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arXiv 0809.0025cond-mat.stat-mech
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时间之箭的长度

The length of time's arrow

Edward H. Feng, Gavin E. Crooks

摘要:

物理学中一个尚未解决的问题是热力学时间箭头是如何从基本的时间可逆动力学中产生的。我们有助于这个问题,通过开发一个措施的时间对称性破缺,并通过使用的工作波动关系,我们确定最近的单分子RNA展开实验的时间不对称性。我们将时间不对称定义为实验轨迹概率分布与其时间反演共轭之间的Jensen-Shannon散度。在其他有趣的属性中,时间箭头的长度限制了平均耗散,并决定了在非平衡实验中准确估计自由能差异的难度。

英文摘要:

An unresolved problem in physics is how the thermodynamic arrow of time arises from an underlying time reversible dynamics. We contribute to this issue by developing a measure of time-symmetry breaking, and by using the work fluctuation relations, we determine the time asymmetry of recent single molecule RNA unfolding experiments. We define time asymmetry as the Jensen-Shannon divergence between trajectory probability distributions of an experiment and its time-reversed conjugate. Among other interesting properties, the length of time's arrow bounds the average dissipation and determines the difficulty of accurately estimating free energy differences in nonequilibrium experiments.

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