我们提出了第一个全面的推导的铁氧铌酸盐超导体在正常状态下的电阻率$ρ$的LaFeAsO $_{1-x}$ F $_x$和SmFeAsO $_{1-x}$ F $_x$的掺杂范围宽的基础上的分析。我们的数据为这些新材料中不寻常的正常状态属性提供了明确的证据。特别地，在低掺杂水平下超导性的出现伴随着正常状态的$ρ$中的明显异常输运行为，这让人想起母体材料中的自旋密度波（SDW）特征。在较高的掺杂水平下，LaFeAsO $_{1-x}$ F $_x$的$ρ$显示出从这种赝隙状行为到费米液体状行为的明显转变，模仿了铜酸盐的相图。此外，我们的数据揭示了异常特征的强度和超导相的稳定性之间的相关性。在SmFeAsO $_{1-x}$ F $_x$中，超导电性增强，类赝隙特征增强，而在具有类费米液体行为的掺杂区，超导电性降低，类赝隙特征消失.
英文摘要：
We present the first comprehensive derivation of the intrinsic electronic phase diagram of the iron-oxypnictide superconductors in the normal state based on the analysis of the electrical resistivity $ρ$ of both LaFeAsO$_{1-x}$F$_x$ and SmFeAsO$_{1-x}$F$_x$ for a wide range of doping. Our data give clear-cut evidence for unusual normal state properties in these new materials. In particular, the emergence of superconductivity at low doping levels is accompanied by distinct anomalous transport behavior in $ρ$ of the normal state which is reminiscent of the spin density wave (SDW) signature in the parent material. At higher doping levels $ρ$ of LaFeAsO$_{1-x}$F$_x$ shows a clear transition from this pseudogap-like behavior to Fermi liquid-like behavior, mimicking the phase diagram of the cuprates. Moreover, our data reveal a correlation between the strength of the anomalous features and the stability of the superconducting phase. The pseudogap-like features become stronger in SmFeAsO$_{1-x}$F$_x$ where superconductivity is enhanced and vanish when superconductivity is reduced in the doping region with Fermi liquid-like behavior.
Multiple Gaps and Superfluid Density from Interband Pairing in Iron Oxypnictides
我们研究了铁氧磷属化合物的四带模型，其中的超导性质被假定为由类空穴和类电子费米面之间的带间耦合决定。我们发现，合理的参数可以解释的角度分辨的光电子能谱显示多个间隙在Ba $_{1-x}$ K $_x$ Fe $_2$ As $_2$，和超流密度的温度依赖性。同时，超流密度的零温值与载流子数呈常规的比例关系。
Doping dependence of Normal-state Property in the Iron-based Oxypnictide Superconductors LaFeAsO1-y probed by 57Fe-NMR and 75As-NMR/NQR
本文报道了贫氧铁基氧氮族化合物超导体LaFeAsO_{1-y} $. A microscopic phase separation between superconducting domains and magnetic domains is shown to take place in the underdoped sample, indicating a local inhomogeneity in association with the density distribution of oxygen deficiencies. As a result, 1/T_1T in the normal state of the superconducting domain decreases significantly upon cooling at both the Fe and As sites regardless of the electron-doping level in LaFeAsO_{1-y}. On the basis of this result, we claim that $ 1/T_1 T $ is not always enhanced by antiferromagnetic fluctuations close to an antiferromagn…
No anomalous spin fluctuation in optimally doped and overdoped iron-based oxypnictide superconductors LaFeAsO$_{1-x}$F$_x$ probed by muon spin relaxation
在最佳掺杂和过掺杂超导体LaFeAsO $_{1-x}$ F $_x$中进行了零场和纵向场μ子自旋弛豫测量，以研究在较宽的温度和纵向场范围内的磁涨落.在μ子的时间窗（10 $^{-5}\sim$ 10 $^{-9}$ s）内，我们没有观察到磁涨落随温度变化的迹象.考虑到目前的结果和其他结果，即，通过中子散射观察到的自旋涨落、核磁共振和光电子能谱观察到的类赝能隙行为，表明不仅自旋涨落，而且费米表面具有几种不同轨道贡献的多带特征可能在LaFeAsO $_{1-x}$ F $_x$的超导配对机制中发挥重要作用。
Interaction-induced singular Fermi surface in a high-temperature oxypnictide superconductor
在铁基超导体家族中，LaFeAsO型材料由于其明显的二维性而具有最简单的电子结构。然而，它们具有最高转变温度Tc=55K的超导电性。早期的电子结构理论预测显示，费米表面有多个大的圆形部分，具有非常好的几何重叠（嵌套），被认为可以增强配对相互作用，从而增强超导性。费米面中这种大的圆形特征的流行已经与许多其他铁基化合物相关联，并且已经在该领域中被普遍接受。在这项工作中，我们表明，1111型的原型化合物，SmFe 0.92 Co 0.08 AsO，是在与这种描述不一致，并具有明显不同的费米面，它由两个奇异的结构形成的边缘的几个带，拉到费米能级从理论上预测的能带结构的深度由强电子相互作用。这种奇异性极大地影响了材料的低能电子特性，包括超导性。我们进一步认为，这些奇异性的发生相关的最大超导转变温度可达到的每个材料类在整个家庭的铁基超导体。
Novel Superconducting Phases in Copper Oxides and Iron-oxypnictides: NMR Studies
我们重新研究了新的反铁磁性（AFM）相图和高Tc的$ superconductivity (HTSC) for a disorder-free CuO$ _2 $ plane based on an evaluation of local hole density ($ p PDMATHABMO_2 $ plane in an underdoped regime of HTSC. The $ T $=0 phase diagram of AFM constructed here is in quantitative agreement with the theories in a strong correlation regime which is unchanged even with mobile holes. This {\it Mott physics} plays a vital role for mediating the Cooper pairs to make $ T_c $ of HTSC very high. By contrast, we address from extensive NMR studies on electron-doped iron-oxypnictides La1111 compounds that the increase in $ T…
A family of titanium oxypnictide materials BaTi2Pn2O (Pn = pnictogen) becomes superconducting when a charge and/or spin density wave is suppressed. With hole doping, isovalent doping and pressure, a whole range of tuning parameters is available. We investigate how charge doping controls the superconducting transition temperature Tc. To this end, we use experimental crystal structure data to determine the electronic structure and Fermi surface evolution along the doping path. We show that a naive approach to calculating Tc via the density of states at the Fermi level and the McMillan formula sy…
Topological superconductors have long been predicted to host Majorana zero modes which obey non-Abelian statistics and have potential for realizing non-decoherence topological quantum computation. However, material realization of topological superconductors is still a challenge in condensed matter physics. Utilizing high-resolution angle-resolved photoemission spectroscopy and first-principles calculations, we predict and then unveil the coexistence of topological Dirac semimetal and topological insulator states in the vicinity of Fermi energy ($E_F$) in the titanium-based oxypnictide supercon…
We have systematically investigated the grain boundary (GB) angle dependence of transport properties for NdFeAs(O,F) fabricated on [001]-tilt symmetric MgO bicrystal substrates. In our previous study, NdFeAs(O,F) bicrystal films showed a weak-link behaviour even at a GB angle of 6°. However, this was caused by an extrinsic effect originating from the damage to both NdFeAs(O,F) and MgO substrate by excess F-diffusion along the grain boundary. To investigate the intrinsic nature of grain boundaries, we minimized the damage to NdFeAs(O,F) and MgO by reducing the deposition temperature of NdOF ove…
Temperature dependence and resonance effects in Raman scattering of phonons in NdFeAsO$_{x}$F$_{1-x}$ single crystals
本文报道了氧铌酸铁超导体NdFeAsO $_{1-x}$ F $x$单晶的平面偏振喇曼散射光谱。该光谱表现出尖锐和对称的声子线与氟掺杂$x$弱的依赖性。温度依赖性没有显示任何声子异常的超导转变。铁相关的声子强度显示出强烈的共振增强低于2eV。我们将共振增强与在光学电导率中观察到的约2 eV的带间跃迁的存在相关联。我们的研究结果指出，在铁氧铌酸盐超导体的拉曼活性声子和电子激发之间的一个相当弱的耦合。
Resistivity saturation in PrFeAsO$_{1-x}$F$_y$ superconductor: An evidence of strong electron-phonon coupling
我们测量了PrFeAsO $_{1-x}$ F $_y$样品在很宽的温度范围内的电阻率，以阐明电子-声子相互作用对正常和超导态性质的作用。$ρ$在170 K以上的线性T依赖性，随后在更高温度下的饱和行为是强电子-声子耦合的明显特征。通过对$ρ$的T依赖性的分析，我们估计了几个正常态参数，这些参数对理解该系统的超导电性起源是有用的。我们的研究结果表明，铁基氧磷属化合物是声子介导的BCS超导体，像Chevrel相和A15化合物。
