Generating nonclassical light offers a benchmark tool for the fundamental research and potential applications in quantum optics. Conventionally, it has become a standard technique to produce the nonclassical light through the nonlinear optical processes occurring in nonlinear crystals. In this review we describe using cold atomic-gas media to generate such nonclassical light, especially focusing on narrow-band biphoton generation. Compared with the standard procedure, the new biphoton source has such properties as long coherence time, long coherence length, high spectral brightness, and high conversion efficiency. In this paper we concentrate on the theoretical aspect of the entangled two-photon state produced from the four-wave mixing in a multilevel atomic ensemble. We show that both linear and nonlinear optical responses to the generated fields play an important role in determining the biphoton waveform and, consequently on the two-photon temporal correlation. There are two characteristic regimes determined by whether the linear or nonlinear coherence time is dominant. In addition, our model provides a clear physical picture that brings insight into understanding biphoton optics with this new source. We apply our model to recent work on generating narrow-band (and even subnatural linewidth) paired photons using the technique of electromagnetically induced transparency and slow-light effect in cold atoms, and find good agreements with experimental results.
In this chapter, we review recent advances in generating narrowband biphotons with long coherence time using spontaneous parametric interaction in monolithic cavity with cluster effect as well as in cold atoms with electromagnetically induced transparency. Engineering and manipulating the temporal waveforms of these long biphotons provide efficient means for controlling light-matter quantum interaction at the single-photon level. We also review recent experiments using temporally long biphotons and single photons.
We describe and demonstrate a quantum state tomography for measuring the complex temporal waveform of narrowband biphotons. Through six sets of two-photon interference measurements projected in different polarization subspaces, we can construct the time-frequency entangled two-photon joint amplitude and phase functions in continuous-variable time domain. For the first time, we apply this technique to experimentally determine the temporal quantum states of narrowband biphotons generated from spontaneous four-wave mixing in cold atoms, and fully confirm the theoretical predictions.
We consider a scheme of multiplexed cold atomic ensembles that generate a frequency-entangled biphoton state with controllable entropy of entanglement. The biphoton state consists of a telecommunication photon (signal) immediately followed by an infrared one (idler) via four-wave mixing with two classical pump fields. Multiplexing the atomic ensembles with frequency and phase-shifted signal and idler emissions, we can manipulate and control the spectral property of the biphoton state. Mapping out the entropy of entanglement in the scheme provides the optimal configuration for entanglement reso…
We demonstrate the generation of narrowband biphotons with polarization-frequency coupled hy- perentanglement from spontaneous four-wave mixing in cold atoms. The coupling between polariza- tion and frequency is realized through a frequency shifter and linear optics. When the polarization- frequency degrees of freedom are decoupled, it is robust to create polarization and frequency Bell states, confirmed by the polarization quantum-state tomography and the two-photon temporal quan- tum beating. Making use of the polarization-frequency coupling to transfer polarization phase retard to the entan…
We report the efficient generation of subnatural-linewidth (< 6 MHz, for Rb D1/D2 lines) biphotons from a Doppler-broadened (530 MHz) hot atomic vapor cell. We use on-resonance spontaneous four-wave mixing in a hot paraffin-coated 87Rb vapor cell at 63 C to produce time-frequency entangled photon pairs with controllable bandwidth (1.9 - 3.2 MHz) and coherence time (47 - 94 ns). Our backward phase-matching scheme with optical pumping is the key to minimize the generation of uncorrelated photons from resonance fluorescence. The result paves the way toward miniature narrowband biphoton source bas…
We systematically studied the temporal profile of biphotons, i.e., pairs of time-correlated single photons, generated from a hot atomic vapor via the spontaneous four-wave mixing process. The measured temporal width of biphoton wave packet or two-photon correlation function against the coupling power was varied from about 70 to 580 ns. We derived an analytical expression of the biphoton's spectral profile in the Doppler-broadened medium. The analytical expression reveals that the spectral profile is mainly determined by the effect of electromagnetically induced transparency (EIT), and behaves …
We theoretically investigate the spectral property of biphoton state from the cascade emissions from a Doppler-broadened atomic ensemble. This biphoton state is spontaneously created in the four-wave-mixing process. The upper transition of the emissions lies in telecom bandwidth, which prevails in fiber-based quantum communication for low-loss transmission. We obtain the spectral property in terms of superradiant decay rates of the lower transition, excitation pulse durations, and temperature of the medium. We quantify their frequency entanglement by Schmidt decomposition and find that more en…
We utilized the all-copropagating scheme, which maintains the phase-match condition, in the spontaneous four-wave mixing (SFWM) process to generate biphotons from a hot atomic vapor. The scheme enables our biphotons not only to surpass those in the previous works of hot-atom SFWM, but also to compete with the biphotons that are generated by either the cold-atom SFWM or the cavity-assisted spontaneous parametric down conversion. The biphoton linewidth in this work is tunable for an order of magnitude. As we tuned the linewidth to 610 kHz, the maximum two-photon correlation function, $g_{s,as}^{…
We theoretically investigate the spectral property of a biphoton state from multiplexed thermal atomic ensembles. This biphoton state originates from the cascade emissions, which can be generated by two weak pump fields under four-wave mixing condition. Under this condition, a signal photon from the upper transition, chosen in a telecommunication bandwidth, can be generated along with a correlated idler photon from the lower infrared transition. We can spectrally shape the biphoton state by multiplexing the atomic ensembles with frequency-shifted emissions, where the entropy of entanglement ca…
We study the generation of paired photons due to the effect of four-wave mixing in an ensemble of pumped two-level systems that decay via an intermediate metastable state. The slow population relaxation of the metastable state to the ground state is utilized to create long-lived coherent population oscillation, leading to narrowband nonlinear response of the medium. The biphotons have a narrow bandwidth, long coherence time and length, which can be controlled by the pump field. In addition, the biphotons are antibunched, with antibunching period determined by the dephasing time. During this pe…
Interference between an unknown two-photon state (a "biphoton") and the two-photon component of a reference state gives a phase-sensitive arrival-time distribution containing full information about the biphoton temporal wave function. Using a coherent state as a reference, we observe this interference and reconstruct the wave function of single-mode biphotons from a low-intensity narrowband squeezed vacuum state.
We report the direct characterization of energy-time entanglement of narrowband biphotons produced from spontaneous four-wave mixing in cold atoms. The Stokes and anti-Stokes two-photon temporal correlation is measured by single-photon counters with nano second temporal resolution, and their joint spectrum is determined by using a narrow linewidth optical cavity. The energy-time entanglement is verified by the joint frequency-time uncertainty product of 0.063 +/- 0.0044, which does not only violate the separability criterion but also satisfies the continuous variable Einstein-Podolsky-Rosen st…
We study narrow-band biphoton generation from spontaneous four-wave mixing with electromagnetically induced transparency in a laser cooled atomic ensemble. We compare two formalisms in the interaction and Heisenberg pictures, and find that they agree in the low gain regime but disagree in the high gain regime. We extend both formalisms accounting the non-uniformity in atomic density and the driving laser fields. We find that for a fixed optical depth and a weak and far-detuned pump laser beam, the two-photon waveform is independent of the atomic density distribution. However, the spatial profi…
Nonclassical photon sources of high brightness are key components of quantum communication technologies. We here demonstrate the generation of narrowband, nonclassical photon pairs by employing spontaneous four-wave mixing in an optically-dense ensemble of cold atoms within a hollow-core fiber. The brightness of our source approaches the limit of achievable generated spectral brightness at which successive photon pairs start to overlap in time. For a generated spectral brightness per pump power of up to $2\times 10^{9} \ \textrm{pairs/(s MHz mW)}$ we observe nonclassical correlations at pump p…
The cascade-emitted biphotons generated from the alkali metal atomic ensembles are an excellent entanglement resource which enables long-distance quantum communication. The communication of quantum information between distant locations can be realized by utilizing the low-loss telecom bandwidth in the upper transition of the cascaded photons in a fiber-based quantum network. Meanwhile, the infrared photon from the lower transition of this highly directional and frequency-correlated biphoton can be created under the four-wave mixing process and can be stored locally as a collective spin wave. H…
We investigate the spectral properties of the biphoton state from the cascade emissions of cold atomic ensembles, which composes of a telecommunication photon (signal) followed by an infrared one (idler) via four-wave mixing.\ With adiabatic conditions for Gaussian driving pulses of width $τ$, the spectrum of the biphoton state has the form of a Gaussian that conserves signal and idler photon energies within $\hbar/τ$ modulated by a Lorentzian with a superradiant linewidth.\ Multiplexing the atomic ensembles with frequency-shifted cascade emissions, we may manipulate and shape the spectrum of …
We show that the wave packet of a biphoton generated via spontaneous parametric down conversion is strongly anisotropic. Its anisotropic features manifest themselves very clearly in comparison of measurements performed in two different schemes: when the detector scanning plane is perpendicular or parallel to the plane containing the crystal optical axis and the laser axis. The first of these two schemes is traditional whereas the second one gives rise to such unexpected new results as anomalously strong narrowing of the biphoton wave packet measured in the coincidence scheme and very high degr…
We propose a novel `butterfly' level scheme to generate highly correlated photon pairs from atomic vapors. With multi-photon Doppler-free pumping, background Rayleigh scattering is dipole-forbidden and collective emission is permitted in all directions. This results in usable pairs generated simultaneously in the full $4π$ solid angle. Collecting these pairs can produce photon pairs at a rate of $\sim 10^{12}$ per second, given only moderate ensemble sizes of $\sim 10^6$ atoms.
Propagation of entangled photons in optical fiber is one of the fundamental issues for realizing quantum communication protocols. When entanglement in polarization is considered, arises the problem of compensating for the fiber effect on photons polarization. In this paper we demonstrate an effective solution where a Faraday mirror allows to cancel undesired effects of polarization drift in fiber. This technique is applied to a protocol for generating Bell states by a narrow temporal selection of the second-order intensity correlation function.
Biphotons of narrow bandwidth and long temporal length play a crucial role in long-distance quantum communication (LDQC) and linear optical quantum computing (LOQC). However, generation of these photons usually requires atomic ensembles with high optical depth or spontaneous parametric down-conversion with sophisticated optical cavity. By manipulating the two-component biphoton wavefunction generated from a low-optical-depth (low-OD) atomic ensemble, we demonstrate biphotons with subnatural linewidth in the sub-MHz regime. The potential of shaping and manipulating the quantum wavepackets of th…
Coherent and reversible storage of multi-photon entanglement with a multimode quantum memory is essential for scalable all-optical quantum information processing. Although single photon has been successfully stored in different quantum systems, storage of multi-photon entanglement remains challenging because of the critical requirement for coherent control of photonic entanglement source, multimode quantum memory, and quantum interface between them. Here we demonstrate a coherent and reversible storage of biphoton Bell-type entanglement with a holographic multimode atomic-ensemble-based quantu…
Spectrally intrinsically uncorrelated biphoton states generated from nonlinear crystals are very important but rare resources for quantum photonics and quantum information applications. Previously, such biphoton states were generated from several kinds of crystals, however, their wavelength ranges and nonlinear efficiencies were still limited for various applications. In order to explore new crystal for wider wavelength range and higher nonlinear efficiency, here we theoretically study the generation of spectrally uncorrelated biphoton states from 14 crystals in the `BBO family', including BBO…
We propose a two-photon beating experiment based upon biphotons generated from a resonant pumping two-level system operating in a backward geometry. On the one hand, the linear optical-response leads biphotons produced from two sidebands in the Mollow triplet to propagate with tunable refractive indices, while the central-component propagates with unity refractive index. The relative phase difference due to different refractive indices is analogous to the pathway-length difference between long-long and short-short in the original Franson interferometer. By subtracting the linear Rayleigh scatt…
The biphotons, generated from a hot atomic vapor via the process of spontaneous four-wave mixing (SFWM), have the following merits: stable and tunable frequencies as well as linewidth. Such merits are very useful in the applications of long-distance quantum communication. However, the hot-atom SFWM biphoton sources previously had far lower values of generation rate per linewidth, i.e., spectral brightness, as compared with the sources of biphotons generated by the spontaneous parametric down conversion (SPDC) process. Here, we report a hot-atom SFWM source of biphotons with a linewidth of 960 …
Elucidating similarities and differences between quantum-optics biphoton interference phenomena and the quantum physics of quasi-one-dimensional double-well optically-trapped ultracold neutral bosonic or fermionic atoms, we show that the analog of the optical biphoton joint-coincidence spectral correlations, studied with massless non-interacting biphotons emanating from EPR-Bell-Bohm single-occupancy sources, corresponds to a distinct contribution in the total second-order momentum correlations of the massive, interacting, and time-evolving ultracold atoms. This single-occupancy contribution c…
Spectrally uncorrelated biphoton state generated from the spontaneous nonlinear optical process is an important resource for quantum information. Currently such spectrally uncorrelated biphoton state can only be prepared from limited kinds of nonlinear media, thus limiting their wavelengths. In order to explore wider wavelength range, here we theoretically study the generation of spectrally uncorrelated biphoton state from 14 isomorphs of potassium dihydrogen phosphate (KDP) crystal. We find that 11 crystals from the `KDP family' still maintain similar nonlinear optical properties of KDP, such…
We theoretically investigated spectrally uncorrelated biphotons generated in a counter-propagating spontaneous parametric downconversion (CP-SPDC) from periodically poled MTiOXO4 (M = K, Rb, Cs; X = P, As) crystals. By numerical calculation, it was found that the five crystals from the KTP family can be used to generate heralded single photons with high spectral purity and wide tunability. Under the type-0 phase-matching condition, the purity at 1550 nm was between 0.91 and 0.92, and the purity can be maintained over 0.90 from 1500 nm to 2000 nm wavelength. Under the type-II phase-matching con…
The cascaded biphoton state generated from a cold atomic ensemble presents one of the strongly correlated resources that can preserve and relay quantum information. Under the four-wave mixing condition, the emitted signal and idler photons from the upper and lower excited states become highly correlated in their traveling directions and entangled in continuous frequency spaces. In this system, we theoretically study the spectral compression of the biphoton source using an external cavity and show the reduction in its frequency entanglement entropy. This indicates, respectively, an improved lig…
We report the experimental verification of nonclassical correlations for a four-wave-mixing process in an ensemble of cold two-level atoms, confirming theoretical predictions by Du et al. in 2007 for the violation of a Cauchy-Schwarz inequality in the system, and obtaining $R = (1.98\pm0.03) \nleq 1$. Quantum correlations are observed in a nano-seconds timescale, in the interference between the central exciting frequency and sidebands dislocated by the detuning to the atomic resonance. They prevail without filters over the noise background coming from linear scattering from the same optical tr…
We report the generation of biphotons, with a temporal full width at the half maximum (FWHM) of 13.4$\pm$0.3 $μ$s and a spectral FWHM of 50$\pm$1 kHz, via the process of spontaneous four-wave mixing. The temporal width is the longest, and the spectral linewidth is the narrowest up to date. This is also the first biphoton result that obtains a linewidth below 100 kHz, reaching a new milestone. The very long biphoton wave packet has a signal-to-background ratio of 3.4, which violates the Cauchy-Schwarz inequality for classical light by 4.8 folds. Furthermore, we demonstrated a highly-tunable-lin…
The dependence of the excitonic two-photon absorption on the quantum correlations (entanglement) of exciting biphotons by a semiconductor quantum well is studied. We show that entangled photon absorption can display very unusual features depending on space-time-polarization biphoton parameters and absorber density of states for both bound exciton states as well as for unbound electron-hole pairs. We report on the connection between biphoton entanglement, as quantified by the Schmidt number, and absorption by a semiconductor quantum well. Comparison between frequency-anti-correlated, unentangle…
Hong-Ou-Mandel interferometry takes advantage of the quantum nature of two-photon interference to increase the resolution of precision measurements of time-delays. Relying on few-photon probe states, this approach is applicable also in cases of extremely sensible samples and it achieves attosecond (nanometer path length) scale resolution, which is relevant to cell biology and two-dimensional materials. Here, we theoretically analyze how the precision of Hong-Ou-Mandel interferometers can be significantly improved by engineering the spectral distribution of two-photon probe states. In particula…
We demonstrate a tunable, narrow-band filter based on optical-pumping-induced circular dichroism in rubidium vapor. The filter achieves a peak transmission of 14.6%, a linewidth of 80 MHz, and an out-of-band extinction >35 dB. The transmission peak can be tuned within the range of the Doppler linewidth of the D1 line of atomic rubidium at 795 nm. While other atomic filters work at frequencies far from absorption, the presented technique provides light resonant with atomic media, useful for atom-photon interaction experiments. The technique could readily be extended to other alkali atoms.
We demonstrate the efficient heralded generation of high purity narrow-bandwidth single photons from a transient collective spin excitation in a hot atomic vapour cell. Employing optical homodyne tomography, we fully reconstruct the density matrix of the generated photon and observe a Wigner function reaching the zero value without correcting for any inefficiencies. The narrow bandwidth of the photon produced is accompanied by a high generation rate yielding a high spectral brightness. The source is therefore compatible with atomic-based quantum memories as well as other applications in light-…
We have experimentally studied the reflection of a weak probe beam from a dense atomic potassium vapor in the presence of a strong laser field tuned to the atomic resonance transition. We have observed an Autler-Townes doublet under hitherto unexplored conditions, namely that the Rabi frequency induced by the strong laser field is much smaller than the self-broadened width of the resonance transition of the unexcited vapor. We attribute our observation to a reduction of the atomic decoherence by the strong drive field. We present a theoretical model of nonlinear processes in a dense atomic gas…
We present measurements of the cross-correlation function of photon pairs at 780 nm and 1367 nm, generated in a hot rubidium vapor cell. The temporal character of the biphoton is determined by the dispersive properties of the medium where the pair generation takes place. We show that short correlation times occur for optically thick samples, which can be understood in terms of off-resonant pair generation. By modifying the linear response of the sample, we produce near-resonant photon pairs, which could in principle be used for entanglement distribution.
Electromagnetically induced transparency (EIT) is observed in gaseous 4He at room temperature. Ultra-narrow (less than 10 kHz) EIT windows are obtained for the first time for purely electronic spins in the presence of Doppler broadening. The positive role of collisions is emphasized through measurements of the power dependence of the EIT resonance. Measurement of slow light opens up possible ways to applications.
We report an experimental realization of a narrow-band polarization-entangled photon source with a linewidth of 9.6 MHz through cavity-enhanced spontaneous parametric down-conversion. This linewidth is comparable to the typical linewidth of atomic ensemble based quantum memories. Single-mode output is realized by setting a reasonable cavity length difference between different polarizations, using of temperature controlled etalons and actively stabilizing the cavity. The entangled property is characterized with quantum state tomography, giving a fidelity of 94% between our state and a maximally…
We observe narrowband pairs of time-correlated photons of wavelengths 776\,nm and 795\,nm from non-degenerate four-wave mixing in a laser-cooled atomic ensemble of $^{87}${Rb} using a cascade decay scheme. Coupling the photon pairs into single mode fibers, we observe an instantaneous rate of 7700 pairs per second with silicon avalanche photodetectors, and an optical bandwidth below 30\,MHz. Detection events exhibit a strong correlation in time ($g^{(2)}(τ=0)\approx5800$), and a high coupling efficiency indicated by a pair-to-single ratio of 23%. The violation of the Cauchy-Schwarz inequality b…
We report a combined theoretical and experimental study of the spectral and polarization dependence of near resonant radiation coherently backscattered from an ultracold gas of 85Rb atoms. Measurements in an approximately 6 MHz range about the 5s^{2}S_{1/2}- 5p^{2}P_{3/2}, F=3 - F'=4 hyperfine transition are compared with simulations based on a realistic model of the experimental atomic density distribution. In the simulations, the influence of heating of the atoms in the vapor, magnetization of the vapor, finite spectral bandwidth, and other nonresonant hyperfine transitions are considered. G…
Simultaneous strong coherent pumping of the two transitions of a V-level atom with very differentdecay rates has been predicted to create almost perfect inversion on the narrower transition. Usingthe example of the blue and red transitions in Strontium we show that for suitable operatingconditions the corresponding resonant gain can be used to continuously operate a laser on thenarrow transition. In particular, for a strong detuning of the pump field with respect to the narrowtransition, coherent laser emission occurs close to the bare atomic transition frequency exhibitingonly a negligible co…
We report the observation of non-classical quantum correlations of continuous light variables from a novel type of source. It is a frequency non-degenerate optical parametric oscillator below threshold, where signal and idler fields are separated by 740MHz corresponding to two free spectrum ranges of the parametric oscillator cavity. The degree of entanglement observed, - 3.8 dB, is the highest to-date for a narrowband tunable source suitable for atomic quantum memory and other applications in atomic physics. Finally we use the latter to visualize the Einstein-Podolsky-Rosen paradox.
