We model collisionless collective conversion of a degenerate Fermi gas into bosonic molecules via a Feshbach resonance, treating the bosonic molecules as a classical field and seeding the pairing amplitudes with random phases. A dynamical instability of the Fermi sea against association into molecules initiates the conversion. The model qualitatively reproduces several experimental observations {[Regal et al., Nature {\bf 424}, 47 (2003)]}. We predict that the initial temperature of the Fermi gas sets the limit for the efficiency of atom-molecule conversion.
Photoassociation and the Feshbach resonance are, in principle, feasible means for creating a molecular Bose-Einstein condensate from an already-quantum-degenerate gas of atoms; however, mean-field shifts and irreversible decay place practical constraints on the efficient delivery of stable molecules using either mechanism alone. We therefore propose Feshbach-stimulated Raman photoproduction, i.e., a combination of magnetic and optical methods, as a viable means to collectively convert degenerate atoms into a stable molecular condensate with near-unit efficiency.
Degenerate Fermi gas interacting with molecules near Feshbach resonance is unstable with respect to formation of a mixed state in which atoms and molecules coexist as a coherent superposition. Theory of this state is developed using a mapping to the Dicke model, treating molecular field in the single mode approximation. The results are accurate in the strong coupling regime relevant for current experimental efforts. The exact solution of the Dicke model is exploited to study stability, phase diagram, and nonadiabatic dynamics of molecular field in the mixed state.
We observe thermalization in the production of a degenerate Fermi gas of polar ${}^{40}\text{K}{}^{87}\text{Rb}$ molecules. By measuring the atom--dimer elastic scattering cross section near the Feshbach resonance, we show that Feshbach molecules rapidly reach thermal equilibrium with both parent atomic species. Equilibrium is essentially maintained through coherent transfer to the ground state. Sub-Poissonian density fluctuations in Feshbach and ground-state molecules are measured, giving an independent characterization of degeneracy and directly probing the molecular Fermi--Dirac distributio…
We report on the observation of ultracold heteronuclear Feshbach molecules. Starting with a $^{87}$Rb BEC and a cold atomic gas of $^{85}$Rb, we utilize previously unobserved interspecies Feshbach resonances to create up to 25,000 molecules. Even though the $^{85}$Rb gas is non-degenerate we observe a large molecular conversion efficiency due to the presence of a quantum degenerate $^{87}$Rb gas; this represents a key feature of our system. We compare the molecule creation at two different Feshbach resonances with different magnetic-field widths. The two Feshbach resonances are located at $265…
We theoretically examine a zero-temperature system of Fermi degenerate atoms coupled to bosonic molecules via collisionless rapid adiabatic passage across a Feshbach resonance, focusing on saturation of the molecular conversion efficiency at the slowest magnetic-field sweep rates. Borrowing a novel MANY-FERMION Fock-state theory, we find that a proper model of the magnetic-field sweep can systematically remove saturation. We also debunk the common misconception that many-body effects are responsible for molecules existing above the two-body threshold.
We theoretically examine the creation of a Fermi-degenerate gas of molecules via a photoassociation or Feshbach resonance applied to a degenerate Bose-Fermi mixture of atoms. This problem raises an interest because, unlike bosons, fermions in general do not behave cooperatively, so that the collective conversion of, say, two million atoms into one million molecules is not to be expected. Nevertheless, we find that the coupled Fermi system displays collective Rabi-like oscillations and adiabatic passage between atoms and molecules, thereby mimicking Bose-Einstein statistics. Cooperative associa…
The dynamical atom/molecule projection, recently used to probe fermion pairing, is fast compared to collective fermion times, but slow on the Feshbach resonance width scale. Theory of detuning-induced dynamics of molecules coupled to resonantly associating atom pairs, employing a time-dependent many-body Green's function approach, is presented. An exact solution is found, predicting a 1/3 power law for molecule production efficiency at fast sweep. The results for $s$- and p-wave resonances are obtained and compared. The predicted production efficiency agrees with experimental observations for …
We report on the creation of ultracold gases of bosonic Feshbach molecules of NaCs. The molecules are associated from overlapping gases of Na and Cs using a Feshbach resonance at 864.12(5) G. We characterize the Feshbach resonance using bound state spectroscopy, in conjunction with a coupled-channel calculation. By varying the temperature and atom numbers of the initial atomic mixtures, we demonstrate the association of NaCs gases over a wide dynamic range of molecule numbers and temperatures, reaching 70 nK for our coldest systems and a phase-space density near 0.1. This is an important stepp…
We report on the formation of ultracold fermionic Feshbach molecules of $^{23}$Na$^{40}$K, the first fermionic molecule that is chemically stable in its ground state. The lifetime of the nearly degenerate molecular gas exceeds 100 ms in the vicinity of the Feshbach resonance. The measured dependence of the molecular binding energy on the magnetic field demonstrates the open-channel character of the molecules over a wide field range and implies significant singlet admixture. This will enable efficient transfer into the singlet vibrational ground state, resulting in a stable molecular Fermi gas …
We investigate magnetoassociation of ultracold fermionic Feshbach molecules in a mixture of $^{40}$K and $^{87}$Rb atoms, where we can create as many as $7\times 10^4$ $^{40}$K$^{87}$Rb molecules with a conversion efficiency as high as 45%. In the perturbative regime, we find that the conversion efficiency depends linearly on the density overlap of the two gases, with a slope that matches a parameter-free model that uses only the atom masses and the known Feshbach resonance parameters. In the saturated regime, we find that the maximum number of Feshbach molecules depends on the atoms' phase-sp…
We report the creation of ultracold bosonic $^{23}$Na$^{87}$Rb Feshbach molecules via magneto-association. By ramping the magnetic field across an interspecies Feshbach resonance, at least 4000 molecules can be produced out of the near degenerate ultracold mixture. Fast loss due to inelastic atom-molecule collisions is observed, which limits the pure molecule number, after residual atoms removal, to 1700. The pure molecule sample can live for 21.8(8) ms in the optical trap, long enough for future molecular spectroscopy studies toward coherently transferring to the singlet ro-vibrational ground…
We directly measured the normalized $\it{s}$-wave scattering cross-section of ultracold $^{40}\rm{K}$ atoms across a magnetic-field Feshbach resonance by colliding pairs of degenerate Fermi gases (DFGs) and imaging the scattered atoms. We extracted the scattered fraction for a range of bias magnetic fields, and measured the resonance location to be $B_0 = 20.206(15)$ mT with width $Δ= 1.0(5)$ mT. To optimize the signal-to-noise ratio of atom number in scattering images, we developed techniques to interpret absorption images in a regime where recoil induced detuning corrections are significant.…
This paper reviews current experimental and theoretical progress in the study of dipolar quantum gases of ground and meta-stable atoms with a large magnetic moment. We emphasize the anisotropic nature of Feshbach resonances due to coupling to fast-rotating resonant molecular states in ultracold s-wave collisions between magnetic atoms in external magnetic fields. The dramatic differences in the distribution of resonances of magnetic $^7$S$_3$ chromium and magnetic lanthanide atoms with a submerged 4f shell and non-zero electron angular momentum is analyzed. We focus on Dysprosium and Erbium as…
We show that the slow driving of a focused laser beam through the cloud of trapped cold fermions allows for a creation of the collective excitation in the system. The method, proposed originally by us for bosons, seems to be quite feasible experimentally -- it requires only an appropriate change in time of the potential in atomic traps, as realized in laboratories already.
We survey results on the creation of heteronuclear Fermi molecules by tuning a degenerate Bose-Fermi mixture into the neighborhood of an association resonance, either photoassociation or Feshbach, as well as the subsequent prospects for Cooper-like pairing between atoms and molecules. In the simplest case of only one molecular state, corresponding to either a Feshbach resonance or one-color photoassociation, the system displays Rabi oscillations and rapid adiabatic passage between a Bose-Fermi mixture of atoms and fermionic molecules. For two-color photoassociation, the system admits stimulate…
Collisional resonances are an important tool which has been used to modify interactions in ultracold gases, for realizing novel Hamiltonians in quantum simulations, for creating molecules from atomic gases and for controlling chemical reactions. So far, such resonances have been observed for atom-atom collisions, atom-molecule collisions and collisions between Feshbach molecules which are very weakly bound. Whether such resonances exist for ultracold ground state molecules has been debated due to the possibly high density of states and/or rapid decay of the resonant complex. Here we report a v…
We present expressions demonstrating that collisional decoherence of ultracold atoms or molecules in a coherent superposition of non-degenerate quantum states is suppressed when both the real and imaginary parts of the scattering lengths for the states in the coherent superposition are equal. We show that the rate of collisional decoherence can be enhanced or suppressed by varying an external magnetic field near a Feshbach resonance. For some resonances, the suppression is very dramatic. We propose a method for measuring the scattering length of ultracold particles in excited quantum states ex…
The association process of Feshbach molecules is well described by a Landau-Zener (LZ) transition above the Fermi temperature, such that two-body physics dominates the dynamics. However, using $^6$Li atoms and the associated Feshbach resonance at $B_r=834.1$ G, we observe an enhancement of the atom-molecule coupling as the fermionic atoms reach degeneracy, demonstrating the importance of many-body coherence not captured by the conventional LZ model. In the experiment, we apply a linear association ramp ranging from adiabatic to non-equilibrium molecule association for various temperatures. We …
This PhD tutorial article is a review of our experiments on heteronuclear quantum gas mixtures at the University of Hamburg. We introduce basic properties of trapped Fermi-Bose mixtures and demonstrate the achievement of large quantum degenerate mixtures of 40K and 87Rb. Using heteronuclear Feshbach resonances, we show how the heteronuclear interaction can be tuned, allowing us to induce phase separation and collapse for large repulsive and attractive interactions, respectively. We realize Fermi-Bose mixtures in 3D optical lattices as a novel quantum many-body system and study coherence proper…
We report on the formation of a stable quantum degenerate mixture of fermionic $^6$Li and bosonic $^{133}$Cs in an optical trap by sympathetic cooling near an interspecies Feshbach resonance. New regimes of the quantum degenerate mixtures are identified. With moderate attractive interspecies interactions, we show that a degenerate Fermi gas of Li can be fully confined in the Cs condensate without external potentials. For stronger attraction where mean-field collapse is expected, no such instability is observed. In this case, we suggest the stability is a result of dynamic equilibrium, where th…
The present paper aims at finding optimal parameters for trapping of Cs$_2$ molecules in optical lattices, with the perspective of creating a quantum degenerate gas of ground-state molecules. We have calculated dynamic polarizabilities of Cs$_2$ molecules subject to an oscillating electric field, using accurate potential curves and electronic transition dipole moments. We show that for some particular wavelengths of the optical lattice, called "magic wavelengths", the polarizability of the ground-state molecules is equal to the one of a Feshbach molecule. As the creation of the sample of groun…
We study an atom-cavity system in which the cavity has several degenerate transverse modes. Mode-resolved cavity transmission spectroscopy reveals well-resolved atom-cavity resonances for several cavity modes, a signature of collective strong coupling for the different modes. Furthermore, the experiment shows that the cavity modes are coupled via the atomic ensemble contained in the cavity. The experimental observations are supported by a detailed theoretical analysis. The work paves the way to the use of interacting degenerate modes in cavity-based quantum information processing, where qubits…
We study the dynamics of an initially degenerate homogeneous Bose gas after an interaction quench to the unitary regime at a magnetic Feshbach resonance. As the cloud decays and heats, it exhibits a crossover from degenerate- to thermal-gas behaviour, both of which are characterised by universal scaling laws linking the particle-loss rate to the total atom number $N$. In the degenerate and thermal regimes the per-particle loss rate is $\propto N^{2/3}$ and $N^{26/9}$, respectively. The crossover occurs at a universal kinetic energy per particle and at a universal time after the quench, in unit…
We demonstrate a generally applicable technique for mixing two-species quantum degenerate bosonic samples in the presence of an optical lattice, and we employ it to produce low-entropy samples of ultracold 87Rb133Cs Feshbach molecules with a lattice filling fraction exceeding 30%. Starting from two spatially separated Bose-Einstein condensates of Rb and Cs atoms, Rb-Cs atom pairs are efficiently produced by using the superfluid-to-Mott insulator quantum phase transition twice, first for the Cs sample, then for the Rb sample, after nulling the Rb-Cs interaction at a Feshbach resonance's zero cr…
A degenerate Fermi gas is rapidly quenched into the regime of strong effective repulsion near a Feshbach resonance. The spin fluctuations are monitored using speckle imaging and, contrary to several theoretical predictions, the samples remain in the paramagnetic phase for arbitrarily large scattering length. Over a wide range of interaction strengths a rapid decay into bound pairs is observed over times on the order of 10\hbar/E_F, preventing the study of equilibrium phases of strongly repulsive fermions. Our work suggests that a Fermi gas with strong short-range repulsive interactions does no…
We report on an efficient production scheme for a large quantum degenerate sample of fermionic lithium. The approach is based on our previous work on narrow-line $ 2S_{1/2}\rightarrow 3P_{3/2} $ laser cooling resulting in a high phase-space density of up to $3\times10^{-4}$. This allows utilizing a large volume crossed optical dipole trap with a total power of $45\,\textrm{W}$, leading to high loading efficiency and $8\times10^6$ trapped atoms. The same optical trapping configuration is used for rapid adiabatic transport over a distance of $25\,\textrm{cm}$ in $0.9\,\textrm{s}$, and subsequent…
