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arXiv 0810.2940cond-mat.mtrl-scicond-mat.stat-mech
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二维纳米粒子阵列的偶极相互作用和热稳定性

Dipolar interactions and thermal stability of two-dimensional nanoparticle arrays

Daniel A Stariolo, Orlando V. Billoni

摘要:

我们显示的蒙特卡罗模拟的单分散磁单畴粒子的阵列,在一个正方形晶格与偶极相互作用和垂直单轴各向异性的结果。我们首先展示了系统的平衡相图,它显示了三个阶段,超顺磁性(SP),面外反铁磁性和面内反铁磁性与最后两个之间的重取向过渡。然后,我们采用最近推出的时间量化的蒙特卡罗方法来研究放松的自相关的粒子阵列的偶极各向异性能量的不同比例。在非相互作用的情况下,我们表明,松弛是指数的时间与特征时间服从布朗的经典结果。当偶极相互作用被打开时,在整个时间窗口中以及在SP和有序相中,松弛由拉伸指数形式很好地描述。弛豫时间仍然服从一个近Arrhenius行为,与一个单一的有效能量势垒,随着偶极相互作用的增加而减少,一个结果,必须解释内的动力学协议。没有发现玻璃化行为的迹象,与模型系统中没有无序一致。

英文摘要:

We show results of Monte Carlo simulations of an array of monodispersed magnetic monodomain particles, in a square lattice with dipolar interactions and perpendicular uniaxial anisotropy. We first show the equilibrium phase diagram of the system, which shows three phases, superparamagnetic (SP), out-of-plane antiferromagnetic and in-plane antiferromagnetic with a reorientation transition between the last two. We then employ a recently introduced time quantified Monte Carlo method to study the relaxation of autocorrelations of the particle array for different ratios of dipolar to anisotropy energies. In the non-interacting case we show that relaxation is exponential in time with characteristic times obeying a classic result by Brown. When dipolar interactions are switched on, the relaxation is very well described by stretched exponential forms in the whole time window and in both the SP and ordered phases. Relaxation times still obey a nearly Arrhenius behaviour, with a single effective energy barrier that decreases as the dipolar interaction increases, a result that must be interpreted within the dynamics protocol. No signs of glassy behaviour were found, in agreement with the absence of disorder in the model system.

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