Given the high power density low discharge rate and decreasing cost rechargeable lithium-ion batteries LiBs have found a wide range of applications such as power grid level storage systems electric vehicles and mobile devices. Developing a framework to accurately model the nonlinear degradation process of LiBs which is indeed a supervised learning problem becomes an important research topic. This paper presents a classical-quantum hybrid machine learning approach to capture the LiB degradation model that assesses battery cell life loss from operating profiles. Our work is motivated by recent advances in quantum computers as well as the similarity between neural networks and quantum circuits. Similar to adjusting weight parameters in conventional neural networks the parameters of the quantum circuit namely the qubits degree of freedom can be tuned to learn a nonlinear function in a supervised learning fashion. As a proof of concept paper our obtained numerical results with the battery dataset provided by NASA demonstrate the ability of the quantum neural networks in modeling the nonlinear relationship between the degraded capacity and the operating cycles. We also discuss the potential advantage of the quantum approach compared to conventional neural networks in classical computers in dealing with massive data especially in the context of future penetration of EVs and energy storage.
Singapore University of Technology and Design（新加坡科技设计大学）；National University of Singapore（新加坡国立大学）
By informing accurate performance (e.g., capacity), health state management plays a significant role in safeguarding battery and its powered system. While most current approaches are primarily based on data-driven methods, lacking in-depth analysis of battery performance degradation mechanism may discount their performances. To fill in the research gap about data-driven battery performance degradation analysis, an invariant learning based method is proposed to investigate whether the battery performance degradation follows a fixed behavior. First, to unfold the hidden dynamics of cycling batte…
This paper proposes the linearized physics-based model of a lithium-ion battery that can be incorporated into the optimization framework for power system economic studies. The proposed model is a linear approximation of the single particle model and it allows to characterize dynamics of the physical processes inside the battery that impact the battery operation. There is a need for such model as a simplistic power-energy model that is widely employed in operation and planning studies with the lithium-ion battery energy storage system (LIBESS) results in infeasible operation and misleading econ…
The penetration of the lithium-ion battery energy storage system (BESS) into the power system environment occurs at a colossal rate worldwide. This is mainly because it is considered as one of the major tools to decarbonize, digitalize, and democratize the electricity grid. The economic viability and technical reliability of projects with batteries require appropriate assessment because of high capital expenditures, deterioration in charging/discharging performance and uncertainty with regulatory policies. Most of the power system economic studies employ a simple power-energy representation co…
Lithium-ion battery systems have been used in practical power systems for peak-shaving, demand response, and frequency regulation. However, a lithium-ion battery is degrading while cycling and would be scrapped when the capacity reduces to a certain threshold (e.g. 80%). Such scrapping criterion may not explore the maximum benefit from the battery storage. In this paper, we propose a novel scrapping criterion for peak-shaving energy storage based on battery efficiency, time-of-use price, and arbitrage benefit. A new battery life model with scrapping parameters is then derived using this criter…
This paper investigates the impact of implantable cardioverter defibrillator (ICD)'s load on its lithium battery power sources through a coupled electro-thermal dynamic model simulation. ICDs are one of the effective treatments available to significantly improve survival of patients with fatal arrhythmia (abnormal heart rhythm) disorders. Using a lithium battery power source, this life-saving device sends electrical shocks or pulses to regulate the heartbeat. The service life and reliability of an ICD is primarily expressed by its battery's lifespan and performance. In this paper we investigat…
This paper examines the problem of estimating the parameters of a Lithium-Sulfur (LiS) battery from experimental cycling data. LiS batteries are attractive compared to traditional Lithium-Ion batteries, thanks largely to their potential to provide higher energy densities. The literature presents a number of different LiS battery models, with different fidelities and complexities. This includes both higher-fidelity diffusion-reaction models as well as "zero-dimensional" models that neglect diffusion dynamics while capturing the physics of the underlying reduction-oxidation reactions. The paper …
Battery aging is a natural process that contributes to capacity and power fade, resulting in a gradual performance degradation over time and usage. State of Charge (SOC) and State of Health (SOH) monitoring of an aging battery poses a challenging task to the Battery Management System (BMS) due to the lack of direct measurements. Estimation algorithms based on an electrochemical model that take into account the impact of aging on physical battery parameters can provide accurate information on lithium concentration and cell capacity over a battery's usable lifespan. A temperature-dependent elect…
Evaluation of Energy- and Capacity-Market Revenues from Lithium-ion Battery Systems for Offshore Wind Using Advanced Battery Models
使用先进的锂离子电池表示法检查了纽约ISO（NYISO）长岛节点的海上风电和储能系统的收入潜力。这些先进的混合整数线性电池模型考虑了电池的动态性能以及电池的退化行为，这在电力系统模型中通常不考虑。研究了多个混合海上风力和电池系统设计，以检查将电池定位在海上与将其定位在陆上的影响。对于所研究的系统，我们探索不同的电池可用荷电状态（SOC）窗口，以及相应的电池调度，以最大限度地提高能源和容量市场的收入。利用2010年至2013年的公开数据，评估了海上风电输出变化以及能源和容量市场价格的影响。将电池安装在岸上带来了更高的收入。对于2013年，结果强调，如果没有准确的电池表示，模型可以高估电池收入高达155%，主要是由于退化相关的成本。使用先进的算法，净收入可以增加29%。结果还表明，更广泛的可用SOC窗口可能会导致更高的净收入从能源市场，由于更高的套利机会，以补偿任何额外的退化相关成本在更高的DOD。兆瓦时的能量存储的附加值从每兆瓦时风能的$2 to $ 3.5变化，这导致所研究的电池系统的盈亏平衡成本范围为每千瓦时$50-$ 95。因此，能源和容量市场的收入被发现不足以收回本分析中考虑的应用的当前电池系统的投资成本。
This paper presents the development of machine learning-enabled data-driven models for effective capacity predictions for lithium-ion batteries under different cyclic conditions. To achieve this, a model structure is first proposed with the considerations of battery ageing tendency and the corresponding operational temperature and depth-of-discharge. Then based on a systematic understanding of covariance functions within the Gaussian process regression, two related data-driven models are developed. Specifically, by modifying the isotropic squared exponential kernel with an automatic relevance …
Lithium-ion battery (LIB) sources have played an essential role in self-sustained transportation energy systems and have been widely deployed in the last few years. To realize reliable battery maintenance, identifying its electrochemical parameters is necessary. However, the battery model contains many parameters while the measurable states are only the current and voltage, inducing the identification inherently an ill-conditioned problem. A parameter identification approach is proposed, including the experiment, model, and algorithm. Electrochemical parameters are first grouped manually based…
User-centric Vehicle-to-Grid Optimization with an Input Convex Neural Network-based Battery Degradation Model
Delft Center for Systems and Control (DCSC), Department of Mechanical Engineering, Delft University of Technology (TU Delft)（代尔夫特系统与控制中心（DCSC）、机械工程系、代尔夫特理工大学）
Islanded microgrids powered by renewable energy require costly energy storage systems due to the uncontrollable generators. Energy storage needs are amplified when load and generation are misaligned on hourly, monthly, or seasonal timescales. Diversification of both loads and generation can smooth out such mismatches. The ideal type of battery to smooth out remaining generation deficits will depend on the duration(s) that energy is stored. This study presents a controls co-design approach to design an islanded microgrid, showing the benefit of hybridizing tidal and solar generation and hybridi…
The penetrations of lithium-ion batteries in transport, energy and communication systems are increasing rapidly. A meticulous model applicable for precise in-situ monitoring and convenient online controlling is in sought to bridge the gap between research and applications. This paper proposes a simplified electro-chemical model and its discrete-time state-space realization derived from the pseudo-two-dimensional model. The solution-phase migration and solid-phase diffusion dynamics with varying parameters are captured and rigorous mathematical expressions of reaction rate distribution and term…
Energy storage systems for transportation and grid applications, and in the future for aeronautical applications, require the ability of providing accurate diagnosis to insure system availability and reliability. In such applications, battery packs may consist of hundreds or thousands of interconnected cells, and of the associated electrical/electronic hardware. This paper presents a systematic methodology for approaching some aspects of the design of battery packs, and in particular understanding the degree of analytical redundancy (AR) in the system that can be used for diagnostic strategies…
The installation capacity of energy storage system, especially the battery energy storage system (BESS), has increased significantly in recent years, which is mainly applied to mitigate the fluctuation caused by renewable energy sources (RES) due to the fast response and high round-trip energy efficiency of BESS. The main components of majority of BESSs are lithium-ion batteries, which will degrade during the BESS daily operation. Heuristic battery degradation models are proposed to consider the battery degradation in the operations of energy systems to optimize the scheduling. However, those …
Accurate tracking of the internal electrochemical states of lithium-ion battery during cycling enables advanced battery management systems to operate the battery safely and maintain high performance while minimizing battery degradation. To this end, techniques based on voltage measurement have shown promise for estimating the lithium surface concentration of active material particles, which is an important state for avoiding aging mechanisms such as lithium plating. However, methods relying on voltage often lead to large estimation errors when the model parameters change during aging. In this …
School of Electrical Engineering, Xi’an Jiaotong University（西安交通大学电气工程学院）
Accurate co-estimations of battery states, such as state-of-charge (SOC), state-of-health (SOH,) and remaining useful life (RUL), are crucial to the battery management systems to assure safe and reliable management. Although the external properties of the battery charge with the aging degree, batteries' degradation mechanism shares similar evolving patterns. Since batteries are complicated chemical systems, these states are highly coupled with intricate electrochemical processes. A state-coupled co-estimation method named Deep Inter and Intra-Cycle Attention Network (DIICAN) is proposed in thi…
Battery energy storage system (BESS) can effectively mitigate the uncertainty of variable renewable generation and provide flexible ancillary services. However, degradation is a key concern for rechargeable batteries such as the most widely used Lithium-ion battery. A neural network based battery degradation (NNBD) model can accurately quantify the battery degradation. When incorporating the NNBD model into security-constrained unit commitment (SCUC), we can establish a battery degradation based SCUC (BD-SCUC) model that can consider the equivalent battery degradation cost precisely. However, …
Robust Parametric Microgrid Dispatch Under Endogenous Uncertainty of Operation- and Temperature-Dependent Battery Degradation
State Key Laboratory of Environmental Adaptability for Industrial Products, China National Electric Apparatus Research Institute Co., Ltd.（工业产品环境适应性国家重点实验室，中国电器科学研究院有限公司）；Department of Mechanical and Automation Engineering, The Chinese University of Hong Kong（香港中文大学机械与自动化工程学系）
This article examines the problem of Lithium-Sulfur (Li-S) battery state estimation. Such estimation is important for the online management of this energy-dense chemistry. The literature uses equivalent circuit models (ECMs) for Li-S state estimation. This article's main goal is to perform estimation using a physics-based model instead. This approach is attractive because it furnishes online estimates of the masses of individual species in a given Li-S cell. The estimation is performed using an experimentally-validated, computationally tractable zero-dimensional model. Reformulation converts t…
The recent decrease in battery manufacturing costs stimulates the market participation of utility-scale battery energy storage systems (BESSs). However, battery degradation remains a major concern for BESS owners while determining their BESS investment and operation strategies. This paper studies the impact of battery degradation on BESS's operation and revenue/cost in real-time energy, reserve, and pay as performance regulation markets. Comparative case studies are performed on two optimization frameworks which model the participation of a price-maker BESS in energy and ancillary services mar…
This work presents an effective state of health indicator to indicate lithium-ion battery degradation based on a long short-term memory (LSTM) recurrent neural network (RNN) coupled with a sliding-window. The developed LSTM RNN is able to capture the underlying long-term dependencies of degraded cell capacity on battery degradation stress factors. The learning performance was robust when there was sufficient training data, with an error of < 5% if more than 1.15 years worth of data was supplied for training.
The increasing uptake of electrical vehicles (EVs) has increased the awareness of battery degradation costs and how they can be minimized. However, from a planning perspective it is difficult to integrate battery degradation models into existing route planning models and to assess how policies that aim at reducing battery degradation affect route planning costs and degradation across the fleet. In this paper, a simple transportation vehicle routing problem (VRP) is formulated as a mixed-integer nonlinear problem (MINLP), with a modification that allows monitoring the maximum and minimum depth-…
