We report a pore-scale numerical study of salt finger convection in porous media, with a focus on the influence of the porosity in the non-Darcy regime, which has received little attention in previous research. The numerical model is based on the lattice Boltzmann method with a multiple-relaxation-time scheme and employs an immersed boundary method to describe the fluid-solid interaction. The simulations are conducted in a two-dimensional, horizontally-periodic domain with an aspect ratio of 4, and the porosity is varied from 0.7 to 1, while the solute Rayleigh number ranges from 4*10^6 to 4*10^9. Our results show that, for all explored Rayleigh number, solute transport first enhances unexpectedly with decreasing porosity, and then decreases when porosity is smaller than a Rayleigh number-dependent value. On the other hand, while the flow strength decreases significantly as porosity decreases at low Rayleigh number, it varies weakly with decreasing porosity at high Rayleigh number and even increases counterintuitively for some porosities at moderate Rayleigh number. Detailed analysis of the salinity and velocity fields reveals that the fingered structures are blocked by the porous structure and can even be destroyed when their widths are larger than the pore scale, but become more ordered and coherent with the presence of porous media. This combination of opposing effects explains the complex porosity-dependencies of solute transport and flow strength. The influence of porous structure arrangement is also examined, with stronger effects observed for smaller porosity and higher Rayleigh number. These findings have important implications for passive control of mass/solute transport in engineering applications.
The amplification and equilibration of three-dimensional salt fingers in unbounded uniform vertical gradients of temperature and salinity is modeled with a Direct Numerical Simulation in a triply periodic computational domain. A fluid dynamics video of the simulation shows that the secondary instability of the fastest growing square-planform finger mode is a combination of the well-known vertical shear instability of two-dimensional fingers [Holyer, 1984] and a new horizontal shear mode.
In this work we study the fingering double diffusive convection, namely the buoyancy-driven convection flow within a fluid layer experiencing an unstable salinity gradient and a stable thermal gradient. Especially, we investigate the influences from a background shear with uniform strength. Linear stability analysis indicates that the unstable modes shift from a circular shape to a sheet-like shape as the shear becomes stronger. Three dimensional direction numerical simulations are conducted for five groups of cases, each of which has the same combination of thermal and salinity gradients (mea…
When ice forms on lakes, dissolved salts are rejected, which can lead to under-ice salt-finger formation. We performed a series of laboratory experiments to visualize these fingers. While we detected salt-fingers in our camera recordings, the signal of these fingers is nearly absent in the temperature record. We quantify the velocity of the salt plumes and measure the bottom salinity increase from these fingers. Further, we estimate that the salinity is often distributed evenly with depth. Comparing the salt fluxes in our experiments with a typical salt flux in lakes, we suggest that condition…
A simple model of nonlinear salt-finger convection in two dimensions is derived and studied. The model is valid in the limit of small solute to heat diffusivity ratio and large density ratio, which is relevant to both oceanographic and astrophysical applications. Two limits distinguished by the magnitude of the Schmidt number are found. For order one Schmidt numbers, appropriate for astrophysical applications, a modified Rayleigh-Bénard system with large-scale damping due to a stabilizing temperature is obtained. For large Schmidt numbers, appropriate for the oceanic setting, the model combine…
Fingering double diffusive convection with real seawater properties is studied by two-dimensional direct numerical simulations for the wall-bounded domain and compared with the results for fully periodic domain. For fixed unstable salinity difference between two horizontal plates, dominant flow structures change from convection rolls to salt fingers as the stable temperature difference increases. Meanwhile the bulk density ratio calculated by the mean scalar gradients exceeds unity. When the bulk thermal Rayleigh number, which is defined by the mean temperature gradient in the bulk and the dom…
We examine the transport in a homogeneous porous medium of a finite slice of a solute which adsorbs on the porous matrix following a Langmuir adsorption isotherm and can influence the dynamic viscosity of the solution. In the absence of any viscosity variation, the Langmuir adsorption induces the formation of a shock layer wave at the frontal interface and of a rarefaction wave at the rear interface of the sample. For a finite width sample, these waves interact after a given time that varies nonlinearly with the adsorption properties to give a triangle-like concentration profile in which the m…
Bifurcation analysis of confined salt-finger convection using single-mode equations obtained from a severely truncated Fourier expansion in the horizontal is performed. Strongly nonlinear staircase-like solutions having, respectively, one (S1), two (S2) and three (S3) regions of mixed salinity in the vertical direction are computed using numerical continuation, and their stability properties are determined. Near onset, the one-layer S1 solution is stable and corresponds to maximum salinity transport among the three solutions. The S2 and S3 solutions are unstable but exert an influence on the s…
Diapycnical eddy diffusivities are formulated from physical relations according to a simple fact that the different formulas are identical for the same parameter. It is found that the dispassion ratio Γis a crucial parameter. When it is above a critical value (about 0.2), the flow is salt finger type; otherwise, it is turbulence. All the density ratio $R_ρ=1/(1-Γ^2)$, eddy flux ratio $γ=1/(1+Γ)$, and eddy diffusivity ratio $R_k=1-Γ$ are simply dependent on the dispassion ratio gamma Γ. We apply these relations to the measurement data in the western tropical Atlantic Ocean. The effective diapyc…
In this paper we investigate the convection phenomenon in the intracluster medium (the weakly-collisional magnetized inhomogeneous plasma permeating galaxy clusters) where the concentration gradient of the Helium ions is not ignorable. To this end, we build upon the general machinery employed to study the salt finger instability found in the oceans. The salt finger instability is a form of double diffusive convection where the diffusions of two physical quantities---heat and salt concentrations---occur with different diffusion rates. The analogous instability in the intracluster medium may res…
Soil salinization is a major cause of soil degradation and hampers plant growth. For soils saturated with saline water, the evaporation of water induces accumulation of salt near the top of the soil. The remaining liquid gets an increasingly larger density due to the accumulation of salt, giving a gravitationally unstable situation, where instabilities in the form of fingers can form. These fingers can hence lead to a net downwards transport of salt. We here investigate the appearance of these fingers through a linear stability analysis and through numerical simulations. The linear stability a…
The density-driven convection coupled with chemical reaction is the preferred mechanism for permanently storing CO2 in saline aquifers. This study uses a 2D visual Hele-Shaw cell to evaluate and visualize the density-driven convection formed due to gravitational instabilities, also known as Rayleigh-Taylor instability. The primary goal of the experiments is to understand the various mechanisms for the mass transfer of gaseous CO2 into brine with different initial ionic concentrations and flow permeability. Moreover, the impact of CO2 flow rates, injection locations, reservoir dipping angle, an…
We study miscible Rayleigh-Taylor (RT) fingering instability in two-dimensional homogeneous porous media, in which the fluid density varies non-monotonically as a function of the solute concentration such that the maximum density lies in the interior of the domain, thus creating a stable and an unstable density gradients that evolve in time. With the help of linear stability analysis (LSA) as well as nonlinear simulations the effects of density gradients on the stability of RT fingers are investigated. As diffusion relaxes the concentration gradient, a non-monotonic density profile emerges in …
Towards the understanding of convective dissolution in confined porous media: thin bead pack experiments, two-dimensional direct numerical simulations and physical models
Thermo-osmotic flows - flows generated in micro and nanofluidic systems by thermal gradients - could provide an alternative approach to harvest waste heat. However, such use would require massive thermo-osmotic flows, which are up to now only predicted for special and expensive materials. There is thus an urgent need to design affordable nanofluidic systems displaying large thermo-osmotic coefficients. In this paper we propose a general model for thermo-osmosis of aqueous electrolytes in charged nanofluidic channels, taking into account hydrodynamic slip, together with the different solvent an…
Double diffusive convection (DDC), which is the buoyancy driven flow with fluid density depending on two scalar components, is ubiquitous in many natural and engineering enviroments. Of great interests are scalers transfer rate and flow structures. Here we systematically investigate DDC flow between two horizontal plates, driven by an unstable salinity gradient and stabilized by a temperature gradient. Counterintuitively, when increasing the stabilizing temperature gradient, the salinity flux first increases, even though the velocity monotonically decreases, before it finally breaks down to th…
Double-diffusive instabilities are often invoked to explain enhanced transport in stably-stratified fluids. The most-studied natural manifestation of this process, fingering convection, commonly occurs in the ocean's thermocline and typically increases diapycnal mixing by two orders of magnitude over molecular diffusion. Fingering convection is also often associated with structures on much larger scales, such as thermohaline intrusions, gravity waves and thermohaline staircases. In this paper, we present an exhaustive study of the phenomenon from small to large scales. We perform the first thr…
The method of neutron imaging was adopted to map the concentration evolution of aqueous paramagnetic Gd(NO3)3 solutions. Magnetic manipulation of the paramagnetic liquid within a miscible nonmagnetic liquid is possible by countering density-difference driven convection. The formation of salt fingers caused by double-diffusive convection in a liquid-liquid system of Gd(NO3)3 and Y(NO3)3 solutions can be prevented by the magnetic field gradient force.
Direct numerical simulations are conducted for double diffusive convection (DDC) bounded by two parallel plates, with fluid properties similar to the values of seawater. The DDC flow is driven by an unstable salinity difference and stabilized at the same time by a temperature difference. For these conditions the flow can be in the finger regime. We develop scaling laws for three key response parameters of the system: The non-dimensional salinity flux $Nu_S$ mainly depends on the salinity Rayleigh number $Ra_S$, which measures the strength of the salinity difference, and exhibits a very weak de…
The double diffusive convection between two parallel plates is numerically studied for a series of parameters. The flow is driven by the salinity difference and stabilized by the thermal field. Our simulations are directly compared to experiments by Hage and Tilgner (\emph{Phys. Fluids} 22, 076603 (2010)) for several sets of parameters and reasonable agreement is found. This in particular holds for the salinity flux and its dependence on the salinity Rayleigh number. Salt fingers are present in all simulations and extend through the entire height. The thermal Rayleigh number seems to have mino…
A two-scale model is presented to simulate the dynamic ion transport and adsorption processes in porous electrodes used for capacitive deionization (CDI). At the pore scale, the Stokes equation governing water flow in porous CDI electrodes is solved using the lattice Boltzmann method and Nernst-Planck equations describing ion transport is solved using the finite volume method. The ion adsorption process is considered at the surface of carbon electrodes. At the continuum scale, Darcy equation and advection-diffusion equation governing water flow and solute transport through CDI cells are solved…
Convective dissolution is the process by which CO$_2$ injected in deep geological formations dissolves into the aqueous phase, which allows storing it perennially by gravity. The process results from buoyancy-coupled Darcy flow and solute transport. Proper theoretical modeling of the process should consider in the transport equation a diffusive term accounting for hydrodynamics (or, mechanical) dispersion, with an effective diffusion coefficient that is proportional to the local interstitial velocity. A few two-dimensional (2D) numerical studies, and three-dimensional (3D) experimental investi…
