Non-Arrhenius grain growth has been observed in a range of polycrystalline materials; however, its fundamental mechanisms, particularly whether the process is thermally activated or exhibits anti-thermally activation, remain controversial. In this study, SrTiO3 was employed as a model system to systematically investigate non-Arrhenius grain growth behavior through combined experimental and theoretical approaches, utilizing a newly developed grain growth model. The results reveal that non-Arrhenius grain growth is a thermally activated process without a definitive characteristic temperature, which is primarily controlled by the interplay between temperature-dependent factors and the temperature-independent parameters such as grain size and its distribution. Moreover, during abnormal grain growth (AGG), the non-Arrhenius behavior of grain growth primarily occurs at lower temperatures and gradually transitions to Arrhenius-type behavior as the temperature increases.
Modeling the Slow Arrhenius Process (SAP) in Polymers
Michigan State University(密歇根州立大学);Technion(以色列理工学院);Universite libre de Bruxelles (ULB)(布鲁塞尔自由大学);Naval Research Laboratory(海军研究实验室);University of Milan(米兰大学)
Graph neural network prediction of temperature-dependent hydrogen diffusion and thermal conductivity tensors of tungsten containing helium bubbles and grain boundaries
Graduate School of Science and Engineering, Yamagata University(山形大学理工学研究科);National Institute for Fusion Science(国立研究開発法人核融合科学研究所)
Grain Growth Kinetics in (Cr,Mo,Ta,V,W)C1-δ High-Entropy Carbide Ceramics
Missouri University of Science and Technology(密苏里科技大学);Pennsylvania State University(宾夕法尼亚州立大学);Duke University(杜克大学);University of California, Irvine(加州大学尔湾分校)
Origin of Large Dielectric Constant with Large Remnant Polarization and Evidence of Magnetoelectric Coupling in Multiferroic La modified BiFeO3-PbTiO3 Solid Solution
Grain boundary ferromagnetism in vanadium-doped In$_2$O$_3$ thin films
室温铁磁性在In $_2$ O $_3 thin films doped with 5 at.% vanadium, prepared by pulsed laser deposition at substrate temperatures ranging from 300 to 600 $ \,^{ \circ }{ \rm C} $. X-ray absorption fine structure measurement indicated that vanadium was substitutionally dissolved in the In$ _2 $O$ _3$主晶格中观察到,从而排除了钒化合物第二相的存在。基于SQUID磁强计和磁性圆二色性的磁性测量证实了磁性在晶界处,也在晶粒中。整体磁化源于晶粒和晶界之间的竞争效应。
Temperature dependent conductivity, dielectric relaxation, electrical modulus and impedance spectroscopy of Ni substituted Na$_{3+2x}$Zr$_{2-x}$Ni$_{x}$Si$_2$PO$_{\rm 12}$