The propagation of excitation along a one-dimensional chain of atoms is simulated by means of NMR. The physical system used as an analog quantum computer is a nucleus of 133-Cs (spin 7/2) in a liquid crystalline matrix. The Hamiltonian of migration is simulated by using a special 7-frequency pulse, and the dynamics is monitored by following the transfer of population from one of the 8 spin energy levels to the other.
Noise-resistant off-resonance π-rotation realized in an NMR system
School of Physics and Technology, Wuhan University（武汉大学物理科学与技术学院）；School of Physics, Hangzhou Normal University（杭州师范大学物理学院）；Hefei National Laboratory（合肥国家实验室）
We report on the implementation of Burgers equation as a type-II quantum computation on an NMR quantum information processor. Since the flow field evolving under the Burgers equation develops sharp features over time, this is a better test of liquid state NMR implementations of type-II quantum computers than the previous examples using the diffusion equation. In particular, we show that Fourier approximations used in the encoding step are not the dominant error. Small systematic errors in the collision operator accumulate and swamp all other errors. We propose, and demonstrate, that the accumu…
The repertoire of problems theoretically solvable by a quantum computer recently expanded to include the approximate evaluation of knot invariants, specifically the Jones polynomial. The experimental implementation of this evaluation, however, involves many known experimental challenges. Here we present experimental results for a small-scale approximate evaluation of the Jones Polynomial by nuclear-magnetic resonance (NMR), in addition we show how to escape from the limitations of NMR approaches that employ pseudo pure states. Specifically, we use two spin 1/2 nuclei of natural abundance chlor…
We present an experimental implementation of the coined discrete time quantum walk on a square using a three qubit liquid state nuclear magnetic resonance (NMR) quantum information processor (QIP). Contrary to its classical counterpart, we observe complete interference after certain steps and a periodicity in the evolution. Complete state tomography has been performed for each of the eight steps making a full period. The results have extremely high fidelity with the expected states and show clearly the effects of quantum interference in the walk. We also show and discuss the importance of choo…
It is exponentially hard to simulate quantum systems by classical algorithms, while quantum computer could in principle solve this problem polynomially. We demonstrate such an quantum-simulation algorithm on our NMR system to simulate an hydrogen molecule and calculate its ground-state energy. We utilize the NMR interferometry method to measure the phase shift and iterate the process to get a high precision. Finally we get 17 precise bits of the energy value, and we also analyze the source of the error in the simulation.
We have developed a concrete quantum simulation scheme and experimentally simulated a pairing model on an NMR quantum computer. The design of our experiment includes choosing an appropriate initial state in order to make our scheme scalable in near future, and the accomplishment of our experiment makes use of twice Fourier transforms so that our method is applicable to other physical models. Our results show that the experimental simulation can give the spectrum of the simulated Hamiltonian. Consequently, the potential power of a quantum computer on the simulation of complex physical systems i…
Quantum simulation can beat current classical computers with minimally a few tens of qubits and will likely become the first practical use of a quantum computer. One promising application of quantum simulation is to attack challenging quantum chemistry problems. Here we report an experimental demonstration that a small nuclear-magnetic-resonance (NMR) quantum computer is already able to simulate the dynamics of a prototype chemical reaction. The experimental results agree well with classical simulations. We conclude that the quantum simulation of chemical reaction dynamics not computable on cu…
Recently, the dynamics simulation of light-harvesting complexes as an open quantum system, in the weak and strong coupling regimes, has received much attention. In this paper, we investigate a digital quantum simulation approach of the Fenna-Matthews-Olson (FMO) photosynthetic pigment-protein complex surrounded with a Markovian bath, i.e., memoryless, based on a nuclear magnetic resonance (NMR) quantum computer. For this purpose, we apply the decoupling(recoupling) method, which is turn off(on) the couplings and also Solovay-Kitaev techniques to decompose Hamiltonian and Lindbladians into effi…
Dymanics of spin dimers in multiple quantum NMR experiment is studied on the 5-qubit superconducting quantum processor of IBM {Quantum Experience} for the both {pure} ground and thermodynamic equilibrium (mixed) initial states. The work can be considered as a first step towards an application of quantum computers to solving problems of magnetic resonance. This article is dedicated to Prof. Klaus Möbius and Prof. Kev Salikhov on the occasion of their 85th birthdays.
Extensions of average Hamiltonian theory to quantum computation permit the design of arbitrary Hamiltonians, allowing rotations throughout a large Hilbert space. In this way, the kinematics and dynamics of any quantum system may be simulated by a quantum computer. A basis mapping between the systems dictates the average Hamiltonian in the quantum computer needed to implement the desired Hamiltonian in the simulated system. The flexibility of the procedure is illustrated with NMR on 13-C labelled Alanine by creating the non-physical Hamiltonian ZZZ corresponding to a three body interaction.
Feynman, in 1982, proposed the idea of using a quantum simulator to perform quantum simulations. A quantum simulator is basically a controllable quantum system that can mimic the dynamics of other quantum systems we wish to study. In this thesis we investigate some aspects of quantum simulation using both unitary and nonunitary controls. In the unitary part, we experimentally simulated the phenomenon of quantum many-body freezing, and also developed a general protocol to decompose an arbitrary unitary operator. In the nonunitary part, we studied phase decoherence by artificially inducing it. W…
IQM Quantum Computers（IQM量子计算机）；Ludwig-Maximilians-Universität München（慕尼黑大学）；Department of Physical Chemistry, University of the Basque Country UPV/EHU（巴斯克大学物理化学系）
Quantum algorithms are known for presenting more efficient solutions to certain computational tasks than any corresponding classical algorithm. It has been thought that the origin of the power of quantum computation has its roots in non-classical correlations such as entanglement or quantum discord. However, it has been recently shown that even a single pure qudit is sufficient to design an oracle-based algorithm which solves a black-box problem faster than any classical approach to the same problem. In particular, the algorithm that we consider determines whether eight permutation functions d…
We report an experimental quantum simulation of unitary dynamics of an XY spin chain with pre-engineered couplings. Using this simulation, we demonstrate the mirror inversion of quantum states, proposed by Albanese et al. [Phys. Rev. Lett. 93, 230502 (2004)]. The experiment is performed with a 5-qubit dipolar coupled spin system using nuclear magnetic resonance techniques. To perform quantum simulation we make use of the recently proposed unitary operator decomposition algorithm of Ajoy et al. [Phys. Rev. A 85, 030303 (2012)] along with numerical pulse optimization techniques. Further, using m…
An algorithm based on quantum phase estimation, which discriminates quantum states nondestructively within a set of arbitrary orthogonal states, is described and experimentally verified by a NMR quantum information processor. The procedure is scalable and can be applied to any set of orthogonal states. Scalability is demonstrated through Matlab simulation.
Anyons have exotic statistical properties, fractional statistics, differing from Bosons and Fermions. They can be created as excitations of some Hamiltonian models. Here we present an experimental demonstration of anyonic fractional statistics by simulating a version of the Kitaev spin lattice model proposed by Han et al[Phys. Rev.Lett. 98, 150404 (2007)] using an NMR quantum information processor. We use a 7-qubit system to prepare a 6-qubit pseudopure state to implement the ground state preparation and realize anyonic manipulations, including creation, braiding and anyon fusion. A $π/2\times…
Nuclear Magnetic Resonance (NMR) has provided a valuable experimental testbed for quantum information processing (QIP). Here, we briefly review the use of nuclear spins as qubits, and discuss the current status of NMR-QIP. Advances in the techniques available for control are described along with the various implementations of quantum algorithms and quantum simulations that have been performed using NMR. The recent application of NMR control techniques to other quantum computing systems are reviewed before concluding with a description of the efforts currently underway to transition to solid st…
A classical computer simulating Schrodinger dynamics of a quantum system requires resources which scale exponentially with the size of the system, and is regarded as inefficient for such purposes. However, a quantum computer made up of a controllable set of quantum particles has the potential to efficiently simulate other quantum systems of matching dimensions. In this work we studied quantum simulations of single particle Schrodinger equation for certain one-dimensional potentials. In particular, we report the following cases: (i) spreading of wave-function of a free-particle, (ii) evolution …
Amplification of a single spin state using nuclear magnetic resonance (NMR) techniques in a rotating frame is considered. The main aim is to investigate the efficient of various schemes for quantum detection. Results of numerical simulation of the time dependence of individual and total nuclear polarizations for one-, two-, and three-dimensional configurations of the spin systems are presented.
Liquid crystals offer several advantages as solvents for molecules used for nuclear magnetic resonance quantum computing (NMRQC). The dipolar coupling between nuclear spins manifest in the NMR spectra of molecules oriented by a liquid crystal permits a significant increase in clock frequency, while short spin-lattice relaxation times permit fast recycling of algorithms, and save time in calibration and signal-enhancement experiments. Furthermore, the use of liquid crystal solvents offers scalability in the form of an expanded library of spin-bearing molecules suitable for NMRQC. These ideas ar…
In this paper we present an analog of the Bell's inequalities violation test for $N$ qubits to be performed in a nuclear magnetic resonance (NMR) quantum computer. This can be used to simulate or predict results for different Bell's inequalities tests, with distinct configurations and larger number of qubits. To demonstrate our scheme, we implemented a simulation of the violation of Clauser, Horne, Shimony and Holt (CHSH) inequality using a two qubit NMR system and compared the results to those of a photon experiment. The experimental results are well described by Quantum Mechanics theory and …
We give out a proposal of quantum simulation of pairing model on an NMR quantum computer. In our proposal, we choose an appropriate initial state which can be easily prepared in experiment. Making use of feature of NMR measure and the technology of the second (discrete) Fourier transformation, our theoretical scheme can obtain the spectrum of paring model in principle. We concretely discuss the case in the concerned subspaces of pairing model and then, as an example, give out a simple initial state to get the gap of two the lowest energy levels in the given subspace. The quantum simulation to …
We propose an iterative algorithm to simulate the dynamics generated by any $n$-qubit Hamiltonian. The simulation entails decomposing the unitary time evolution operator $U$ (unitary) into a product of different time-step unitaries. The algorithm product-decomposes $U$ in a chosen operator basis by identifying a certain symmetry of $U$ that is intimately related to the number of gates in the decomposition. We illustrate the algorithm by first obtaining a polynomial decomposition in the Pauli basis of the $n$-qubit Quantum State Transfer unitary by Di Franco et. al. (Phys. Rev. Lett. 101, 23050…
We discuss the commonly encountered problem when optimizing NMR pulses using optimal control that the otherwise very precise NMR theory does not provide as excellent agreement with experiments. We hypothesize that this disagreement is due to phase transients in the pulse due to abrupt phase- and amplitude changes resulting in a large bandwidth. We apply the GROUP algorithm that gives high fidelity pulses with a low bandwidth compared to the typical GRAPE pulses. Our results obtain a better agreement between experiment and simulations supporting our hypothesis and solution to the problem.
NMR is emerging as a valuable testbed for the investigation of foundational questions in quantum mechanics. The present paper outlines the preparation of a class of mixed states, called pseudo-pure states, that emulate pure quantum states in the highly mixed environment typically used to describe solution-state NMR samples. It also describes the NMR observation of spinor behavior in spin 1/2 nuclei, the simulation of wave function collapse using a magnetic field gradient, the creation of entangled (or Bell) pseudo-pure states, and a brief discussion of quantum computing logic gates, including …
Experimental realization of quantum information processing in the field of nuclear magnetic resonance (NMR) has been well established. Implementation of conditional phase shift gate has been a significant step, which has lead to realization of important algorithms such as Grover's search algorithm and quantum Fourier transform. This gate has so far been implemented in NMR by using coupling evolution method. We demonstrate here the implementation of the conditional phase shift gate using transition selective pulses. As an application of the gate, we demonstrate Grover's search algorithm and qua…
Recently developed quantum algorithms suggest that in principle, quantum computers can solve problems such as simulation of physical systems more efficiently than classical computers. Much remains to be done to implement these conceptual ideas into actual quantum computers. As a small-scale demonstration of their capability, we simulate a simple many-fermion problem, the Fano-Anderson model, using liquid state Nuclear Magnetic Resonance (NMR). We carefully designed our experiment so that the resource requirement would scale up polynomially with the size of the quantum system to be simulated. T…
Quantum computing exploits fundamentally new models of computation based on quantum mechanical properties instead of classical physics, and it is believed that quantum computers are able to dramatically improve computational power for particular tasks. At present, nuclear magnetic resonance (NMR) has been one of the most successful platforms amongst all current implementations. It has demonstrated universal controls on the largest number of qubits, and many advanced techniques developed in NMR have been adopted to other quantum systems successfully. In this review, we show how NMR quantum proc…
The effects of shot noise on the quantum computation of NMR spectra
Institut für Theoretische Physik and Center for Integrated Quantum Science and Technology, Universität Tübingen（蒂宾根大学理论物理研究所与集成量子科学与技术中心）；HQS Quantum Simulations GmbH（HQS量子模拟有限公司）；The University of Nottingham（诺丁汉大学）
The quantum nature of bulk ensemble NMR quantum computing --the center of recent heated debate, is addressed. Concepts of the mixed state and entanglement are examined, and the data in a 2 qubit liquid NMR quantum computation are analyzed. It is pointed out that the key problem in the current debate is the understanding of entanglement in a mixed state system. The following points are concluded in this Letter: 1)Density matrix describes the "state" of an average particle in an ensemble. It can not describe the state of an individual particle in an ensemble in detail; 2) Entanglement is a prope…
Nuclear magnetic resonance spectroscopy is one of the few remaining areas of physical chemistry for which polynomially scaling simulation methods have not so far been available. Here, we report such a method and illustrate its performance by simulating common 2D and 3D liquid state NMR experiments (including accurate description of spin relaxation processes) on isotopically enriched human ubiquitin - a protein containing over a thousand nuclear spins forming an irregular polycyclic three-dimensional coupling lattice. The algorithm uses careful tailoring of the density operator space to only in…
Random local measurements have recently been proposed to construct entanglement witnesses and thereby detect the presence of bipartite entanglement. We experimentally demonstrate the efficacy of one such scheme on a two-qubit NMR quantum information processor. We show that a set of three random local measurements suffices to detect the entanglement of a general two-qubit state. We experimentally generate states with different amounts of entanglement, and show that the scheme is able to clearly witness entanglement. We perform complete quantum state tomography for each state and compute state f…
We employ a nuclear magnetic resonance (NMR) quantum information processor to simulate the ground state of an XXZ spin chain and measure its NMR analog of entanglement, or pseudo-entanglement. The observed pseudo-entanglement for a small-size system already displays singularity, a signature which is qualitatively similar to that in the thermodynamical limit across quantum phase transitions, including an infinite-order critical point. The experimental results illustrate a successful approach to investigate quantum correlations in many-body systems using quantum simulators.
Memoryless time evolutions are ubiquitous in nature but often correspond to a resolution-induced approximation, i.e. there are correlations in time whose effects are undetectable. Recent advances in the dynamical control of small quantum systems provide the ideal scenario to probe some of these effects. Here we experimentally demonstrate the precise induction of memory effects on the evolution of a quantum coin (qubit) by correlations engineered in its environment. In particular, we design a collisional model in Nuclear Magnetic Resonance (NMR) and precisely control the strength of the effects…
We experimentally emulate interaction induced blockade and local spin freezing in two and three qubit Nuclear Magnetic Resonance (NMR) architecture. These phenomena are identical to the Rydberg blockade and Rydberg biased freezing. In Rydberg blockade, the simultaneous excitation of two or more atoms is blocked due to the level shift induced by the strong Van der Waal's interaction. In such a strong interaction regime, one can also observe Rydberg biased freezing, wherein the dynamics is confined to a subspace, with the help of multiple drives with unequal amplitudes. Here we drive NMR qubits …
We investigate the limits of effectiveness of classical spin simulations for predicting free induction decays (FIDs) measured by solid-state nuclear magnetic resonance (NMR) on systems of quantum nuclear spins. The specific limits considered are associated with the range of interaction, the size of individual quantum spins and the long-time behavior of the FID signals. We compare FIDs measured or computed for lattices of quantum spins (mainly spins 1/2) with the FIDs computed for the corresponding lattices of classical spins. Several cases of excellent quantitative agreement between quantum an…
Development of Neural Network-Based Optimal Control Pulse Generator for Quantum Logic Gates Using the GRAPE Algorithm in NMR Quantum Computer
Sharif University of Technology（谢里夫理工大学）；Centre for Quantum Engineering and photonics Technology, Sharif University of Technology（谢里夫理工大学量子工程与光子技术中心）；Koc University（科奇大学）
In recent years, the performance of different entanglement indicators obtained directly from tomograms has been assessed in continuous-variable and hybrid quantum systems. In this paper, we carry out this task in the case of spin systems. We compute the entanglement indicators from actual experimental data obtained from three liquid-state NMR experiments, and compare them with standard entanglement measures calculated from the corresponding density matrices, both experimentally reconstructed and numerically computed. The gross features of entanglement dynamics and spin squeezing properties are…
We report an ensemble nuclear magnetic resonance (NMR) implementation of a quantum lattice gas algorithm for the diffusion equation. The algorithm employs an array of quantum information processors sharing classical information, a novel architecture referred to as a type-II quantum computer. This concrete implementation provides a test example from which to probe the strengths and limitations of this new computation paradigm. The NMR experiment consists of encoding a mass density onto an array of 16 two-qubit quantum information processors and then following the computation through 7 time step…
Transport of quantum information in linear spin chains has been the subject of much theoretical work. Experimental studies by nuclear spin systems in solid-state by NMR (a natural implementation of such models) is complicated since the dipolar Hamiltonian is not solely comprised of nearest-neighbor XY-Heisenberg couplings. We present here a similarity transformation between the XY-Heisenberg Hamiltonian and the grade raising Hamiltonian, an interaction which is achievable with the collective control provided by radio-frequency pulses in NMR. Not only does this second Hamiltonian allows us to s…
This paper presents an overview of the Fokker-Planck formalism for non-biological magnetic resonance simulations, describes its existing applications and proposes some novel ones. The most attractive feature of Fokker-Planck theory compared to the commonly used Liouville - von Neumann equation is that, for all relevant types of spatial dynamics (spinning, diffusion, flow, etc.), the corresponding Fokker-Planck Hamiltonian is time-independent. Many difficult NMR, EPR and MRI simulation problems (multiple rotation NMR, ultrafast NMR, gradient-based zero-quantum filters, diffusion and flow NMR, o…
The loss of coherence in quantum mechanical superposition states limits the time for which quantum information remains useful. Similarly, it limits the distance over which quantum information can be transmitted, resembling Anderson localization, where disorder causes quantum mechanical states to become localized. Here, we investigate in a nuclear spin-based quantum simulator, the localization of the size of spin clusters that are generated by a Hamiltonian driving the transmission of information, while a variable-strength perturbation counteracts the spreading. We find that the system reaches …
Exact NMR simulation of protein-size spin systems using tensor train formalism
University of Southampton, School of Chemistry（南安普顿大学化学学院）；University of Southampton, Centre for Biological Systems（南安普顿大学生物系统中心）；Max-Planck Institute for Mathematics in the Sciences（马普科学数学研究所）
Superradiant phase transition (SPT) in thermal equilibrium, as a fundamental concept bridging the statistical physics and electrodynamics, can offer the key resources for quantum information science. Notwithstanding its fundamental and practical significances, equilibrium SPT has never been observed in experiments since the first proposal in the 1970s. Furthermore, the existence of equilibrium SPT in the cavity quantum electrodynamics (QED) systems is still subject of ongoing debates, due to the no-go theorem induced by the so-called A2 term. Based on the platform of nuclear magnetic resonance…
We propose and experimentally demonstrate an efficient framework for the quantum simulation of quantum channels in NMR. Our approach relies on the suitable decomposition of non-unitary operators in a linear combination of $d$ unitary ones, which can be then experimentally implemented with the assistance of a number of ancillary qubits that grows logarithmically in $d$. As a proof-of-principle demonstration, we realize the quantum simulation of three quantum channels for a single-qubit: phase damping (PD), amplitude damping (AD), and depolarizing (DEP) channels. For these paradigmatic cases, we…
We performed a banged-digital-analog simulation of a quantum annealing protocol in a two-qubit Nuclear Magnetic Resonance (NMR) quantum computer. Our experimental simulation employed up to 235 Trotter steps, with more than 2000 gates (pulses), and we obtained a protocol success above 80%. Given the exquisite control of the NMR quantum computer, we performed the simulation with different noise levels. We thus analyzed the reliability of the quantum annealing process, and related it to the level of entanglement produced during the protocol. Although the presence of entanglement is not a sufficie…
We theoretically investigate thermalization and spin diffusion driven by a quantum spin bath for a realistic solid-state NMR experiment. We consider polycrystalline L-alanine, and investigate how the spin polarization spreads among several $^{13}$C nuclear spins, which interact via dipole-dipole coupling with the bath of strongly dipolar-coupled $^1$H nuclear (proton) spins. We do this by using direct numerical simulation of the many-spin time-dependent Schrödinger equation. We find that, although the proton spins located near the carbon sites interact most strongly with the $^{13}$C spins, th…
We consider simulating the BCS Hamiltonian, a model of low temperature superconductivity, on a quantum computer. In particular we consider conducting the simulation on the qubus quantum computer, which uses a continuous variable ancilla to generate interactions between qubits. We demonstrate an O(N^3) improvement over previous work conducted on an NMR computer [PRL 89 057904 (2002) & PRL 97 050504 (2006)] for the nearest neighbour and completely general cases. We then go on to show methods to minimise the number of operations needed per time step using the qubus in three cases; a completely ge…
In this paper, we briefly discuss the methodology for simulating a quantum computer which performs Shor's algorithm on a 7-qubit system to factorise 15. Using this simulation and the overlooked quantum brachistochrone method, we devised a Monte Carlo algorithm to calculate the expected time a theoretical quantum computer could perform this calculation under the same energy conditions as current working quantum computers. We found that, experimentally, a nuclear magnetic resonance quantum computer would take $1.59 \pm 0.04$ s to perform our simulated computation, whereas the expected optimal ti…
