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arXiv 2409.09686cond-mat.str-elcond-mat.mtrl-sci
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具有强梯级相互作用的双腿自旋梯化合物Ba2RE2Ge4O13(RE = Pr, Nd, Gd-Ho)的结构与磁性

Structure and magnetic properties of a family of two-leg spin ladder compounds Ba2RE2Ge4O13 (RE = Pr, Nd, and Gd-Ho) with strong rung interaction

Jin Zhou, Andi Liu, Fangyuan Song, Langsheng Ling, Jingxin Li, Wei Tong, Zhengcai Xia, Gaoshang Gong, Yongqiang Wang, Jinkui Zhao, Hanjie Guo, Zhaoming Tian

AI总结:

报道了一族稀土基双腿自旋梯化合物Ba2RE2Ge4O13,具有强梯级相互作用和反铁磁行为,其中Ba2Dy2Ge4O13表现出自旋二聚化与长程磁有序共存,为4f电子自旋梯物理提供了新平台。

摘要:

与对基于3d过渡金属(TM)的自旋梯化合物的深入研究相比,由稀土(RE)离子构建的自旋梯化合物受到的关注较少。在此,我们报道了一族稀土基自旋梯化合物Ba2RE2Ge4O13(RE = Pr, Nd, Gd-Ho),其结晶为单斜结构,空间群为C2/c。RE离子沿b轴排列成双腿自旋梯 motif,其中梯级和腿的交换相互作用分别通过RE-O-RE路径和RE-O-Ge-O-RE路径桥接。此外,RE2O12二聚体单元中的梯级距离远短于腿距离,表明Ba2RE2Ge4O13是一个强梯级自旋梯系统。所有合成的Ba2RE2Ge4O13(RE = Pr, Nd, Gd-Ho)化合物均表现出主导的反铁磁(AFM)相互作用,并且在1.8 K以下没有磁有序。在该族成员中,Ba2Dy2Ge4O13可以用Jeff = 1/2 Kramers双重态来描述,低温比热表明自旋二聚化态(在约2.4 K处有宽峰)与长程反铁磁有序(TN = 0.81 K)共存。因此,这一族Ba2RE2Ge4O13化合物为研究由4f电子构建的新型自旋梯物理提供了一个稀有平台。

英文摘要:

Compared to the intensive investigation on the 3d transition-metal (TM)-based spin ladder compounds, less attention has been paid to the ones constructed by the rare-earth (RE) ions. Herein, we report a family of RE-based spin ladder compounds Ba2RE2Ge4O13 (RE = Pr, Nd, Gd-Ho) crystallized into the monoclinic structure with the space group C2/c. The RE ions are arranged on a two-leg spin ladder motif along the b-axis, where the rung and leg exchange interactions are bridged via the RE-O-RE pathways and RE-O-Ge-O-RE routes, respectively. Moreover, the much shorter rung distance in the RE2O12 dimer units than the leg distance suggests Ba2RE2Ge4O13 to be a strong-rung spin ladder system. All the synthesized Ba2RE2Ge4O13 (RE = Pr, Nd, Gd-Ho) compounds exhibit the dominant antiferromagnetic (AFM) interactions and absence of magnetic order down to 1.8 K. Among the family members, Ba2Dy2Ge4O13 can be described by Jeff = 1/2 Kramers doublet states, the low temperature specific heat indicates the coexistence of spin dimerized state with broad maximum at ~ 2.4 K and long-range AFM order with TN = 0.81 K. This family of Ba2RE2Ge4O13 compounds thereby provides a rare platform to investigate the novel spin ladder physics constructed by 4f electrons.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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