We study the trap depth requirement for the realization of an optical clock using atoms confined in a lattice. We show that site-to-site tunnelling leads to a residual sensitivity to the atom dynamics hence requiring large depths (50 to $100 E\_r$ for Sr) to avoid any frequency shift or line broadening of the atomic transition at the $10^{-17}-10^{-18}$ level. Such large depths and the corresponding laser power may, however, lead to difficulties (e.g. higher order light shifts, two-photon ionization, technical difficulties) and therefore one would like to operate the clock in much shallower traps. To circumvent this problem we propose the use of an accelerated lattice. Acceleration lifts the degeneracy between adjacents potential wells which strongly inhibits tunnelling. We show that using the Earth's gravity, much shallower traps (down to $5 E\_r$ for Sr) can be used for the same accuracy goal.
Laser cooling is a key ingredient for quantum control of atomic systems in a variety of settings. In divalent atoms, two-stage Doppler cooling is typically used to bring atoms to the uK regime. Here, we implement a pulsed radial cooling scheme using the ultranarrow 1S0-3P0 clock transition in ytterbium to realize sub-recoil temperatures, down to tens of nK. Together with sideband cooling along the one-dimensional lattice axis, we efficiently prepare atoms in shallow lattices at an energy of 6 lattice recoils. Under these conditions key limits on lattice clock accuracy and instability are reduc…
A Wannier-Stark optical lattice clock has demonstrated unprecedented measurement precision for optical atomic clocks. We present a systematic evaluation of the lattice light shift, a necessary next step for establishing this system as an accurate atomic clock. With precise control of the atomic motional states in the lattice, we report accurate measurements of the multipolar and the hyperpolar contributions and the operational lattice light shift with a fractional frequency uncertainty of 3.5$\times$10${}^{-19}$.
We report a vapor-cell magneto-optical trapping of Hg isotopes on the ${}^1S_0-{}^3P_1$ intercombination transition. Six abundant isotopes, including four bosons and two fermions, were trapped. Hg is the heaviest non-radioactive atom trapped so far, which enables sensitive atomic searches for ``new physics'' beyond the standard model. We propose an accurate optical lattice clock based on Hg and evaluate its systematic accuracy to be better than $10^{-18}$. Highly accurate and stable Hg-based clocks will provide a new avenue for the research of optical lattice clocks and the time variation of t…
We present an experiment to characterize our new linear ion trap designed for the operation of a many-ion optical clock using 115-In^+ as clock ions. For the characterization of the trap as well as the sympathetic cooling of the clock ions we use 172-Yb^+. The trap design has been derived from finite element method (FEM) calculations and a first prototype based on glass-reinforced thermoset laminates was built. This paper details on the trap manufacturing process and micromotion measurement. Excess micromotion is measured using photon-correlation spectroscopy with a resolution of 1.1nm in moti…
Collisions with background gas particles can shift the resonance frequencies of atoms in atomic clocks. The internal quantum states of atoms can also become entangled with their motional states due to the recoil imparted by a collision, which leads to a further shift of the clock frequency through the relativistic Doppler shift. It can be complicated to evaluate the Doppler and collisional frequency shifts for clock atoms in such entangled states, but estimates of these shifts are essential in order to improve the accuracy of optical atomic clocks. We present a formalism that describes collisi…
Collisions with background gas can perturb the transition frequency of trapped ions in an optical atomic clock. We develop a non-perturbative framework based on a quantum channel description of the scattering process, and use it to derive a master equation which leads to a simple analytic expression for the collisional frequency shift. As a demonstration of our method, we calculate the frequency shift of the Sr$^+$ optical atomic clock transition due to elastic collisions with helium.
An ultrastable optical clock based on neutral atoms trapped in an optical lattice is proposed. Complete control over the light shift is achieved by employing the $5s^2 {}^1S_0 \to 5s5p {}^3P_0$ transition of ${}^{87}{\rm Sr}$ atoms as a "clock transition". Calculations of ac multipole polarizabilities and dipole hyperpolarizabilities for the clock transition indicate that the contribution of the higher-order light shifts can be reduced to less than 1 mHz, allowing for a projected accuracy of better than $ 10^{-17}$.
We report on the design of a segmented linear Paul trap for optical clock applications using trapped ion Coulomb crystals. For an optical clock with an improved short-term stability and a fractional frequency uncertainty of 10^-18, we propose 115In+ ions sympathetically cooled by 172Yb+. We discuss the systematic frequency shifts of such a frequency standard. In particular, we elaborate on high precision calculations of the electric radiofrequency field of the ion trap using the finite element method. These calculations are used to find a scalable design with minimized excess micromotion of th…
Al$^+$ ions optical clock is a very promising optical frequency standard candidate due to its extremely small blackbody radiation shift. It has been successfully demonstrated with indirect cooled, quantum-logic-based spectroscopy technique. Its accuracy is limited by second-order Doppler shift, and its stability is limited by the number of ions that can be probed in quantum logic processing. We propose a direct laser cooling scheme of Al$^+$ ions optical clocks where both the stability and accuracy of the clocks are greatly improved. In the proposed scheme, two Al$^+$ ions traps are utilized. …
We report frequency measurement of the clock transition in an 115In+ ion sympathetically-cooled with Ca+ ions in a linear rf trap. The Ca+ ions are used as a probe of the external electromagnetic field and as the coolant for preparing the cold In+. The frequency is determined to be 1 267 402 452 901 049.9 (6.9) Hz by averaging 36 measurements using an optical frequency comb referenced to the frequency standards located in the same site.
We predict the possibility of "triply-magic" optical lattice trapping of neutral divalent atoms. In such a lattice, the ${^1}\!S_{0}$ and ${^3}\!P_{0}$ clock states and an additional Rydberg state experience identical optical potentials, fully mitigating detrimental effects of the motional decoherence. In particular, we show that this triply magic trapping condition can be satisfied for Yb atom at optical wavelengths and for various other divalent systems (Ca, Mg, Hg and Sr) in the UV region. We assess the quality of triple magic trapping conditions by estimating the probability of excitation …
For the past 15 years, tremendous progress within the fields of laser stabilization, optical frequency combs and atom cooling and trapping have allowed the realization of optical atomic clocks with unrivaled performances. These instruments can perform frequency comparisons with fractional uncertainties well below $10^{-17}$, finding applications in fundamental physics tests, relativistic geodesy, and time and frequency metrology. Even though most optical clocks are currently laboratory setups, several proposals for using these clocks for field measurements or within an optical clock network ha…
Progress in atomic optical clocks with total uncertainty of $10^{-18}$ or below requires a precise estimation of multipolar and higher-order effects due to atom-field interactions. Magnesium is an attractive candidate for optical lattice clocks because it is insensitive to blackbody radiation and has a large quality factor. We employ a combined method of the Dirac-Fock plus core polarization and the relativistic configuration interaction to calculate the dynamic multipolar polarizabilities and the hyperpolarizabilities of the atomic Mg clock. The lattice light shift against variation of the la…
We present a continuous-wave, 810 nm laser with watt-level powers. Our system is based on difference-frequency generation of 532 nm and 1550 nm fiber lasers in a single pass through periodically poled lithium niobate (PPLN). We measure the broadband spectral noise and residual intensity noise to be compatible with off-resonant dipole trapping of ultracold atoms. Given the large bandwidth of the fiber amplifiers, the output can be optimized for a range of wavelengths, including the strontium clock-magic wavelength of 813 nm. Furthermore, with the exploration of more appropriate nonlinear crysta…
We report the first direct excitation of the strongly forbidden 5s2 1S0-5s5p 3P0 transition in 87Sr. Its frequency is 429 228 004 235 (20) kHz. A resonant laser creates a small leak in a magneto-optical trap (MOT): atoms build up to the metastable 3P0 state and escape the trapping process, leading to a detectable decrease in the MOT fluorescence. This line has a natural width of 10^{-3} Hz and can be used for a new generation of optical frequency standards using atoms trapped in a light shift free dipole trap.
We investigate the effects of stimulated scattering of optical lattice photons on atomic coherence times in a state-of-the art ${}^{87}\mathrm{Sr}$ optical lattice clock. Such scattering processes are found to limit the achievable coherence times to less than 12 s (corresponding to a quality factor of $1 \times 10^{16}$), significantly shorter than the predicted 145(40) s lifetime of ${}^{87}\mathrm{Sr}$'s excited clock state. We suggest that shallow, state-independent optical lattices with increased lattice constants can give rise to sufficiently small lattice photon scattering and motional d…
This dissertation reports on the development of a low-power, high-stability miniature atomic frequency standard based on 171Yb+ ions. The ions are buffer-gas cooled and held in a linear quadrupole trap that is integrated into a sealed, getter-pumped vacuum package, and interrogated on the 12.6 GHz hyperfine transition. We hope to achieve a long-term fractional frequency stability of 10^-14 with a miniature clock that consumes only 50 mW of power and occupies a volume of 5 cm^3. I discuss our progress over several years of work on this project. We began by building a conventional tabletop clock…
Examination of loading the isotopes $^{85}$Rb and $^{87}$Rb simultaneously into a shallow far-off-resonance trap (FORT) has revealed an unexpected decrease in maximum atom number loaded as compared to loading either isotope alone. The simultaneous loading of the FORT will be affected by additional homonuclear and heteronuclear light-assisted collisional losses. However, these losses are measured and found to be insufficient to explain the observed drop in total number of atoms loaded into the FORT. We find that our observations are consistent with a decrease in loading rate caused by inter-iso…
For the first time, we experimentally determine the infrared magic wavelength for the $^{40}$Ca$^{+}$ $4s\, ^{2}\!S_{1/2} \rightarrow 3d\,^{2}\!D_{5/2}$ electric quadrupole transition by observation of the light shift canceling in $^{40}$Ca$^{+}$ optical clock. A "magic" magnetic field direction is chosen to make the magic wavelength insensitive to both the linear polarization purity and the polarization direction of the laser. The determined magic wavelength for this transition is 1056.37(9)~nm, which is not only in good agreement with theoretical predictions but also more precise by a factor…
We present measurements and calculations of the trap loss rate for laser cooled Rb atoms confined in either a magneto-optic or a magnetic quadrupole trap when exposed to a room temperature background gas of Ar. We study the loss rate as a function of trap depth and find that copious glancing elastic collisions, which occur in the so-called quantum-diffractive regime and impart very little energy to the trapped atoms, result in significant differences in the loss rate for the MOT compared to a pure magnetic trap due solely to the difference in potential depth. This finding highlights the import…
We report sympathetic cooling of $^{113}$Cd$^+$ by laser-cooled $^{40}$Ca$^+$ in a linear Paul trap for microwave clocks. Long-term low-temperature confinement of $^{113}$Cd$^+$ ions was achieved. The temperature of these ions was measured at $90(10)$ mK, and the corresponding uncertainty arising from the second-order Doppler shifts was estimated to a level of $2\times10^{-17}$. Up to $4.2\times10^5$ Cd$^+$ ions were confined in the trap, and the confinement time constant was measured to be 84 hours. After three hours of confinement, there were still $10^5$ Cd$^+$ ions present, indicating that…
We consider optimization of a rubidium atom clock that uses magnetically trapped Bose condensed atoms in a highly elongated trap, and determine the optimal conditions for minimum Allan variance of the clock using microwave Ramsey fringe spectroscopy. Elimination of magnetic field shifts and collisional shifts are considered. The effects of spin-dipolar relaxation are addressed in the optimization of the clock. We find that for the interstate interaction strength equal to or larger than the intrastate interaction strengths, a modulational instability results in phase separation and symmetry bre…
We have developed an optical lattice clock that can operate in dual modes: a strontium (Sr) clock mode and an ytterbium (Yb) clock mode. Dual-mode operation of the Sr-Yb optical lattice clock is achieved by alternately cooling and trapping $^{87}$Sr and $^{171}$Yb atoms inside the vacuum chamber of the clock. Optical lattices for Sr and Yb atoms were arranged with horizontal and vertical configurations, respectively, resulting in a small distance of the order of 100 $μ$m between the trapped Sr and Yb atoms. The $^{1}$S$_{0}$-$^{3}$P$_{0}$ clock transitions in the trapped atoms were interrogate…
We present our experimental investigation of an optical Raman transition between the magnetic clock states of $^{87}$Rb in an atom chip magnetic trap. The transfer of atomic population is induced by a pair of diode lasers which couple the two clock states off-resonantly to an intermediate state manifold. This transition is subject to destructive interference of two excitation paths, which leads to a reduction of the effective two-photon Rabi-frequency. Furthermore, we find that the transition frequency is highly sensitive to the intensity ratio of the diode lasers. Our results are well describ…
We describe a framework for calculating the frequency shift and uncertainty of trapped-ion optical atomic clocks caused by background-gas collisions, and apply this framework to an $^{27}$Al$^+$ clock to enable a total fractional systematic uncertainty below $10^{-18}$. For this clock, with 38(19) nPa of room temperature H$_2$ background gas, we find that collisional heating generates a non-thermal distribution of motional states with a mean time-dilation shift of order $10^{-16}$ at the end of a 150 ms probe, which is not detected by sideband thermometry energy measurements. However, the cont…
We examine the effect of a parasitic rf magnetic field, attributed to ion trapping, on the highly anticipated nuclear clock based on $^{229}$Th$^{3+}$ [C. J. Campbell et al., Phys. Rev. Lett. 108, 120802 (2012)]. The rf magnetic field induces an ac Zeeman shift to the clock frequency. As we demonstrate, this shift threatens to be the dominant systematic frequency shift for the clock, exceeding other systematic frequency shifts and the projected systematic uncertainty of the clock by orders of magnitude. We propose practical means to suppress or eliminate this shift.
An ultra-stable optical clock based on coherent population trapping effect of alkaline-earth ions, such as Ca$^+$, Sr$^+$, Ba$^+$, is analyzed here. The proposed transitions use the odd isotopes, so that the frequency shift is insensitive to the applied magnetic field. To enhance the signal, a large number of ions are trapped in a linear Paul trap, and laser cooled to crystallize such that the ions are in the Lamb-Dicke regime to avoid first order Doppler shift. Other relevant frequency shifts are also analyzed. Further techniques to improve the stability of the clock signal are discussed.
We report the observation of the higher order frequency shift due to the trapping field in a $^{87}$Sr optical lattice clock. We show that at the magic wavelength of the lattice, where the first order term cancels, the higher order shift will not constitute a limitation to the fractional accuracy of the clock at a level of $10^{-18}$. This result is achieved by operating the clock at very high trapping intensity up to $400 $kW/cm$^2$ and by a specific study of the effect of the two two-photon transitions near the magic wavelength.
Precision measurements and quantum information processing with cold atoms may benefit from trapping atoms with specially engineered, "magic" optical fields. At the magic trapping conditions, the relevant atomic properties remain immune to strong perturbations by the trapping fields. Here we develop a theoretical analysis of a recently observed magic trapping for especially valuable Zeeman-insensitive clock transitions in alkali-metal atoms. The involved mechanism relies on applying "magic" bias B-field along circularly polarized trapping laser field. We map out these B-fields as a function of …
After pumped from $5s_{1/2}$ ground state to $6p_{1/2}$ state, the population inversion between $6s_{1/2}$ and $5p_{1/2,3/2}$ will be established for Rubidium four-level active optical clock. In this paper, we calculate AC Stark shift due to lattice trapping laser which dominates the frequency shift of clock transition in lattice trapped Rubidium four-level active optical clock. Several magic wavelengths are found that can form desired optical lattice trapping potential. By choosing a proper intensity and linewidth of trapping laser, the fractional frequency uncertainty of clock transition due…
A transportable optical clock refer to the $4s^2S_{1/2}-3d^2D_{5/2}$ electric quadrupole transition at 729 nm of single $^{40}Ca^+$ trapped in mini Paul trap has been developed. The physical system of $^{40}Ca^+$ optical clock is re-engineered from a bulky and complex setup to an integration of two subsystems: a compact single ion unit including ion trapping and detection modules, and a compact laser unit including laser sources, beam distributor and frequency reference modules. Apart from the electronics, the whole equipment has been constructed within a volume of 0.54 $m^3$. The systematic f…
We excite spin-waves with spatially inhomogeneous pulses and study the resulting frequency shifts of a chip-scale atomic clock of trapped $^{87}$Rb. The density-dependent frequency shifts of the hyperfine transition simulate the s-wave collisional frequency shifts of fermions, including those of optical lattice clocks. As the spin polarizations oscillate in the trap, the frequency shift reverses and it depends on the area of the second Ramsey pulse, exhibiting a predicted beyond mean-field frequency shift. Numerical and analytic models illustrate the observed behaviors.
In this paper, we study the dynamics of a trapped atom interferometer with internal state labelling in the presence of interactions. We consider two situations: an atomic clock in which the internal states remain superposed, and an inertial sensor configuration in which they are separated. From the average spin evolution, we deduce the fringe contrast and the phase-shift. In the clock configuration, we recover the well-known identical spin rotation effect (ISRE) which can significantly increase the spin coherence time. We also find that the magnitude of the effect depends on the trap geometry …
We have examined loading of 85Rb atoms into a shallow Far-Off-Resonance Trap (FORT) from an optical molasses and compared it to loading from a Magneto-Optical Trap (MOT). We found that substantially more atoms could be loaded into the FORT via an optical molasses as compared to loading from the MOT alone. To determine why this was the case, we measured the rate of atoms loaded into the FORT and the losses from the FORT during the loading process. For both MOT and molasses loading, we examined atom load rate and losses over a range of detunings as well as hyperfine pump powers. We found that th…
We analyze doubly magic trapping of Cs hyperfine transitions including previously neglected contributions from the ground state hyperpolarizability and the interaction of the laser light and a static magnetic field. Extensive numerical searches do not reveal any doubly magic trapping conditions for any pair of hyperfine states. However, including the hyperpolarizability reveals light intensity insensitive traps for a wide range of wavelengths at specific intensities. We then investigate the possibility of using bichromatic trapping light fields. Deploying a bichromatic scheme, we demonstrate d…
It has been proposed to use magnetically trapped atomic ensembles to enhance the interrogation time in microwave clocks. To mitigate the perturbing effects of the magnetic trap, near-magic-field configurations are employed, where the involved clock transition becomes independent of the atom's potential energy to first order. Still, higher order effects are a dominating source for dephasing, limiting the performance of this approach. Here we propose a simple method to cancel the energy dependence to both first and second order, using weak radio-frequency dressing. We give values for dressing fr…
In order to improve the short-term stability of trapped-ion optical clocks, we are developing a frequency standard based on ${}^{115}$In${}^+$ / ${}^{172}$Yb${}^+$ Coulomb crystals. For this purpose, we have developed scalable segmented Paul traps which allow a high level of control for multiple ion ensembles. In this article, we detail on our recent results regarding the reduction of the leading sources of frequency uncertainty introduced by the ion trap: 2nd-order Doppler shifts due to micromotion and the heating of secular motion, as well as the black-body radiation shift due to warming of …
We present a joint theoretical and experimental characterization of the coherent population trapping (CPT) resonance excited on the D1 line of 87Rb atoms by bichromatic linearly polarized laser light. We observe high-contrast transmission resonances (up to 25%), which makes this excitation scheme promising for miniature all-optical atomic clock applications. We also demonstrate cancellation of the first-order light shift by proper choice of the frequencies and relative intensities of the two laser field components. Our theoretical predictions are in good agreement with the experimental results…
We report on building of a compact vacuum chamber for spectroscopy of ultracold thulium and trapping of up to 13 million atoms. Compactness is achieved by obviating a classical Zeeman slower section and placing an atomic oven close to a magneto-optical trap (MOT), specifically at the distance of 11 cm. In this configuration, we significantly gained in solid angle of an atomic beam, which is affected by MOT laser beams, and reached 1 million atoms loaded directly in the MOT. By exploiting Zeeman-like deceleration of atoms with an additional laser beam, we increased the number of trapped atoms t…
We report calculations designed to assess the ultimate precision of an atomic clock based on the 578 nm $6 ^1S_0 --> 6 ^3P^o_0$ transition in Yb atoms confined in an optical lattice trap. We find that this transition has a natural linewidth less than 10 mHz in the odd Yb isotopes, caused by hyperfine coupling. The shift in this transition due to the trapping light acting through the lowest order AC polarizability is found to become zero at the magic trap wavelength of about 752 nm. The effects of Rayleigh scattering, higher-order polarizabilities, vector polarizability, and hyperfine induced e…
Optical atomic clocks represent the state-of-the-art in the frontier of modern measurement science. In this article we provide a detailed review on the development of optical atomic clocks that are based on trapped single ions and many neutral atoms. We discuss important technical ingredients for optical clocks, and we present measurement precision and systematic uncertainty associated with some of the best clocks to date. We conclude with an outlook on the exciting prospect for clock applications.
Clocks based on cold atoms offer unbeatable accuracy and long-term stability, but their use in portable quantum technologies is hampered by a large physical footprint. Here, we use the compact optical layout of a grating magneto-optical trap (gMOT) for a precise frequency reference. The gMOT collects $10^7$ $^{87}$Rb atoms, which are subsequently cooled to $20\,μ$K in optical molasses. We optically probe the microwave atomic ground-state splitting using lin$\perp$lin polarised coherent population trapping and a Raman-Ramsey sequence. With ballistic drop distances of only $0.5\,$mm, the measure…
Compact and robust ion traps for thorium are enabling technology for the next generation of atomic clocks based on a low-energy isomeric transition in the thorium-229 nucleus. We aim at a laser ablation loading of single triply ionized thorium in a radio-frequency electromagnetic linear Paul trap. Detection of ions is based on a modified mass spectrometer and a channeltron with single-ion sensitivity. In this study, we successfully created and detected 232Th+ and 232Th2+ ions from plasma plumes, studied their yield evolution, and compared the loading to a quadrupole ion trap with Yb. We explor…
With the advent of optical clocks featuring fractional frequency uncertainties on the order of $10^{-17}$ and below, new applications such as chronometric levelling with few-cm height resolution emerge. We are developing a transportable optical clock based on a single trapped aluminium ion, which is interrogated via quantum logic spectroscopy. We employ singly-charged calcium as the logic ion for sympathetic cooling, state preparation and readout. Here we present a simple and compact physics and laser package for manipulation of $^{40}\mathrm{Ca}^+$. Important features are a segmented multi-la…
We present and implement a non-destructive detection scheme for the transition probability readout of an optical lattice clock. The scheme relies on a differential heterodyne measurement of the dispersive properties of lattice-trapped atoms enhanced by a high finesse cavity. By design, this scheme offers a 1st order rejection of the technical noise sources, an enhanced signal-to-noise ratio, and an homogeneous atom-cavity coupling. We theoretically show that this scheme is optimal with respect to the photon shot noise limit. We experimentally realize this detection scheme in an operational str…
Optical clocks benefit from tight atomic confinement enabling extended interrogation times as well as Doppler- and recoil-free operation. However, these benefits come at the cost of frequency shifts that, if not properly controlled, may degrade clock accuracy. Numerous theoretical studies have predicted optical lattice clock frequency shifts that scale nonlinearly with trap depth. To experimentally observe and constrain these shifts in an $^{171}$Yb optical lattice clock, we construct a lattice enhancement cavity that exaggerates the light shifts. We observe an atomic temperature that is propo…
Black-body radiation (BBR) shifts of $^3\!P_0-^1\!S_0$ clock transition in divalent atoms Cd and Zn are evaluated using accurate relativistic many-body techniques of atomic structure. Static polarizabilities of the clock levels and relevant electric-dipole matrix elements are computed. We also present a comparative overview of the BBR shifts in optical clocks based on neutral divalent atoms trapped in optical lattices.
We present a compact atomic clock interrogating ultracold 87Rb magnetically trapped on an atom chip. Very long coherence times sustained by spin self-rephasing allow us to interrogate the atomic transition with 85% contrast at 5 s Ramsey time. The clock exhibits a fractional frequency stability of $5.8\times 10^{-13}$ at 1 s and is likely to integrate into the $1\times10^{-15}$ range in less than a day. A detailed analysis of 7 noise sources explains the measured frequency stability. Fluctuations in the atom temperature (0.4 nK shot-to-shot) and in the offset magnetic field ($5\times10^{-6}$ r…
Recently invented and demonstrated, optical lattice clocks hold great promise for improving the precision of modern timekeeping. These clocks aim at the 10^-18 fractional accuracy, which translates into a clock that would neither lose or gain a fraction of a second over an estimated age of the Universe. In these clocks, millions of atoms are trapped and interrogated simultaneously, dramatically improving clock stability. Here we discuss the principles of operation of these clocks and, in particular, a novel concept of "magic" trapping of atoms in optical lattices. We also highlight recently pr…
