排斥增加:束缚费米子的泡利不相容原理和能量守恒相互排斥
Increasing Exclusion: The Pauli Exclusion Principle and Energy Conservation for Bound Fermions are Mutually Exclusive
摘要:
对标准量子力学的那些形式的回顾,包括泡利不相容原理,因为它被应用于原子物种,(即多电子和多轨道的量子版本)表明它们与能量守恒不一致。特别关注的是氦,它表明,能量守恒是不符合目前的模式。如果基态中的两个电子,根据电流理论,处于与电离能相同的能量,则证明根据标准理论,在电离期间损失约30 eV,或者可替代地,在电离/电子附着期间产生约30 eV的能量。电离后能级弛豫过程中的能量损失的相同问题被证明存在于所有的原子物种,从而表明,泡利不相容原理(PEP)和能量守恒是不一致的任何原子物种的当前形式的可区分的电子形式的量子理论。只有具有单个轨道的量子形式,并且只能计算出一个电离能(即最初的薛定谔形式),才符合能量平衡。然而,这种形式与普通的光谱学结果并不一致,并且有人认为PEP在这种形式的量子理论中没有意义。与此相反,一个新的模型,经典量子力学(CQM),由R。米尔斯,修改后,是符合所有的光谱和能量守恒的束缚电子系统。这个新模型是基于麦克斯韦方程组和牛顿定律在所有尺度下的有效性。详细的,非常简单的,计算确定基态能级在一个和两个电子系统使用CQM。与数据的协议非常好。
英文摘要:
A review of those forms of standard quantum mechanics that include the Pauli Exclusion Principle as it is applied to atomic species, (that is versions of quantum that are multi-electron and multi-orbital) shows they are not consistent with energy conservation. Particular focus is given to helium in which it is shown that energy conservation is not consistent with current models. If the two electrons in the ground state, per current theory, are at the same energy as the ionization energy, it is demonstrated that according to the standard theory approximately 30 eV are lost during ionization, or alternatively, about 30 eV of energy are created during ionization/electron attachment. The same issue of energy loss during relaxation of energy levels following ionization is shown to exist for all atomic species, thus demonstrating that the Pauli Exclusion Principle (PEP) and energy conservation are not consistent for any atomic species for current forms of distinguishable electron forms of quantum theory. Only that form of quantum that has a single orbital, and for which only one ionization energy can be computed (that is the original Schrodinger form), is consistent with an energy balance. However, this form is not consistent with common spectroscopy results, and it is argued PEP has no meaning in this form of quantum theory. In contrast a new model, Classical Quantum Mechanics (CQM), invented by R. Mills,, following modification, is consistent with all spectroscopy and energy conservation for bound electron systems. This new model is based on the validity of Maxwell s Equations and Newton s Laws at all scales. Detailed, and remarkably simple, computations for determining the ground state energy levels in one and two electron systems using CQM are presented. Agreements with data are excellent.
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