Gunnar Haeffler, Andreas E. Klinkmueller, Jonas Rangell, Uldis Berzinsh, Dag Hanstorp
The electron affinity of tellurium has been determined to 1.970 876(7) eV. The threshold for photodetachment of Te^-(^{2} P_{3/2}) forming neutral Te in the ground state was investigated by measuring the total photodetachment cross section using a collinear laser-ion beam geometry. The electron affinity was obtained from a fit to the Wigner law in the threshold region.
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Today, the electron affinity is experimentally well known for most of the elements and is a useful guideline for developing ab initio computational methods. However, the measurements of isotope shifts on the electron affinity are limited by both resolution and sensitivity. In this context, theory eventually contributes to the knowledge and understanding of atomic structures, even though correlation plays a dominant role in negative ions properties and, particularly, in the calculation of the specific mass shift contribution. The present study solves the longstanding discrepancy between calcula…
Relativistic coupled cluster calculations of the electron affinity and ionization potentials of lawrencium
在相对论耦合簇框架内计算了镥和铹的电离电位及铹的电子亲和能，并修正了基组极限与高阶贡献，预测结果与实验值高度一致，验证了方法准确性。
We have investigated the threshold of photodetachment of Li^- leading to the formation of the residual Li atom in the $2p ^2P$ state. The excited residual atom was selectively photoionized via an intermediate Rydberg state and the resulting Li^+ ion was detected. A collinear laser-ion beam geometry enabled both high resolution and sensitivity to be attained. We have demonstrated the potential of this state selective photodetachment spectroscopic method by improving the accuracy of Li electron affinity measurements an order of magnitude. From a fit to the Wigner law in the threshold region, we …
The specific mass shift in the electron affinity between ^{35}Cl and ^{37}Cl has been determined by tunable laser photodetachment spectroscopy to be -0.51(14) GHz. The isotope shift was observed as a difference in the onset of the photodetachment process for the two isotopes. In addition, the electron affinity of Cl was found to be 29138.59(22) cm^{-1}, giving a factor of 2 improvement in the accuracy over earlier measurements. Many-body calculations including lowest-order correlation effects demonstrates the sensitivity of the specific mass shift and show that the inclusion of higher-order co…
The electron affinities eA(S) are measured for the two isotopes 32S and 34S (16752.9753(41) and 16752.9776(85) cm-1, respectively). The isotope shift in the electron affinity is found to be positive, eA(34S)-eA(32S) = +0.0023(70) cm-1, but the uncertainty allows for the possibility that it may be either "normal" (eA(34S) > eA(32S)) or "anomalous" (eA(34S) < eA(32S)). The isotope shift is estimated theoretically using elaborate correlation models, monitoring the electron affinity and the mass polarization term expectation value. The theoretical analysis predicts a very large specific mass shift…
Core-polarization interactions are investigated in low-energy electron elastic scattering from the atoms In,Sn,Eu,Au and At through the calculation of their electron affinities. The complex angular momentum method wherein is embedded the vital electron-electron correlations is used. The core-polarization effects are studied through the well investigated rational function approximation of the Thomas-Fermi potential,which can be analytically continued into the complex plane. The EAs are extracted from the large resonance peaks in the calculated low-energy electron atom scattering total cross sec…
Ionization potentials and electron affinity of oganesson
本文利用高精度相对论耦合簇方法计算 Og 的第一、第二电离势和电子亲和势，并通过基组外推、高阶激发、Breit 与 QED 修正及参数分析给出可靠不确定度。
Revisiting the electron affinity of selenium
本研究针对硒电子亲和能原有LPM测量值与早期实验值偏差却长期作为标准的问题，采用慢电子速度成像法重新测量，经同位素与能级分裂验证后给出修正值，且与LPT实验结果一致。
Theoretical calculations based on the Dirac--Coulomb--Breit relativistic coupled cluster method have been carried out for the electron affinities and ionization potentials of the superheavy element nihonium (Nh) and its lighter homologues In and Tl. The In and Tl calculations are in agreement with measurement within uncertainties. For Nh, where experiment is yet unknown, we predict the ionization potential of 7.569(48) eV and electron affinity of 0.776(30) eV.
The electron affinity (EA) of superheavy element Og is calculated by the use of the relativistic Fock-space coupled cluster (FSCC) and configuration interaction methods. The FSCC cluster operator expansion included single, double, and triple excitations treated in a non-perturbative manner. The Gaunt and retardation electron-electron interactions are taken into account. Both methods yield the results that are in agreement with each other. The quantum electrodynamics correction to EA is evaluated using the model Lamb-shift operator approach. The electron affinity of Og is obtained to be 0.076(4…
One of the most important properties influencing the chemical behavior of an element is the energy released with the addition of an extra electron to the neutral atom, referred to as the electron affinity (EA). Among the remaining elements with unknown EA is astatine, the purely radioactive element 85. Astatine is the heaviest naturally occurring halogen and its isotope $^{211}$At is remarkably well suited for targeted radionuclide therapy of cancer. With the At$^-$ anion being involved in many aspects of current astatine labelling protocols, the knowledge of the electron affinity of this elem…
We investigate the (0001) surface of single crystal quartz with a submonolayer of Rb adsorbates. Using Rydberg atom electromagnetically induced transparency, we investigate the electric fields resulting from Rb adsorbed on the quartz surface, and measure the activation energy of the Rb adsorbates. We show that the adsorbed Rb induces a negative electron affinity (NEA) on the quartz surface. The NEA surface allows low energy electrons to bind to the surface and cancel the electric field from the Rb adsorbates. Our results are important for integrating Rydberg atoms into hybrid quantum systems a…
Ionization potential and electron affinity of superheavy element 119: relativistic high-order coupled cluster study with QED corrections
本研究通过含QED修正、考虑Gaunt相互作用与直至四重激发的相对论高阶耦合簇方法，高精度计算119号元素的电离能与电子亲和势，收窄了此前的估计值，为超重元素周期律实验研究提供参考。
Atomic negative ions are fragile quantum systems in which correlation among the valence electrons plays a very important role. For doubly excited states correlation becomes dominant. Photodetachment is the process where a negative ion absorbs a photon and as a consquence ejects the outermost electron. A new detection scheme has been developed. The residual atom of a photodetachment is state selectively ionised by resonance ionisation spectroscopy. Investigations of the photodetachment threshold of tellurium with neutral particle detection yielded an electron affinity of 1589618(5) m^-1. With s…
We present the results of experimental studies of photon-negative ion interactions involving the dynamics of two electrons. Resonances associated with doubly excited states of Li^- and He^- have been observed using laser photodetachment spectroscopy. Total and partial photodetachment cross sections have been investigated. In the former case, the residual atoms are detected irrespective of their excitation state, while in the latter case only those atoms in specific states are detected. This was achieved by the use of a state selective detection scheme based on the resonant ionization of the re…
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