This paper addresses the three following questions. (i) How the structures of group and of chain of groups enter nuclear, atomic and molecular spectroscopy? (ii) How these structures can be exploited, in a quantum- mechanical framework, in the problems of state labelling and (external) symmetry breaking? (iii) How it is possible to associate a Wigner-Racah algebra to a group or a chain of groups for making easier the calculation of quantum-mechanical matrix elements? Numerous examples illustrate the philosophy of qualitative and quantitative applications to spectroscopy.
Various applications of quantum algebraic techniques in nuclear structure physics and in molecular physics are briefly reviewed and a recent application of these techniques to the structure of atomic clusters is discussed in more detail.
The erbium atomic system is a promising candidate for an atomic Bose-Einstein condensate of atoms with a non-vanishing orbital angular momentum ($L \neq 0$) of the electronic ground state. In this paper we report on the frequency stabilization of a blue external cavity diode laser system on the 400.91 $nm$ laser cooling transition of atomic erbium. Doppler-free saturation spectroscopy is applied within a hollow cathode discharge tube to the corresponding electronic transition of several of the erbium isotopes. Using the technique of frequency modulation spectroscopy, a zero-crossing error sign…
We investigated the Autler-Townes splitting produced by microwave transitions between atomic Rydberg states explored by optical spectroscopy from the ground electronic state. The laser-atom Hamiltonian describing the double irradiation of such a multilevel system is analysed on the basis of the Morris-Shore transformation. The application of this transformation to the microwave-dressed atomic system allows the identification of bright, dark, and spectator states associated with different configurations of atomic states and microwave polarisation. We derived synthetic spectra that show the main…
A new approach to precise determination of atomic matrix elements is described whereby measurement of spectral locations of zeros in the Rayleigh scattering cross-section allows frequency-domain extraction of matrix elements in terms of a fiducial quantity. Illustrations are made for scattering off the ground state in Li and Cs.
The dynamics of spontaneous emission of an atomic system is studied in the framework of an open quantum system. The resulting quantum master equation for the atomic system is non hermitian. The generator $\mathcal{L}$ can possess non-hermitian degeneracies, i.e. exceptional points ($EP$), for specific values of the external laser driving amplitude and detuning from the atomic lines. We suggest to employ the special properties of these $EP$s for accurate parameter estimation. The method is demonstrated for the atomic spectrum of $S \rightarrow P$ transitions of $~^{85}$Rb and $~^{40}$Ca$~^+$.
Quantum algebras (also called quantum groups) are deformed versions of the usual Lie algebras, to which they reduce when the deformation parameter q is set equal to unity. From the mathematical point of view they are Hopf algebras. Their use in physics became popular with the introduction of the q-deformed harmonic oscillator as a tool for providing a boson realization of the quantum algebra SUq(2), although similar mathematical structures had already been known. Initially used for solving the quantum Yang-Baxter equation, quantum algebras have subsequently found applications in several branch…
Measurements of hyperfine polarization quantum beats are used determine the magnetic dipole (A) and electric quadrupole (B) coupling constants in the excited atomic Cs 8p level. The experimental approach is a novel combination of pulsed optical pumping and time-delayed stimulated emission probing of the excited level. From the measured evolution of the atomic linear polarization degree as a function of probe delay time, we determine the hyperfine coupling constants A = 7.42(6) MHz and B = 0.14(29) MHz.
We report the fabrication of alkali-metal vapor cells using femtosecond laser machining. This laser-written vapor-cell (LWVC) technology allows arbitrarily-shaped 3D interior volumes and has potential for integration with photonic structures and optical components. We use non-evaporable getters both to dispense rubidium and to absorb buffer gas. This enables us to produce cells with sub-atmospheric buffer gas pressures without vacuum apparatus. We demonstrate sub-Doppler saturated absorption spectroscopy and single beam optical magnetometry with a single LWVC. The LWVC technology may find appl…
We present a general discussion of the techniques of destabilizing dark states in laser-driven atoms with either a magnetic field or modulated laser polarization. We show that the photon scattering rate is maximized at a particular evolution rate of the dark state. We also find that the atomic resonance curve is significantly broadened when the evolution rate is far from this optimum value. These results are illustrated with detailed examples of destabilizing dark states in some commonly-trapped ions and supported by insights derived from numerical calculations and simple theoretical models.
We show that optical spectroscopy of Rydberg states can provide accurate {\em in situ} thermometry at room-temperature. Transitions from a metastable state to Rydberg states with principal quantum numbers of 25 to 30 have 200 times larger fractional frequency sensitivities to blackbody radiation than the Strontium clock transition. We demonstrate that magic wavelength lattices exist for both Strontium and Ytterbium transitions between the metastable and Rydberg states. Frequency measurements of Rydberg transitions with $10^{-16}$ accuracy provide $10 \, \mathrm{mK}$ resolution and yield a blac…
We present a general and non-invasive probing scheme to perform full momentum-resolved spectroscopy of a cold atomic gas loaded into an optical lattice using a single quantum impurity. The protocol relies on weak collisional interactions and subsequent population measurements of the impurity. By tuning a few controllable external parameters the impurity-lattice interaction can be engineered, and using two sets of measurements, performed with the impurity in two different positions, the full dispersion relation of the superfluid phonons can be reliably extracted.
Coherent control of reactive atomic and molecular collision processes remains elusive experimentally due to quantum interference-based requirements. Here, with insights from symmetry conditions, a viable method for controlling Penning and Associative ionization in atomic collisions is proposed. Computational applications to He$^*({}^3\text{S})$-Li(${^2\text{S}}$) and Ne$^*{}(^3\text{P}_2$)-Ar($^1\text{S}_0$) show extensive control over the ionization processes under experimentally feasible conditions.
Miniature atomic beams can provide new functionalities for atom based sensing instruments such as atomic clocks and interferometers. We recently demonstrated a planar silicon device for generating well-collimated thermal atomic beams [Nat Commun 10, 1831 (2019)]. Here, we present a near-source fluorescence spectroscopy (NSFS) technique that can fully characterize such miniature beams even when measured only a few millimeters from the nozzle exit. We also present a recipe for predicting the fluorescence spectrum, and therefore, the source angular distribution, even under conditions of strong la…
We report on spectroscopy of cold dysprosium atoms on the $1001\,\mathrm{nm}$ transition and present measurements of the excited state lifetime which is at least $87.2(6.7)\,\mathrm{ms}$ long. Due to the long excited state lifetime we are able to measure the ratio of the excited state polarizability to the ground state polarizability at $1064\,\mathrm{nm}$ to be $0.828(0.129)$ by parametric heating in an optical dipole trap. In addition we measure the isotope shifts of the three most abundant bosonic isotopes of dysprosium on the $1001\,\mathrm{nm}$ transition with an accuracy better than $30\…
Spin noise spectroscopy is emerging as a powerful technique for studying the dynamics of various spin systems also beyond their thermal equilibrium and linear response. Here, we study spin fluctuations of room-temperature neutral atoms in a Bell-Bloom type magnetometer. Driven by indirect pumping and undergoing a parametric excitation, this system is known to produce noise-squeezing. Our measurements not only reveal a strong asymmetry in the noise distribution of the atomic signal quadratures at the magnetic resonance, but also provide insight into the mechanism behind its generation and evolu…
Atomic spectroscopy, an essential tool for frequency estimation, is widely used in quantum sensing. Atom-atom interaction can be used to generate entanglement for achieving quantum enhanced sensing. However, atom-atom interaction always induces collision shift, which brings systematic error in determining the resonance frequency. Contradiction between utilizing atom-atom interaction and suppressing collision shift generally exists in atomic spectroscopy. Here, we propose an antisymmetric Rabi spectroscopy protocol without collision shift in the presence of atom-atom interactions. We analytical…
We consider a hydrogen atom confined in a thick brane embedded in a higher-dimensional space. Due to effects of the extra dimensions, the gravitational potential is amplified in distances smaller than the size of the supplementary space, in comparison with the Newtonian potential. Studying the influence of the gravitational interaction modified by the extra dimensions on the energy levels of the hydrogen atom, we find independent constraints for the higher-dimensional Planck mass in terms of the thickness of the brane by using accurate measurements of atomic transition frequencies. The constra…
Symmetry plays a fundamental role in physics. The quasi-degeneracy between single-particle orbitals $(n, l, j = l + 1/2)$ and $(n-1, l + 2, j = l + 3/2)$ indicates a hidden symmetry in atomic nuclei, the so-called pseudospin symmetry (PSS). Since the introduction of the concept of PSS in atomic nuclei, there have been comprehensive efforts to understand its origin. Both splittings of spin doublets and pseudospin doublets play critical roles in the evolution of magic numbers in exotic nuclei discovered by modern spectroscopic studies with radioactive ion beam facilities. Since the PSS was recog…
We report on the collapse and revival of Ramsey fringe visibility when a spatially dependent phase is imprinted in the coherences of a trapped ensemble of two-level atoms. The phase is imprinted via the light shift from a Gaussian laser beam which couples the dynamics of internal and external degrees of freedom for the atoms in an echo spectroscopy sequence. The observed revivals are directly linked to the oscillatory motion of atoms in the trap. An understanding of the effect is important for quantum state engineering of trapped atoms.
We measured the spin noise spectroscopy (SNS) of rubidium atomic ensemble with two different atomic vapor cells (filled with the buffer gases or coated with paraffin film on the inner wall), and demonstrated the enhancement of signal to noise ratio (SNR) by using of the polarization squeezed state (PSS) of 795 nm light field with Stokes operator S2 squeezed. PSS is prepared by locking the relative phase between the squeezed vacuum state of light obtained by a sub-threshold optical parametric oscillator and the orthogonal polarized local oscillator beam by means of the quantum noise lock. Under…
We review experimental and theoretical studies of coherent backscattering of near resonant radiation from an ultracold atomic gas in the weak localization regime. Recent accomplishments in high resolution spectroscopy of atomic ensembles based on the coherent backscattering process are discussed. We also propose several new experimental schemes for time-dependent spectroscopy as applied to multiple scattering in the regime of weak localization.
A spectroscopic application of the atom laser is suggested. The spectroscopy termed 2PACC employs the coherent properties of matter-waves from a two pulse atom laser. These waves are employed to control a gas-surface chemical recombination reaction. The method is demonstrated for an Eley-Rideal reaction of a hydrogen or alkali atom-laser pulse where the surface target is an adsorbed hydrogen atom. The reaction yields either a hydrogen or alkali hydride molecule. The desorbed gas phase molecular yield and its internal state is shown to be controlled by the time and phase delay between two atom-…
Cryogenic source of atomic tritium for neutrino-mass measurements and precision spectroscopy
University of Turku（图尔库大学）；Sorbonne Université（索邦大学）；ENS-PSL Université（巴黎文理研究大学）；Collège de France（法兰西公学院）；Institut Max von Laue - Paul Langevin（马克斯·冯·劳厄-保罗·朗之万研究所）；Marietta Blau Institute for Particle Physics, Austrian Academy of Sciences（奥地利科学院玛丽亚·布劳粒子物理研究所）；Institute for Particle Physics and Astrophysics, ETH（苏黎世联邦理工学院粒子物理与天体物理研究所）；Institute for Astroparticle Physics (IAP), Karlsruhe Institute of Technology (KIT)（卡尔斯鲁厄理工学院亚原子物理研究所）
We study a two-level impurity coupled locally to a quantum gas on an optical lattice. For state-dependent interactions between the impurity and the gas, we show that its evolution encodes information on the local excitation spectrum of gas at the coupling site. Based on this, we design a nondestructive method to probe the system's excitations in a broad range of energies by measuring the state of the probe using standard atom optics methods. We illustrate our findings with numerical simulations for quantum lattice systems, including realistic dephasing noise on the quantum probe, and discuss p…
We analyze atomic photoexcitation into the discrete states by twisted photons, or photons carrying extra orbital angular momentum along their direction of propagation. From the angular momentum and parity considerations, we are able to relate twisted-photon photoexcitation amplitudes to their plane-wave analogues, independently of the details of the atomic wave functions. We analyzed the photo-absorption cross sections of mixed-multipolarity $E2-M1$ transitions in ionized atoms and found fundamental differences coming from the photon topology. Our theoretical analysis demonstrates that it is p…
We report on a low-noise diode laser oscillator at 972 nm actively stabilized to an ultra-stable vibrationally- and thermally compensated reference cavity. To increase the fraction of laser power in the carrier we designed a 20 cm long external cavity diode laser with an intra-cavity electro-optical modulator. The fractional power in the carrier reaches 99.9% which corresponds to a rms phase noise of $ϕ^2_\textrm{rms}=1\,\textrm{mrad}^2$ in 10\,MHz bandwidth. Using this oscillator we recorded 1S-2S spectra in atomic hydrogen and have not observed any significant loss of the excitation efficien…
Quantum control and measurement are two sides of the same coin. To affect a dynamical map, well-designed time-dependent control fields must be applied to the system of interest. To read out the quantum state, information about the system must be transferred to a probe field. We study a particular example of this dual action in the context of quantum control and measurement of atomic spins through the light-shift interaction with an off-resonant optical probe. By introducing an irreducible tensor decomposition, we identify the coupling of the Stokes vector of the light field with moments of the…
Ultraviolet (UV) diode lasers are widely used in many photonics applications. But their frequency stabilization schemes are not as mature as frequency-doubling lasers, mainly due to some limitations in the UV spectral region. Here we developed a high-performance UV frequency stabilization technique implemented directly on UV diode lasers by combining the dichroic atomic vapor laser lock and the resonant transfer cavity lock. As an example, we demonstrate a stable locking with frequency standard deviations of approximately 200 KHz and 300 KHz for 399nm and 370nm diode lasers in 20 minutes. We a…
