The results obtained by Pauli, in his 1926 article on the hydrogen atom, made essential use of the dynamical so(4) symmetry of the bound states. Pauli used this symmetry to compute the perturbed energy levels of an hydrogen atom in a uniform electric field (Stark effect) and in uniform electric and magnetic fields. Although the experimental check of the single Stark effect on the hydrogen atom has been studied experimentally, Pauli's results in mixed fields have been studied only for Rydberg states of rubidium atoms in crossedfields and lithium atoms in parallel fields.
The de Broglie-Bohm causal theory of quantum mechanics is applied to the hydrogen atom in the fully spin-dependent and relativistic framework of the Dirac equation, and in the nonrelativistic but spin-dependent framework of the Pauli equation. Eigenstates are chosen which are simultaneous eigenstates of the energy H, total angular momentum M, and z component of the total angular momentum M_z. We find the trajectories of the electron, and show that in these eigenstates, motion is circular about the z-axis, with constant angular velocity. We compute the rates of revolution for the ground (n=1) s…
We derive the Pauli equation for a charged spin particle confined to move on a spatially curved surface $\mathcal{S}$ in an electromagnetic field. Using the thin-layer quantization scheme to constrain the particle on $\mathcal{S}$, and in the transformed spinor representations, we obtain the well-known geometric potential $V_g$ and the presence of $e^{-iφ}$, which can generate additive spin connection geometric potentials by the curvilinear coordinate derivatives, and we find that the two fundamental evidences in the literature [Giulio Ferrari and Giampaolo Cuoghi, Phys. Rev. Lett. 100, 230403…
The Bohm trajectories for several hydrogen atom eigenstates are determined, taking into account the additional momentum term that arises from the Pauli current. Unlike the original Bohmian result, the spin-dependent term yields nonstationary trajectories. The relationship between the trajectories and the standard visualizations of orbitals is discussed. The trajectories for a model problem that simulates a 1s-2p transition in hydrogen are also examined.
The Pauli method of quantizing the Hydrogen system using the Runge-Lenz vector is ingenious. It is well known that the energy spectrum is identical with the one obtained from the Schrödinger equation and the consistency contributed significantly to the development of Quantum Mechanics in the early days. Since the Runge-Lenz vector is a vector and it commutes with the Hamiltonian, it is natural to use it to connect energy eigenstate $|n,l,m\rangle$ with other degenerate states $|n, l\pm 1,m'\rangle$. Recursive relations can be obtained and the wave functions of the whole spectrum can be obtaine…
The supersymmetry of the electron in both the nonstationary magnetic and electric fields in a two-dimensional case is studied. The supercharges which are the integrals of motion and their algebra are established. Using the obtained algebra the solutions of nonstationary Pauli equation are generated.
The exact bound state solutions of the Dirac-Pauli equation are studied for an appropriate position-dependent mass function by using the Nikiforov-Uvarov method. For a central electric field having a shifted inverse linear term, all two kinds of solutions for bound states are obtained in closed forms.
The discrete spectrum of a q-analogue of the hydrogen atom is obtained from a deformation of the Pauli equations. As an alternative, the spectrum is derived from a deformation of the four-dimensional oscillator arising in the application of the Kustaanheimo-Stiefel transformation to the hydrogen atom. A model of the 2s-2p Dirac shift is proposed in the context of q-deformations.
We demonstrate that neutral Dirac particles in external electric fields, which are equivalent to generalized Dirac oscillators, are physical examples of quasi-exactly solvable systems. Electric field configurations permitting quasi-exact solvability of the system based on the $sl(2)$ symmetry are discussed separately in spherical, cylindrical, and Cartesian coordinates. Some exactly solvable field configurations are also exhibited.
A Dirac particle in general dimensions moving in a 1/r potential is shown to have an exact N = 2 supersymmetry, for which the two supercharge operators are obtained in terms of (a D-dimensional generalization of) the Johnson-Lippmann operator, an extension of the Runge-Lenz-Pauli vector that relativistically incorporates spin degrees of freedom. So the extra symmetry (S(2))in the quantum Kepler problem, which determines the degeneracy of the levels, is so robust as to accommodate the relativistic case in arbitrary dimensions.
We consider a gas of hydrogen atoms illuminated by a broadband, unpolarized radiation with zero anisotropy. In the absence of external fields, the atomic J-levels are thus isotropically populated. While this condition persists in the presence of a magnetic field, we show instead that electric fields can induce the alignment of those levels. We also show that this electric alignment cannot occur in a two-term model of hydrogen (e.g., if only the Ly-alpha transition is excited), or if the level populations are distributed according to Boltzmann's law.
An AC electric field applied to a donor-bound electron in a semiconductor modulates the orbital character of its wave function, which affects the electron's spin dynamics via the spin-orbit interaction. Numerical calculations of the spin dynamics of a hydrogenic donor (Si) embedded in GaAs, using a real-space multi-band k.p formalism, show the high symmetry of the hydrogenic donor state results in strongly nonlinear dependences of the electronic g tensor on applied fields. A nontrivial consequence is that the most rapid Rabi oscillations occur for electric fields modulated at a subharmonic of …
We review in this article the role which the work of Pauli and Weisskopf played in formulating a quantum field theory of spinless particles. To make our computations as transparent as possible, we offer a physicist's derivation of the Klein-Gordon-Fock equation. Since invariant functions play a significant part in our paper, we will discuss them in great detail. We emphasize Pauli's and Weisskopf's view that Dirac's hole theory is totally obsolete in formulating a consistent quantum field theory, be it for scalar or spinor particles. As an important example we present the calculation for produ…
We study the population transfer between resonance states for a time-dependent loop around exceptional points in spectra of the hydrogen atom in parallel electric and magnetic fields. Exceptional points are well-suited for population transfer mechanisms, since a closed loop around these in parameter space commutes eigenstates. We address the question how shape and duration of the dynamical parameter loop affects the transferred population, in order to optimize the latter. Since the full quantum dynamics of the expansion coefficients is time-consuming, we furthermore present an approximation me…
This study presents the confinement influences of Aharonov-Bohm-flux (AB-flux), electric and magnetic fields directed along $z$-axis and encircled by quantum plasmas, on the hydrogen atom. The all-inclusive effects result to a strongly attractive system while the localizations of quantum levels change and the eigenvalues decrease. We find that, the combined effect of the fields is stronger than solitary effect and consequently, there is a substantial shift in the bound state energy of the system. We also find that to perpetuate a low-energy medium for hydrogen atom in quantum plasmas, strong e…
The order dependent mapping method, its convergence has recently been proven for the energy eigenvalue of the anharmonic oscillator, is applied to re-sum the standard perturbation series for Stark effect of the hydrogen atom. We perform a numerical experiment up to the fiftieth order of the perturbation expansion. A simple mapping suggested by the analytic structure and the strong field behavior gives an excellent agreement with the exact value for an intermediate range of the electric field, $0.03\leq E\leq0.25$. The imaginary part of the energy (the decay width) as well as the real part of t…
We study a system composed of a hydrogen atom interacting with an infinite conductor wall. The interaction energy decays like $L^{-3}$, where $L$ is the distance between the atom and the wall, due to the emergence of the van der Waals forces. In this paper we show how, considering the contributions from the quantum fluctuations of the electromagnetic field, the interaction is weakened to a decay of order $L^{-4}$ giving rise to the retardation effects which fall under the name of Casimir-Polder effect. The analysis is done by studying a suitable Pauli-Fierz model associated to the system, in d…
Consider the problem: why does the bound state spectrum $E(n) < 0$, of hydrogen atom Hamiltonian $H$ have more degenerate eigenstates than those required by rotational symmetry? The answer is well known and was demonstrated by Pauli. It is due to an additional conserved vector, $\vec A$, of $H$, called the Laplace-Runge-Lenz vector, that was first discovered for planetary orbits. However, surprisingly, a direct link between degenerate eigenstates of $H$ and the physical labels that describe them is missing. To provide such a link requires, as we show, solving a subtle problem of self adjoint o…
We revisit the definition of the probability current for the Schrodinger equation. First, we prove that the Dirac probability currents of stationary wave functions of the hydrogen atom and of the isotrop harmonic oscillator are not nil and correspond to a circular rotation of the probability. Then, we recall how it is necessary to add to classical Pauli and Schrodinger currents, an additional spin-dependant current, the Gordan current. Consequently, we get a circular probability current in the Schrodinger approximation for the hydrogen atom and the isotrop harmonic oscillator.
Motivated by recent experiments we analyse the classical dynamics of a hydrogen atom in parallel static and microwave electric fields. Using an appropriate representation and averaging approximations we show that resonant ionisation is controlled by a separatrix, and provide necessary conditions for a dynamical resonance to affect the ionisation probability. The position of the dynamical resonance is computed using a high-order perturbation series, and estimate its radius of convergence. We show that the position of the dynamical resonance does not coincide precisely with the ionisation maxima…
The purpose of this work is to retrace the steps that were made by scientists of XX century, like Bohr, Schrodinger, Heisenberg, Pauli, Dirac, for the formulation of what today represents the modern quantum mechanics and that, within two decades, put in question the classical physics. In this context, the study of the electronic structure of hydrogen atom has been the main starting point for the formulation of the theory and, till now, remains the only real case for which the quantum equation of motion can be solved exactly. The results obtained by each theory will be discussed critically, hig…
Recently observed Pauli crystals are structures formed by trapped ultracold atoms with the Fermi statistics. Interactions between these atoms are switched off, so their relative positions are determined by joined action of the trapping potential and the Pauli exclusion principle. Numericalmodeling is used in this paper to find the Pauli crystals in a two-dimensional isotropic harmonic trap, three-dimensional harmonic trap, and a two-dimensional square well trap. The Pauli crystals do not have the symmetry of the trap -- the symmetry is broken by the measurement of positions and, in many cases,…
Studies of atomic systems in electric fields are challenging because of the diverging perturbation series. However, physically meaningful Stark shifts and ionization rates can be found by analytical continuation of the series using appropriate branch cut functions. We apply this approach to low-dimensional hydrogen atoms in order to study the effects of reduced dimensionality. We find that modifications by the electric field are strongly suppressed in reduced dimensions. This finding is explained from a Landau-type analysis of the ionization process.
In this paper we examine the effects of varying several experimental parameters in the Kane quantum computer architecture: A-gate voltage, the qubit depth below the silicon oxide barrier, and the back gate depth to explore how these variables affect the electron density of the donor electron. In particular, we calculate the resonance frequency of the donor nuclei as a function of these parameters. To do this we calculated the donor electron wave function variationally using an effective mass Hamiltonian approach, using a basis of deformed hydrogenic orbitals. This approach was then extended to…
We consider the dispersion interaction between two ground-state hydrogen atoms, interacting with the quantum electromagnetic field in the vacuum state, in the presence of an external static electric field, both in the nonretarded and in the retarded Casimir-Polder regime. We show that the presence of the external field strongly modifies the dispersion interaction between the atoms, changing its space dependence. Moreover, we find that, for specific geometrical configurations of the two atoms with respect to the external field and/or the relative orientation of the fields acting on the two atom…
We consider the resummation of the perturbation series describing the energy displacement of a hydrogenic bound state in an electric field (known as the Stark effect or the LoSurdo-Stark effect), which constitutes a divergent formal power series in the electric field strength. The perturbation series exhibits a rich singularity structure in the Borel plane. Resummation methods are presented which appear to lead to consistent results even in problematic cases where isolated singularities or branch cuts are present on the positive and negative real axis in the Borel plane. Two resummation prescr…
For the hydrogen atom in combined magnetic and electric fields we investigate the dependence of the quantum spectra, classical dynamics, and statistical distributions of energy levels on the mutual orientation of the two external fields. Resonance energies and oscillator strengths are obtained by exact diagonalization of the Hamiltonian in a complete basis set, even far above the ionization threshold. At high excitation energies around the Stark saddle point the eigenenergies exhibit strong level repulsions when the angle between the fields is varied. The large avoided crossings occur between …
