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arXiv 2302.04232physics.atom-phphysics.chem-ph

$^{85}$Rb和$^{87}$Rb超精细共振在Ar、Kr和Xe缓冲气体中非线性压力位移的同位素研究

Isotope study of the nonlinear pressure shifts of $^{85}$Rb and $^{87}$Rb hyperfine resonances in Ar, Kr, and Xe buffer gases

B. H. McGuyer

AI总结:

本文通过同位素测量和改进的分子模型,揭示了$^{85}$Rb和$^{87}$Rb超精细共振在Ar、Kr、Xe缓冲气体中的非线性压力位移机制,并用共享参数统一拟合了两种同位素的线性和非线性位移,对原子钟等器件具有实际意义。

摘要:

对基态$^{85}$Rb原子0--0超精细共振频率的测量表明,其随缓冲气体Ar、Kr和Xe的压力呈非线性依赖关系。这些非线性与之前在$^{87}$Rb和$^{133}$Cs中观察到的现象相似,并被认为来源于碱金属—惰性气体范德瓦尔斯分子。然而,在Xe中观察到的非线性形状与先前的理论相矛盾,而Ar和Kr中的非线性也与先前$^{87}$Rb结果所预期的同位素标度关系不一致。通过将转动进行量子力学处理并考虑分子中额外的自旋相互作用,改进后的模型缓解了大部分这些差异。引入偶极-超精细相互作用后,可以用一组最少的、与同位素无关的共享参数,同时拟合$^{85}$Rb和$^{87}$Rb在Ar、Kr或Xe缓冲气体中的线性和非线性位移。在实验精度范围内,He和N$_2$中的位移随压力呈线性变化。这些结果对蒸气室原子钟及相关器件具有实际意义。

英文摘要:

Measurements of the 0--0 hyperfine resonant frequencies of ground-state $^{85}$Rb atoms show a nonlinear dependence on the pressure of the buffer gases Ar, Kr, and Xe. The nonlinearities are similar to those previously observed with $^{87}$Rb and $^{133}$Cs and presumed to come from alkali-metal--noble-gas van der Waals molecules. However, the shape of the nonlinearity observed for Xe conflicts with previous theory, and the nonlinearities for Ar and Kr disagree with the expected isotopic scaling of previous $^{87}$Rb results. Improving the modeling alleviates most of these discrepancies by treating rotation quantum mechanically and considering additional spin interactions in the molecules. Including the dipolar-hyperfine interaction allows simultaneous fitting of the linear and nonlinear shifts of both $^{85}$Rb and $^{87}$Rb in either Ar, Kr, or Xe buffer gases with a minimal set of shared, isotope-independent parameters. To the limit of experimental accuracy, the shifts in He and N$_2$ were linear with pressure. The results are of practical interest to vapor-cell atomic clocks and related devices.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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