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arXiv 2603.18552cond-mat.mtrl-sci
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非阿伦尼乌斯行为的晶粒生长起源

On the origin of non-Arrhenius behavior of grain growth

School of Materials Science and Engineering, Shanghai University(上海大学材料科学与工程学院)

Xinlei Pan, Jingyu Li, Jianfeng Hu

AI总结:

通过实验和理论结合方法,研究了SrTiO3中非阿伦尼乌斯晶粒生长行为,发现其为热激活过程,受温度依赖因素和晶粒尺寸等参数的相互作用控制。

摘要:

非阿伦尼乌斯晶粒生长在多种多晶材料中已被观察到;然而,其基本机制,特别是该过程是否为热激活或表现出反热激活,仍存在争议。在本研究中,SrTiO3被用作模型系统,通过结合实验和理论方法,利用新发展的晶粒生长模型系统研究非阿伦尼乌斯晶粒生长行为。结果表明,非阿伦尼乌斯晶粒生长是一种热激活过程,没有确定的特征温度,主要由温度依赖因素和温度无关参数(如晶粒尺寸及其分布)的相互作用控制。此外,在异常晶粒生长(AGG)过程中,晶粒生长的非阿伦尼乌斯行为主要在较低温度下发生,并随着温度升高逐渐过渡到阿伦尼乌斯型行为。

英文摘要:

Non-Arrhenius grain growth has been observed in a range of polycrystalline materials; however, its fundamental mechanisms, particularly whether the process is thermally activated or exhibits anti-thermally activation, remain controversial. In this study, SrTiO3 was employed as a model system to systematically investigate non-Arrhenius grain growth behavior through combined experimental and theoretical approaches, utilizing a newly developed grain growth model. The results reveal that non-Arrhenius grain growth is a thermally activated process without a definitive characteristic temperature, which is primarily controlled by the interplay between temperature-dependent factors and the temperature-independent parameters such as grain size and its distribution. Moreover, during abnormal grain growth (AGG), the non-Arrhenius behavior of grain growth primarily occurs at lower temperatures and gradually transitions to Arrhenius-type behavior as the temperature increases.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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