$^{115}$In$^+$-$^{172}$Yb$^+$ Coulomb crystal clock with $2.5\times10^{-18}$ systematic uncertainty
H. N. Hausser, J. Keller, T. Nordmann, N. M. Bhatt, J. Kiethe, H. Liu, I. M. Richter, M. von Boehn, J. Rahm, S. Weyers, E. Benkler, B. Lipphardt, S. Doerscher, … 展开作者
H. N. Hausser, J. Keller, T. Nordmann, N. M. Bhatt, J. Kiethe, H. Liu, I. M. Richter, M. von Boehn, J. Rahm, S. Weyers, E. Benkler, B. Lipphardt, S. Doerscher, K. Stahl, J. Klose, C. Lisdat, M. Filzinger, N. Huntemann, E. Peik, T. E. Mehlstäubler
We present a scalable mixed-species Coulomb crystal clock based on the $^1S_0$ $\leftrightarrow$ $^3P_0$ transition in $^{115}$In$^+$. $^{172}$Yb$^+$ ions are co-trapped and used for sympathetic cooling. Reproducible interrogation conditions for mixed-species Coulomb crystals are ensured by a conditional preparation sequence with permutation control. We demonstrate clock operation with a 1In$^+$-3Yb$^+$ crystal, achieving a relative systematic uncertainty of $2.5\times10^{-18}$ and a relative frequency instability of $1.6\times10^{-15}/\sqrt{τ/1\;\mathrm{s}}$. We report on absolute frequency measurements with an uncertainty of $1.3\times10^{-16}$ and optical frequency comparisons with clocks based on $^{171}$Yb$^+$ (E3) and $^{87}$Sr. With a fractional uncertainty of $4.4\times10^{-18}$, the former is - to our knowledge - the most accurate frequency ratio value reported to date. For the $^{115}$In$^+$/$^{87}$Sr ratio, we improve upon the best previous measurement by more than an order of magnitude. We also demonstrate operation with four $^{115}$In$^+$ clock ions, which reduces the instability to $9.2\times10^{-16}/\sqrt{τ/1\;\mathrm{s}}$.
Trapped ions are ideally suited for precision spectroscopy, as is evident from the remarkably low systematic uncertainties of single-ion clocks. The major weakness of these clocks is the long averaging time, necessitated by the low signal of a single atom. An increased number of ions can overcome this limitation and allow for the implementation of novel clock schemes. However, this presents the challenge to maintain the excellent control over systematic shifts of a single particle in spatially extended and strongly coupled many-body systems. We measure and deduce systematic frequency uncertain…
Trapped-ion optical clocks are capable of achieving systematic fractional frequency uncertainties of $10^{-18}$ and possibly below. However, the stability of current ion clocks is fundamentally limited by the weak signal of single-ion interrogation. We present an operational, scalable platform for extending clock spectroscopy to arrays of Coulomb crystals consisting of several tens of ions, while allowing systematic shifts as low as $10^{-19}$. Using a newly developed technique, we observe 3D excess micromotion amplitudes inside a Coulomb crystal with atomic spatial resolution and sub-nanomete…
Light-induced control of ions within small Coulomb crystals is investigated. By intense intracavity optical standing wave fields, subwavelength localization of individual ions is achieved for one-, two-, and three-dimensional crystals. Based on these findings, we illustrate numerically how the application of such optical potentials can be used to tailor the normal mode spectra and patterns of multi-dimensional Coulomb crystals. The results represent, among others, important steps towards controlling the crystalline structure of Coulomb crystals, investigating heat transfer processes at the qua…
We present a novel method for engineering an optical clock transition that is robust against external field fluctuations and is able to overcome limits resulting from field inhomogeneities. The technique is based on the application of continuous driving fields to form a pair of dressed states essentially free of all relevant shifts. Specifically, the clock transition is robust to magnetic shifts, quadrupole and other tensor shifts, and amplitude fluctuations of the driving fields. The scheme is applicable to either a single ion or an ensemble of ions, and is relevant for several types of ions,…
We demonstrate light-induced localization of Coulomb-interacting particles in multi-dimensional structures. Subwavelength localization of ions within small multi-dimensional Coulomb crystals by an intracavity optical standing wave field is evidenced by measuring the difference in scattering inside symmetrically red- and blue-detuned optical lattices and is observed even for ions undergoing substantial radial micromotion. These results are promising steps towards the structural control of ion Coulomb crystals by optical fields as well as for complex many-body simulations with ion crystals or fo…
Proposal for a multi-ion optical clock with hundreds of ions
P.N. Lebedev Physical Institute of the Russian Academy of Sciences（俄罗斯科学院列别杰夫物理研究所）；Key Laboratory of Quantum State Construction and Manipulation (Ministry of Education), School of Physics, Renmin University of China（中国人民大学物理学院量子态构建与操控教育部重点实验室）；Russian Quantum Center, Skolkovo（斯科尔科沃俄罗斯量子中心）；Beijing Academy of Quantum Information Sciences（北京量子信息科学研究院）
We study nanofriction in an ion Coulomb crystal under the presence of topological defects. We observe signatures of the pinning to sliding transition, namely the transverse vibrational soft mode signaling the transition and the symmetry breaking of the crystal configuration. We present details on experimental measurements and numerical simulations of this system, including the gaps in the hull function and the spectroscopy of the localized defect mode. We also investigate how external forces, such as those due to anharmonic potentials or differential light pressure, break the intrinsic crystal…
We present experiments on polarization gradient cooling of Ca$^+$ multi-ion Coulomb crystals in a linear Paul trap. Polarization gradient cooling of the collective modes of motion whose eigenvectors have overlap with the symmetry axis of the trap is achieved by two counter-propagating laser beams with mutually orthogonal linear polarizations that are blue-detuned from the S$_{1/2}$ to P$_{1/2}$ transition. We demonstrate cooling of linear chains of up to 51 ions and 2D-crystals in zig-zag configuration with 22 ions. The cooling results are compared with numerical simulations and the prediction…
We experimentally investigate the transient dynamics of an optical cavity field interacting with large ion Coulomb crystals in a situation of electromagnetically induced transparency (EIT). EIT is achieved by injecting a probe field at the single photon level and a more intense control field with opposite circular polarization into the same mode of an optical cavity to couple Zeeman substates of a metastable level in 40Ca+ ions. The EIT interaction dynamics are investigated both in the frequency-domain - by measuring the probe field steady state reflectivity spectrum - and in the time-domain -…
This paper reports the direct temperature determination of sympathetically cooled 113Cd+ ions with laser-cooled 24Mg+ in a linear Paul trap. The sympathetically cooled ion species distribute in the outer shell of the large ensembles, which contain up to 3.3E5 ions. With optimized parameters, the minimum temperature of the sympathetically cooled 113Cd+ ions was measured to be tens of mK. These results indicate promising performance for microwave atomic clocks. The second order Doppler frequency shift is two orders of magnitudes lower and the Dick effect is suppressed.
For conventional ion traps, the trapping potential is close to independent of the electronic state, providing confinement for ions dependent primarily on their charge-to-mass ratio $Q/m$. In contrast, storing ions within an optical dipole trap results in state-dependent confinement. Here we experimentally study optical dipole potentials for $^{138}\mathrm{Ba}^+$ ions stored within two distinctive traps operating at 532 nm and 1064 nm. We prepare the ions in either the $6\mathrm{S}_{\mathrm{1/2}}$ electronic ground or the $5\mathrm{D}_{\mathrm{3/2}}$/ $5\mathrm{D}_{\mathrm{5/2}}$ metastable exc…
In order to improve the short-term stability of trapped-ion optical clocks, we are developing a frequency standard based on ${}^{115}$In${}^+$ / ${}^{172}$Yb${}^+$ Coulomb crystals. For this purpose, we have developed scalable segmented Paul traps which allow a high level of control for multiple ion ensembles. In this article, we detail on our recent results regarding the reduction of the leading sources of frequency uncertainty introduced by the ion trap: 2nd-order Doppler shifts due to micromotion and the heating of secular motion, as well as the black-body radiation shift due to warming of …
We demonstrate the preparation and coherent control of the angular momentum state of a two-ion crystal. The ions are prepared with an average angular momentum of $7780\hbar$ freely rotating at 100~kHz in a circularly symmetric potential, allowing us to address rotational sidebands. By coherently exciting these motional sidebands, we create superpositions of states separated by up to four angular momentum quanta. Ramsey experiments show the expected dephasing of the superposition which is dependent on the number of quanta separating the states. These results demonstrate coherent control of a co…
We reported the realization of a $^{174}\mathrm{Yb}^+$-$^{113}\mathrm{Cd}^+$ bi-species Coulomb crystal comprising $^{174}\mathrm{Yb}^+$ ions as coolant and verified its potential for application as a $^{113}\mathrm{Cd}^+$ microwave frequency standard employing sympathetic cooling.The two species of massive ions stably trapped in a Paul trap make up this large two-component crystal. The $^{113}\mathrm{Cd}^+$ ions are trapped in the center, which reduces considerably RF heating and excess micromotion to which the $^{113}\mathrm{Cd}^+$ ions are subjected. Under this scheme, the uncertainty due t…
Tsinghua University（清华大学）；Beijing Academy of Quantum Information Sciences（北京量子信息科学研究院）；Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences（中国科学院上海光学精密机械研究所）；University of Chinese Academy of Sciences（中国科学院大学）
We investigate the motional resonances of dual-species Coulomb crystals comprised of $^9$Be$^+$ and $^{24}$Mg$^+$ ions held in a 4-rod linear Paul trap. Our experimental data and simulations show that the secular motion of such mixed crystals has rich dynamics. Their secular spectra can differ significantly from those of pure ion crystals. We propose a simple model based on mechanical coupling with Coulomb interactions between the two different ion species that explains many features of the secular spectrum. Our findings contribute to a more reliable identification of the ion species in mixed …
Ion Coulomb crystals: an exotic form of condensed matter
Theoretische Physik, Universität des Saarlandes（萨尔兰大学理论物理系）；National Institute of Standards and Technology（美国国家标准与技术研究院）；University of Aarhus（奥胡斯大学）；Technion（以色列理工学院）；Bar-Ilan University（巴伊兰大学）
Atomic clocks use atomic transitions as frequency references. The susceptibility of the atomic transition to external fields limits clock stability and introduces systematic frequency shifts. Here, we propose to realize an atomic clock that utilizes an entangled superposition of states of multiple atomic species, where the reference frequency is a sum of the individual transition frequencies. The superposition is selected such that the susceptibilities of the respective transitions, in individual species, destructively interfere leading to improved stability and reduced systematic shifts. We p…
Optical clocks based on ensembles of trapped ions offer the perspective of record frequency uncertainty with good short-term stability. Most suitable atomic species lack closed transitions for fast detection such that the clock signal has to be read out indirectly through transferring the quantum state of clock ions to co-trapped logic ions by means of quantum logic operations. For ensembles of clock ions existing methods for quantum logic readout require a linear overhead in either time or the number of logic ions. Here we report a quantum algorithmic readout whose overhead scales logarithmic…
The electronic and motional degrees of freedom of trapped ions can be controlled and coherently coupled on the level of individual quanta. Assembling complex quantum systems ion by ion while keeping this unique level of control remains a challenging task. For many applications, linear chains of ions in conventional traps are ideally suited to address this problem. However, driven motion due to the magnetic or radio-frequency electric trapping fields sometimes limits the performance in one dimension and severely affects the extension to higher dimensional systems. Here, we report on the trappin…
Coulomb crystallization of xenon highly charged ions in a laser-cooled Ca+ matrix
University of Birmingham（伯明翰大学）；Max-Planck-Institut für Kernphysik（马克斯·普朗克核物理研究所）；Humboldt-Universität zu Berlin（柏林洪堡大学）；Deutsches Elektronen-Synchrotron (DESY)（德国电子同步辐射中心）；Physikalisch-Technische Bundesanstalt（德国联邦物理技术研究院）
We investigate the non-equilibrium dynamics of coupled Coulomb crystals of different sizes trapped in a double well potential. The dynamics is induced by an instantaneous quench of the potential barrier separating the two crystals. Due to the intra- and inter-crystal Coulomb interactions and the asymmetric population of the potential wells we observe a complex reordering of ions within the two crystals as well as ion transfer processes from one well to the other. The study and analysis of the latter processes constitutes the main focus of this work. In particular we examine the dependence of t…
The $^{27}$Al$^+$ ion optical clock is one of the most attractive optical clocks due to its own advantages, such as low blackbody radiation shift at room temperature and insensitive to the magnetic drift. However, it cannot be laser-cooled directly in the absence of 167 nm laser to date. This problem can be solved by sympathetic cooling. In this work, a linear Paul trap is used to trap both $^{40}$Ca$^{+}$ and $^{27}$Al$^+$ ions simultaneously, and a single Doppler-cooled $^{40}$Ca$^+$ ion is employed to sympathetically cool a single $^{27}$Al$^+$ ion. Thus a "bright-dark" two-ion crystal has …
Investigation into thorium sulfate as a spinless crystal for a high-performance solid-state $^{229}Th$ nuclear clock
University of Manchester（曼彻斯特大学）；University of California, Los Angeles（加州大学洛杉矶分校）；Johns Hopkins University（约翰斯·霍普金斯大学）；University of Nevada, Reno（内华达大学里诺分校）；Los Alamos National Laboratory（洛斯阿拉莫斯国家实验室）
While it is straightforward to count laser-cooled trapped ions by fluorescence imaging, detecting the number of dark ions embedded and sympathetically cooled in a mixed ion crystal is more challenging. We demonstrate a method to track the number of dark ions in real time with single-particle sensitivity. This is achieved by observing discrete steps in the amount of fluorescence emitted from the coolant ions while exciting secular motional resonances of dark ions. By counting the number of fluorescence steps, we can identify the number of dark ions without calibration and without relying on any…
Trapped atomic ions find wide applications ranging from precision measurement to quantum information science and quantum computing. Among the different atomic species employed, beryllium ions are widely used due to its light mass and convenient atomic structure. However, the ion loading process requires a high temperature for sufficient vapor pressure, generating undesirable gas load for the background vacuum and limiting the lifetime of a long ion chain. Here, we demonstrate a simple method to rapidly produce pure linear chains of beryllium ions with pulsed laser ablation, serving as a starti…
Using the ab initio computed Potential Energy Surface (PES) for the electronic interaction of the MgH$^+$ ($^1Σ$) ion with the He($^1$S) atom, we calculate the relevant state-changing rotationally inelastic collision cross sections from a quantum treatment of the multichannel scattering problem. We focus on the quantum dynamics at the translationally low energies for the present partners discussed in the earlier, cold ion trap experiments (see below) which we wish to model in detail. The corresponding state-changing rates computed between the lower rotational states of the molecular ion are em…
