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arXiv physics/9905054physics.atom-phphysics.plasm-ph
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锂二聚体吸收光谱的理论研究

Theoretical study of the absorption spectra of the lithium dimer

H. -K. Chung, K. Kirby, J. F. Babb

摘要:

对于锂二聚体,我们计算辐射吸收的截面从振动-转动水平的基础X [单重态Sigma g +]电子状态的振动水平和连续的激发A [单重态Sigma u +]和B [单重态Pi u]电子状态。理论和实验数据被用来表征的分子特性,利用最近获得的知识,从光缔合光谱和超冷原子碰撞研究。的量子力学计算进行的温度范围从1000至2000 K,并与以前的计算和测量进行比较。

英文摘要:

For the lithium dimer we calculate cross sections for absorption of radiation from the vibrational-rotational levels of the ground X [singlet Sigma g +] electronic state to the vibrational levels and continua of the excited A [singlet Sigma u +] and B [singlet Pi u] electronic states. Theoretical and experimental data are used to characterize the molecular properties taking advantage of knowledge recently obtained from photoassociation spectroscopy and ultra-cold atom collision studies. The quantum-mechanical calculations are carried out for temperatures in the range from 1000 to 2000 K and are compared with previous calculations and measurements.

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