We re-interprete the microcanonical conditions in the quantum domain as constraints for the interaction of the "gas-subsystem" under consideration and its environment ("container"). The time-average of a purity-measure is found to equal the average over the respective path in Hilbert-space. We then show that for typical (degenerate or non-degenerate) thermodynamical systems almost all states within the allowed region of Hilbert-space have a local von Neumann-entropy S close to the maximum and a purity P close to its minimum, respectively. Typically thermodynamical systems should therefore obey the second law.
We present in this continuation paper a new axiomatic derivation of the Schrödinger equation from three basic postulates. This new derivation sheds some light on the thermodynamic character of the quantum formalism. We also show the formal connection between this derivation and the one previously done by other means. Some considerations about metaestability are also drawn. We return to an example previously developed to show how the connection between both derivations works.
In this paper a thermodynamical derivation of the quantum potential is pro- posed. Within the framework of Bohmian mechanics we show how the quantum potential can be derived, by adding an additional informational degree of freedom to the ordinary degrees of freedom of a physical system. Such a derivation uses the First Law of thermodynamics for this additional degree of freedom and basic equilibrium thermodynamics methods. By doing that, one may associate a temper- ature to each wave function. Features and behavior of this temperature in different situations is studied.
Thermodynamics entails a set of mathematical conditions on quantum Markovian dynamics. In particular, strict energy conservation between the system and environment implies that the dissipative dynamical map commutes with the unitary system propagator. Employing spectral analysis we prove the general form of the ensuing master equation. We compare this result to master equations obtained from standard microscopic derivations. The obtained formal structure can be employed to test the compatibility of approximate derivations with thermodynamics. For example, it designates that global master equat…
One more derivation of the quantum probability rule is presented in order to shed more light on the versatile aspects of this fundamental law. It is shown that the change of state in minimal quantum non-demolition measurement, also known as ideal measurement, implies the probability law in a simple way. Namely, the very requirement of minimal change of state, put in proper mathematical form, gives the well known Lueders formula, which contains the probability rule.
Products and tensor products are linked by a universal property. Imposing the invariance of the laws of Nature under tensor composition along with Leibniz identity determines quantum and classical mechanics algebraic structure through the interplay between products, coproducts, and the tensor product. Violations of Bell's inequalities distinguishes quantum from classical mechanics.
Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where such foundational questions also become practically relevant for emergent nanotechnologies. The derivation is based on a microscopic definition of five essential quantities: internal energy, thermodynamic entropy, work, heat and temperature. These definitions are shown to satisfy the phenomenological laws of nonequilibrium thermodynamics for a large class of…
Excluding the concept of probability in quantum mechanics, we derive Born's law from the remaining postulates in quantum mechanics using type method. We also give a way of determining the unknown parameter in a state vector based on an indirect measurement model. While Deutsch adopt a concept of rational decision-maker who introduces probability, we adopt a concept of statistician in our measurement model and clarifies the distinguished feature of quantum measurement. Like many worlds interpretation, our scenario gives a simple solution for problem of measurement.
Asher Peres' proof that a violation of No Cloning Theorem would imply a violation of the Second Law of Thermodynamics is shown not to take into account the algorithmic-information's contribution to the Thermodynamical Entropy of the semi-permeable membranes of Peres' engine.
The coarse-graining approach to deriving the quantum Markovian master equation is revisited, with close attention given to the underlying approximations. It is further argued that the time interval over which the coarse-graining is performed is a free parameter that can be given a physical measurement-based interpretation. In the case of the damping of composite systems to reservoirs of different temperatures, currently of much interest in the study of quantum thermal machines with regard to the validity of `local' and `global' forms of these equations, the coupling of the subsystems leads to …
Based on quantum statistical mechanics and microscopic quantum dynamics, we prove Planck's and Kelvin's principles for macroscopic systems in a general and realistic setting. We consider a hybrid quantum system that consists of the thermodynamic system, which is initially in thermal equilibrium, and the "apparatus" which operates on the former, and assume that the whole system evolves autonomously. This provides a satisfactory derivation of the second law for macroscopic systems. Although the main body of the article is self-contained there are two supplemental notes on closely related topics,…
Quantum thermodynamics addresses the emergence of thermodynamical laws from quantum mechanics. The link is based on the intimate connection of quantum thermodynamics with the theory of open quantum systems. Quantum mechanics inserts dynamics into thermodynamics giving a sound foundation to finite-time-thermodynamics. The emergence of the 0-law I-law II-law and III-law of thermodynamics from quantum considerations is presented. The emphasis is on consistence between the two theories which address the same subject from different foundations. We claim that inconsistency is the result of faulty an…
Arguments are presented that the assumption, implicit to traditional statistical thermodynamics, that at zero temperature all erratic motions cease, should be dispensed with. Assuming instead a random ultrarelativistic unobservable motion, similar to zitterbewegung, it is demonstrated that in an ideal gas of classical particles the energy equipartition fails in a way that complies with the third law of thermodynamics.
We investigate the fine-grained uncertainty relations for qubit system by measurements corresponding respectively to two and three spin operators. Then we derive the general bound for a combination of two probabilities of projective measurements in mutually unbiased bases in $d$-dimensional Hilbert space. All of those uncertainty inequalities can be applied to construct different thermodynamic cycles such that the violation of those inequalities will lead to the violation of the second law of thermodynamics. This reveals the relationship between fine-grained uncertainty and the second law of t…
The second law of classical thermodynamics, based on the positivity of the entropy production, only holds for deterministic processes. Therefore the Second Law in stochastic quantum thermodynamics may not hold. By making a fundamental connection between thermodynamics and information theory we will introduce a new way of defining the Second Law which holds for both deterministic classical and stochastic quantum thermodynamics. Our work incorporates information well into the Second Law and also provides a thermodynamic operational meaning for negative and positive entropy production.
The third law of thermodynamics has a controversial past and a number of formulations due to Planck, Einstein, and Nernst. It's most accepted version, the unattainability principle, states that "any thermodynamic process cannot reach the temperature of absolute zero by a finite number of steps and within a finite time." Although formulated in 1912, there has been no general proof of the principle, and the only evidence we have for it is that particular cooling methods become less efficient as the temperature decreases. Here we provide the first derivation of a general unattainability principle…
In quantum statistical mechanics, equilibrium states have been shown to be the typical states for a system that is entangled with its environment, suggesting a possible identification between thermodynamic and von Neumann entropies. In this paper, we investigate how the relaxation toward equilibrium is made possible through interactions that do not lead to significant exchange of energy, and argue for the validity of the second law of thermodynamics at the microscopic scale.
We argue that on its face, entanglement theory satisfies laws equivalent to thermodynamics if the theory can be made reversible by adding certain bound entangled states as a free resource during entanglement manipulation. Subject to plausible assumptions, we prove that this is not the case in general, and discuss the implications of this for the thermodynamics of entanglement.
The quantum thermodynamic property of the fractional damping system is investigated extensively. A fractional power-law decaying entropy function is revealed which presents another evidence for the validity of the third law of thermodynamics in the quantum dissipative region. Several non-trivial characters are excavated such as that the entropy varies from a non-linear diverging function to a semi-linear decaying function of the fractional exponent as the temperature tends to absolute zero.
We reconsider the basic building blocks of classical phenomenological thermodynamics. While doing so we show that the zeroth law is a redundant postulate for the theory by deriving it from the first and the second laws. This is in stark contrast to the prevalent conception that the three laws, the zeroth, first and second, are all necessary and independent axioms.
