Based on the observation that the thermodynamic equilibrium free energy of an open quantum system in contact with a thermal environment can be understood as the difference between the free energy of the total system and that of the bare environment, the validity of the Crooks theorem and of the Jarzynski equality is extended to open quantum systems. No restrictions on the nature of the environment or on the strength of the coupling between system and environment need to be imposed. This free energy entering the Crooks theorem and the Jarzynski equality is closely related to the Hamiltonian of mean force that generalizes the classical statistical mechanical concept of the potential of mean force.
The nonequilibrium Time-Reversible Baker Map provides simple illustrations of the Fluctuation Theorem, the Central Limit Theorem, and the Biased Random Walk. This is material in preparation for the Book form of Carol's and my 2016 Kharagpur Lectures.
It is demonstrated that today's quantum fluctuation theorems are component part of old quantum fluctuation-dissipation relations [Sov.Phys.-JETP 45, 125 (1977)], and typical misunderstandings in this area are pointed out.
We derive a general fluctuation theorem for quantum maps. The theorem applies to a broad class of quantum dynamics, such as unitary evolution, decoherence, thermalization, and other types of evolution for quantum open systems. The theorem reproduces well-known fluctuation theorems in a single and simplified framework and extends the Hatano-Sasa theorem to quantum nonequilibrium processes. Moreover, it helps to elucidate the physical nature of the environment inducing a given dynamics in an open quantum system.
Fluctuation theorems are fundamental results in non-equilibrium thermodynamics. Considering the fluctuation theorem with respect to the entropy production and an observable, we derive a new thermodynamic uncertainty relation which also applies to non-cyclic and time-reversal non-symmetric protocols. Furthermore, we investigate the relation between the thermodynamic uncertainty relation and the correlation between the entropy and the observable.
We give a novel derivation of Holevo's bound using an important result from nonequilibrium statistical physics, the fluctuation theorem. To do so we develop a general formalism of quantum fluctuation theorems for two-time measurements, which explicitly accounts for the back action of quantum measurements as well as possibly non-unitary time evolution. For a specific choice of observables this fluctuation theorem yields a measurement-dependent correction to the Holevo bound, leading to a tighter inequality. We conclude by analyzing equality conditions for the improved bound.
We derive detailed and integral quantum fluctuation theorems for heat exchange in a quantum correlated bipartite thermal system using the framework of dynamic Bayesian networks. Contrary to the usual two-projective-measurement scheme that is known to destroy quantum features, these fluctuation relations fully capture quantum correlations and quantum coherence at arbitrary times.
The fluctuation theorem of Gallavotti and Cohen holds for finite systems undergoing Langevin dynamics. In such a context all non-trivial ergodic theory issues are by-passed, and the theorem takes a particularly simple form. As a particular case, we obtain a nonlinear fluctuation-dissipation theorem valid for equilibrium systems perturbed by arbitrarily strong fields.
The Gallavotti-Cohen fluctuation theorem suggests a general symmetry in the fluctuations of the entropy production, a basic concept in the theory of irreversible processes, based on results in the theory of strongly chaotic maps. We study this symmetry for some standard models of nonequilibrium steady states. We give a general strategy to derive a 'local' fluctuation theorem exploiting the Gibbsian features of the stationary space-time distribution. This is applied to spin flip processes and to the asymmetric exclusion process.
We derive the fluctuation theorem for quantum-state statistics that can be obtained when we initially measure the total energy of a quantum system at thermal equilibrium, let the system evolve unitarily, and record the quantum-state data reconstructed at the end of the process. The obtained theorem shows that the quantum-state statistics for the forward and backward processes is related to the equilibrium free-energy difference through an infinite series of independent relations, which gives the quantum work fluctuation theorem as a special case, and reproduces the out-of-time-order fluctuatio…
We comment on: E. Iyoda, K. Kaneko, and T. Sagawa, "Fluctuation Theorem for Many-Body Pure Quantum States", Phys. Rev. Lett. 119, 100601 (2017). We also respond to the reply by the afore mentioned authors: "arXiv:1712.05172". The response at hand concludes our discussion of the subject on the arXiv.
For macroscopic quantum systems, we study what are measured when equilibrium fluctuations of macrovariables are measured in an ideal way that mimics classical ideal measurements as closely as possible. We find that the symmetrized time correlation (symTC) is always obtained for such measurements. As an important consequence, we show that the fluctuation-dissipation theorem (FDT) is partially violated as a relation between observed quantities in macroscopic quantum systems even if measurements are made in such an ideal way.
We study fluctuation theorems for open quantum systems with a non-Markovian heat bath using the approach of quantum master equations and examine the physical quantities that appear in those fluctuation theorems. The approach of Markovian quantum master equations to the fluctuation theorems was developed by Esposito and Mukamel [Phys. Rev. E {\bf73}, 046129 (2006)]. We show that their discussion can be formally generalized to the case of a non-Markovian heat bath when the local system is linearly connected to a Gaussian heat bath with the spectrum distribution of the Drude form. We found by num…
Near term quantum hardware promises unprecedented computational advantage. Crucial in its development is the characterization and minimization of computational errors. We propose the use of the quantum fluctuation theorem to benchmark the performance of quantum annealers. This versatile tool provides simple means to determine whether the quantum dynamics are unital, unitary, and adiabatic, or whether the system is prone to thermal noise. Our proposal is experimentally tested on two generations of the D-Wave machine, which illustrates the sensitivity of the fluctuation theorem to the smallest a…
We discuss the role of contextuality within quantum fluctuation theorems, in the light of a recent no-go result by Perarnau \emph{et al}. We show that any fluctuation theorem reproducing the two-point-measurement scheme for classical states either admits a notion of work quasi-probability or fails to describe protocols exhibiting contextuality. Conversely, we describe a protocol that smoothly interpolates between the two-point measurement work distribution for projective measurements and Allahverdyan's work quasi-probability for weak measurements, and show that the negativity of the latter is …
It is demonstrated that the "generalized fluctuation-dissipation theorem" [Physica A 106, 443 (1981)] covers the later suggested "fluctuation theorems" and related statistical equalities.
We consider heat fluctuations and fluctuation theorems for systems driven by multiple reservoirs. We establish a fundamental symmetry obeyed by the joint probability distribution for the heat transfers and system coordinates. The symmetry leads to a generalisation of the asymptotic fluctuation theorem for large deviations at large times. As a result the presence of multiple reservoirs influence the tails in the heat distribution. The symmetry, moreover, allows for a simple derivation of a recent exact fluctuation theorem valid at all times. Including a time dependent work protocol we also pres…
It is shown that quantum fluctuation theorems remain unaffected if measurements of any kind and number of observables are performed during the action of a force protocol. That is, although the backward and forward probabilities entering the fluctuation theorems are both altered by these measurements, their ratio remains unchanged. This observation allows to describe the measurement of fluxes through interfaces and, in this way, to bridge the gap between the current theory, based on only two measurements performed at the beginning and end of the protocol, and experiments that are based on conti…
In recent letter [Phys.~Rev.~Lett {\bf 123}, 110602 (2019)], Y.~Hasegawa and T.~V.~Vu derived a thermodynamic uncertainty relation. But the bound of their relation is loose. In this comment, through minor changes, an improved bound is obtained. This improved bound is the same as the one obtained in [Phys.~Rev.~Lett {\bf 123}, 090604 (2019)] by A.~M.~Timpanaro {\it et. al.}, but the derivation here is straightforward.
Recently the ``Fluctuation theorem'' has been criticized and incorrect incorrect contents have been atributed to it. Here I reestablish and comment the original statements.
Exploiting previous results on Markovian dynamics and fluctuation theorems, we study the consequences of memory effects on single realizations of nonequilibrium processes within an open system approach. The entropy production along single trajectories for forward and backward processes is obtained with the help of a recently proposed classical-like non-Markovian stochastic unravelling, which is demonstrated to lead to a correction of the standard entropic fluctuation theorem. This correction is interpreted as resulting from the interplay between the information extracted from the system throug…
Fluctuation theorems for multipartite quantum coherence and correlation dynamics
School of Physics, Northwest University（西北大学物理学院）；Shaanxi Key Laboratory for Theoretical Physics Frontiers（陕西省理论物理前沿重点实验室）；Peng Huanwu Center for Fundamental Theory（彭桓武理论物理中心）；Fundamental Discipline Research Center for Quantum Science and technology of Shaanxi Province（陕西省量子科学与技术基础学科研究中心）；QSTAR, INO-CNR, and LENS（QSTAR、意大利国家研究委员会光学研究所（INO-CNR）和莱纳·塞恩实验中心（LENS））；Department of Chemistry, Stony Brook University, and Department of Physics and Astronomy, Stony Brook University（石溪大学化学系及物理与天文学系）
The fluctuation theorem of the Crooks type is studied for thermodynamic nonlinear- multivariate systems. In particular, a bivariate system having a limit cycle is discussed in detail. It is explicitly shown how the time reversal operation has to be combined with the parity transformation in order to derive the fluctuation theorem for the change of the renormalized entropy. Furthermore, breakdown of the symmetry in a limit-cycle model due to the effect of fluctuations is also discussed.
We derive an extended fluctuation theorem for a geometric pumping in a spin-boson system under a periodic control of environmental temperatures by using a Markovian quantum master equation. We perform the Monte-Carlo simulation and obtain the current distribution, the average current and the fluctuation. Using the extended fluctuation theorem we try to explain the results of our simulation. The fluctuation theorem leads to the fluctuation dissipation relations but the absence of the conventional reciprocal relation.
Quantum analogues of the transient fluctuation theorem(TFT) and steady-state fluctuation theorem(SSFT) are investigated for a harmonic oscillator linearly coupled with a harmonic reservoir. The probability distribution for the work done externally is derived and quantum correction for TFT and SSFT are calculated.
A generalization of fluctuation theorems in stochastic processes is proposed. The new theorem is written in terms of posterior probabilities, which are introduced via the Bayes theorem. In usual fluctuation theorems, a forward path and its time reversal play an important role, so that a microscopically reversible condition is essential. In contrast, the microscopically reversible condition is not necessary in the new theorem. It is shown that the new theorem adequately recovers various theorems and relations previously known, such as the Gallavotti-Cohen-type fluctuation theorem, the Jarzynski…
There are two related theorems which hold even in far from equilibrium, namely fluctuation theorem and Jarzynski equality. Fluctuation theorem states the existence of symmetry of fluctuation of entropy production, while Jarzynski equality enables us to estimate the free energy change between two states by using irreversible processes. On the other hand, relationship between these theorems was investigated by Crooks for the classical stochastic systems. In this letter, we derive quantum analogues of fluctuation theorem and Jarzynski equality microscopic reversibility condition. In other words, …
The Fluctuation Theorem gives an analytical expression for the probability of observing second law violating dynamical fluctuations, in nonequilibrium systems. At equilibrium statistical mechanical fluctuations are known to be ensemble dependent. In this paper we generalise the Transient and Steady State Fluctuation Theorems to various nonequilibrium dynamical ensembles. The Transient and Steady State Fluctuation Theorem for an isokinetic ensemble of isokinetic trajectories is tested using nonequilibrium molecular dynamics simulations of shear flow.
It is shown that the quantum fluctuation dissipation theorem can be considered as a mathematical formulation in the spectral representation of Onsager hypothesis on the regression of fluctuations in physical systems. It is shown that the quantum fluctuation dissipation theorem can be generalized to an arbitrary stationary state.
We present a simple derivation of the integral fluctuation theorems for excess housekeeping heat for an underdamped Langevin system, without using the concept of dual dynamics. In conformity with the earlier results, we find that the fluctuation theorem for housekeeping heat holds when the steady state distributions are symmetric in velocity, whereas there is no such requirement for the excess heat. We first prove the integral fluctuation theorem for the excess heat, and then show that it naturally leads to the integral fluctuation theorem for housekeeping heat. We also derive the modified det…
In the attempt to derive the regression theorem from the fluctuation dissipation theorem several authors claim the violation of the former theorem in the quantum case. Here we pose the question: does it exists a quantum fluctuation dissipation theorem (QFDT) in its conventional interpretation? It is shown that the relation usually called as the QFDT is the condition of detailed macroscopic energetic balance. Following this interpretation the existing conflict between the two theorems in the quantum case is removed.
We establish a novel generalization of the fluctuation theorem for partially-masked nonequilibrium dynamics. We introduce a partial entropy production with a subset of all possible transitions, and show that the partial entropy production satisfies the integral fluctuation theorem.Our result reveals the fundamental properties of a broad class of autonomous nanomachines as well as non-autonomous ones. In particular, our result gives a unified fluctuation theorem for both autonomous and non-autonomous Maxwell's demons, where mutual information plays a crucial role. Furthermore, we derive a novel…
In this study, we rederive the fluctuation theorems in presence of feedback, by assuming the known Jarzynski equality and detailed fluctuation theorems. We first reproduce the already known work theorems for a classical system, and then extend the treatment to the other classical theorems. For deriving the extended quantum fluctuation theorems, we have considered open systems. No assumption is made on the nature of environment and the strength of system-bath coupling. However, it is assumed that the measurement process involves classical errors.
Fluctuation theorem is derived for a quantum current system around a nonequilibrium steady state. It is demonstrated that the fluctuation theorem can be a part of the generalized Green-Kubo formula or a nonlinear response theory of an external field or a change of the chemical potential difference.
In their recent paper [Phys. Rev. Lett. 98, 094101 (2007)], A. Porporato et al. studied the irreversibility and fluctuation theorem for stationary time series. In this comment, we point out that the fluctuation theorem is in fact the trivial outcome of a symmetry operation, and hence its physical contect is less convincing.
Fluctuation Theorem(FT) has been studied as far from equilibrium theorem, which relates the symmetry of entropy production. To investigate the application of this theorem, especially to biological physics, we consider the FT for tilted rachet system. Under, natural assumption, FT for steady state is derived.
The statistics of heat exchange between two classical or quantum finite systems initially prepared at different temperatures are shown to obey a fluctuation theorem.
Fluctuation Theorems are statements about the entropy of systems far from thermal equilibrium. In this Letter relativistic Fluctuation Theorems for Brownian motion are presented and proven. Though there is a known discretization dilemma leading to a certain class of Brownian processes, the Fluctuation Theorems are shown to cover the entire class, and to determine the physical process within this class. In the general-relativistic case the heat responsible for entropy production is the exchanged 4-momentum projected on the local time axis of the heat bath.
We derive an exact expression of the response function to an infinitesimal magnetic field for the Ising-Glauber model with arbitrary exchange couplings.nThe result is expressed in terms of thermodynamic averages and does not depend on initial conditions or dimension of space. The comparison with the equilibrium case gives some understanding on the way the fluctuation-dissipation theorem is violated out-of-equilibrium.
We derive a generalized version of the work fluctuation theorem for nonequilibrium systems with spatio-temporal temperature fluctuations. For chi-square distributed inverse temperature we obtain a generalized fluctuation theorem based on q-exponentials, whereas for other temperature distributions more complicated formulae arise. Since q-exponentials have a power law decay, the decay rate in this generalized fluctuation theorem is much slower than the conventional exponential decay. This implies that work fluctuations can be of relevance for the design of micro and nano structures, since the wo…
Heat fluctuations are studied in a dissipative system with both mechanical and stochastic components for a simple model: a Brownian particle dragged through water by a moving potential. An extended stationary state fluctuation theorem is derived. For infinite time, this reduces to the conventional fluctuation theorem only for small fluctuations; for large fluctuations, it gives a much larger ratio of the probabilities of the particle to absorb rather than supply heat. This persists for finite times and should be observable in experiments similar to a recent one of Wang et al.
In some situations in stochastic thermodynamics not all relevant slow degrees of freedom are accessible. Consequently, one adopts an effective description involving only the visible degrees of freedom. This gives rise to an apparent entropy production that violates standard fluctuation theorems. We present an analytically solvable model illustrating how the fluctuation theorems are modified. Furthermore, we define an alternative to the apparent entropy production: the marginal entropy production which fulfills the fluctuation theorems in the usual form. We show that the non-Markovianity of the…
A unified viewpoint is presented in margin to the ``Work, dissipation and fluctuations in nonequilibrium physics'', Bruxelles 22-25 March, 2006, where the topics were discussed by various authors and it became clear the need that the very different viewpoints be consistently presented by their proponents.
The fluctuation theorem is the fundamental equality in nonequilibrium thermodynamics that is used to derive many important thermodynamic relations, such as the second law of thermodynamics and the Jarzynski equality. Recently, the thermodynamic uncertainty relation was discovered, which states that the fluctuation of observables is lower bounded by the entropy production. In the present Letter, we derive a thermodynamic uncertainty relation from the fluctuation theorem. We refer to the obtained relation as the fluctuation theorem uncertainty relation, and it is valid for arbitrary dynamics, st…
We examine classical, transient fluctuation theorems within the unifying framework of Langevin dynamics. We explicitly distinguish between the effects of non-conservative forces that violate detailed balance, and non-autonomous dynamics arising from the variation of an external parameter. When both these sources of nonequilibrium behavior are present, there naturally arise two distinct fluctuation theorems.
We analyze the microscopic evolution of a system undergoing a far-from-equilibrium thermodynamic process. Explicitly accounting for the degrees of freedom of participating heat reservoirs, we derive a hybrid result, similar in form to both the fluctuation theorem, and a statement of detailed balance. We relate this result to the steady-state fluctuation theorem, and to a free energy relation valid far from equilibrium.
By taking full advantage of the dynamic property imposed by the detailed balance condition, we derive a new refined unified fluctuation theorem (FT) for general stochastic thermodynamic systems. This FT involves the joint probability distribution functions of the final phase space point and a thermodynamic variable. Jarzynski equality, Crooks fluctuation theorem, and the FTs of heat as well as the trajectory entropy production can be regarded as special cases of this refined unified FT, and all of them are generalized to arbitrary initial distributions. We also find that the refined unified FT…
The Fluctuation Theorem (FT) is a generalisation of the Second Law of Thermodynamics that applies to small systems observed for short times. For thermostatted systems it gives the probability ratio that entropy will be consumed rather than produced. In this paper we derive the Transient and Steady State Fluctuation Theorems using Lyapunov weights rather than the usual Gibbs weights. At long times the Fluctuation Theorems so derived are identical to those derived using the more standard Gibbs weights.
We prove a generalized fluctuation-dissipation theorem for a certain class of out-of-time-ordered correlators (OTOCs) with a modified statistical average, which we call bipartite OTOCs, for general quantum systems in thermal equilibrium. The difference between the bipartite and physical OTOCs defined by the usual statistical average is quantified by a measure of quantum fluctuations known as the Wigner-Yanase skew information. Within this difference, the theorem describes a universal relation between chaotic behavior in quantum systems and a nonlinear-response function that involves a time-rev…
We derive the generalized Green-Kubo relation and an integral form of the fluctuation theorem that apply to uniformly sheared granular systems in which microscopic time-reversal symmetry is broken. The former relation provides an exact representation of nonequilibrium steady-state properties as the integral of the time-correlation function describing transient dynamics from an initial quiescent towards a final sheared steady state. We also investigate implications of the integral fluctuation theorem on the approach towards the steady state and on the possible form of the steady-state distribut…
We re-derive the Nyquist theorem and Callen-Welton fluctuation-dissipation theorem (FDT) as a consequence of detailed balance principle applied to a harmonic oscillator. The usage of electrical notions in the beginning makes the consideration understandable for every physicists. Perhaps it is the simplest derivation of these well-known theorems in statistical physics. The classical limit is understandable as a consequence of Waterston-Herapath equipartition theorem.
The inclusion of the factor $\ln (1/N!)$ in the thermodynamic entropy proposed by Gibbs is shown to be equivalent to the validity of the fluctuation theorem with absolute irreversibility for gas mixing.
We present fluctuation theorems and moment generating function equalities for generalized thermodynamic observables and quantum dynamics described by completely positive trace preserving (CPTP) maps, with and without feedback control. Our results include the quantum Jarzynski equality and Crooks fluctuation theorem, and clarify the special role played by the thermodynamic work and thermal equilibrium states in previous studies. We show that for a specific class of generalized measurements, which include projective measurements, unitality replaces microreversibility as the condition for the phy…
Detailed fluctuation theorem, a microscopic version of the steady state fluctuation theorem, has been proposed by Jarzynski and demonstrated in the case of Hamiltonian systems weakly coupled with reservoirs. We show that an identical theorem for phase space compressibility rate can be derived for systems evolving under non-Hamiltonian extended system dynamics, without certain limiting assumptions made in the original work. Our derivation is based on the non-Hamiltonian phase space formulation of statistical mechanics and does not rely on any assumptions of thermodynamic nature. This version of…
We demonstrate the validity of the current fluctuation theorem for a double quantum dot surrounded by four terminals within the Born-, Markov- and secular approximations beyond the Coulomb-blockade regime. The electronic tunneling to two fermionic contacts conserves the total number of electrons, and the internal tunneling is phonon-assisted by two bosonic baths. Adapted choice of thermodynamic parameters between the baths may drive a current against an existing electric or thermal gradient. We study the apparent violation of the fluctuation theorem when only some of the energy and matter curr…
