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arXiv 0812.0245cond-mat.soft
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纳米级刷子:如何构建智能表面涂层

Nano-scale brushes: How to build a smart surface coating

Holger Merlitz, Gui-Li He, Chen-Xu Wu, Jens-Uwe Sommer

摘要:

通过计算机模拟,我们展示了如何密集接枝层的聚合物,一个{ \it刷},可以变成一个有效的开关,通过化学修饰的一些终端单体。以这种方式,可以构造具有可逆切换特性的表面涂层。我们分析了其功能背后的基本物理原理,最近发现的表面不稳定性,并证明了高接枝密度,膨胀的端基尺寸和高度的单分散性的组合是开关的最佳功能的条件。

英文摘要:

Via computer simulations, we demonstrate how a densely grafted layer of polymers, a {\it brush}, could be turned into an efficient switch through chemical modification of some of its end-monomers. In this way, a surface coating with reversibly switchable properties can be constructed. We analyze the fundamental physical principle behind its function, a recently discovered surface instability, and demonstrate that the combination of a high grafting density, an inflated end-group size and a high degree of monodispersity are conditions for an optimal functionality of the switch.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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