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arXiv 0706.3148cond-mat.mtrl-sci
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有限尺寸对表面过剩量的影响:应用于外延层的晶体生长和表面熔化

Finite size effects on surface excess quantities: application to crystal growth and surface melting of epitaxial layers

P. Muller

摘要:

从宏观的角度来看,表面熔化或二维(2D)向三维(3D)生长模式(Stranski-Krastanov转变)的相变可以用尺寸效应适当修正的吉布斯过剩量来描述(因为通常的吉布斯过剩量只对半无限系统有很好的定义)。本研究的目的是考虑这样的修正量来描述外延层的表面熔化和Stranski-Krastanov转变。通过引入这种尺寸效应,我们可以预测出在Stranski-Krastanov生长模式下的润湿层的平衡厚度,并可以描述和分类两种不同的熔化情况:由一级相变所引起的不完全熔化和由连续过热所引起的连续预熔化

英文摘要:

From a macroscopic point of view phase transitions as surface melting or two dimensional (2D) towards three dimensional (3D) growth mode (Stranski-Krastanov transition) can be described in terms of Gibbs excess quantity duly amended by size effects (since usual Gibbs excess quantities are only well defined for semi-infinite systems). The aim of this study is to consider such amended quantities to describe surface melting and Stranski-Krastanov transition of epitaxial layers. the so-introduced size effects allows us to predict the equilibrium thickness of the wetting layer of the Stranski-Krastanov growth mode and to describe and classify two different melting cases: the incomplete melting relayed by a first order transition and the continuous premelting relayed by continuous overheating

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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