We report new observations of molecular anions with the Yebes 40m and IRAM 30m telescopes toward the cold dense clouds TMC-1 CP, Lupus-1A, L1527, L483, L1495B, and L1544. We detected for the first time C3N- and C5N- in Lupus-1A and C4H- and C6H- in L483. In addition, we report new lines of C6H- toward the six targeted sources, of C4H- toward TMC-1 CP, Lupus-1A, and L1527, and of C8H- and C3N- in TMC-1 CP. Excitation calculations indicate that the lines of anions accessible to radiotelescopes run from subthermally excited to thermalized as the size of the anion increases, with the degree of departure from thermalization depending on the H2 volume density and the line frequency. We noticed that the collision rate coefficients available for the radical C6H cannot explain various observational facts, which advises for a revisitation of the collision data for this species. The observations presented here, together with observational data from the literature, are used to model the excitation of interstellar anions and to constrain their abundances. In general, the anion-to-neutral ratios derived here agree within 50 % (a factor of two at most) with literature values, when available, except for the C4H-/C4H ratio, which shows higher differences due to a revision of the dipole moment of C4H. From the set of anion-to-neutral abundance ratios derived two conclusions can be drawn. First, the C6H-/C6H ratio shows a tentative trend in which it increases with increasing H2 density, as expected from theoretical grounds. And second, it is incontestable that the higher the molecular size the higher the anion-to-neutral ratio, which supports a formation mechanism based on radiative electron attachment. Nonetheless, calculated rate coefficients for electron attachment to the medium size species C4H and C3N are probably too high and too low, respectively, by more than one order of magnitude.
We report the detection of microwave emission lines from the hydrocarbon anion C6H- and its parent neutral C6H in the star-forming region L1251A (in Cepheus), and the pre-stellar core L1512 (in Auriga). The carbon-chain-bearing species C4H, HC3N, HC5N, HC7N and C3S are also detected in large abundances. The observations of L1251A constitute the first detections of anions and long-chain polyynes and cyanopolyynes (with more than 5 carbon atoms) in the Cepheus Flare star-forming region, and the first detection of anions in the vicinity of a protostar outside of the Taurus molecular cloud complex…
Interstellar Polycyclic Aromatic Hydrocarbon (PAH) molecules exist in diverse forms depending on the local physical environment. Formation of ionized PAHs (anions and cations) is favourable in the extreme conditions of the ISM. Besides in their pure form, PAHs are also likely to exist in substituted forms; for example, PAHs with functional groups, dehydrogenated PAHs etc. A dehydrogenated PAH molecule might subsequently form fullerenes in the ISM as a result of ongoing chemical processes. This work presents a Density Functional Theory (DFT) calculation on dehydrogenated PAH anions to explore t…
Long-chain hydrocarbon anions CnH- (n=4, 6, 8) have recently been found to be abundant in a variety of interstellar clouds. In order to explain their large abundances in the denser (prestellar/protostellar) environments, new chemical models are constructed that include gas-grain interactions. Models including accretion of gas-phase species onto dust grains and cosmic-ray-induced desorption of atoms are able to reproduce the observed anion-to-neutral ratios, as well as the absolute abundances of anionic and neutral carbon chains, with a reasonable degree of accuracy. Due to their destructive ef…
Results are presented from a survey for molecular anions in seven nearby Galactic star-forming cores and molecular clouds. The hydrocarbon anion C6H- is detected in all seven target sources, including four sources where no anions have been previously detected: L1172, L1389, L1495B and TMC-1C. The C6H-/C6H column density ratio is greater than about 1.0% in every source, with a mean value of 3.0% (and standard deviation 0.92%). Combined with previous detections, our results show that anions are ubiquitous in dense clouds wherever C6H is present. The C6H-/C6H ratio is found to show a positive cor…
We report on the first detection of C3N- and C5N- towards the cold dark core TMC-1 in the Taurus region, using the Yebes 40 m telescope. The observed C3N/C3N- and C5N/C5N- abundance ratios are 140 and 2, respectively; that is similar to those found in the circumstellar envelope of the carbon-rich star IRC+10216. Although the formation mechanisms for the neutrals are different in interstellar (ion-neutral reactions) and circumstellar clouds (photodissociation and radical-neutral reactions), the similarity of the C3N/C3N- and C5N/C5N- abundance ratios strongly suggests a common chemical path for…
We have investigated the role of molecular anion chemistry in pseudo-time dependent chemical models of dark clouds. With oxygen-rich elemental abundances, the addition of anions results in a slight improvement in the overall agreement between model results and observations of molecular abundances in TMC-1 (CP). More importantly, with the inclusion of anions, we see an enhanced production efficiency of unsaturated carbon-chain neutral molecules, especially in the longer members of the families CnH, CnH2, and HCnN. The use of carbon-rich elemental abundances in models of TMC-1 (CP) with anion ch…
C$_3$P$^-$ is analogous to the known interstellar anion C$_3$N$^-$ with phosphorus replacing the nitrogen in a simple step down the periodic table. In this work, it is shown that C$_3$P$^-$ is likely to possess a dipole-bound excited state. It has been hypothesized and observationally supported that dipole-bound excited states are an avenue through which anions could be formed in the interstellar medium. Additionally, C$_3$P$^-$ has a valence excited state that may lead to further stabilization of this molecule, and C$_3$P$^-$ has a larger dipole moment than neutral C$_3$P ($\sim 6$ D vs. $\si…
We investigate the relative efficiencies of low-temperature chemical reactions in the Interstellar medium (ISM) with H$^-$ anion reacting in the gas phase with cyanopolyyne neutral molecules, leading to the formation of anionic C$_x$N$^-$ linear chains of different length and of H$_2$. All the reactions turn out to be without barriers, highly exothermic reactions which provide a chemical route to the formation of anionic chains of the same length . Some of the anions have been observed in the dark molecular clouds and in the diffuse interstellar envelopes.Quantum calculations are carried for t…
Using data from the GOTHAM (GBT Observations of TMC-1: Hunting for Aromatic Molecules) survey, we report the first astronomical detection of the C10H- anion. The astronomical observations also provided the necessary data to refine the spectroscopic parameters of C10H-. From the velocity stacked data and the matched filter response, C10H- is detected at >9σ confidence level at a column density of 4.04e11 cm-2. A dedicated search for the C10H radical was also conducted towards TMC-1. In this case, the stacked molecular emission of C10H was detected at a ~3.2σ confidence interval at a column dens…
We present the first astronomical detection of a diatomic negative ion, the cyanide anion CN-, as well as quantum mechanical calculations of the excitation of this anion through collisions with para-H2. CN- is identified through the observation of the J = 2-1 and J = 3-2 rotational transitions in the C-star envelope IRC +10216 with the IRAM 30-m telescope. The U-shaped line profiles indicate that CN-, like the large anion C6H-, is formed in the outer regions of the envelope. Chemical and excitation model calculations suggest that this species forms from the reaction of large carbon anions with…
For decades astronomers and astrophysicists believed that only positively charged ions were worthy of relevance in drawing the networks for possible chemical reactions in the interstellar medium, as well as in modeling the physical conditions in most of astrophysical environments. Thus, molecular negative ions received minor attention until their possible existence was observationally confirmed (discovery of the first interstellar anion, C6H-), about thirty years after the first physically reasonable proposal on their actual detection was theoretically surmised by E.Herbst. In an astrophysical…
Elements in the interstellar medium (ISM) exist in the form of gas or dust. The interstellar extinction and elemental abundances provide crucial constraints on the composition, size and quantity of interstellar dust. Most of the extinction modeling efforts have assumed the total abundances (both in gas and in dust) of the dust-forming elements---known as the "interstellar abundances", the "interstellar reference abundances", or the "cosmic abundances"---to be solar and the gas-phase abundances to be independent of the interstellar environments. However, it remains unclear if the solar abundanc…
It has long been suggested that CH2CN- might be a carrier of one of the many poorly characterized diffuse interstellar bands. In this paper, our aim is to study various forms of CH2CN in the interstellar medium. Aim of this paper is to predict spectroscopic characteristics of various forms of CH2CN and its deuterated derivatives. Moreover, we would like to model the interstellar chemistry for making predictions for the column densities of such species around dark cloud conditions. A detailed quantum chemical simulations to present the spectral properties of various forms of the CH2CN. MP2 theo…
Gaussian analysis of new, high-angular-resolution interstellar 21-cm neutral hydrogen emission profile structure more clearly reveals the presence of the previously reported signature of the critical ionization velocity ({\it CIV}) of Helium (34 km s$^{-1}$). The present analysis includes 1496 component line widths for 178 neutral hydrogen profiles in two areas of sky at galactic latitudes around $-$50$^\circ$, well away from the galactic plane. The new data considered here allow the interstellar abundance of Helium to be calculated, and the derived value of 0.095 $\pm$ 0.020 compares extremel…
A continuous supersonic flow reactor has been used to measure rate constants for the C + NH3 reaction over the temperature range 50 to 296 K. C atoms were created by the pulsed laser photolysis of CBr4. The kinetics of the title reaction were followed directly by vacuum ultra-violet laser induced fluorescence (VUV LIF) of C loss and through H formation. The experiments show unambiguously that the reaction is rapid at 296 K, becoming faster at lower temperatures, reaching a value of 1.8 10-10 cm3 molecule-1 s-1 at 50 K. As this reaction is not currently included in astrochemical networks, its i…
Using integral field data we extract the optical spectra of shocked interstellar clouds in Kepler's supernova remnant located in the inner regions of our Galaxy, as well as in the Large Magellanic Cloud (LMC), the Small Magellanic Cloud (SMC), NGC6822 and IC 1613. Using self-consistent shock modelling, we make a new determination of the chemical composition of the interstellar medium (ISM) in N, O, Ne, S, Cl and Ar in these galaxies and obtain accurate estimates of the fraction of refractory grains destroyed in the shock. By comparing our derived abundances with those obtained in recent works …
We compiled the polarimetric data for a sample of lines of sight with known abundances of Mg, Si, and Fe. We correlated the degree of interstellar polarization $P$ and polarization efficiency (the ratio of $P$ to the colour excess $E(B-V)$ or extinction $A_V$) with dust phase abundances. We detect an anticorrelation between $P$ and the dust phase abundance of iron in non silicate - containing grains $< [\rm Fe(rest)/H > ]_\rm d$, a correlation between $P$ and the abundance of Si, and no correlation between $P/E(B-V)$ or $P/A_V$ and dust phase abundances. These findings can be explained if main…
The question, what is the role of freeze-out of chemical species in determining the molecular abundances in the interstellar gas is a matter of debate. We investigate a theoretical case of a dense interstellar molecular cloud core by time-dependent modelling of chemical kinetics, where grain surface reactions deliberately are not included. That means, the gas-phase and solid-phase abundances are influenced by gas reactions, accretion on grains, and desorption, only. We compare the results to a reference model, where no accretion occurs and only gas-phase reactions are included. We can trace th…
We present a comprehensive survey of boron abundances in diffuse interstellar clouds from observations made with the Space Telescope Imaging Spectrograph (STIS) of the Hubble Space Telescope. Our sample of 56 Galactic sight lines is the result of a complete search of archival STIS data for the B II 1362 resonance line, with each detection confirmed by the presence of absorption from O I 1355, Cu II 1358, and Ga II 1414 (when available) at the same velocity. Five previous measurements of interstellar B II from Goddard High Resolution Spectrograph observations are incorporated in our analysis, y…
The low density interstellar medium (ISM) close to the Sun and inside of the heliosphere provides a unique laboratory for studying interstellar dust grains. Grain characteristics in the nearby ISM are obtained from observations of interstellar gas and dust inside of the heliosphere and the interstellar gas towards nearby stars. Comparison between the gas composition and solar abundances suggests that grains are dominated by olivines and possibly some form of iron oxide. Measurements of the interstellar Ne/O ratio by the Interstellar Boundary Explorer spacecraft indicate that a high fraction of…
The comparison of chemical abundances in the neutral gas of galaxies to photospheric abundances of old and young stars, ionized gas abundances, and abundances in galactic halos can trace the chemical enrichment of the universe through cosmic times. In particular, our understanding of chemical enrichment through spectroscopic observations of damped Lyman alpha systems (DLAs) relies on corrections for depletion of metals from the gas to the dust phase. These corrections must be determined in the nearby universe, where both gas-phase abundances and photospheric abundances of young stars recently …
While it is well recognized that both the Galactic interstellar extinction curves and the gas-phase abundances of dust-forming elements exhibit considerable variations from one sight line to another, as yet most of the dust extinction modeling efforts have been directed to the Galactic average extinction curve, which is obtained by averaging over many clouds of different gas and dust properties. Therefore, any details concerning the relationship between the dust properties and the interstellar environments are lost. Here we utilize the wealth of extinction and elemental abundance data obtained…
The Suzaku X-ray satellite observed the nearby S0 galaxy NGC 1316, a merger remnant aged 3 Gyr. The total good exposure time was 48.7 ksec. The spectra were well represented by a two-temperature thermal model for the interstellar medium (ISM) plus a power-law model. The cool and hot temperatures of the thermal model were 0.48 +/- 0.03 and 0.92 +/- 0.04 keV, respectively. The excellent spectral sensitivity of Suzaku enables for the first time to measure the metal abundances of O, Ne, Mg, Si, and Fe in the ISM. The resultant abundance pattern of O, Ne, Mg, Si, and Fe is close to that of the new …
We analyze mutual relations between interstellar extinction E(B-V) and column densities of diatomic molecules such as CN, CH and CH cation observed along translucent sightlines. Observational material acquired using five echelle spectrographs, situated in both northern and southern hemispheres, was used in this study. While column densities of CH, CH+ correlate reasonably tightly with E(B-V) the similar relation built for CN shows a large scatter. This result suggests that CH and CH+ molecules are quite well spatially correlated to interstellar dust while CN requires another conditions to be f…
As the Galaxy evolves, the abundance of deuterium in the interstellar medium (ISM) decreases from its primordial value: deuterium is "astrated". The deuterium astration factor, f_D, the ratio of the primordial D abundance (the D to H ratio by number) to the ISM D abundance, is determined by the competition between stellar destruction and infall, providing a constraint on models of the chemical evolution of the Galaxy. Although conventional wisdom suggests that the local ISM (i.e., within ~1-2 kpc of the Sun) should be well mixed and homogenized on timescales short compared to the chemical evol…
Hydroxylamine, NH2OH, is one of the already detected interstellar molecules with the highest prebiotic potential. Yet, the abundance of this molecule found by astronomical observations is rather low for a relatively simple molecule, $\sim$ 10$^{-10}$ relative to H2. This seemingly low abundance can be rationalized by destruction routes operating on interstellar dust grains. In this work, we tested the viability of this hypothesis under several prisms, finding that the origin of a lower abundance of \ce{NH2OH} can be explained by two chemical processes, one operating at low temperature (10 K) a…
We reanalyzed interstellar Cl I and Cl II spectra acquired with the Copernicus satellite. The directions for this study come from those of Crenny & Federman and sample the transition from atomic to molecular rich clouds where the unique chemistry leading to molecules containing chlorine is initiated. Our profile syntheses relied on up-to-date laboratory oscillator strengths and component structures derived from published high-resolution measurements of K I absorption that were supplemented with Ca II and Na I D results. We obtain self-consistent results for the Cl I lines at 1088, 1097, and 13…
Hydrocarbons are ubiquitous in the interstellar medium, observed in diverse environments ranging from diffuse to molecular dark clouds and strong photon-dominated regions near HII regions. Recently, two broad diffuse interstellar bands (DIBs) at 4881Å and 5450Å were attributed to the linear version of propynylidene l-C3H2, a species whose more stable cyclic conformer c-C3H2 has been widely observed in the diffuse interstellar medium at radio wavelengths. This attribution has already been criticized on the basis of indirect plausibility arguments because the required column densities are quite …
We present a comprehensive survey of B abundances in diffuse interstellar clouds from HST/STIS observations along 56 Galactic sight lines. Our sample is the result of a complete search of archival STIS data for the B II resonance line at 1362 angstroms, with each detection confirmed by the presence of absorption from other dominant ions at the same velocity. The data probe a range of astrophysical environments including both high-density regions of massive star formation as well as low-density paths through the Galactic halo, allowing us to clearly define the trend of B depletion onto interste…
We present the detection of two H2C3O isomers, propynal and cyclopropenone, toward various starless cores and molecular clouds, together with upper limits for the third isomer propadienone. We review the processes controlling the abundances of H2C3O isomers in interstellar media showing that the reactions involved are gas-phase ones. We show that the abundances of these species are controlled by kinetic rather than thermodynamic effects.
We present the first identification in interstellar space of the thioformyl radical (HCS) and its metastable isomer HSC. These species were detected toward the molecular cloud L483 thanks to observations carried out with the IRAM 30m telescope in the 3 mm band. We derive beam-averaged column densities of 7e12 cm-2 for HCS and 1.8e11 cm-2 for HSC, which translate to fractional abundances relative to H2 of 2e-10 and 6e-12, respectively. Although the amount of sulfur locked by these radicals is low, their detection allows to put interesting constraints on the chemistry of sulfur in dark clouds. I…
CONTEXT: The attachment of free electrons to polycondensed aromatic ring molecules (PAHs) is studied for the variety of these molecules with different numbers of condensed rings and over a broad range of electron temperatures, using a multichannel quantum scattering approach. The calculations of the relevant cross sections are used in turn to model the corresponding attachment rates for each of the systems under study, and these rates are parametrized as a function of temperature using a commonly employed expression for two-body processes in the interstellar medium (ISM). AIM: The scope of thi…
We present an extensive analysis of the gas-phase abundances and depletion behaviors of neutron-capture elements in the interstellar medium (ISM). Column densities (or upper limits to the column densities) of Ga II, Ge II, As II, Kr I, Cd II, Sn II, and Pb II are determined for a sample of 69 sight lines with high- and/or medium-resolution archival spectra obtained with the Space Telescope Imaging Spectrograph onboard the Hubble Space Telescope. An additional 59 sight lines with column density measurements reported in the literature are included in our analysis. Parameters that characterize th…
The relative column densities of the structural isomers methyl formate, glycolaldehyde, and acetic acid are derived for a dozen positions towards the massive star-forming regions MM1 and MM2 in the NGC 6334I complex, which are separated by $\sim$4000 AU. Relative column densities of these molecules are also gathered from the literature for 13 other star-forming regions. In this combined dataset, a clear bi-modal distribution is observed in the relative column densities of glycolaldehyde and methyl formate. No such distribution is evident with acetic acid. The two trends are comprised of star-f…
We present Jansky Very Large Array observations of 20 - 37 GHz absorption lines from nearby Galactic diffuse molecular gas seen against four cosmologically-distant compact radio continuum sources. The main new observational results are that \linearC3H\ and \methCN\ are ubiqitous in the local diffuse molecular interstellar medium at \AV\ $\la 1$ while HC$_3$N was seen only toward B0415 at \AV\ $>$ 4 mag. The linear/cyclic ratio is much larger in C$_3$H than in C$_3$\HH\ and the ratio \methCN/HCN is enhanced compared to TMC-1, although not as much as toward the Horsehead Nebula. More consequenti…
Using high-resolution (~85000) and high signal-to-noise ratio (~200) optical spectra acquired with the European Southern Observatory Ultraviolet and Visual Echelle Spectrograph, we have determined the interstellar column densities of C2 for six Galactic lines of sight with E(B- V) ranging from 0.33 to 1.03. For our purposes, we identified and measured absorption lines belonging to the (1, 0), (2, 0) and (3, 0) Phillips bands A1Πu-X1Σ+g. We report on the identification of a few lines of the C2 (4, 0) Phillips system towards HD 147889. The curve-of-growth method is applied to the equivalent widt…
We investigate the composition of interstellar grains along the line of sight toward Zeta Ophiuchi, a well-studied environment near the diffuse-dense cloud transition. A spectral decomposition analysis of the solid-state absorbers is performed using archival spectroscopic observations from the Spitzer Space Telescope and Infrared Space Observatory. We find strong evidence for the presence of sub-micron-sized amorphous silicate grains, principally comprised of olivine-like composition, with no convincing evidence of H2O ice mantles. However, tentative evidence for thick H2O ice mantles on large…
We present a general parameter study, in which the abundance of interstellar argonium (ArH$^+$) is predicted using a model for the physics and chemistry of diffuse interstellar gas clouds. Results have been obtained as a function of UV radiation field, cosmic-ray ionization rate, and cloud extinction. No single set of cloud parameters provides an acceptable fit to the typical ArH$^+$, OH$^+$ and $\rm H_2O^+$ abundances observed in diffuse clouds within the Galactic disk. Instead, the observed abundances suggest that ArH$^+$ resides primarily in a separate population of small clouds of total vi…
We present recent UV laboratory spectra of various polycyclic aromatic hydrocarbons (PAHs) and explore the potential of these molecules as carriers of the DIBs. From a detailed comparison of gas-phase and Ne-matrix absorption spectra of anthracene, phenanthrene, pyrene, 2,3-benzofluorene, benzo[ghi]perylene, and hexabenzocoronene with new interstellar spectra, we infer upper limits in the abundance of these PAHs in the interstellar medium. Upper limits in the column densities of anthracene of $0.8 - 2.8 \times 10^{12}$\ cm$^{-2}$ and of pyrene and 2,3-benzofluorene ranging from $2 - 8 \times 1…
School of Mathematics and Physics, Anhui Jianzhu University（安徽建筑大学数学与物理学院）；Department of Physics and Astronomy, University of Missouri（密苏里大学物理与天文学系）；Key Laboratory of Particle Astrophysics, Institute of High Energy Physics, Chinese Academy of Sciences（中国科学院高能物理研究所粒子天体物理重点实验室）
Molecular oxygen has been the subject of many observational searches as chemical models predicted it to be a reservoir of oxygen. Although it has been detected in two regions of the interstellar medium, its rarity is a challenge for astrochemical models. In this paper, we have combined the physical conditions computed with smoothed particle hydrodynamics (SPH) simulations with our full gas-grain chemical model Nautilus, to study the predicted O2 abundance in interstellar material forming cold cores. We thus follow the chemical evolution of gas and ices in parcels of material from the diffuse i…
We report the results of a sensitive search for the 443.952902 GHz $J=1-0$ transition of the LiH molecule toward two interstellar clouds in the Milky Way, W49N and Sgr B2 (Main), that has been carried out using the Atacama Pathfinder Experiment (APEX) telescope. The results obtained toward W49N place an upper limit of $1.9 \times 10^{-11}\, (3σ)$ on the LiH abundance, $N({\rm LiH})/N({\rm H}_2)$, in a foreground, diffuse molecular cloud along the sight-line to W49N, corresponding to 0.5% of the solar system lithium abundance. Those obtained toward Sgr B2 (Main) place an abundance limit $N({\rm…
In this work we make use of available Integral Field Unit (IFU) spectroscopy and slit spectra of several nearby galaxies. The pre-existing empirical R and S calibrations for abundance determinations are constructed using a sample of HII regions with high quality slit spectra. In this paper, we test the applicability of those calibrations to the IFU spectra. We estimate the calibration-based abundances obtained using both the IFU and the slit spectroscopy for eight nearby galaxies. The median values of the slit and IFU spectra-based abundances in bins of 0.1 in fractional radius Rg (normalized …
This is the first in a series of three papers describing a project with the Cosmic Origins Spectrograph on the Hubble Space Telescope to measure abundances of the neutral interstellar medium (ISM) in a sample of 9 nearby star-forming galaxies. The goal is to assess the (in)homogeneities of the multiphase ISM in galaxies where the bulk of metals can be hidden in the neutral phase, yet the metallicity is inferred from the ionized gas in the HII regions. The sample, spanning a wide range in physical properties, is to date the best suited to investigate the metallicity behavior of the neutral gas …
In this work, we identify carbodiimide (HNCNH), which is an isomer of the well-known interstellar species cyanamide (NH2CN), in weak maser emission, using data from the GBT PRIMOS survey toward Sgr B2(N). All spectral lines observed are in emission and have energy levels in excess of 170 K, indicating that the molecule likely resides in relatively hot gas that characterizes the denser regions of this star forming region. The anticipated abundance of this molecule from ice mantle experiments is ~10% of the abundance of NH2CN, which in Sgr B2(N) corresponds to ~2 x 10^13 cm-2. Such an abundance …
The metallicity and gas density dependence of interstellar depletions, the dust-to-gas (D/G), and dust-to-metal (D/M) ratios have important implications for how accurately we can trace the chemical enrichment of the universe; either by using FIR dust emission as a tracer of the ISM; or by using spectroscopy of damped Lyman-alpha systems (DLAs) to measure chemical abundances over a wide range of redshifts. We collect and compare large samples of depletion measurements in the Milky Way (MW), LMC (Z=0.5 Zsun), and SMC (Z=0.2 Zsun). The relation between the depletions of different elements do not …
We present numerical computations and analytic scaling relations for interstellar ion-molecule gas phase chemistry down to very low metallicities ($ 10^{-3} \times$ solar), and/or up to high driving ionization rates. Relevant environments include the cool interstellar medium (ISM) in low-metallicity dwarf galaxies, early enriched clouds at the reionization and Pop-II star formation era, and in dense cold gas exposed to intense X-ray or cosmic-ray sources. We focus on the behavior for H$_2$, CO, CH, OH, H$_2$O and O$_2$, at gas temperatures $\sim 100$ K, characteristic of a cooled ISM at low me…
Studies measuring the chemical abundances of the neutral gas in star-forming galaxies (SFGs) require ionization correction factors (ICFs) to accurately measure their metal contents. In the work presented here we calculate newly improved ICFs for a sample of SFGs. These new corrections include both the contaminating ionized gas along the line of sight (ICF$_{\rm ionized}$) and unaccounted higher ionization stages in the neutral gas (ICF$_{\rm neutral}$). We make use of recently acquired spectroscopic observations taken with the Cosmic Origins Spectrograph (COS) on board Hubble to measure column…
Many chemical models of dense interstellar clouds predict that the majority of gas-phase elemental nitrogen should be present as N2, with an abundance approximately five orders of magnitude less than that of hydrogen. As a homonuclear diatomic molecule, N2 is difficult to detect spectroscopically through infrared or millimetre-wavelength transitions so its abundance is often inferred indirectly through its reaction product N2H+. Two main formation mechanisms each involving two radical-radical reactions are the source of N2 in such environments. Here we report measurements of the low temperatur…
We report the first detection in the interstellar medium of the Z-isomer of cyanomethanimine (HNCHCN), an HCN dimer proposed as precursor of adenine. We identified six transitions of Z-cyanomethanimine, along with five transitions of E-cyanomethanimine, using IRAM 30m observations towards the Galactic Center quiescent molecular cloud G+0.693. The Z-isomer has a column density of (2.0$\pm$0.6)$\times$10$^{14}$ cm$^{-2}$ and an abundance of 1.5$\times$10$^{-9}$. The relative abundance ratio between the isomers is [Z/E]$\sim$6. This value cannot be explained by the two chemical formation routes p…
(abridged) The fairly recent detection of a variety of anions in the Interstellar Molecular Clouds have underlined the importance of realistically modeling the processes governing their abundance. To this aim, our earlier calculations for the radiative electron attachment (REA) rates for C4H-, C6H-, and C8H- are employed to generate the corresponding column density ratios of anion/neutral (A/N) relative abundances. The latter are then compared with those obtained from observational measurements. The calculations involved the time-dependent solutions of a large network of chemical processes ove…
We have investigated the water abundance in shock-heated molecular gas, making use of $Herschel$ measurements of far-infrared CO and H$_2$O line emissions in combination with $Spitzer$ measurements of mid-IR H$_2$ rotational emissions. We present far-infrared line spectra obtained with $Herschel$'s PACS instrument in range spectroscopy mode towards two positions in the protostellar outflow NGC 2071 and one position each in the supernova remnants W28 and 3C391. These spectra provide unequivocal detections, at one or more positions, of 12 rotational lines of water, 14 rotational lines of CO, 8 r…
We report the detection of the carbon-chain radical HC$_5$O for the first time in the interstellar medium toward the dark cloud TMC-1 using the 100 m Green Bank Telescope. We observe four hyperfine components of this radical in the $J = 17/2 \rightarrow 15/2$ rotational transition that originates from the $^2Π_{1/2}$ fine structure level of its ground state, and calculate an abundance of $n/n_{H_2}$ = $1.7\times 10^{-10}$, assuming an excitation temperature of $T_{ex} = 7$~K. No indication of HC$_3$O, HC$_4$O, HC$_6$O, is found in these or archival observations of the source, while we report t…
We describe the assignment of a previously unidentified interstellar absorption line to ArH$^+$ and discuss its relevance in the context of hydride absorption in diffuse gas with a low H$_2$ fraction. The column densities along several lines of sight are determined and discussd in the framework of chemical models. The column densities of ArH$^+$ are compared to those of other species, tracing interstellar medium (ISM) components with different H$_2$ abundances. Chemical models are constructed, taking UV radiation and cosmic ray ionization into account. Due to the detection of two isotopologues…
The high interstellar abundances of polycyclic aromatic hydrocarbons (PAHs) and their size distribution are the result of complex chemical processes implying dust, UV radiation, and the main gaseous components (H, C+, and O). These processes must explain the high abundance of relatively small PAHs in the diffuse interstellar medium (ISM) and imply the continuous formation of some PAHs that are small enough (number of carbon atoms NC <~ 35-50) to be completely dehydrogenated by interstellar UV radiation. The carbon clusters Cn thus formed are constantly exposed to the absorption of ~10-13.6 eV …
