We consider the environment-affected dynamics of $N$ self-interacting particles living in one-dimensional double wells. Two topics are dealt with. First, we consider the production of entangled states of two-level systems. We show that by adiabatically varying the well biases we may dynamically generate maximally entangled states, starting from initially unentangled product states. Entanglement degradation due to a common type of environmental influence is then computed by solving a master equation. However, we also demonstrate that entanglement production is unaffected if the system-environment coupling is of the type that induces ``motional narrowing''. As our second but related topic, we construct a different master equation that seamlessly merges error protection/detection dynamics for quantum information with the environmental couplings responsible for producing the errors in the first place. Adiabatic avoided crossing schemes are used in both topics.
We investigate ways to optimize adiabaticity and diabaticity in the Landau-Zener model with non-uniform sweeps. We show how diabaticity can be engineered with a pulse consisting of a linear sweep augmented by an oscillating term. We show that the oscillation leads to jumps in populations whose value can be accurately modeled using a model of multiple, photon-assisted Landau-Zener transitions, which generalizes work by Wubs et al. [New J. Phys. 7, 218 (2005)]. We extend the study on diabaticity using methods derived from optimal control. We also show how to preserve adiabaticity with optimal pu…
Two recent preprints [B. Altshuler, H. Krovi, and J. Roland, "Quantum adiabatic optimization fails for random instances of NP-complete problems", arXiv:0908.2782 and "Anderson localization casts clouds over adiabatic quantum optimization", arXiv:0912.0746] argue that random 4th order perturbative corrections to the energies of local minima of random instances of NP-complete problem lead to avoided crossings that cause the failure of quantum adiabatic algorithm (due to exponentially small gap) close to the end, for very small transverse field that scales as an inverse power of instance size N. …
We show that a simple approximation based on concepts underlying the Kibble-Zurek theory of second order phase transition dynamics can be used to treat avoided level crossing problems. The approach discussed in this paper provides an intuitive insight into quantum dynamics of two level systems, and may serve as a link between the theory of dynamics of classical and quantum phase transitions. To illustrate these ideas we analyze dynamics of a paramagnet-ferromagnet quantum phase transition in the Ising model. We also present exact unpublished solutions of the Landau-Zener like problems.
We provide a pedagogical approach to the problem of avoided crossings between electronic molecular curves and to diabatic and adiabatic transitions when the nuclei of a diatomic molecule move according to classical mechanics. For simplicity we restrict the analysis to only two electronic states.
Adiabatic quantum algorithms represent a promising approach to universal quantum computation. Whilst in a closed system these algorithms are limited by avoided level crossings, where the gap becomes exponentially small in the system size, their robustness in open systems remains unresolved. We study the dynamics in the proximity of such an avoided level crossing associated with the adiabatic quantum search algorithm in a quantum system that is coupled to a generic environment. At zero temperature, we find that the algorithm remains scalable provided the noise spectral density of the environmen…
We explain the concept of superadiabatic approximations and show how in the context of the Born- Oppenheimer approximation they lead to an explicit formula that can be used to predict transitions at avoided crossings. Based on this formula, we present a simple method for computing wave packet dynamics across avoided crossings. Only knowledge of the adiabatic electronic energy levels near the avoided crossing is required for the computation. In particular, this means that no diabatization procedure is necessary, the adiabatic energy levels can be computed on the fly, and they only need to be co…
An asymptotic approach for a Schroedinger type equation with a non selfadjoint slowly varying Hamiltonian of a special type is developed. The Hamiltonian is assumed to be the result of a small perturbation of an operator with a twofold degeneracy (turning) point, which can be diagonalized at this point. The non-adiabatic transformation of modes is studied in the case where two small parameters are dependent: the parameter characterizing an order of the perturbation is a square root of the adiabatic parameter. The perturbation of the Hamiltonian produces a close pair of simple degeneracy points…
University of Waterloo（滑铁卢大学）；Perimeter Institute for Theoretical Physics（理论物理珀金斯研究所）；Institute for Quantum Computing, University of Waterloo（滑铁卢大学量子计算研究所）
We present a new paradigm in the field of cavity QED by bringing out remarkable features associated with the avoided crossing of the dressed state levels of the Jaynes Cummings model. We demonstrate how the parametric couplings, realized by a second order nonlinearity in the cavity, can turn the crossing of dressed states into avoided crossings. We show how one can generate coherence between the avoided crossing of dressed states. Such coherences result, for example, in quantum beats in the excitation probability of the qubit. The quality of quantum beats can be considerably improved by adiaba…
For a frequency-tunable two-qubit system, a controlled-Z (CZ) gate can be realized by adiabatically driving the qubit system through an avoided level crossing between an auxiliary state and computational levels. Here, we theoretically propose a fast CZ gate using a shortcut-to-adiabaticity (STA). Experimentally, the STA CZ gate is implemented with a 52 ns control pulse for two coupled superconducting Xmon qubits. Measured fidelity of the STA CZ gate is higher than 96.0%, in both quantum process tomography and randomized benchmarking. The protocol allows a flexible design of the evolution time …
We present a three-cavity network model with two modes in each cavity and a non-linear medium that generates a Kerr type interaction via both self-phase and cross-phase modulation processes. We have two main goals. The first one is to generate a multipartite Maximally Entangled State (MES), starting from the ground state of the system. We address the problem both without and with dissipation. Secondly, we want to protect the MES from decoherence. While studying the MES, we analyze different bipartite and multipartite entanglement measures. We also study the effect of an Avoided Level Crossing …
We provide and analyze examples that counter the widely made claim that tunneling is needed for a quantum speedup in optimization problems. The examples belong to the class of perturbed Hamming-weight optimization problems. In one case, featuring a plateau in the cost function in Hamming weight space, we find that the adiabatic dynamics that make tunneling possible, while superior to simulated annealing, result in a slowdown compared to a diabatic cascade of avoided level-crossings. This, in turn, inspires a classical spin vector dynamics algorithm that is at least as efficient for the plateau…
The inevitable dissipative interaction of an entangled quantum system with its environment causes degradation in quantum correlations present in the system. This can lead to a finite-time disappearance of entanglement, which is known as entanglement sudden death (ESD). Here, we consider an initially entangled qubit-qutrit system and a dissipative noise which leads to ESD, and propose a set of local unitary operations, which when applied on the qubit, qutrit, or both subsystems during the decoherence process, cause ESD to be hastened, delayed, or avoided altogether, depending on its time of app…
We study suppression of nonadiabatic transitions during adiabatic generation of a cat-like state (a superposition of different size cat states) and a spin squeezed state in a bosonic Josephson junction. In order to minimize the adiabatic error, we use quantum adiabatic brachistochrone, which enables us to track a geometrically efficient path in parameter space under given conditions without requiring additional terms. For creation of a cat-like state, divergence of the quantum geometric tensor associated with gap closing at the critical point is avoided because of the parity conservation. The …
Optically addressable paramagnetic defects in wide-band-gap semiconductors are promising platforms for quantum communications and sensing. The presence of avoided crossings between the electronic levels of these defects can substantially alter their quantum dynamics and be both detrimental and beneficial for quantum information applications. Avoided crossings give rise to clock transitions, which can significantly improve protection from magnetic noise and favorably increase coherence time. However, the reduced coupling between electronic and nuclear spins at an avoided crossing may be detrime…
Resonant transverse driving of a two-level system as viewed in the rotating frame couples two degenerate states at the Rabi frequency, an amazing equivalence that emerges in quantum mechanics. While spectacularly successful at controlling natural and artificial quantum systems, certain limitations may arise (e.g., the achievable gate speed) due to non-idealities like the counter-rotating term. Here, we explore a complementary approach to quantum control based on non-resonant, non-adiabatic driving of a longitudinal parameter in the presence of a fixed transverse coupling. We introduce a superc…
The ground electronic, vibrational and rotational state of the OH molecule is currently of interest as it can be manipulated by electric and magnetic fields for experimental studies in ultracold chemistry and quantum degeneracy. Based on our recent exact solution of the corresponding effective Stark-Zeeman Hamiltonian, we present an analytical study of the crossings and avoided crossings in the spectrum. These features are relevant to non-adiabatic transitions, conical intersections and Berry phases. Specifically, for an avoided crossing employed in the evaporative cooling of OH, we compare ou…
Direct dynamics methods using Gaussian wavepackets have to rely only on local properties, such as gradients and hessians at the center of the wavepacket, so as to be compatible with the usual quantum chemistry methods. Matrix elements of the potential energy surfaces between wavepackets therefore usually have to be approximated. It is shown, that if a modified form of valence bond theory is used instead of the usual MO-based theories, the matrix elements can be obtained exactly. This is so because the molecular Hamiltonian only contains the Coulomb potential, for which matrix elements between …
Metastability of a particle trapped in a well with a time-periodically oscillating barrier is studied in the Floquet formalism. It is shown that the oscillating barrier causes the system to decay faster in general. However, avoided crossings of metastable states can occur with the less stable states crossing over to the more stable ones. If in the static well there exists a bound state, then it is possible to stabilize a metastable state by adiabatically increasing the oscillating frequency of the barrier so that the unstable state eventually cross-over to the stable bound state. It is also fo…
The decomposition of electronic and nuclear motion presented in~[A. Abedi, N. T. Maitra, and E. K. U. Gross, Phys. Rev. Lett. 105, 123002 (2010)] yields a time-dependent potential that drives the nuclear motion and fully accounts for the coupling to the electronic subsystem. Here we show that propagation of an ensemble of independent classical nuclear trajectories on this exact potential yields dynamics that are essentially indistinguishable from the exact quantum dynamics for a model non-adiabatic charge transfer problem. We point out the importance of step and bump features in the exact pote…
We present a theoretical study of the rotational dynamics of asymmetry top molecules in an electric field and a parallel non-resonant linearly polarized laser pulse. The time-dependent Schrödinger equation is solved within the rigid rotor approximation. Using the benzonitrile molecule as prototype, we investigate the field-dressed dynamics for experimentally accessible field configurations and compare these results to the adiabatic predictions. We show that for an asymmetric top molecule in parallel fields, the formation of the pendular doublets and the avoided crossings between neighboring le…
A quantum particle in a slowly-changing potential well $V(x,t)=V(x-x_0(εt))$, periodically shaken in time at a slow frequency $ε$, provides an important quantum mechanical system where the adiabatic theorem fails to predict the asymptotic dynamics over time scales longer than $ \sim 1 / ε$. Specifically, we consider a double-well potential $V(x)$ sustaining two bound states spaced in frequency by $ω_0$ and periodically-shaken in complex plane. Two different spatial displacements $x_0(t)$ are assumed: the real spatial displacement $x_0(εt)=A \sin (εt)$, corresponding to ordinary Hermitian shaki…
We provide a detailed theoretical analysis of the adiabatic evolution of degenerate open quantum systems, where the dynamics is induced by time-dependent fluctuating loop paths in control parameter space. For weak system-bath coupling, the fluctuations around a deterministic base path obey Gaussian statistics, where we assume that the quantum adiabatic theorem is also satisfied for fluctuating paths. We show that universal non-Abelian geometric dephasing (NAGD) contributions are contained in the fluctuation-averaged evolution operator. This operator plays a key role in all experimental protoco…
Incorporating protection against quantum errors into adiabatic quantum computing (AQC) is an important task due to the inevitable presence of decoherence. Here we investigate an error-protected encoding of the AQC Hamiltonian, where qubit ensembles are used in place of qubits. Our Hamiltonian only involves total spin operators of the ensembles, offering a simpler route towards error-corrected quantum computing. Our scheme is particularly suited to neutral atomic gases where it is possible to realize large ensemble sizes and produce ensemble-ensemble entanglement. We identify a critical ensembl…
Cold and ultracold polar molecules with nonzero electronic angular momentum are of great interest for studies in quantum chemistry and control, investigations of novel quantum systems, and precision measurement. However, in mixed electric and magnetic fields, these molecules are generically subject to a large set of avoided crossings among their Zeeman sublevels; in magnetic traps, these crossings lead to distorted potentials and trap loss from electric bias fields. We have characterized these crossings in OH by microwave-transferring trapped OH molecules from the upper |f; M = +3/2> parity st…
While adiabatic quantum computation (AQC) possesses some intrinsic robustness to noise, it is expected that a form of error control will be necessary for large scale computations. Error control ideas developed for circuit-model quantum computation do not transfer easily to the AQC model and to date there have been two main proposals to suppress errors during an AQC implementation: energy gap protection and dynamical decoupling. Here we show that these two methods are fundamentally related and may be analyzed within the same formalism. We analyze the effectiveness of such error suppression tech…
Avoided crossings of level pairs with opposite slopes can form potential energy curves for the external degree of freedom of quantum particles. We investigate nonadiabatic decay of metastable states on such avoided crossings (MSACs) using diabatic and adiabatic representations. The system is described by a single scaled adiabaticity parameter, $V$. The time-independent two-component Schrödinger equation is solved in both representations, and the nonadiabatic lifetimes of MSACs are determined from a wave-function flux calculation and from the Breit-Wigner formula, leading to four lifetime value…
The Kitaev honeycomb model is a system allowing for experimentally realisable quantum computation with topological protection of quantum information. Practical implementation of quantum information processing typically relies on adiabatic, i.e. slow dynamics. Here we show that the restriction to adiabatic dynamics can be overcome with optimal control theory, enabled by an extension of the fermionization of the Kitaev honeycomb model to the time-dependent case. Moreover we present a quantum control method that is applicable to large lattice models due to sub-exponential scaling.
We analyze the evolution of an electromagnetic field inside a double cavity when the difference in length between the two cavities is changed, e.g. by translating the common mirror. We find that this allows photons to be moved deterministically from one cavity to the other. We are able to obtain the conditions for adiabatic transfer by first mapping the Maxwell wave equation for the electric field onto a Schroedinger-like wave equation, and then using the Landau-Zener result for the transition probability at an avoided crossing. Our analysis reveals that this mapping only rigorously holds when…
A nonlinear Landau-Zener model was proposed recently to describe, among a number of applications, the nonadiabatic transition of a Bose-Einstein condensate between Bloch bands. Numerical analysis revealed a striking phenomenon that tunneling occurs even in the adiabatic limit as the nonlinear parameter $C$ is above a critical value equal to the gap $V$ of avoided crossing of the two levels. In this paper, we present analytical results that give quantitative account of the breakdown of adiabaticity by mapping this quantum nonlinear model into a classical Josephson Hamiltonian. In the critical r…
We study the dynamics of a quantum two state system driven through an avoided crossing under the influence of a super Ohmic environment, i.e. a longitudinal as well as a transversal one. The crossing time window, in which relaxation influences the dynamics, is centered around the avoided crossing. We determine the dynamics and the Landau-Zener probability employing the numerical exact quasi-adiabatic path integral. At weak coupling we show that the numerically less demanding nonequilibrium Bloch equations provide an accurate description. The crossing time depends strongly not only on the syste…
Tunneling is often claimed to be the key mechanism underlying possible speedups in quantum optimization via quantum annealing (QA), especially for problems featuring a cost function with tall and thin barriers. We present and analyze several counterexamples from the class of perturbed Hamming-weight optimization problems with qubit permutation symmetry. We first show that, for these problems, the adiabatic dynamics that make tunneling possible should be understood not in terms of the cost function but rather the semi-classical potential arising from the spin-coherent path integral formalism. W…
We demonstrate quantum control and entanglement generation using a Landau-Zener beam splitter formed by coupling two transmon qubits to a superconducting cavity. Single passage through the cavity-mediated qubit-qubit avoided crossing provides a direct test of the Landau-Zener transition formula. Consecutive sweeps result in Landau-Zener-Stuckelberg interference patterns, with a visibility that can be sensitively tuned by adjusting the level velocity through both the non-adiabatic and adiabatic regimes. Two-qubit state tomography indicates that a Bell state can be generated via a single passage…
Time evolution of spin-orbit-coupled cold atoms in an optical lattice is studied, with a two-band energy spectrum having two avoided crossings. A force is applied such that the atoms experience two consecutive Landau-Zener tunnelings while transversing the avoided crossings. Stückelberg interference arises from the phase accumulated during the adiabatic evolution between the two tunnelings. This phase is gauge field-dependent and thus provides new opportunities to measure the synthetic gauge field, which is verified via calculation of spin transition probabilities after a double passage proces…
A periodically driven quantum system with avoided-level crossing experiences both non-adiabatic transitions and wave-function phase changes. These result in coherent interference fringes in the system's occupation probabilities. For qubits, with repelling energy levels, such interference, named after Landau-Zener-Stuckelberg-Majorana, displays arc-shaped resonance lines. We demonstrate that in the case of a multi-level system with an avoided-level crossing of the two lower levels, the shape of the resonances can change from convex arcs to concave heart-shaped and harp-shaped resonance lines. I…
A multi-band semiclassical model for surface hopping quantum dynamics
University of California, Santa Barbara（加州大学圣塔芭芭拉分校）；Shanghai Jiao Tong University（上海交通大学）；University of Wisconsin-Madison（威斯康星大学麦迪逊分校）；California Institute of Technology（加州理工学院）；CNRS and University of Strasbourg（法国国家科学研究中心与斯特拉斯堡大学）
Coherent quantum control over many-particle quantum systems requires high fidelity dynamics. One way of achieving this is to use adiabatic schemes where the system follows an instantaneous eigenstate of the Hamiltonian over timescales that do not allow transitions to other states. This, however, makes control dynamics very slow. Here we introduce another concept that takes advantage of preventing unwanted transitions in fermionic systems by using Pauli blocking: excitations from a protected ground state to higher-lying states are avoided by adding a layer of buffer fermions, such that the prot…
Adiabatic quantum computation (AQC) is known to possess some intrinsic robustness, though it is likely that some form of error correction will be necessary for large scale computations. Error handling routines developed for circuit-model quantum computation do not transfer easily to the AQC model since these routines typically require high-quality quantum gates, a resource not generally allowed in AQC. There are two main techniques known to suppress errors during an AQC implementation: energy gap protection and dynamical decoupling. Here we show that both these methods are intimately related a…
In topological quantum computing, unitary operations on qubits are performed by adiabatic braiding of non-Abelian quasiparticles, such as Majorana zero modes, and are protected from local environmental perturbations. In the adiabatic regime, with timescales set by the inverse gap of the system, the errors can be made arbitrarily small by performing the process more slowly. To enhance the performance of quantum information processing with Majorana zero modes, we apply the theory of optimal control to the diabatic dynamics of Majorana-based qubits. While we sacrifice complete topological protect…
We study the S-matrix for the transitions at an avoided crossing of several energy levels, which is a multilevel generalization of the Landau-Zener problem. We demonstrate that, by extending the Schroedinger evolution to complex time, one can obtain an exact answer for some of the transition amplitudes. Similar to the Landau-Zener case, our result covers both the adiabatic regime (slow evolution.) and the diabatic regime (fast evolution). The form of the exact transition amplitude coincides with that obtained in a sequential pairwise level crossing approximation, in accord with the conjecture …
The Landau-Zener formula provides an analytical expression for the final excitation of a quantum system after passage of an avoided crossing of two energy levels. If the two levels correspond to a ground state, and to an excited state which is subject to radiative decay, the probability of exciting the system by adiabatic passage of the level crossing is reduced. In this article we use a stochastic master equation to study the level crossing dynamics when the system is subject to continuous probing of the emitted radiation. The measurement backaction on the system associated with the fluctuati…
WavePacket is an open-source program package for numerical simulations in quantum dynamics. Building on the previous Part I [Comp. Phys. Comm. 213, 223-234 (2017)] and Part II [Comp. Phys. Comm. 228, 229-244 (2018)] which dealt with quantum dynamics of closed and open systems, respectively, the present Part III adds fully classical and mixed quantum-classical propagations to WavePacket. In those simulations classical phase-space densities are sampled by trajectories which follow (diabatic or adiabatic) potential energy surfaces. In the vicinity of (genuine or avoided) intersections of those su…
Coupled nanomechanical resonators have recently attracted much attention for both fundamental studies in physics and broad applications in high-precession detection or sensing. By studying the Landau-Zener transitions and Rabi oscillation of two coupled resonators, it has been shown that such a two-mode system acts as a classical two-level system bearing the analog to a quantum mechanical two-level one. Here we construct a Stückelberg interferometer with two coupled cantilevers by driving the system through the avoided crossing twice. By measuring the non-adiabatic phase acquired at the Landau…
Quantum control of the wave function of two interacting electrons confined in quasi-one-dimensional double-well semiconductor structures is demonstrated. The control strategies are based on the knowledge of the energy spectrum as a function of an external uniform electric field. When two low-lying levels have avoided crossings our system behaves dynamically to a large extent as a two-level system. This characteristic is exploited to implement coherent control strategies based on slow (adiabatic passage) and rapid (diabatic Landau-Zener transition) changes of the external field. We apply this m…
