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arXiv 0802.0699cond-mat.stat-mech
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开放系统的连续时间随机游动:涨落定理和计数统计

Continuous time random walk for open systems: Fluctuation theorems and counting statistics

Massimiliano Esposito, Katja Lindenberg

摘要:

我们考虑连续时间随机游动(CTRW)的开放系统,交换能量和物质与多个水库。每个等待时间分布(WTD)的特征在于一个正参数a,如果它在长时间内衰减至少与t^{-2}一样快,因此具有有限的一阶矩,则将其设置为a=1。a<1的WTD衰减为t^{-a-1}。定义为轨迹概率与时间反转轨迹概率之比的对数的轨迹量R的涨落定理对任何CTRW成立。然而,只有当WTD具有a=1并且满足可分性(也称为“方向时间独立性”)时,R才可以被识别为轨迹熵变化。对于a=1的不可分WTD,R只能在长时间内被识别为轨迹熵变,并且熵变的涨落定理仅在长时间内成立。对于0<a<1的WTD,不能导出有意义的波动定理。我们还表明,(实验上可访问)的能量和物质之间的转移系统和一个给定的水库的增长作为t^{n a}在很长的时间的第n时刻。

英文摘要:

We consider continuous time random walks (CTRW) for open systems that exchange energy and matter with multiple reservoirs. Each waiting time distribution (WTD) for times between steps is characterized by a positive parameter a, which is set to a=1 if it decays at least as fast as t^{-2} at long times and therefore has a finite first moment. A WTD with a<1 decays as t^{-a-1}. A fluctuation theorem for the trajectory quantity R, defined as the logarithm of the ratio of the probability of a trajectory and the probability of the time reversed trajectory, holds for any CTRW. However, R can be identified as a trajectory entropy change only if the WTDs have a=1 and satisfy separability (also called "direction time independence"). For nonseparable WTDs with a=1, R can only be identified as a trajectory entropy change at long times, and a fluctuation theorem for the entropy change then only holds at long times. For WTDs with 0<a<1 no meaningful fluctuation theorem can be derived. We also show that the (experimentally accessible) n'th moments of the energy and matter transfers between the system and a given reservoir grow as t^{n a} at long times.

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