficiently calculate NMR shielding constants in small and medium-sized molecules. The pcSseg-n series of basis sets are shown to have similar accuracy to the pcS-n series when n $\geq1$ and can slightly reduce compute costs. We identify two different LDBS partition schemes that perform very effectively for density functional calculations. We select a large subset of the recent NS372 database containing 290 H, C, N, and O shielding values evaluated by reference methods on …
We propose various composite $π$-pulse sequences for implementing robust z-axis rotation gates widely used in quantum information processing (QIP) scenarios, and discuss their error tolerance of the pulse strength error (PSE) and off-resonance error (ORE), i.e., two typical systematic errors in NMR systems. Compared to existing composite gates, our designed composite pulses exhibit higher gate fidelity and shorter sequence time cost. Furthermore, such short pulse sequences are generalized by simple analytic formulas which can suppress these errors to any desired order simultaneously with linea…
We evaluate various sources of errors that occur when attempting to produce a specified coherent change of a two-state quantum system using six popular coherent control techniques: resonant excitation, adiabatic following, composite adiabatic passage, universal composite pulses, shortcut to adiabaticity, and single-shot shaped pulses. As error sources we consider spatial intensity distribution, transit time variation, inhomogeneous broadening, Doppler broadening, unwanted chirp and shape errors. For the various error types different techniques emerge as the best performers but overall, we find…
Adiabatic elimination is a perturbative model reduction technique based on timescale separation and often used to simplify the description of composite quantum systems. We here analyze a quantum experiment where the perturbative expansion can be carried out to arbitrary order, such that: (i) we can formulate in the end an exact reduced model in quantum form; (ii) as the series provides accuracy for ever larger parameter values, we can discard any condition on the timescale separation, thereby analyzing the intermediate regime where the actual experiment is performing best; (iii) we can clarify…
The non-local nature of the correlations possessed by quantum systems may be revealed by experimental demonstrations of the violation of Bell-type inequalities. Recent work has placed bounds on the correlations that quantum systems can possess in an actual experiment. These bounds were limited to a composite quantum system comprising of a few lower-dimensional subsystems. In a more general approach, it has been shown that fewer body correlations can reveal the non-local nature of the correlations arising from a quantum mechanical description of nature. Such tests on the correlations can be tra…
When a composite Lindblad system consists of weakly coupled sub-systems with fast and slow timescales, the description of slow dynamics can be simplified by discarding fast degrees of freedom. This model reduction technique is called adiabatic elimination. While second-order perturbative expansion with respect to the timescale separation has revealed that the evolution of a reduced state is completely positive, this paper presents an example exhibiting complete positivity violation in the fourth-order expansion. Despite the non-uniqueness of slow dynamics parametrization, we prove that complet…
We present a complete topological characterization of a bilayer composite of two Chern insulators (specifically, Haldane models) and explicitly establish the bulk-boundary correspondences. We show that an appropriately defined Chern number accurately maps out all the possible phases of the system and remains well-defined even in the presence of degeneracies in the occupied bands. Importantly, our result paves the way for realizing adiabatic preparation of monolayer Chern insulators. This has been a major challenge till date, given the impossibility of unitarily connecting inequivalent topologi…
本文介绍了用双扫描法设计高分辨核磁共振宽带激发脉冲的方法。我们首先展示了一个脉冲序列的设计，产生宽带激发的布洛赫球赤道与相位线性分散的频率。我们展示了如何通过两个绝热反演（扫描）之间的嵌套自由演化来重新聚焦这种线性色散。然后，我们将展示如何将这种结构推广到激励任意大带宽，而不增加峰值射频幅度，并通过纳入更多的绝热扫描。最后，我们展示了如何基本的设计，然后可以被修改，以提供一个宽带$x$旋转在任意大的带宽和有限的射频幅度。显示了$99.5\%$ D $_2$ 0样品中残余HDO信号的实验激发曲线作为共振偏移的函数。激发的应用显示为丙氨酸标记样品中的$^{13}$ C激发。
This work addresses quantum adiabatic decoherence of many-body spin systems coupled with a boson field in the framework of open quantum systems theory. We generalize the traditional spin-boson model by considering a system-environment interaction Hamiltonian that represents a partition of non-interacting subsystems and highlights the collective correlation that appears exclusively due to the coupling with a common environment. Remarkably, this simple, exactly solvable model encompasses relevant aspects of a many-body open quantum system and features the subtle quantum effects that arise when t…
Probing an atomic resonance without disturbing it is an ubiquitous issue in physics. This problem is critical in high-accuracy spectroscopy or for the next generation of atomic optical clocks. Ultra-high resolution frequency metrology requires sophisticated interrogation schemes and robust protocols handling pulse length errors and residual frequency detuning offsets . This review reports recent progress and perspective in such schemes, using sequences of composite laser-pulses tailored in pulse duration, frequency and phase, inspired by NMR techniques and quantum information processing. After…
