We investigate the evolution of entanglement in multiple-quantum (MQ) NMR experiments in crystals with pairs of close nuclear spins-1/2. The initial thermodynamic equilibrium state of the system in a strong external magnetic field evolves under the non-secular part of the dipolar Hamiltonian. As a result, MQ coherences of the zeroth and plus/minus second orders appear. A simple condition for the emergence of entanglement is obtained. We show that the measure of the spin pair entanglement, concurrence, coincides qualitatively with the intensity of MQ coherences of the plus/minus second order and hence the entanglement can be studied with MQ NMR methods. We introduce an Entanglement Witness using MQ NMR coherences of the plus/minus second order.
We show that it is possible to transfer two-bit information via encoding a single qubit in a conventional nuclear magnetic resonance (NMR) experiment with two very weakly polarized nuclear spins. Nevertheless, the experiment can not be regarded as a demonstration of superdense coding by means of NMR because it is based on the large number of molecules being involved in the ensemble state rather than the entanglement of the NMR states. Following the discussions, an entanglement witness, particularly applicable for NMR, is introduced based on separate and simultaneous measurement of the individu…
Entanglement witnesses (EW) allow the detection of entanglement in a quantum system, from the measurement of some few observables. They do not require the complete determination of the quantum state, which is regarded as a main advantage. On this paper it is experimentally analyzed an entanglement witness recently proposed in the context of Nuclear Magnetic Resonance (NMR) experiments to test it in some Bell-diagonal states. We also propose some optimal entanglement witness for Bell-diagonal states. The efficiency of the two types of EW's are compared to a measure of entanglement with tomograp…
A bipartite quantum system in a mixed state can exhibit nonclassical correlations, which can go beyond quantum entanglement. While quantum discord is the standard measure of quantifying such general quantum correlations, the nonclassicality can be determined by simpler means via the measurement of witness operators. We experimentally construct a positive map to witness nonclassicality of two qubits in an NMR system. The map can be decomposed so that a single run of an experiment on an ensemble of spins suffices to detect the nonclassicality in the state, if present. We let the state evolve in …
Multiple quantum (MQ) NMR with a dipolar ordered initial state opens new possibilities for the exploration of many-spin entanglement. In this paper, we investigate many-spin entanglement in a gas of spin-carrying molecules (atoms) in nanocavities in the conditions of MQ NMR with a dipolar ordered initial state. The second moment of the distribution of the intensities of MQ NMR coherences, which provides a lower bound on the quantum Fisher information, is used for an estimate of the number of the entangled spins. Many-spin entanglement is investigated at different temperatures and different num…
We use multiple quantum (MQ) NMR dynamics of a gas of spin-carrying molecules in nanocavities at high and low temperatures for an investigation of many-particle entanglement. A distribution of MQ NMR intensities is obtained at high and low temperatures in a system of 201 spins 1/2. The second moment of the distribution, which provides a lower bound on the quantum Fisher information, sheds light on the many-particle entanglement in the system. The dependence of the many-particle entanglement on the temperature is investigated. Almost all spins are entangled at low temperatures.
In this essay we discuss the issue of quantum information and recent nuclear magnetic resonance (NMR) experiments. We explain why these experiments should be regarded as quantum information processing (QIP) despite the fact that, in present liquid state NMR experiments, no entanglement is found. We comment on how these experiments contribute to the future of QIP and include a brief discussion on the origin of the power of quantum computers.
An entanglement witness is an observable detecting entanglement for a subset of states. We present a framework that makes an entanglement witness twice as powerful due to the general existence of a second (lower) bound, in addition to the (upper) bound of the very definition. This second bound, if non-trivial, is violated by another subset of entangled states. Differently stated, we prove via the structural physical approximation that two witnesses can be compressed into a single one. Consequently, our framework shows that any entanglement witness can be upgraded to a witness $2.0$. The genera…
In this paper based on the notion of entanglement witness, a new measure of entanglement called floating entanglement witness measure is introduced which satisfies some of the usual properties of a good entanglement measure. By exploiting genetic algorithm, we introduce a classical algorithm that computes floating entanglement witness measure. This algorithm also provides a method for finding entanglement witness for a given entangled state.
Quantum entanglement lies at the heart of quantum mechanical and quantum information processing. Following the question who \emph{witnesses} entanglement witnesses, we show entangled states play as the role of super entanglement witnesses. We show separable states play the role of "super super entanglement witnesses" and "witness" other observables than entanglement witnesses. We show that there exists a hierarchy structure of witnesses and there exist "witnesses" everywhere. Furthermore, we show the properties and characterization of entangled states as super entanglement witnesses. By the ro…
Random local measurements have recently been proposed to construct entanglement witnesses and thereby detect the presence of bipartite entanglement. We experimentally demonstrate the efficacy of one such scheme on a two-qubit NMR quantum information processor. We show that a set of three random local measurements suffices to detect the entanglement of a general two-qubit state. We experimentally generate states with different amounts of entanglement, and show that the scheme is able to clearly witness entanglement. We perform complete quantum state tomography for each state and compute state f…
We describe the experimental implementation of a recently proposed quantum algorithm involving quantum entanglement at the level of two qubits using NMR. The algorithm solves a generalisation of the Deutsch problem and distinguishes between even and odd functions using fewer function calls than is possible classically. The manipulation of entangled states of the two qubits is essential here, unlike the Deutsch-Jozsa algorithm and the Grover's search algorithm for two bits.
The ultrafine entanglement witness, introduced in [F. Shahandeh, M. Ringbauer, J.C. Loredo, and T.C. Ralph, Phys. Rev. Lett. \textbf{118}, 110502 (2017)], can seamlessly and easily improve any standard entanglement witness. In this paper, by combining the constraint and the test operators, we rotate the hyperplane determined by the test operator and improve further the original ultrafine entanglement witness. In particular, we present a series of new ultrafine entanglement witnesses, which not only can detect entangled states that the original ultrafine entanglement witnesses cannot detect, bu…
Motivated by Buscemi's semi-quantum nonlocal game [PRL 108, 200401(2012)], We propose an entanglement witness game, a quantum game based on entanglement witness. Similar as the semi-quantum nonlocal game, the existence of entanglement shared by the players is necessary and sufficient for obtaining a positive average payoff in our entanglement witness game. Two explicit examples are constructed to demonstrate how to play our entanglement witness game and its relations with the CHSH nonlocal game.
In recent years, the performance of different entanglement indicators obtained directly from tomograms has been assessed in continuous-variable and hybrid quantum systems. In this paper, we carry out this task in the case of spin systems. We compute the entanglement indicators from actual experimental data obtained from three liquid-state NMR experiments, and compare them with standard entanglement measures calculated from the corresponding density matrices, both experimentally reconstructed and numerically computed. The gross features of entanglement dynamics and spin squeezing properties are…
We study entanglement witness and present a construction of entanglement witnesses in terms of the symmetric informationally complete measurements (SIC-POVM). The capability of our witness is shown by some examples and it can be found this witness detects more entanglement than previous separability method given also by SIC-POVM. What's more, comparing with the dimension dependence of SIC-POVM, we also give the entanglement witnesses can be always constructed from general symmetric informationally complete measurements (GSIC-POVM).
We study entanglement witness and present a construction of entanglement witnesses in terms of the mutually unbiased measurements (MUMs). These witnesses include the entanglement witnesses constructed from mutually unbiased bases (MUBs) as a special case. Comparing with the dimension dependence of MUBs, the witnesses can be always constructed from a complete set of $d+1$ MUMs for any dimension $d$. We show that our witness can detect entanglement better than previous separability criterion given also by MUMs. And the approach can be experimentally implemented.
The entanglement witness is an important and experimentally applicable tool for entanglement detection. In this paper, we provide a nonlinear improvement of any entanglement witness for $2\otimes d$ quantum systems. Compared with any existing entanglement witness, the improved separability criterion only needs two more measurements on local observables. Detailed examples are employed to illustrate the efficiency of the nonlinear improvement for general, optimal and non-decomposable entanglement witnesses.
A scheme to execute an n-bit Deutsch-Jozsa (D-J) algorithm using n qubits has been implemented for up to three qubits on an NMR quantum computer. For the one and two bit Deutsch problem, the qubits do not get entangled, hence the NMR implementation is achieved without using spin-spin interactions. It is for the three bit case, that the manipulation of entangled states becomes essential. The interactions through scalar J-couplings in NMR spin systems have been exploited to implement entangling transformations required for the three bit D-J algorithm.
Entanglement witness is a Hermitian operator that is useful for detecting the genuine multipartite entanglement of mixed states. Nonlinear entanglement witnesses have the advantage of a wider detection range in the entangled region. We construct genuine entanglement witnesses for four qubits density matrices in the mutually unbiased basis. First, we find the convex feasible region with positive partial transpose states. Then, to reveal the entangled regions, we present some appropriate linear entanglement witnesses and, we find the envelope of this family of linear witnesses as a nonlinear wit…
Quantum correlations in multiple quantum (MQ) NMR experiments are investigated in two-spin systems (dimers). In the initial moment of time one spin is in a pure quantum polarized state and the other spin is in the thermodynamic equilibrium state defined by the temperature of the sample. MQ NMR dynamics of dimers is investigated. It is shown that MQ NMR coherences of only the zeroth and second orders emerge in such a system. The intensities of those coherences are calculated. Entangled states appear in the course of the system evolution in the MQ NMR experiment. The quantum discord is obtained …
We derive an experimentally observable lower bound on concurrence of mixed quantum states in terms of an entanglement witness, relating measurements on single states with those on two copies.
We develop an approach of quantifying entanglement in mixed quantum states by the optimal entanglement witness operator. We identify the convex set of mixed states for which a single witness provides the exact value of an entanglement measure, and show that the convexity, properties, and symmetries of entanglement or of a target state considerably fix the form of the optimal witness. This greatly reduces difficulty in computing and experimentally determining entanglement measures. As an example, we show how to experimentally quantify bound entanglement in four-qubit noisy Smolin states and thr…
We investigate the dynamics of entanglement and quantum discord of two qubits in liquid state homonuclear NMR. Applying a phenomenological description for NMR under relaxation process, and taking a group of typical parameters of NMR, we show that when a zero initial state $|00> $ experiences a relaxation process, its entanglement disappears completely after a sequence of so-called sudden deaths and revivals, while the quantum discord retains remarkable values after a sequence of oscillations. That is to say, the quantum discord is more robust than entanglement.
We study the optimal entanglement witness with respect to multiqubits W-states. We show such entanglement witnesses can be used to distinguish genuine entangled states, different biseparable states and fully separable states.
In the discussion about the quantumness of NMR computation a conclusion is done that computational states are separable and therefore can not be entangled. This conclusion is based on the assumption that the initial density matrix of an individual molecule coincides with whole sample molecules distribution over single molecule energy levels. This means that quantum stochasticity is replaced by classical stochasticity. In the present paper it is shown, that quantum NMR computation can create genuine entangled states if initial system states are thermodynamical equilibrium ones. A separability a…
We introduce a feasible method of constructing the entanglement witness that detects the genuine entanglement of a given pure multiqubit state. We illustrate our method in the scenario of constructing the witnesses for the multiqubit states that are broadly theoretically and experimentally investigated. It is shown that our method can construct the effective witnesses for experiments. We also investigate the entanglement detection of symmetric states and mixed states.
Using an NMR quantum computer, we experimentally simulate the quantum phase transition of a Heisenberg spin chain. The Hamiltonian is generated by a multiple pulse sequence, the nuclear spin system is prepared in its (pseudo-pure) ground state and the effective Hamiltonian varied in such a way that the Heisenberg chain is taken from a product state to an entangled state and finally to a different product state.
Teleportation witnesses are hermitian operators which can identify useful entanglement for quantum teleportation. Here we provide a systematic method to construct teleportation witnesses from entanglement witnesses corresponding to general qudit systems. The witnesses so constructed are shown to be optimal for qubit and qutrit systems, and therefore detect the largest set of states useful for teleportation within a given class. We demonstrate the action of the witness pertaining to different classes of states in qubits and qutrits. Decomposition of the witness in terms of spin operators facili…
We show that each entanglement witness detecting given bipartite entangled state provides an estimation of its concurrence. We illustrate our result with several well known examples of entanglement witnesses and compare the corresponding estimation of concurrence with other estimations provided by the trace norm of partial transposition and realignment.
There always exists an entanglement witness for every entangled quantum state. Negativity of the expectation value of an entanglement witness operator guarantees entanglement of the corresponding state, given that the measurement devices involved are perfect, i.e., the performed measurements actually constitute the witness operator for the state under consideration. In a realistic situation, there are two possible ways of measurements to drive the process away from the ideal one. Firstly, wrong measurements may be performed, and secondly, while the measurement operators are implemented correct…
The entanglement witness and the entropy uncertainty are investigated by using the pseudomode theory for the open two-atom system under the quantum Zeno effect. The results show that, only when the two spectrums satisfy strong coupling with the atom, the time of entanglement witness can be prolonged and the lower bound of the entropic uncertainty can be reduced, and the entanglement can be witnessed many times. We also gave the corresponding physical explanation by the non-Markovianity. The Zeno effect not only can very effectively prolong the time of entanglement witness and reduce the lower …
We propose a method to witness entanglement between two continuous-variable systems in a Gaussian state. Its key ingredient is a local lossy state transfer from the original spatially separated systems onto two spatially separated qubits. The qubits are initially in a pure product state, therefore by detecting entanglement between the qubits we witness entanglement between the two original systems. This method greatly simplifies entanglement witnessing in complex systems.
We derive a set of algebraic equations, the so-called multipartite separability eigenvalue equations. Based on their solutions, we introduce a universal method for the construction of multipartite entanglement witnesses. We witness multipartite entanglement of $10^3$ coupled quantum oscillators, by solving our basic equations analytically. This clearly demonstrates the feasibility of our method for studying ultra-high orders of multipartite entanglement in complex quantum systems.
Quantum mechanics predicts the existence of correlations between composite systems -- multipartite entanglement (ME) -- that, while puzzling our physical intuition, enable technologies not accessible in a classical world. Notwithstanding, there is still no efficient general method to theoretically quantify and experimentally detect ME. Here we propose a novel paradigm based on the measurement of the statistical response of a quantum systems to a collective parametric evolution. As a major difference with respect to current approaches based on the implementation of entanglement witness operator…
An entanglement witness approach to quantum coherent state key distribution and a system for its practical implementation are described. In this approach, eavesdropping can be detected by a change in sign of either of two witness functions, an entanglement witness S or an eavesdropping witness W. The effects of loss and eavesdropping on system operation are evaluated as a function of distance. Although the eavesdropping witness W does not directly witness entanglement for the system, its behavior remains related to that of the true entanglement witness S. Furthermore, W is easier to implement …
We describe an entanglement witness for $N$-qubit mixed states based on the properties of $N$-point correlation functions. Depending on the degree of violation, this witness can guarantee that no more than $M$ qubits are separable from the rest of the state for any $M\leq N$, or that there is some genuine $M$-party or greater multipartite entanglement present. We illustrate the use our criterion by investigating the existence of entanglement in thermal stabilizer states, where we demonstrate that the witness is capable of witnessing bound-entangled states. Intriguingly, this entanglement can b…
In this paper we introduce a criterion for the characterization of Entanglement Witness for multipartite quantum systems. Our approach is based on the characterization of the "tangent space" to the set of pure product states.
Entanglement, the essential resource in quantum information processing, should be witnessed in many tasks such as quantum computing and quantum communication. The conventional entanglement witness method, relying on an idealized implementation of measurements, could wrongly conclude a separable state to be entangled due to imperfect detections. Inspired by the idea of a time-shift attack, we construct an attack on the conventional entanglement witness process and demonstrate that a separable state can be falsely identified to be entangled. To close such detection loopholes, based on a recently…
Entanglement control of qubits in a photoisomerizing molecule is studied in the context of an NMR quantum computer by taking azobenzene as an example. Azobenzene has two different isomers, {\it{}trans}-azobenzene (TAB) and {\it{}cis}-azobenzene (CAB), which can be interconverted by photoisomerization. Changing molecular structure leads to change in the spin-spin coupling constant, and hence leads to change in entangling operation time. We first obtain stable structures of TAB and CAB by {\it ab initio} calculation. Then, we calculate the NMR spectra of these isomers and verify that they reprod…
Linear and nonlinear entanglement witnesses for a given bipartite quantum systems are constructed. Using single particle feasible region, a way of constructing effective entanglement witnesses for bipartite systems is provided by exact convex optimization. Examples for some well known two qutrit quantum systems show these entanglement witnesses in most cases, provide necessary and sufficient conditions for separability of given bipartite system. Also this method is applied to a class of bipartite qudit quantum systems with details for d=3, 4 and 5. Keywords: non-linear and linear entanglement …
We investigate numerically the time dependence of the multiple quantum coherences and entanglement in linear chains up to nine nuclear spins of 1/2 coupled by the dipole-dipole interactions. Two models are considered: (1) a spin chain with nearest-neighbor dipole -dipole interactions; (2) a more realistic model with interactions between all spins. It is shown that the entangled states appear between remote particles which do not interact directly (model 1), while the interaction between all spins (model 2) not always results in entanglement between remote spins.
We show that macroscopic thermodynamical properties - such as functions of internal energy and magnetization - can detect quantum entanglement in solids at nonzero temperatures in the thermodynamical limit. We identify the parameter regions (critical values of magnetic field and temperature) within which entanglement is witnessed by these thermodynamical quantities.
We demonstrate that non-linear entanglement witnesses can be made particularly useful for entanglement detection in hyper-entangled or multilevel states. We test this idea experimentally on the platform of linear optics using a hyper-entangled state of two photons. Instead of several simultaneous copies of two-photon entangled states, one can directly measure the witness on single copy of a hyper-entangled state. Our results indicate that hyper-entanglement can be used for quick entanglement detection and it provides a practical testbed for experiments with non-linear entanglement witnesses.
We examine various notions related with the optimality for entanglement witnesses arising from Choi type positive linear maps. We found examples of optimal entanglement witnesses which are non-decomposable, but which are not `non-decomposable optimal entanglement witnesses' in the sense of [M. Lewenstein, B. Kraus, J. Cirac, and P. Horodecki, Phys. Rev. A 62, 052310 (2000)]. We suggest to use the term `PPTES witness' and `optimal PPTES witness' in the places of `non-decomposable entanglement witness' and `non-decomposable optimal entanglement witnesses' in order to avoid possible confusion. We…
Second-order interference and Hanbury-Brown and Twiss type experiments can provide an operational framework for the construction of witness operators that can test classical and nonclassical properties of a Gaussian squeezed state (GSS), and provide entanglement witness operators to study the separability properties of correlated Gaussian squeezed sates.
We study the problem of witnessing entanglement among indistinguishable particles. For this purpose, we derive a set of equations which results in necessary and sufficient conditions for probing multipartite entanglement between arbitrary systems of Bosons or Fermions. The solution of these equations yields the construction of optimal entanglement witnesses for partial and full entanglement in discrete and continuous variable systems. Our approach unifies the verification of entanglement for distinguishable and indistinguishable particles. We provide general solutions for certain observables t…
An entanglement witness is an observable with the property that a negative expectation value signals the presence of entanglement. The question arises how a witness can be improved if the expectation value of a second observable is known, and methods for doing this have recently been discussed as so-called ultrafine entanglement witnesses. We present several results on the characterization of entanglement given the expectation values of two observables. First, we explain that this problem can naturally be tackled with the method of the Legendre transformation, leading even to a quantification …
The controlled generation of entangled states and their subsequent detection are integral aspects of quantum information science. In this work, we analyse the application of nonlinear witnesses to the verification of entanglement, and we demonstrate experimentally that nonlinear witnesses perform significantly better than linear witnesses. Specifically, we demonstrate that a single non- linear entanglement witness is able to determine to a high degree of certainty that a mixed state containing orbital angular momentum (OAM) entanglement of specific forms is entangled for any relative phase and…
In this study, the spin-momentum correlation of one massive spin-1/2 and spin-1 particle states, which are made based on projection of a relativistic spin operator into timelike direction is investigated. It is shown that by using Non-Linear entanglement witnesses (NLEWs), the effect of Lorentz transformation would decrease both the amount and the region of entanglement.
We present the experimental detection of genuine multipartite entanglement using entanglement witness operators. To this aim we introduce a canonical way of constructing and decomposing witness operators so that they can be directly implemented with present technology. We apply this method to three- and four-qubit entangled states of polarized photons, giving experimental evidence that the considered states contain true multipartite entanglement.
The quantum nature of bulk ensemble NMR quantum computing --the center of recent heated debate, is addressed. Concepts of the mixed state and entanglement are examined, and the data in a 2 qubit liquid NMR quantum computation are analyzed. It is pointed out that the key problem in the current debate is the understanding of entanglement in a mixed state system. The following points are concluded in this Letter: 1)Density matrix describes the "state" of an average particle in an ensemble. It can not describe the state of an individual particle in an ensemble in detail; 2) Entanglement is a prope…
We show that if the ground state entanglement exceeds the total entropy of a given system, then this system is in an entangled state. This is a universal entanglement witness that applies to any physical system and yields a temperature below which we are certain to find some entanglement. Our witness is then applied to generic bosonic and fermionic many body systems to derive the corresponding "critical" temperatures that have a very broad validity.
The evolution of entanglement in a 3-spin chain with nearest-neighbor Heisenberg-XY interactions for different initial states is investigated here. In an NMR experimental implementation, we generate multipartite entangled states starting from initial separable pseudo-pure states by simulating nearest-neighbor XY interactions in a 3-spin linear chain of nuclear spin qubits. For simulating XY interactions, we follow algebraic method of Zhang et al. [Phys. Rev. A 72, 012331 (2005)]. Bell state between end qubits has been generated by using only the unitary evolution of the XY Hamiltonian. For gen…
We consider a possible detector-efficiency loophole in experiments that detect entanglement via the local measurement of witness operators. Here, only local properties of the detectors are known. We derive a general threshold for the detector efficiencies which guarantees that a negative expectation value of a witness is due to entanglement, rather than to erroneous detectors. This threshold depends on the local decomposition of the witness and its measured expectation value. For two-qubit witnesses we find the local operator decomposition that is optimal with respect to closing the loophole.
