The energetic environment and the dense interstellar medium in ULIRGs
O. Vega, M. S. Clemens, A. Bressan, G. L. Granato, L. Silva, P. Panuzzo
备注：
6 pages, 4 figures, Proceedings of "A Long Walk Through Astronomy: A Celebration of Luis Carrasco's 60th Birthday", Huatulco, Mexico, October 2008, ed. E. Recillas, L. Aguilar, A. Luna, and J.R. Valdes; RevMexAA (Serie de Conferencias)
We fit the near-infrared to radio spectral energy distributions of a sample of 30 luminous and ultra-luminous infrared galaxies with models that include both starburst and AGN components. The aim of the work was to determine important physical parameters for this kind of objects such as the optical depth towards the luminosity source, the star formation rate, the star formation efficiency and the AGN fraction. We found that although about half of our sample have best-fit models that include an AGN component, only 30 % have an AGN which accounts for more than 10 % of the infrared luminosity whereas all have an energetically dominant starburst. Our models also determine the mass of dense molecular gas. Assuming that this mass is that traced by the HCN molecule, we reproduce the observed linear relation between HCN luminosity and infrared luminosity found by Gao and Solomon (2004). However, our derived conversion factor between HCN luminosity and the mass of dense molecular gas is a factor of 2 smaller than that assumed by these authors. Finally, we find that the star formation efficiency falls as the starburst ages.
We explore the relationship between gas, dust and star formation in a sample of 12 ultra-luminous infrared galaxies (ULIRGs) at high redshift compared to a similar sample of local galaxies. We present new CO observations and/or Spitzer mid-IR spectroscopy for 6 70 micron selected galaxies at z~1 in order to quantify the properties of the molecular gas reservoir, the contribution of an active galactic nuclei (AGN) to the mid-IR luminosity and the star formation efficiency (SFE=LIR/L'CO). The mid-IR spectra show strong polycyclic aromatic hydrocarbon (PAH) emission and our spectral decomposition…
We report on the energetics of molecular outflows in 14 local Ultraluminous Infrared Galaxies (ULIRGs) that show unambiguous outflow signatures (P-Cygni profiles or high-velocity absorption wings) in the far-infrared lines of OH measured with the Herschel/PACS spectrometer. Detection of both ground-state (at 119 and 79 um) and one or more radiatively-excited (at 65 and 84 um) lines allows us to model the nuclear gas (<~300 pc) as well as the more extended components using spherically symmetric radiative transfer models. The highest molecular outflow velocities are found in buried sources, in w…
We present high-resolution ALMA observations of the C$^{18}$O, $^{13}$CO and $^{12}$CO $J$=1-0 isotopologues in 3 nearby ultra-luminous infrared galaxies (ULIRGS; Arp 220, IRAS 13120-5453, IRAS 17208-0014) and 1 nearby post-merger galaxy (NGC 2623). In all 4 systems, we measure high $^{12}$CO/C$^{18}$O and $^{12}$CO/$^{13}$CO integrated line ratios while the $^{13}$CO/C$^{18}$O ratio is observed to be extremely low in comparison to typical star-forming disks, supporting previous work. We investigate whether these unusual line ratios are due to dynamical effects, astrochemistry within the gas, …
We present the results of Spitzer IRS infrared 5-35 micron low-resolution spectroscopic energy diagnostics of ultraluminous infrared galaxies (ULIRGs) at z > 0.15, classified optically as non-Seyferts. Based on the equivalent widths of polycyclic aromatic hydrocarbon emission and the optical depths of silicate dust absorption features, we searched for signatures of intrinsically luminous, but optically elusive, buried AGNs in these optically non-Seyfert ULIRGs. We then combined the results with those of non-Seyfert ULIRGs at z < 0.15 and non-Seyfert galaxies with infrared luminosities L(IR) < …
The Interstellar Boundary Explorer (IBEX) mission is exploring the frontiers of the heliosphere where energetic neutral atoms (ENAs) are formed from charge exchange between interstellar neutral hydrogen atoms and solar wind ions and pickup ions. The geography of this frontier is dominated by an unexpected nearly complete arc of ENA emission, now known as the IBEX 'Ribbon'. While there is no consensus agreement on the Ribbon formation mechanism, it seems certain this feature is seen for sightlines that are perpendicular to the interstellar magnetic field as it drapes over the heliosphere. At th…
It is thought that a class of broad absorption line (BAL) QSOs, characterised by Fe absorption features in their UV spectra (called `FeLoBALs'), could mark a transition stage between the end of an obscured starburst event and a youthful QSO beginning to shed its dust cocoon, where Fe has been injected into the interstellar medium by the starburst. To test this hypothesis we have undertaken deep SCUBA-2 850 $μ$m observations of a sample of 17 FeLoBAL QSOs with 0.89 $\leq$ z $\leq$ 2.78 and -23.31 $\leq$ M$_{B}$ $\leq$-28.50 to directly detect an excess in the thermal emission of the dust which …
I describe DESPOTIC, a code to Derive the Energetics and SPectra of Optically Thick Interstellar Clouds. DESPOTIC represents such clouds using a one-zone model, and can calculate line luminosities, line cooling rates, and in restricted cases line profiles using an escape probability formalism. It also includes approximate treatments of the dominant heating, cooling, and chemical processes for the cold interstellar medium, including cosmic ray and X-ray heating, grain photoelectric heating, heating of the dust by infrared and ultraviolet radiation, thermal cooling of the dust, collisional energ…
We used the Spitzer Infrared Spectrograph (IRS) to study the mid-IR properties and investigate the energetics of 24 Submillimeter Galaxies (SMGs). This is the largest sample of SMGs observed with Spitzer IRS and covers the full extent of properties of the radio-identified population of SMGs in the redshift range of z ~ 0.65-3.2. We observe broad emission features from Polycyclic Aromatic Hydrocarbons (PAHs) in more than 80% of our sample. We find that the median mid-IR spectrum is well described by a starburst component with an additional power law, Fnu ~ nu^-2, likely representing a < 32% AGN…
We present a study of interstellar medium in the host galaxies of 9 QSOs at 0.1<z<0.2 with blackhole masses of $3\times10^7\,M_\odot$ to $3\times10^9\,M_\odot$ based on the far-IR spectroscopy taken with {\it Herschel Space Observatory}. We detect the [OI]63$μ$m ([CII]158$μ$m) emission in 6(8) out of 8(9) sources. Our QSO sample has far-infrared luminosities (LFIR)~several times $10^{11}L_\odot$. The observed line-to-LFIR ratios (LOI/LFIR and LCII/LFIR) are in the ranges of $2.6\times10^{-4}$-$10^{-2}$ and $2.8\times10^{-4}$-$2\times10^{-3}$ respectively (including upper limits). These ratios …
We analyze the physical conditions in the low-ionization component of starburst outflows (in contrast to the high-ionization wind fluid observed in X-rays), based on new Keck/LRIS spectroscopy of partially resolved absorption troughs in near-ultraviolet and optical spectra of Ultraluminous Infrared Galaxies. The large velocity width and blueshift present in seven, atomic transitions indicate a macroscopic velocity gradient within the outflowing gas. The \mgII 2796, 2803 (and \feII 2587, 2600) doublet lines in these data constrains the gas kinematics better than the heavily blended \nad 5892, 9…
The interstellar magnetic field (ISMF) near the heliosphere is a basic part of the solar neighborhood that can only be studied using polarized starlight. Results of an ongoing survey of polarized starlight are analyzed with the goal of linking the interstellar magnetic field that shapes the heliosphere to the nearby field in interstellar space. New results for the direction of the nearby ISMF, based on a merit function that utilizes polarization position angles, identify several magnetic components. The dominant interstellar field, B_pol, is aligned with the direction L,B= 36.2,49.0 (+/-16.0) …
The detection of the amino acid glycine and its amine precursor methylamine on the comet 67P/Churyumov-Gerasimenko by the Rosetta mission provides strong evidence for a cosmic origin of prebiotics on Earth. How and when such complex organic molecules form along the process of star- and planet-formation remains debated. We report the first laboratory detection of glycine formed in the solid phase through atom and radical-radical addition surface reactions under cold dense interstellar cloud conditions. Our experiments, supported by astrochemical models, suggest that glycine forms without the ne…
Supernovae are the most energetic stellar events and influence the interstellar medium by their gasdynamics and energetics. By this, both also affect the star formation positively and negatively. In this paper, we review the development of the complexity of investigations aiming at understanding the interchange between supernovae and their released hot gas with the star-forming molecular clouds. Commencing from analytical studies the paper advances to numerical models of supernova feedback from superbubble scales to galaxy structure. We also discuss parametrizations of star-formation and super…
Context. Interstellar ice is the main form of metal species in dark molecular clouds. Experiments and observations have shown that the ice is significantly processed after the freeze-out of molecules onto grains. The processing is caused by cosmic-ray particles and cosmic-ray-induced UV photons. These transformations are included in current astrochemical models only to a very limited degree. Aims. We aim to establish a model of the "cold" chemistry in interstellar ices and to evaluate its general impact on the composition of interstellar ices. Methods. The ice was treated as consisting of two …
Ethanol (CH$_3$CH$_2$OH) is a relatively common molecule, often found in star forming regions. Recent studies suggest that it could be a parent molecule of several so-called interstellar complex organic molecules (iCOMs). Yet, the formation route of this species remains debated. In the present work, we study the formation of ethanol through the reaction of CCH with one H$_2$O molecule belonging to the ice, as a test case to investigate the viability of chemical reactions based on a "radical + ice component" scheme as an alternative mechanism for the synthesis of iCOMs, beyond the usual radical…
Submillimeter galaxies (SMGs) at $z\gtrsim1$ are luminous in the far-infrared and have star-formation rates, SFR, of hundreds to thousands of solar masses per year. However, it is unclear whether they are true analogs of local ULIRGs or whether the mode of their star formation is more similar to that in local disk galaxies. We target these questions by using Herschel-PACS to examine the conditions in the interstellar medium (ISM) in far-infrared luminous SMGs at z~1-4. We present 70-160 micron photometry and spectroscopy of the [OIV]26 micron, [FeII]26 micron, [SIII]33 micron, [SiII]34 micron,…
We present Herschel far-IR photometry and spectroscopy as well as ground based CO observations of an intermediate redshift (0.21 < z < 0.88) sample of Herschel-selected (ultra)-luminous infrared galaxies (L_IR > 10^11.5L_sun). With these measurements we trace the dust continuum, far-IR atomic line emission, in particular [CII]\,157.7microns, as well as the molecular gas of z~0.3 (U)LIRGs and perform a detailed investigation of the interstellar medium of the population. We find that the majority of Herschel-selected intermediate redshift (U)LIRGs have L_CII/L_FIR ratios that are a factor of abo…
In order to understand the evolution and feedback of Active Galactic Nuclei (AGN) and star formation it is important to use molecular lines as probes of physical conditions and chemistry. We use H$_{2}$S to investigate the impact of starburst and AGN activity on the chemistry of the molecular interstellar medium in luminous infrared galaxies. Using the APEX single dish telescope, we have observed the $1_{10}$--$1_{01}$ transition of ortho-H$_{2}$S at 168 GHz towards the centres of twelve nearby luminous infrared galaxies. We have also observed the same line towards the ultra luminous infrared …
Ice as a Photochemical Shield: Adsorption Energetics and Spectroscopic Modulation of Interstellar Thiocyanates HCSCN and HCSCCH in TMC-1
Department of Chemistry, Indian Institute of Space Science and Technology（印度空间科学与技术学院化学系）；Department of Physics and Astrophysics, University of Delhi（德里大学物理与天体物理学系）
Primordial black holes are a viable dark matter candidate. They decay via Hawking evaporation. Energetic particles from the Hawking radiation interact with interstellar gas, depositing their energy as heat and ionization. For a sufficiently high Hawking temperature, fast electrons produced by black holes deposit a substantial fraction of energy as heat through the Coulomb interaction. Using the dwarf galaxy Leo T, we place an upper bound on the fraction of primordial black hole dark matter. For $M < 5 \times 10^{-17} M_\odot$, our bound is competitive with or stronger than other bounds.
Leading models of galaxy formation require large-scale energetic outflows to regulate the growth of distant galaxies and their central black holes. However, current observational support for this hypothesis at high redshift is mostly limited to rare z>2 radio galaxies. Here we present Gemini-North NIFS Intregral Field Unit (IFU) observations of the [OIII] emission from a z~2 ultraluminous infrared galaxy (L_IR>10^12 solar luminosities) with an optically identified Active Galactic Nucleus (AGN). The spatial extent (~4-8 kpc) of the high velocity and broad [OIII] emission are consistent with tha…
Solid state astrochemical reaction pathways have the potential to link the formation of small nitrogen-bearing species, like NH3 and HNCO, and prebiotic molecules, specifically amino acids. To date, the chemical origin of such small nitrogen containing species is still not well understood, despite the fact that ammonia is an abundant constituent of interstellar ices toward young stellar objects and quiescent molecular clouds. This is mainly because of the lack of dedicated laboratory studies. The aim of the present work is to experimentally investigate the formation routes of NH3 and HNCO thro…
An interstellar energetic and non-aqueous pathway to peptide formation
Aarhus University（奥胡斯大学）；Queen Mary University of London（伦敦大学玛丽女王学院）；HUN-REN Institute for Nuclear Research (Atomki)（匈牙利研究与教育网络核研究所）；University of Debrecen（德布勒森大学）；Queen’s University Belfast（贝尔法斯特女王大学）
Supernovae are the most energetic stellar events and influence the interstellar medium by their gasdynamics and energetics. By this, both also affect the star formation positively and negatively. In this paper, we review the complexity of investigations aiming at understanding the interchange between supernova explosions with the star-forming molecular clouds. Commencing from analytical studies the paper advances to numerical models of supernova feedback from superbubble scales to galaxy structure. We also discuss parametrizations of star-formation and supernova-energy transfer efficiencies. S…
Resolving the Multiphase Outflow, Shock Signatures, and PAHs in the AGN-Starburst Composite ULIRG F10565+2448 with JWST MIRI/MRS
University of Maryland, College Park（马里兰大学帕克分校）；Joint Space-Science Institute, Department of Astronomy, University of Maryland, College Park（马里兰大学帕克分校联合空间科学研究所）；Rhodes College（罗兹学院）；Universidad de Alcalá（阿尔卡拉大学）；Centro de Astrobiología (CAB), CSIC-INTA（天体生物学中心（CAB），西班牙国家研究委员会-国家航空航天技术研究所）
Massive stars drive the evolution of the interstellar medium through their radiative and mechanical energy input. After their birth, they form bubbles of hot gas surrounded by a dense shell. Traditionally, the formation of bubbles is explained through the input of a powerful stellar wind, even though direct evidence supporting this scenario is lacking. Here we explore the possibility that interstellar bubbles seen by the Spitzer- and Herschel space telescopes, blown by stars with log(L/L_sun) < 5.2, form and expand due to the thermal pressure accompanying ionization of the surrounding gas. We …
Star formation is slow, in the sense that the gas consumption time is much longer than the dynamical time. It is also inefficient; essentially all star formation in local galaxies takes place in giant molecular clouds (GMCs), but the fraction of a GMC converted to stars is very small, ~5%. In the most luminous starbursts, the GMC lifetime is shorter than the main sequence lifetime of even the most massive stars, so that supernovae can play no role in GMC disruption. We investigate the disruption of GMCs across a wide range of galaxies, from normal spirals to the densest starbursts; we take int…
The ULIRG Mrk 231 exhibits very strong water rotational lines between λ= 200-670μm, comparable to the strength of the CO rotational lines. High redshift quasars also show similar CO and H2O line properties, while starburst galaxies, such as M82, lack these very strong H2O lines in the same wavelength range, but do show strong CO lines. We explore the possibility of enhancing the gas phase H2O abundance in X-ray exposed environments, using bare interstellar carbonaceous dust grains as a catalyst. Cloud-cloud collisions cause C and J shocks, and strip the grains of their ice layers. The internal…
Interstellar ice mantles on the surfaces of dust grains are thought to have a bi-layered structure, with a H2O-rich polar layer, covered by a CO-rich apolar layer that probably harbors H2 and other volatiles such as N2. In this work, we explore the chemistry induced by 2 keV electrons and Ly-alpha photons in H2:CO:15N2 ice analogs of the CO-rich layer when exposed to similar fluences to those expected from the cosmic-ray-induced secondary electrons and UV photons during the typical lifetime of dense clouds. Six products were identified upon 2 keV electron irradiation: CO2, C2O (and other carbo…
We use local Cartesian simulations with a vertical gravitational potential to study how supernova (SN) feedback in stratified galactic discs drives turbulence and launches galactic winds. Our analysis includes three disc models with gas surface densities ranging from Milky Way-like galaxies to gas-rich ultra-luminous infrared galaxies (ULIRGs), and two different SN driving schemes (random and correlated with local gas density). In order to isolate the physics of SN feedback, we do not include additional feedback processes. We find that, in these local box calculations, SN feedback excites rela…
Shocks are ubiquitous in the interstellar medium of galaxies, where they contribute to the energetic balance and to the cycle of matter, and where they are thought to be the primary sites for cosmic rays acceleration. Most of the time: in jets and outflows, supernova remnants, or colliding flows, they are linked with star formation. The study of shocks is hence a powerful tool to probe the evolution of the interstellar medium and to better understand star formation. To these aims, the most precise observations must be compared with the most precise models of shocks. The SOFIA/GREAT instrument …
Massive stars drive strong winds that impact the surrounding interstellar medium, producing parsec-scale bubbles for isolated stars and superbubbles around young clusters. These bubbles can be observed across the electromagnetic spectrum, both the wind itself and the swept up interstellar gas. Runaway massive stars produce bow shocks that strongly compresses interstellar gas, producing bright infrared, optical and radio nebulae. With the detection of non-thermal radio emission from bow shocks, particle acceleration can now also be investigated. I review research on wind bubbles and bow shocks …
In Tombesi et al. (2015), we reported the first direct evidence for a quasar accretion disk wind driving a massive molecular outflow. The target was F11119+3257, an ultraluminous infrared galaxy (ULIRG) with unambiguous type-1 quasar optical broad emission lines. The energetics of the accretion disk wind and molecular outflow were found to be consistent with the predictions of quasar feedback models where the molecular outflow is driven by a hot energy-conserving bubble inflated by the inner quasar accretion disk wind. However, this conclusion was uncertain because the energetics were estimate…
Complex organic molecules (COMs) can be produced by energetic processing of interstellar ice mantles accreted on top of dust grains. Two COMs with proposed energetic ice formation pathways are formamide and acetaldehyde. Both have been detected in Solar System comets, and in different circumstellar and interstellar environments. In this work, we study the NH2CHO and CH3CHO formation upon UV photoprocessing of CO:NH3 and CO:CH4 ice samples. The conversion from NH2 radicals to NH2CHO is 2-16 times higher than the conversion from CH3 radicals to CH3CHO under the explored experimental conditions, …
Small organic molecules are thought to provide building blocks for the formation of complex interstellar polycyclic aromatic hydrocarbons (PAHs). However, the underlying chemical mechanisms remain unclear, particularly concerning the role of interstellar dust. Using molecular dynamics, we simulate the chemical reaction between dehydrogenated benzene molecules in the gas phase or on the surface of an onion-like carbon nanoparticle (NP). The reaction leads to the formation of PAHs of complex structures. The size of the formed molecules is found to roughly increase with increasing temperature up …
The astronomical detection of formamide (NH$_2$CHO) toward various star-forming regions and in cometary material implies that the simplest amide might have an early origin in dark molecular clouds at low temperatures. Laboratory studies have proven the efficient NH$_2$CHO formation in interstellar CO:NH$_3$ ice analogs upon energetic processing. However, it is still under debate, whether the proposed radical-radical recombination reactions forming complex organic molecules remain valid in an abundant H$_2$O environment. The aim of this work was to investigate the formation of NH$_2$CHO in H$_2…
Context. Spatially resolved observations of the ionized and molecular gas are critical for understanding the physical processes that govern the interstellar medium (ISM) in galaxies. Aims. To study the morpho-kinematic properties of the ionized and molecular gas in three dusty starburst galaxies at $z = 0.12-0.17$ to explore the relation between molecular ISM gas phase dynamics and the star-formation activity. Methods. We analyse $\sim$kpc-scale ALMA CO(1--0) and seeing limited SINFONI Paschen-$α$ observations. We use a dynamical mass model, which accounts for beam-smearing effects, to constra…
Interstellar space hosts nanometre- to micron-sized dust grains. The carbonaceous-rich component of these grain populations emits in infrared bands, observed remotely for decades with telescopes and satellites. They are a key ingredient of astrochemical dust evolution. The precise carriers for most of these bands are still unknown and not well reproduced in the laboratory. In this work, we show the high-energy mechanochemical synthesis of disordered aromatic and aliphatic analogues provides interstellar relevant dust particles. The mechanochemical milling of carbon-based solids under a hydroge…
The simultaneous detection of organic molecules of the form C$_2$H$_{\text{n}}$O, such as ketene (CH$_2$CO), acetaldehyde (CH$_3$CHO), and ethanol (CH$_3$CH$_2$OH), toward early star-forming regions offers hints of shared chemical history. Several reaction routes have been proposed and experimentally verified under various interstellar conditions to explain the formation pathways involved. Most noticeably, the non-energetic processing of C$_2$H$_2$ ice with OH-radicals and H-atoms was shown to provide formation routes to ketene, acetaldehyde, ethanol, and vinyl alcohol (CH$_2$CHOH) along the H…
(abridged) In this work we have a closer look at the gas content or fraction and the associated star formation rate in main sequence and starburst galaxies at z=0 and z~1-2 by applying an analytical model of galactic clumpy gas disks to samples of local spiral galaxies, ULIRGs, submillimeter (smm), and high-z starforming galaxies. The model gas and dust temperatures are determined by the heating and cooling equilibrium. Dense clouds are heated by turbulent mechanical and cosmic ray heating. The molecular abundances of individual gas clouds are determined by a detailed chemical network involvin…
We present a CO(3-2) study of four systems composed of six (ultra) luminous infrared galaxies (U/LIRGs), located at 0.28 < z < 0.44, that straddle the transition region between regular star forming galaxies and starbursts. These galaxies benefit from previous multi-wavelength analysis allowing in depth exploration of an understudied population of U/LIRGs at a time when the universe is experiencing a rapid decline in star formation rate density. We detect CO(3-2) emission in four targets and these galaxies fall between the loci of regular star forming galaxies and starbursts on the Kennicutt-Sc…
The interstellar medium (ISM) is constantly evolving due to unremitting injection of energy in various forms. Energetic radiation transfers energy to the ISM: from the UV photons, emitted by the massive stars, to X- and $γ$-ray ones. Cosmic rays are another source of energy. Finally, mechanical energy is injected through shocks or turbulence. Shocks are ubiquitous in the interstellar medium of galaxies. They are associated to star formation (through jets and bipolar outflows), life (via stellar winds), and death (in AGB stellar winds or supernovae explosion). The dynamical processes leading to…
Recent ALMA large surveys unveiled the presence of significant dust continuum emission in star-forming galaxies at $z>4$. Unfortunately, such large programs -- i.e. ALPINE ($z\sim 5$) and REBELS ($z \sim 7$) -- only provide us with a single Far-Infrared (FIR) continuum data point for their individual targets. Therefore, high-$z$ galaxies FIR spectral energy densities (SEDs) remain mostly unconstrained, hinging on an assumption for their dust temperature ($T_{\rm d}$) in the SED fitting procedure. This introduces uncertainties in the inferred dust masses ($M_{\rm d }$), infrared luminosities ($…
Recent studies show the importance of the star formation feedback in changing the energetic and structure of galaxies. Dissecting the physics of the feedback is hence crucial to understand the evolution of galaxies. Full polarization radio continuum surveys can be ideally performed to trace not only star formation but also the energetic components of the interstellar medium (ISM), the magnetic fields and cosmic ray electrons. Using the SKA precursors, we investigate the effect of the massive star formation on the ISM energy balance in nearby galaxies. Our multi-scale and multi-frequency survey…
We investigate the properties of the interstellar medium, star formation, and the current-day stellar population in the strongly-lensed star-forming galaxy H-ATLAS J091043.1-000321 (SDP.11), at z = 1.7830, using new Herschel and ALMA observations of far-infrared fine-structure lines of carbon, oxygen and nitrogen. We report detections of the [O III] 52 um, [N III] 57 um, and [O I] 63 um lines from Herschel/PACS, and present high-resolution imaging of the [C II] 158 um line, and underlying continuum, using ALMA. We resolve the [C II] line emission into two spatially-offset Einstein rings, traci…
Context. In dense clouds, hydrogenation reactions on icy dust grains are key in the formation of molecules, like formaldehyde, methanol, and complex organic molecules (COMs). These species form through the sequential hydrogenation of CO ice. Although molecular hydrogen (H2) abundances can be four orders of magnitude higher than those of free H-atoms in dense clouds, H2 surface chemistry has been largely ignored; several laboratory studies show that H2 does not actively participate in non-energetic ice chemistry because of the high activation energies required. Aims. For the example of CO ice h…
The hydrogen abstraction reaction between H and H$_2$S, yielding HS and H$_2$ as products, has been studied within the framework of interstellar surface chemistry. High-temperature rate constants up to 2000 K are calculated in the gas phase and are in agreement with previously reported values. Subsequently low-temperature rate constants down to 55 K are presented for the first time that are of interest to astrochemistry, i.e., covering both bimolecular and unimolecular reaction mechanisms. For this, a so-called implicit surface model is used. Strictly speaking, this is a structural gas-phase m…
Interstellar grains are known to be important actors in the formation of interstellar molecules such as H$_2$, water, ammonia, and methanol. It has been suggested that the so-called interstellar complex organic molecules (iCOMs) are also formed on the interstellar grain icy surfaces by the combination of radicals via reactions assumed to have an efficiency equal to unity. In this work, we aim to investigate the robustness or weakness of this assumption by considering the case of acetaldehyde (CH$_3$CHO) as a starting study case. In the literature, it has been postulated that acetaldehyde is fo…
For decades, the detection of phosphorus-bearing molecules in the interstellar medium was restricted to high-mass star-forming regions (as e.g. SgrB2 and Orion KL) and the circumstellar envelopes of evolved stars. However, recent higher-sensitivity observations have revealed that molecules such as PN and PO are present not only toward cold massive cores and low-mass star-forming regions with PO/PN ratios >1, but also toward the Giant Molecular Clouds in the Galactic Center known to be exposed to highly energetic phenomena such as intense UV radiation fields, shock waves and cosmic rays. In thi…
Supersonic turbulence is a large reservoir of suprathermal energy in the interstellar medium. Its dissipation, because it is intermittent in space and time, can deeply modify the chemistry of the gas. We further explore a hybrid method to compute the chemical and thermal evolution of a magnetized dissipative structure, under the energetic constraints provided by the observed properties of turbulence in the cold neutral medium. For the first time, we model a random line of sight by taking into account the relative duration of the bursts with respect to the thermal and chemical relaxation timesc…
Outflows have been shown to be prevalent in galaxies hosting luminous active galactic nuclei (AGNs) and present a physically plausible way to couple the AGN energy output with the interstellar medium of their hosts. Despite their prevalence, accurate characterization of these outflows has been challenging. In the second of a series of papers, we use Gemini Multi-Object Spectrograph IFU data of 6 local (z<0.1) and moderate-luminosity Type 2 AGNs to study the ionization properties and energetics of AGN-driven outflows. We find strong evidence that connect the extreme kinematics of the ionized ga…
The formation of double and triple C-C bonds from the processing of pure c-C6H12 (cyclohexane) and mixed H2O:NH3:c-C6H12 (1:0.3:0.7) ices by highly-charged, and energetic ions (219 MeV O^{7+} and 632 MeV Ni^{24+}) is studied. The experiments simulate the physical chemistry induced by medium-mass and heavy-ion cosmic rays in interstellar ices analogs. The measurements were performed inside a high vacuum chamber at the heavy-ion accelerator GANIL (Grand Accelératéur National d'Ions Lourds) in Caen, France. The gas samples were deposited onto a polished CsI substrate previously cooled to 13 K. In…
