The vortex electronic structure in the multiband superconductor NbSe2 is studied by means of Scanning Tunneling Spectroscopy (STS) using a superconducting tip. The use of a superconducting tip (Pb) as a probe provides an enhancement of the different features related to the DOS of NbSe2 in the tunneling conductance curves. This use allows the observation of rich patterns of electronic states in the conductance images around the vortex cores in a wide range of temperature, as well as the simultaneous acquisition of Josephson current images in the vortex state.
Vortices play a crucial role in determining the properties of superconductors as well as their applications. Therefore, characterization and manipulation of vortices, especially at the single vortex level, is of great importance. Among many techniques to study single vortices, scanning tunneling microscopy (STM) stands out as a powerful tool, due to its ability to detect the local electronic states and high spatial resolution. However, local control of superconductivity as well as the manipulation of individual vortices with the STM tip is still lacking. Here we report a new function of the ST…
We report the first low temperature scanning tunnelling microscopy and spectroscopy study of high quality Bi2223 crystals. We present atomic resolution and show spectroscopic data acquired on two different samples. In one case, for Tc= 109K and a transition width of only 1K, we obtained an extremely homogeneous sample with a gap value of 60 meV over at least 50 nm. In the other case, the respective parameters were Tc= 111K with a transition width of 1.7K and yielded a slightly less homogeneous sample with a gap of 45 meV. We evidence strong similarities with Bi2Sr2CaCu2O8 (Bi2212) and discuss …
We performed scanning tunneling spectroscopy of c-axis oriented YBCO films on top of which ferromagnetic SRO islands were grown epitaxially in-situ. When measured on the ferromagnetic islands, the density of states exhibits small gap-like features consistent with the expected short range penetration of the order parameter into the ferromagnet. However, anomalous split-gap structures are measured on the superconductor in the vicinity of ferromagnetic islands. This observation may provide evidence for the recently predicted induced magnetization in the superconductor side of a superconductor/ fe…
We report on a controlled method to fabricate in-situ a superconducting (SC) nanostructure at the apex of the standard W tip of a Scanning Tunnelling Microscope (STM) by pulsing the tunnelling voltage on a graphene covered metal surface. We have characterized the SC properties of the resulting tip as a function of temperature and magnetic field, obtaining a transition temperature of 3.3 K and a critical field well above 3T. The SC nanotip is robust, stable, and achieves atomic resolution. The non-SC tip can be easily recovered by controlled voltage pulsing on a clean metal surface. The present…
We introduce a mode of operation for studying the vortex phase in superconductors using scanning tunnelling microscopy (STM). While in the conventional STM method, the tip is scanned over a sample in which a fixed vortex pattern is prepared, in our "Lazy Fisherman" method the STM tip is kept fixed at a selected location while the vortices are being moved by varying the applied magnetic field. By continuously acquiring the local tunnelling conductance spectra, dI/dV(V), we detect the changes in the local density of states under the tip due to the vortex motion. With no need for scanning, the me…
Superconducting scanning tunneling microscope tips have been fabricated with a high degree of reproducibility. The fabrication process relies on sequential deposition of superconducting Pb and a proximity-coupled Ag capping layer onto a Pt/Ir tip. The tips were characterized by tunneling into both normal-metal and superconducting films. The simplicity of the fabrication process, along with the stability and reproducibility of the tips, clear the way for tunneling studies with a well-characterized, scannable superconducting electrode.
The scanning tunnelling spectroscopy results from (Ca2-xNax)CuO2Cl2 in a strong magnetic field are reinterpreted in a substantially different fashion. Instead of looking, as Hanaguri et al do, to a B1g BCS-based interpretation and relying heavily upon 'coherence effects', the very detailed changes wrought in the tunnelling characteristics are re-addressed following the present author's negative-U, boson-fermion, resonant crossover modelling of the High Temperature Superconducting Cuprate (HTSC) phenomenon. As with a great many other now quite sophisticated and discriminatory experimental assau…
We discuss how variations in the scanning tunneling microscope (STM) tip, whether unintentional or intentional, can lead to changes in topographic images and dI/dV spectra. We consider the possibility of utilizing functionalized tips in order to improve the sensitivity of STM experiments to local irregularities at the surface or hidden below the surface layers. The change in the tip symmetry can radically alter the contrast of the topographic image due to changes in tip-surface overlap. The dI/dV curves change their shape according to which sample bands the tip orbital tends to overlap. In add…
We report a simple method for the fabrication of Niobium superconducting (SC) tips for scanning tunnelling microscopy which allow atomic resolution. The tips, formed in-situ by the mechanical breaking of a niobium wire, reveal a clear SC gap of 1.5 meV and a critical temperature Tc=9.2+-0.3 K as deduced from Superconductor Insulator Normal metal (NIS) and Superconductor Insulator Superconductor (SIS) spectra. These match the values of bulk Nb samples. We systematically find an enhanced value of the critical magnetic field in which superconductivity in the tip is destroyed (around 1 T for some …
The search for topological phases of matter is evolving towards strongly interacting systems, including magnets and superconductors, where exotic effects emerge from the quantum-level interplay between geometry, correlation and topology. Over the past decade or so, scanning tunnelling microscopy has become a powerful tool to probe and discover emergent topological matter, because of its unprecedented spatial resolution, high-precision electronic detection and magnetic tunability. Scanning tunnelling microscopy can be used to probe various topological phenomena, as well as complement results fr…
We use a scanning superconducting quantum interference device (SQUID) to image the magnetic flux produced by a superconducting device designed for quantum computing. The nanometer-scale SQUID-on-tip probe reveals the flow of superconducting current through the circuit as well as the locations of trapped magnetic flux. In particular, maps of current flowing out of a flux-control line in the vicinity of a qubit show how these elements are coupled, providing insight on how to optimize qubit control.
Fourier transform scanning tunneling microscopy on BSCCO subgap resonances has deciphered an octet of "quasi-particle" states that are consistent with the Fermi surface and energy gap observed by ARPES, but the origin of the high-intensity k-space octets and the sharply defined r-space checkerboard is unexplained. The filamentary ferroelastic nanodomain model that predicted the r-space checkerboard also explains the k-space octets and the origin of the apparent anisotropic surface d-wave gap by using strong electron-phonon interactions outside the CuO2 planes. The topological model identifies …
In this work we fabricate and characterize a functionalized superconducting (SC) Nb tip of a scanning tunnelling microscope (STM). The tip is functionalized with a Tetracyanoquinodimethane molecule (TCNQ) that accepts charge from the tip and develops a magnetic moment. As a consequence, in scanning tunnelling spectroscopy (STS), sharp, bias symmetric sub-gap states identified as Yu-Shiba-Rusinov (YSR) bound states appear against the featureless density of states of a metallic gr/Ir(111) sample. Although the coupling regime of the magnetic impurity with the SC tip depends on the initial absorpt…
We present Scanning Tunneling Spectroscopy measurements at 0.1 K using tips made of Al. At zero field, the atomic lattice and charge density wave of 2HNbSe2 are observed, and under magnetic fields the peculiar electronic surface properties of vortices are precisely resolved. The tip density of states is influenced by the local magnetic field of the vortex, providing for a new probe of the magnetic field at nanometric sizes.
We report a reproducible technique for the fabrication of sharp superconducting Nb tips for scanning tunneling microscopy (STM) and scanning tunneling spectroscopy. Sections of Nb wire with 250 $μ$m diameter are dry etched in an SF$_6$ plasma in a Reactive Ion Etcher. The gas pressure, etching time and applied power are chosen to produce a self-sharpening effect to obtain the desired tip shape. The resulting tips are atomically sharp, with radii of less than 100 nm, and generate good STM images and spectroscopy on single crystal samples of Au(111), Au(100), and Nb(100), as well as a doped topo…
We describe a new type of scanning probe microscope based on a superconducting quantum interference device (SQUID) that resides on the apex of a sharp tip. The SQUID-on-tip is glued to a quartz tuning fork which allows scanning at a tip-sample separation of a few nm. The magnetic flux sensitivity of the SQUID is 1.8 μ_0/Hz^{1/2} and the spatial resolution is about 200 nm, which can be further improved. This combination of high sensitivity, spatial resolution, bandwidth, and the very close proximity to the sample provides a powerful tool for study of dynamic magnetic phenomena on the nanoscale.…
We have developed a method for the reproducible fabrication of superconducting scanning tunneling microscope (STM) tips. We use these tips to form superconductor/insulator/superconductor tunnel junctions with the STM tip as one of the electrodes. We show that such junctions exhibit fluctuation dominated Josephson effects, and describe how the Josephson product IcRn can be inferred from the junctions' tunneling characteristics in this regime. This is first demonstrated for tunneling into Pb films, and then applied in studies of single crystals of NbSe2. We find that in NbSe2, IcRn is lower than…
Dynes ansatz is a broadly utilized procedure to extract the superconducting energy gap from the tunnelling differential conductance, a quantity that is measured by scanning tunnelling microscopy (STM) techniques. In this letter we investigate the limit of applicability of this ansatz in nano-scale superconductors and propose a generalization that permits to study thermal and quantum fluctuations in STM experiments.
We present scanning tunnelling spectroscopy measurements on the heavy fermion superconductor PrOs$_4$Sb$_{12}$. Our results show that the superconducting gap opens over a large part of the Fermi surface. The deviations from isotropic BCS s-wave behavior are discussed in terms of a finite distribution of values of the superconducting gap.
We have studied the electrodynamic response of strongly disordered superconducting TiN films using microwave resonators, where the disordered superconductor is the resonating element in a high- quality superconducting environment of NbTiN. We describe the response assuming an effective pair-breaking mechanism modifying the density of states, and compare this to local tunnelling spectra obtained using scanning tunnelling spectroscopy. For the least disordered film (kFl = 8.7, Rs = 13 Ω), we find good agreement, whereas for the most disordered film (kFl = 0.82, Rs = 4.3 kΩ), there is a strong di…
We discuss basics of scanning tunneling microscopy and spectroscopy (STM/S) of the superconducting state with normal and superconducting tips. We present a new method to measure the local variations in the Andreev reflection amplitude between a superconducting tip and the sample. This method is termed Scanning Andreev Reflection Spectroscopy (SAS). We also briefly discuss vortex imaging with STM/S under an applied current through the sample, and show the vortex lattice as a function of the angle between the magnetic field and sample's surface.
We report a new technique of scanning capacitance microscopy at microwave frequencies. A near field scanning microwave microscope probe is kept at a constant height of about 1nm above the samplewith the help of Scanning Tunneling Microscope (STM) feedback. The microwaves are incident onto the sample through a coaxial resonator that is terminated at one end with a sharp tip (the same tip is used to conduct STM), and capacitively coupled to a feedback circuit and microwave source at the other end. The feedback circuit keeps the source locked onto the resonance frequency of the resonator and outp…
