We discuss mixing/segregation phenomena in a schematic hard spheres lattice model for binary mixtures of granular media, by analytical evaluation, within Bethe-Peierls approximation, of Edwards' partition function. The presence of fluid-crystal phase transitions in the system drives segregation as a form of phase separation. Within a pure phase, gravity can also induce a kind of vertical segregation not associated to phase transitions.
The segregation of large spheres in a granular bed under vertical vibrations is studied. In our experiments we systematically measure rise times as a function of density, diameter and depth; for two different sinusoidal excitations. The measurements reveal that: at low frequencies, inertia and convection are the only mechanisms behind segregation. Inertia (convection) dominates when the relative density is greater (less) than one. At high frequencies, where convection is suppressed, fluidization of the granular bed causes either buoyancy or sinkage and segregation occurs.
In the framework of schematic hard spheres lattice models we discuss Edwards' Statistical Mechanics approach to granular media. As this approach appears to hold here to a very good approximation, by analytical calculations of Edwards' partition function at a mean field level we derive the system phase diagram and show that ``jamming'' corresponds to a phase transition from a ``fluid'' to a ``glassy'' phase, observed when crystallization is avoided. The nature of such a ``glassy'' phase turns out to be the same found in mean field models for glass formers. In the same context, we also briefly d…
Motivated by a novel method for granular segregation, we analyze the one dimensional drift-diffusion between two absorbing boundaries. The time evolution of the probability distribution and the rate of absorption are given by explicit formulae, the splitting probability and the mean first passage time are also calculated. Applying the results we find optimal parameters for segregating binary granular mixtures.
Segregation by thermal diffusion of an intruder immersed in a sheared granular gas is analyzed from the (inelastic) Boltzmann equation. Segregation is induced by the presence of a temperature gradient orthogonal to the shear flow plane and parallel to gravity. We show that, like in analogous systems without shear, the segregation criterion yields a transition between upwards segregation and downwards segregation. The form of the phase diagrams is illustrated in detail showing that they depend sensitively on the value of gravity relative to the thermal gradient. Two specific situations are cons…
Processes of mixing and segregation in a packed bed of granular material stirred by a periodically moving rectangular bar are simulated by the discrete element method (DEM). Influence of mechanical properties of the particle material (dynamic friction coefficient, density, elastic modulus) on the segregation intensity is researched. Dynamic friction coefficient was found to have the most noticeable influence to the segregation intensity.
Size segregation of granular mixtures which are almost completely packed in a rotating drum is discussed with an effective simulation and a brief analysis. Instead of a 3D drum, we simulate 2D rotating thin box which is almost completely packed with granular mixtures. The phase inversion of radially segregated pattern which was found in a 3D experiment are qualitatively reproduced with this simulation, and a brief analysis is followed. Moreover in our simulation, a global convection appears after radial segregation pattern is formed, and this convection induces axially segregated pattern.
The intruder segregation dependence on size and density is investigated in the framework of a hydrodynamic theoretical model for vibrated granular media. We propose a segregation mechanism based on the difference of densities between different regions of the granular system, which give origin to a buoyant force that acts on the intruder. From the analytic solution of the segregation velocity we can analyze the transition from the upward to downward intruder's movement.
We report on a segregation scheme for granular binary mixtures, where the segregation is performed by a ratchet mechanism realized by a vertically shaken asymmetric sawtooth-shaped base in a quasi-two-dimensional box. We have studied this system by computer simulations and found that most binary mixtures can be segregated using an appropriately chosen ratchet, even when the particles in the two components have the same size, and differ only in their normal restitution coefficient or friction coefficient. These results suggest that the components of otherwise non-segregating granular mixtures m…
We study segregation of granular mixtures in the continuous avalanche regime (for frequencies above ~ 1 rpm) in thin rotating drums using a continuum theory for surface flows of grains. The theory predicts profiles in agreement with experiments only when we consider a flux dependent velocity of flowing grains. We find the segregation of species of different size and surface properties, with the smallest and roughest grains being found preferentially at the center of the drum. For a wide difference between the species we find a complete segregation in agreement with experiments. In addition, we…
A low density binary mixture of granular gases is considered within the Boltzmann kinetic theory. One component, the intruders, is taken to be dilute with respect to the other, and thermal segregation of the two species is described for a special exact solution to the Boltzmann equation. This solution has a macroscopic hydrodynamic representation with a constant temperature gradient and is referred to as the Fourier state. The thermal diffusion factor characterizing conditions for segregation is calculated without the usual restriction to Navier-Stokes hydrodynamics. Molecular dynamics simulat…
Recently several authors studied the segregation of particles for a system composed of mono-dispersed inelastic spheres contained in a box divided by a wall in the middle. The system exhibited a symmetry breaking leading to an overpopulation of particles in one side of the box. Here we study the segregation of a mixture of particles composed of inelastic hard spheres and fluidized by a vibrating wall. Our numerical simulations show a rich phenomenology: horizontal segregation and periodic behavior. We also propose an empirical system of ODEs representing the proportion of each type of particle…
We investigate the segregation of a dense binary mixture of granular particles that only differ in their restitution coefficient. The mixture is vertically vibrated in the presence of gravity. We find a partial segregation of the species, where most dissipative particles submerge in the less dissipative ones. The segregation occurs even if one type of the particles is elastic. In order to have a complete description of the system, we study the structure of the fluid at microscopic scale (few particle diameters). The density and temperature pair distribution functions show strong enhancements r…
We present results from an extensive experimental investigation into granular segregation of a shallow binary mixture in which particles are driven by frictional interactions with the surface of a vibrating horizontal tray. Three distinct phases of the mixture are established viz; binary gas (unsegregated), segregation liquid and segregation crystal. Their ranges of existence are mapped out as a function of the system's primary control parameters using a number of measures based on Voronoi tessellation. We study the associated transitions and show that segregation can be suppressed is the tota…
We investigate the role of friction in compaction and segregation of granular materials by combining Edwards' thermodynamic hypothesis with a simple mechanical model and mean-field based geometrical calculations. Systems of single species with large friction coefficients are found to compact less. Binary mixtures of grains differing in frictional properties are found to segregate at high compactivities, in contrary to granular mixtures differing in size, which segregate at low compactivities. A phase diagram for segregation vs. friction coefficients of the two species is generated. Finally, th…
We report the results of an experimental investigation of segregation in a binary mixture of dry particles subjected to horizontal oscillatory excitation. The thin layer of particles was driven by the stick--slip frictional interaction with the surface of a horizontal tray. As the packing fraction of the mixture was increased the evolution of distinct phases was observed. We identified them as a binary gas, segregation liquid and segregation crystal and provide both microscopic and macroscopic measures to identify their properties. Finally, we draw some analogies between segregation in our gra…
We present a hydrodynamic theoretical model for "Brazil nut" size segregation in granular materials. We give analytical solutions for the rise velocity of a large intruder particle immersed in a medium of monodisperse fluidized small particles. We propose a new mechanism for this particle size-segregation due to buoyant forces caused by density variations which come from differences in the local "granular temperature". The mobility of the particles is modified by the energy dissipation due to inelastic collisions and this leads to a different behavior from what one would expect for an elastic …
The difference of temperatures between an impurity and the surrounding gas in an open vibrated granular system is studied. It is shown that, in spite of the high inhomogeneity of the state, the temperature ratio remains constant in the bulk of the system. The lack of energy equipartition is associated to the change of sign of the pressure diffusion coefficient for the impurity at certain values of the parameters of the system, leading to a segregation criterium. The theoretical predictions are consistent with previous experimental results, and also in agreement with molecular dynamics simulati…
We study segregation and stratification of mixtures of grains differing in size, shape and material properties poured in two-dimensional silos using a microscopic lattice model for surface flows of grains. The model incorporates the dissipation of energy in collisions between rolling and static grains and an energy barrier describing the geometrical asperities of the grains. We study the phase diagram of the different morphologies predicted by the model as a function of the two parameters. We find regions of segregation and stratification, in agreement with experimental finding, as well as a r…
A recent solution of the inelastic Boltzmann equation that applies for strong dissipation and takes into account non-equipartition of energy is used to derive an explicit expression for the thermal diffusion factor. This parameter provides a criterion for segregation that involves all the parameters of the granular binary mixture (composition, masses, sizes, and coefficients of restitution). The present work is consistent with recent experimental results and extends previous results obtained in the intruder limit case.
We present the results of an experimental study of patterned segregation in a horizontally shaken shallow layer of a binary mixture of dry particles. As the compacity, $C$, of the mixture was increased, the evolution of three distinct phases was observed. We classify them as binary gas, segregation liquid and segregation crystal phases using macroscopic and microscopic measures. The binary gas to segregation liquid transition is consistent with a continuous phase transition and includes the characteristic feature of critical slowing down. At high compacities we observed an intriguing slow osci…
A simple phenomenological model of a binary granular mixture is developed and investigated numerically. We attempt to model the experimental system of [1,2] where a horizontally vibrated binary monolayer was found to exhibit a transition from a mixed to a segregated state as the filling fraction of the mixture was increased. This model is found to reproduce much of the experimentally observed behaviour, most importantly the transition from the mixed to the segregated state. We use the model to investigate granular segregation mechanisms and explain the experimentally observed behaviour.
In order to study analytically the nature of the size segregation in granular mixtures, we introduce a mean field theory in the framework of a statistical mechanics approach, based on Edwards' original ideas. For simplicity we apply the theory to a lattice model for hard sphere binary mixture under gravity, and we find a new purely thermodynamic mechanism which gives rise to the size segregation phenomenon. By varying the number of small grains and the mass ratio, we find a crossover from Brasil nut to reverse Brasil nut effect, which becomes a true phase transition when the number of small gr…
We present extensive Molecular Dynamics simulations on species segregation in a granular mixture subject to vertical taps. We discuss how grain properties, e.g., size, density, friction, as well as, shaking properties, e.g., amplitude and frequency, affect such a phenomenon. Both Brazil Nut Effect (larger particles on the top, BN) and the Reverse Brazil Nut Effect (larger particles on the bottom, RBN) are found and we derive the system comprehensive ``segregation diagram'' and the BN to RBN crossover line. We also discuss the role of friction and show that particles which differ only for their…
Segregation induced by a thermal gradient of an impurity in a driven low-density granular gas is studied. The system is enclosed between two parallel walls from which we input thermal energy to the gas. We study here steady states occurring when the inelastic cooling is exactly balanced by some external energy input (stochastic force or viscous heating), resulting in a uniform heat flux. A segregation criterion based on Navier-Stokes granular hydrodynamics is written in terms of the tracer diffusion transport coefficients, whose dependence on the parameters of the system (masses, sizes and coe…
Granular mixtures frequently segregate by grain size along the axis of partially-filled, horizontal, rotating tubes. When segregation approaches saturation at the surface, a well-defined pattern of bands with wavelength $λ$ emerges. The long-term dynamics of the pattern involves a much slower coarsening process. We characterized the initial saturated wavelength $λ$ as a function of the diameter of the tube $D$ for a filling fraction of 30 %, for $1.9 {\rm cm} \leq D \leq 11.5 {\rm cm}$. We also studied the initial growth-rate of the bands as $D$ varies. We find that $λ/D$ is not constant, but …
Granular media are examined with the focus on polydisperse mixtures in the presence of two localized heat-baths. If the two driving energies are similar, the large particles prefer to stay in the `cold' regions of the system -- as far away from the energy source as possible. If one of the temperatures is larger than the other, the cold region is shifted towards the colder reservoir; if the temperature of one source is much higher, a strong, almost constant temperature gradient builds up between the two reservoirs and the large particles are found close to the cold reservoir. Furthermore, clust…
We study segregation of an impurity in a driven granular fluid under two types of \emph{steady} states. In the first state, the granular gas is driven by a stochastic volume force field with a Fourier-type profile while in the second state, the granular gas is sheared in such a way that inelastic cooling is balanced by viscous heating. We compare theoretical results derived from a solution of the (inelastic) Boltzmann equation at Navier-Stokes (NS) order with those obtained from the Direct Monte Carlo simulation (DSMC) method and molecular dynamics (MD) simulations. Good agreement is found bet…
We present the generalization of the minimal model for surface flows of granular mixtures, proposed by Boutreux and de Gennes [J. Phys. I France 6, 1295 (1996)]. The minimal model was valid for grains differing only in their surface properties. The present model also takes into account differences in the size of the grains. We apply the model to study segregation in two-dimensional silos of mixtures of grains differing in size and/or surface properties. When the difference in size is small, the model predicts that a continuous segregation appears in the static phase during the filling of a sil…
Diffusion induced by a thermal gradient in a granular binary mixture is analyzed in the context of the (inelastic) Enskog equation. Although the Enskog equation neglects velocity correlations among particles which are about to collide, it retains spatial correlations arising from volume exclusion effects and thus it is expected to apply to moderate densities. In the steady state with gradients only along a given direction, a segregation criterion is obtained from the thermal diffusion factor $Λ$ measuring the amount of segregation parallel to the thermal gradient. As expected, the sign of the …
Spontaneous stratification of granular mixtures has been reported by Makse et al. [Nature 386, 379 (1997)] when a mixture of grains differing in size and shape is poured in a quasi-two-dimensional heap. We study this phenomenon using two different approaches. First, we introduce a cellular automaton model that illustrates clearly the physical mechanism; the model displays stratification whenever the large grains are rougher than the small grains, in agreement with the experiments. Moreover, the dynamics are close to those of the experiments, where the layers are built through a ``kink'' at whi…
We present an experimental study of segregation of granular matter in a quasi-two dimensional silo emptying out of an orifice. Size separation is observed when multi-sized particles are used with the larger particles found in the center of the silo in the region of fastest flow. We use imaging to study the flow inside the silo and quantitatively measure the concentration profiles of bi-disperse beads as a function of position and time. The angle of the surface is given by the angle of repose of the particles, and the flow occurs in a few layers only near the top of this inclined surface. The f…
The mass flux of a low-density granular binary mixture obtained previously by solving the Boltzmann equation by means of the Chapman-Enskog method is considered further. As in the elastic case, the associated transport coefficients $D$, $D_p$ and $D'$ are given in terms of the solutions of a set of coupled linear integral equations which are approximately solved by considering the first and second Sonine approximations. The diffusion coefficients are explicitly obtained as functions of the coefficients of restitution and the parameters of the mixture (masses, diameters and concentration) and t…
A solution of the inelastic Enskog equation that goes beyond the weak dissipation limit and applies for moderate densities is used to determine the thermal diffusion factor of an intruder immersed in a dense granular gas under gravity. This factor provides a segregation criterion that shows the transition between the Brazil-nut effect (BNE) and the reverse Brazil-nut effect (RBNE) by varying the parameters of the system (masses, sizes, density and coefficients of restitution). The form of the phase-diagrams for the BNE/RBNE transition depends sensitively on the value of gravity relative to the…
When a mixture of two kinds of grains differing in size and shape is poured in a vertical two-dimensional cell, the mixture spontaneously stratifies in alternating layers of small and large grains, whenever the large grains are more faceted than the small grains. Otherwise, the mixture spontaneously segregates in different regions of the cell when the large grains are more rounded than the small grains. We address the question of the origin of the instability mechanism leading to stratification using a recently proposed set of equations for surface flow of granular mixtures. We show that the s…
In a half-filled rotating drum, the size segregation of particles of equal density builds a ring pattern of the large particles, whose location continuously varies from the periphery to the center depending on the size ratio between particles [Thomas, Phys. Rev. E 62, 1 (2000) 961-974]. For small size ratios (typically15): large beads are close to the bottom in a reversing position. The existence of circles with an intermediate radius shows that the segregation at an intermediate level within a flow is possible. In this paper, we experimentally study the segregation of particles of different d…
A recent segregation criterion [V. Garzó, Phys. Rev. E \textbf{78}, 020301(R) (2008)] based on the thermal diffusion factor $Λ$ of an intruder in a heated granular gas described by the inelastic Enskog equation is revisited. The sign of $Λ$ provides a criterion for the transition between the Brazil-nut effect (BNE) and the reverse Brazil-nut effect (RBNE). The present theory incorporates two extra ingredients not accounted for by the previous theoretical attempt. First, the theory is based upon the second Sonine approximation to the transport coefficients of the mass flux of intruder. Second, …
We have studied the effect of small amounts of added liquid on the dynamic behavior of a granular system consisting of a mixture of glass beads of two different sizes. Segregation of the large beads to the top of the sample is found to depend in a nontrivial way on the liquid content. A transition to viscoplastic behavior occurs at a critical liquid content, which depends upon the bead size. We show that this transition can be interpreted as a condensation due to the hysteretic liquid bridge forces connecting the beads, and provide the corresponding phase diagram.
Applications of the kinetic theory for a model of a confined quasi-two dimensional granular mixture: Stability analysis and thermal diffusion segregation
We study the segregation of granular mixtures in two-dimensional silos using a set of coupled equations for surface flows of grains. We study the thick flow regime, where the grains are segregated in the rolling phase. We incorporate this dynamical segregation process, called kinematic sieving, free-surface segregation or percolation, into the theoretical formalism and calculate the profiles of the rolling species and the concentration of grains in the bulk in the steady state. Our solution shows the segregation of the mixture with the large grains being found at the bottom of the pile in qual…
An experimental study of a binary granular mixture submitted to a transient shear flow in a cylindrical container is reported. The formation of ripples with a spiral shape is observed. The appearance of phase segregation in those spiral patterns is shown. The relative grain size bewteen sand species is found to be a relevant parameter leading to phase segregation. However, the relative repose angle is an irrelevant parameter. The formation of sedimentary structures is also presented. They result from a ripple climbing process. The ``sub-critical'' or ``super-critical'' character of the laminat…
The size segregation of granular materials in a vibrating container is investigated using Molecular Dynamics. We find that the rising of larger particles is accompanied by the existence of convection cells even in the case of the lowest possible frequencies. The convection can, however, also be triggered by the larger particle itself. The possibility of rising through this mechanism strongly depends on the depth of the larger particle.
Dynamical instabilities in fluid mechanics are responsible of a variety of important common phenomena, such as waves on the sea surface or Taylor vorteces in Couette flow. In granular media dynamical instabilities has just begun to be discovered. Here we show by means of molecular dynamics simulation the existence of a new dynamical instability of a granular mixture under oscillating horizontal shear, which leads to the formation of a striped pattern where the components are segregated. We investigate the properties of such a Kelvin-Helmholtz like instability and show how it is connected to pa…
We give a statistical-mechanical theory of stress transmission in disordered arrays of rigid grains with perfect friction. Starting from the equations of microscopic force and torque balance we derive the fundamental equations of stress equilibrium. We illustrate the validity of our approach by solving the stress distribution of a homogeneous and isotropic array.
In a mixture of two species of grains of equal size but different mass, placed in a vertically vibrated shallow box, there is spontaneous segregation. Once the system is at least partly segregated and clusters of the heavy particles have formed, there are sudden peaks of the horizontal kinetic energy of the heavy particles, that is otherwise small. Together with the energy peaks the clusters rapidly expand and the segregation is partially lost. The process repeats once segregation has taken place again. Depending on the experimental or numerical parameters, the energy bursts can occur either r…
Based on the Boltzmann-Enskog kinetic theory, we develop a hydrodynamic theory for the well known (reverse) Brazil nut segregation in a vibro-fluidized granular mixture. Using an analogy with standard fluid mechanics, we have recently suggested a novel mechanism of segregation in granular mixtures based on a {\it competition between buoyancy and geometric forces}: the Archimedean buoyancy force, a pseudo-thermal buoyancy force due to the difference between the energies of two granular species, and two geometric forces, one compressive and the other-one tensile in nature, due to the size-differ…
We show that the main dynamical features of granular media can be understood by means of simple models of fragile-glass forming liquid provided that gravity alone is taken into account. In such lattice-gas models of cohesionless and frictionless particles, the compaction and segregation phenomena appear as purely non-equilibrium effects unrelated to the Boltzmann-Gibbs measure which in this case is trivial. They provide a natural framework in which slow relaxation phenomena in granular and glassy systems can be explained in terms of a common microscopic mechanism given by a free-volume kinetic…
A new segregation criterion based on the inelastic Enskog kinetic equation is derived to show the transition between the Brazil-nut effect (BNE) and the reverse Brazil-nut effect (RBNE) by varying the different parameters of the system. In contrast to previous theoretical attempts the approach is not limited to the near-elastic case, takes into account the influence of both thermal gradients and gravity and applies for moderate densities. The form of the phase-diagrams for the BNE/RBNE transition depends sensitively on the value of gravity relative to the thermal gradient, so that it is possib…
We present several numerical results on granular mixtures. In particular, we examine the efficiency of diffusion as a mixing mechanism in these systems. The collisions are inelastic and to compensate the energy loss, we thermalize the grains by adding a random force. Starting with a segregated system, we show that uniform agitation (heating) leads to a uniform mixture of grains of different sizes. We define a characteristic mixing time, $τ_{mix}$, and study theoretically and numerically its dependence on other parameters like the density. We examine a model for bidisperse systems for which we …
A model for the dynamical evolution of a granular binary mixture is analyzed. This system is submitted to a tapping procedure, similarly to what is done in real experiments. In the weak vibration limit, an effective dynamics for the tapping process is derived, and the steady state probability distribution is analytically found. The steady probability does not depend on the details of the configuration, but only on the number of particles of each of the two species. Depending on the values of their fugacities, the system can be either almost full of small or big particles, i.e., segregation eff…
We show that a mixture of two species of granular particles with equal sizes but differing densities can be either segregated or mixed by adjusting the granular temperature gradient and the magnitude of the gravitational force. In the absence of gravity, the dense, heavy particles move to the colder regions. If the temperature gradient is put into a gravitational field with the colder regions above the hotter, a uniform mixture of light and heavy particles can be attained. This situation can be realized in a container of finite height with a vibrating bottom, placed in a gravitational field. W…
We report a series of molecular dynamics simulations and investigate the possibility to separate a granular mixture of inelastic hard spheres by vigorously shaking it in a box made of two connected compartments. As its one-component counterpart, the system exhibits a ``left-right'' symmetry breaking entirely due to the inelasticity of grain-grain collisions, and triggered by increasing the number of particles. In the compartment where the density of grains is larger, we observe a partial segregation with a predominance of heavy particles. However, this compartment still has a higher density of…
By detailed Molecular Dynamics and Monte Carlo simulations %of a realistic model we show that granular materials at rest can be described as thermodynamics systems. First we show that granular packs can be characterized by few parameters, as much as fluids or solids. Then, in a second independent step, we demonstrate that these states can be described in terms of equilibrium distributions which coincide with the Statistical Mechanics of powders first proposed by Edwards. We also derive the system equation of state as a function of the ``configurational temperature'', its new intensive thermody…
We report two phenomena, induced by dynamical correlations, that occur during the free cooling of a two-dimensional mixture of inelastic hard disks. First, we show that, due to the onset of velocity correlations, the ratio of the kinetic energies associated with the two species changes from the value corresponding to the homogeneous cooling state to a value approximately given by the mass ratio m_1/m_2 of the two species. Second, we report a novel segregation effect that occurs in the late stage of cooling, where interconnected domains appear. Spectral analysis of the composition field reveals…
Motivated by recent experiments we have carried out an Event Driven computer simulation of a diluted binary mixture of granular particles vertically vibrated in the presence of gravity. The simulations not only confirm that the kinetic energies of the two species are not equally distributed, as predicted by various theoretical models, but also seem to reproduce rather well the density and temperature profiles measured experimentally. Rotational degrees of freedom do not seem to play any important qualitative role. Instead, simulation shows the onset of a clustering instability along the horizo…
