arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 0902.2855cond-mat.stat-mech
收藏

分子混沌的真相

A truth of molecular chaos

Yuriy E. Kuzovlev

摘要:

研究了粒子与理想气体相互作用的BBGKY方程族。本文揭示了它的解的主要性质,它们是联系粒子路径概率分布及其对气体密度的导数和气体分子与路径之间的不可约多粒子关联的精确恒等式,它们表明,所有关联对路径分布的演化总是作出同等重要的贡献,因此,即使在任意小的气体密度下,精确的理论也不会简化为经典动力学。

英文摘要:

The BBGKY hierarchy of equations for a particle interacting with an ideal gas is investigated. Principal properties of its solutions are disclosed, as exact identities which connect probability distribution of path of the particle, its derivatives in respect to gas density and irreducible many-particle correlations between gas molecules and the path. They show that all the correlations always give equally important contributions to evolution of the path distribution, and therefore the exact theory does not reduce to the classical kinetics even at arbitrary small gas density.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

↑