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arXiv 0712.2273cond-mat.supr-concond-mat.other
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镁内扩散法制备高性能MgB2丝材

Fabrication of high performance MgB2 wires by an internal Mg diffusion process

J. M. Hur, K. Togano, A. Matsumoto, H. Kumakura, H. Wada, K. Kimura

摘要:

我们成功地制造了高Jc的MgB 2/Fe线应用内扩散(IMD)工艺与纯Mg核心和SiC的添加。将直径为2 mm的纯Mg棒置于Fe管的中心,并在Mg和Fe管之间填充B粉或B-(5mol%)SiC的粉末混合物。将复合材料冷加工成直径为1.2 mm的线材,最后在高于Mg的熔点(~ 650 oC)的温度下进行热处理。在热处理过程中,液态Mg渗入B层并与B反应生成MgB 2。X射线衍射分析表明,反应层中的主相是MgB 2。SEM分析表明,MgB 2层的密度高于通常的粉末在管(PIT)处理的电线。在670 ° C下热处理的添加5mol%SiC的线材在8 T下的Jc值高于105 A/cm 2,在4.2K下在10 T下的Jc值高于41,000 A/cm 2。这些值远高于通常的PIT处理的线材,甚至与添加SiC的线材相比。通过扩散反应获得的较高密度的MgB 2层是这种优异的Jc值的主要原因。

英文摘要:

We succeeded in the fabrication of high-Jc MgB2/Fe wires applying the internal Mg diffusion (IMD) process with pure Mg core and SiC addition. A pure Mg rod with 2 mm diameter was placed at the center of a Fe tube, and the space between Mg and Fe tube was filled with B powder or the powder mixture of B-(5mol%)SiC. The composite was cold worked into 1.2mm diameter wire and finally heat treated at temperatures above the melting point of Mg(~650oC). During the heat treatment liquid Mg infiltrated into B layer and reacted with B to form MgB2. X-ray diffraction analysis indicated that the major phase in the reacted layer is MgB2. SEM analysis shows that the density of MgB2 layer is higher than that of usual powder-in-tube(PIT) processed wires. The wires with 5mol% SiC addition heat treated at 670oC showed Jc values higher than 105A/cm2 in 8T and 41,000A/cm2 in 10T at 4.2K. These values are much higher than those of usual PIT processed wires even compared to the ones with SiC addition. Higher density of MgB2 layer obtained by the diffusion reaction is the major cause of this excellent Jc values.

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