An effective Hamiltonian and equations of motion for treating both the resonant dipole-dipole interaction between two-level atoms and the resonant atom-field interaction are derived, which can suitably be used for studying the influence of arbitrary dispersing and absorbing material surroundings on these interactions. It is shown that the dipole-dipole interaction and the atom-field interaction, respectively, are closely related to the real part and the imaginary part of the (classical) Green tensor. The theory is applied to the study of the transient behavior of two atoms that initially share a single excitation, with special emphasis on the role of the two competing processes of virtual and real photon exchange in the energy transfer between the atoms. To illustrate the powerfulness of the theory, specific results for the case of the atoms being near a dispersing and absorbing microsphere are presented. In particular, the regimes of weak and strong atom-field coupling are addressed.
By using the Green-function concept of quantization of the electromagnetic field in dispersing and absorbing media, the quantized field in the presence of a dispersing and absorbing dielectric multilayer plate is studied. Three-dimensional input-output relations are derived for both amplitude operators in the ${\bf k}$-space and the field operators in the coordinate space. The conditions are discussed, under which the input-output relations can be expressed in terms of bosonic operators. The theory applies to both (effectively) free fields and fields, created by active atomic sources inside an…
The theory developed by Gruner and Welsch [Phys. Rev. A 54, 1661 (1996)] for calculating the 1D input-output relations of the quantized electromagnetic field at dispersing and absorbing dielectric (multilayer) plates is generalized to the three-dimensional case. First a general recipe for the derivation of the reflection and transmission coefficients at an arbitrary body that separates two half spaces from each other is presented. The general theory is then applied to the case of planar multilayer structures, for which the Green tensor is well-known.
Within the frame of macroscopic quantum electrodynamics in causal media, the van der Waals interaction between an atomic system and an arbitrary arrangement of dispersing and absorbing dielectric bodies including metals is studied. It is shown that the minimal-coupling scheme and the multipolar-coupling scheme lead to essentially the same formula for the van der Waals potential. As an application, the vdW potential of an atom in the presence of a sphere is derived. Closed expressions for the long-distance (retardation) and short-distance (non-retardation) limits are given, and the effect of ma…
By making use of the Green function concept of quantization of the electromagnetic field in Kramers--Kronig consistent media, a rigorous quantum mechanical derivation of the rate of intermolecular energy transfer in the presence of arbitrarily shaped, dispersing, and absorbing material bodies is given. Applications to bulk material, multi-slab planar structures, and microspheres are studied. It is shown that when the two molecules are near a planar interface, then surface-guided waves can strongly affect the energy transfer and essentially modify both the (Förster) short-range $R^{-6}$ depende…
A general theory of the interaction of the quantized electromagnetic field with atoms in the presence of dispersing and absorbing dielectric bodies of given Kramers--Kronig consistent permittivities is developed. It is based on a source-quantity representation of the electromagnetic field, in which the electromagnetic-field operators are expressed in terms of a continuous set of fundamental bosonic fields via the Green tensor of the classical problem. Introducing scalar and vector potentials, the formalism is extended in order to include in the theory the interaction of the quantized electroma…
Within the framework of quantization of the macroscopic electromagnetic field, a master equation describing both the resonant dipole-dipole interaction (RDDI) and the resonant atom-field interaction (RAFI) in the presence of dispersing and absorbing macroscopic bodies is derived, with the relevant couplings being expressed in terms of the surroundings-assisted Green tensor. It is shown that under certain conditions the RDDI can be regarded as being governed by an effective Hamiltonian. The theory, which applies to both weak and strong atom-field coupling, is used to study the resonant energy e…
Within the framework of quantization of the macroscopic electromagnetic field, equations of motion and an effective Hamiltonian for treating both the resonant dipole-dipole interaction between two-level atoms and the resonant atom-field interaction are derived, which can suitably be used for studying the influence of arbitrary dispersing and absorbing material surroundings on these interactions. The theory is applied to the study of the transient behavior of two atoms that initially share a single excitation, with special emphasis on the role of the two competing processes of virtual and real …
After giving an outline of the quantization scheme based on the microscopic Hopfield model of a dielectric bulk material, we show how the classical phenomenological Maxwell equations of the electromagnetic field in the presence of dielectric matter of given space- and frequency-dependent complex permittivity can be transferred to quantum theory. Including in the theory the interaction of the medium-assisted field with atomic systems, we present both the minimal-coupling Hamiltonian and the multipolar-coupling Hamiltonian in the Coulomb gauge. To illustrate the concept, we discuss the input--ou…
A formalism for studying spontaneous decay of an excited two-level atom in the presence of dispersing and absorbing dielectric bodies is developed. An integral equation, which is suitable for numerical solution, is derived for the atomic upper-state-probability amplitude. The emission pattern and the power spectrum of the emitted light are expressed in terms of the Green tensor of the dielectric-matter formation including absorption and dispersion. The theory is applied to the spontaneous decay of an excited atom at the center of a three-layered spherical cavity, with the cavity wall being mod…
Within the framework of exact quantum electrodynamics in dielectric, we study the topological Berry phase of a classically pumped $Λ$-type three-level atom, prepared initially in a superposition of its two pumped levels and located near a planar dielectric half-space with model permittivity of Lorentz type, interacts with a vacuum field. The effects of material losses, expressed in terms of the Green tensor of the dielectric-matter formation including dispersion and absorption, on the topological Berry phase of the photon transition between the pumped levels have been studied. The outcomes are…
We present a formalism for studying the influence of dispersive and absorbing dielectric bodies on a radiating atom in the framework of quantization of the phenomenological Maxwell equations for given complex permittivities of the bodies. In Markov approximation, the rate of spontaneous decay and the line shift associated with it can then be related to the complex permittivities and geometries of the bodies via the dyadic Green function of the classical boundary value problem of electrodynamics -- a result which is in agreement with second-order calculations for microscopic model systems. The …
Recently two methods have been developed for the quantization of the electromagnetic field in general dispersing and absorbing linear dielectrics. The first is based upon the introduction of a quantum Langevin current in Maxwell's equations [T. Gruner and D.-G. Welsch, Phys. Rev. A 53, 1818 (1996); Ho Trung Dung, L. Knöll, and D.-G. Welsch, Phys. Rev. A 57, 3931 (1998); S. Scheel, L. Knöll, and D.-G. Welsch, Phys. Rev. A 58, 700 (1998)], whereas the second makes use of a set of auxiliary fields, followed by a canonical quantization procedure [A. Tip, Phys. Rev. A 57, 4818 (1998)]. We show that…
After giving a summary of the basic-theoretical concept of quantization of the electromagnetic field in the presence of dispersing and absorbing (macroscopic) bodies, their effect on spontaneous decay of an excited atom is studied. Various configurations such as bulk material, planar half space media, spherical cavities, and microspheres are considered. In particular, the influence of material absorption on the local-field correction, the decay rate, the line shift, and the emission pattern are examined. Further, the interplay between radiative losses and losses due to material absorption is a…
Recently the influence of dielectric and geometrical properties on the Casimir force between dispersing and absorbing multilayered plates in the zero-temperature limit has been studied within a 1D quantization scheme for the electromagnetic field in the presence of causal media [R. Esquivel-Sirvent, C. Villarreal, and G.H. Cocoletzi, Phys. Rev. Lett. 64, 052108 (2001)]. In the present paper a rigorous 3D analysis is given, which shows that for complex heterostructures the 1D theory only roughly reflects the dependence of the Casimir force on the plate separation in general. Further, an extensi…
Spontaneous decay of an excited atom near a dispersing and absorbing microsphere of given complex permittivity that satisfies the Kramers-Kronig relations is studied, with special emphasis on a Drude-Lorentz permittivity. Both the whispering gallery field resonances below the band gap (for a dielectric sphere) and the surface-guided field resonances inside the gap (for a dielectric or a metallic sphere) are considered. Since the decay rate mimics the spectral density of the sphere-assisted ground-state fluctuation of the radiation field, the strengths and widths of the field resonances essenti…
Within leading-order perturbation theory, the Casimir-Polder potential of a ground-state atom placed within an arbitrary arrangement of dispersing and absorbing linear bodies can be expressed in terms of the polarizability of the atom and the scattering Green tensor of the body-assisted electromagnetic field. Based on a Born series of the Green tensor, a systematic expansion of the Casimir-Polder potential in powers of the susceptibilities of the bodies is presented. The Born expansion is used to show how and under which conditions the Casimir-Polder force can be related to microscopic many-at…
The van der Waals potential of two atoms in the presence of an arbitrary arrangement of dispersing and absorbing magnetodielectric bodies is studied. Starting from a polarizable atom placed within a given geometry, its interaction with a second polarizable/magnetizable atom is deduced from its Casimir-Polder interaction with a weakly polarizable/magnetizable test body. The general expressions for the van der Waals potential hence obtained are illustrated by considering first the case of two atoms in free space, with special emphasis on the interaction between (i) two polarizable atoms and (ii)…
We establish a general relation between dispersion forces. First, based on QED in causal media, leading-order perturbation theory is used to express both the single-atom Casimir-Polder and the two-atom van der Waals potentials in terms of the atomic polarizabilities and the Green tensor for the body-assisted electromagnetic field. Endowed with this geometry-independent framework, we then employ the Born expansion of the Green tensor together with the Clausius-Mosotti relation to prove that the macroscopic Casimir-Polder potential of an atom in the presence of dielectric bodies is due to an inf…
Based on macroscopic QED in linear, causal media, we present a consistent theory for the Casimir-Polder force acting on an atom positioned near dispersing and absorbing magnetodielectric bodies. The perturbative result for the van-der-Waals energy is shown to exhibit interesting new features in the presence of magnetodielectric bodies. To go beyond perturbation theory, we start with the center-of-mass equation of motion and derive a dynamical expression for the Casimir-Polder force acting on an atom prepared in an arbitrary electronic state. For a non-driven atom in the weak coupling regime, t…
The influence of the size and shape of a dispersing and absorbing dielectric body on the local-field corrected spontaneous-decay of an excited atom embedded in the body is studied on the basis of the real-cavity model. By means of a Born expansion of the Green tensor of the system it is shown that to linear order in the susceptibility of the body the decay rate exactly follows Tomas's formula found for the special case of an atom at the center of a homogeneous dielectric sphere [Phys. Rev. A 63, 053811 (2001)]. It is further shown that for an atom situated at the interior of an arbitrary diele…
A scheme for non-conditional generation of long-living maximally entangled states between two spatially well separated atoms is proposed. In the scheme, $Λ$-type atoms pass a resonator-like equipment of dispersing and absorbing macroscopic bodies giving rise to body-assisted electromagnetic field resonances of well-defined heights and widths. Strong atom-field coupling is combined with weak atom-field coupling to realize entanglement transfer from the dipole-allowed transitions to the dipole-forbidden transitions, thereby the entanglement being preserved when the atoms depart from the bodies a…
Based on a unified approach to macroscopic QED that allows for the inclusion of amplification in a limited space and frequency range, we study the Casimir force as a Lorentz force on an arbitrary partially amplifying system of linearly locally responding (isotropic) magnetoelectric bodies. We demonstrate that the force on a weakly polarisable/magnetisable amplifying object in the presence of a purely absorbing environment can be expressed as a sum over the Casimir--Polder forces on the excited atoms inside the body. As an example, the resonant force between a plate consisting of a dilute gas o…
A general theory of the Casimir-Polder interaction of single atoms with dispersing and absorbing magnetodielectric bodies is presented, which is based on QED in linear, causal media. Both ground-state and excited atoms are considered. Whereas the Casimir-Polder force acting on a ground-state atom can conveniently be derived from a perturbative calculation of the atom-field coupling energy, an atom in an excited state is subject to transient force components that can only be fully understood by a dynamical treatment based on the body-assisted vacuum Lorentz force. The results show that the Casi…
The phenomenological Maxwell field is quantized for arbitrarily space- and frequency-dependent complex permittivity. The formalism takes account of the Kramers--Kronig relation and the dissipation-fluctuation theorem and yields the fundamental equal-time commutation relations of QED. Applications to the quantum-state transformation at absorbing and amplifying four-port devices and to the spontaneous decay of an excited atom in the presence of absorbing dielectric bodies are discussed.
In this article, we review the principles of macroscopic quantum electrodynamics and discuss a variety of applications of this theory to medium-assisted atom-field coupling and dispersion forces. The theory generalises the standard mode expansion of the electromagnetic fields in free space to allow for the presence of absorbing bodies. We show that macroscopic quantum electrodynamics provides the link between isolated atomic systems and magnetoelectric bodies, and serves as an important tool for the understanding of surface-assisted atomic relaxation effects and the intimately connected positi…
Using fourth-order perturbation theory, a general formula for the van der Waals potential of two neutral, unpolarized, ground-state atoms in the presence of an arbitrary arrangement of dispersing and absorbing magnetodielectric bodies is derived. The theory is applied to two atoms in bulk material and in front of a planar multilayer system, with special emphasis on the cases of a perfectly reflecting plate and a semi-infinite half space. It is demonstrated that the enhancement and reduction of the two-atom interaction due to the presence of a perfectly reflecting plate can be understood, at le…
We consider the resonant van der Waals interaction between two correlated identical two-level atoms (at least one of which being excited) within the framework of macroscopic cavity quantum electrodynamics in linear, dispersing and absorbing media. The interaction of both atoms with the body-assisted electromagnetic field of the cavity is assumed to be strong. Our time-independent evaluation is based on an extended Jaynes-Cummings model. For a system prepared in a superposition of its dressed states, we derive the general form of the van der Waals forces, using a Lorentzian single mode approxim…
Within the framework of exact quantum electrodynamics in dispersing and absorbing media, we have studied the quantum state of the radiation emitted from an initially in the upper state prepared two-level atom in a high-$Q$ cavity, including the regime where the emitted photon belongs to a wave packet that simultaneously covers the areas inside and outside the cavity. For both continuing atom--field interaction and short-term atom--field interaction, we have determined the spatio-temporal shape of the excited outgoing wave packet and calculated the efficiency of the wave packet to carry a one-p…
On the basis of a general formula obtained earlier via fourth-order erturbation theory within the framework of macroscopic quantum electrodynamics, the van der Waals potential between two neutral, unpolarized, ground-state atoms in the presence of a homogeneous, dispersing and absorbing magnetoelectric sphere is studied. When the radius of the sphere becomes sufficiently large, the result asymptotically agrees with that for two atoms near a planar interface. In the opposite limit of a very small sphere, the sphere can effectively be regarded as being a third ground-state atom, and the nonaddit…
