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arXiv 2304.05331physics.atom-ph
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Lr^+(Z = 103)在氦中的态分辨离子迁移率

State-specific ion mobilities of Lr^+ (Z = 103) in helium

Harry Ramanantoanina, Anastasia Borschevsky, Michael Block, Larry Viehland, Mustapha Laatiaoui

AI总结:

本研究采用MRCI方法和Gram-Charlier算法计算Lr^+与Lu^+在氦中的态分辨离子迁移率,发现100K以上不同态迁移率差异显著,室温下相对差异达13%-15%,可支持激光共振色谱分析。

摘要:

我们计算了Lr^+(Z = 103)及其较轻的化学同系物Lu^+(Z = 71)在氦气中基态^1S_0和最低亚稳态^3D_1的离子迁移率。为此,我们采用多参考组态相互作用(MRCI)方法计算不同态下的离子-原子相互作用势。基于计算得到的相互作用势,使用求解玻尔兹曼方程的Gram-Charlier方法推导不同电子态的迁移率。研究发现,Lr^+和Lu^+离子的零场离子迁移率相近。此外,在100K以上的温度下,不同态的离子迁移率存在显著差异。室温下,Lu^+和Lr^+离子基态与激发态迁移率的相对差异分别约为15%和13%,这一差异足够大,可实现这些离子的激光共振色谱(LRC)分析。

英文摘要:

Ion mobilities of Lr^+ (Z = 103) and of its lighter chemical homolog Lu^+ (Z = 71) in helium were calculated for the ground state ^1S_0 and the lowest metastable state ^3D_1. To this end we applied the multi-reference configuration interaction (MRCI) method to calculate the ion-atom interaction potentials in the different states. The Gram-Charlier approach to solving the Boltzmann equation was used to deduce the mobilities of the different electronic states, based on the calculated interaction potentials. We found that the zero-field ion mobilities are similar for the Lr^+ and Lu^+ ions. In addition, the ion mobilities of the different states are substantially different for temperatures above 100K. The relative differences between the mobilities of the ground and excited states at room temperature are about 15\% and 13\% for Lu^+ and Lr^+ ions, respectively, which should be sufficiently large enough to enable laser resonance chromatography (LRC) of these ions.

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