Ca $_2$ MnReO $_6$双钙钛矿是具有奇异磁性的自旋-轨道辅助的Mott绝缘体,包括很大程度上非共线的Mn $^{2+}$自旋排列和这种自旋与小得多的Re $5d$磁矩之间的几乎正交耦合。在这里,研究了电子掺杂化合物Ca $_{1.7}$ Y $_{0.3}$ MnReO $_6$。中子和X-射线粉末衍射证实,几乎完整的化学秩序保持在Mn和Re网站下的Y取代在Ca网站。X射线吸收测量和Mn-O/Re-O键距的分析表明,Mn的氧化态在+2保持稳定,而Re在掺杂时减少。电子掺杂将磁有序温度从$T_c = 121$提高到$150$ K,并且还显著增强了Mn自旋的铁磁分量,但牺牲了在基础温度($T=3$ K)下的反铁磁分量。在母体化合物中观察到的$T_c$的晶格参数异常被电子掺杂抑制。讨论了Ca $_{1.7}$ Y $_{0.3}$ MnReO $_6$磁性增强和磁弹耦合抑制的可能原因。
英文摘要:
The Ca$_2$MnReO$_6$ double perovskite is a spin-orbit-assisted Mott insulator with exotic magnetic properties, including a largely non-collinear Mn$^{2+}$ spin arrangement and nearly orthogonal coupling between such spins and the much smaller Re $5d$ magnetic moments. Here, the electron-doped compound Ca$_{1.7}$Y$_{0.3}$MnReO$_6$ is investigated. Neutron and X-ray powder diffraction confirm that nearly full chemical order is maintained at the Mn and Re sites under the Y substitution at the Ca site. X-ray absorption measurements and an analysis of the Mn-O/Re-O bond distances show that the Mn oxidation state remains stable at +2 whereas Re is reduced upon doping. The electron doping increases the magnetic ordering temperature from $T_c = 121$ to $150$ K and also enhances significantly the ferromagnetic component of the Mn spins at the expense of the antiferromagnetic component at the base temperature ($T=3$ K). The lattice parameter anomalies at $T_c$ observed in the parent compound are suppressed by the electron doping. The possible reasons for the enhanced magnetism and the suppressed magnetoelastic coupling in Ca$_{1.7}$Y$_{0.3}$MnReO$_6$ are discussed.
Monopole matter from magnetoelastic coupling in the Ising pyrochlore
烧绿石氧化物晶格上的伊辛模型通常与自旋冰材料和“磁单极子”有关。越来越多的影响连接磁性和弹性自由度的报告,这些和其他相关的挫折材料。在这里,我们扩展了自旋冰哈密顿量,包括自旋和O $^{-2}$离子介导的超交换之间的耦合,我们称之为磁弹性自旋冰模型(MeSI)。人们一直在寻找一个模型,在这个模型中,磁单极子会自发地成为新基态的基石:MeSI哈密顿量就是这样一个模型。尽管它的简单和经典的方法,它描述(自旋和氧晶格)的双层结晶观察Tb $_2$ Ti $_2$ O $_7$。值得注意的是,单单极子的偶极电矩作为磁性的探针出现。作为一个例子,我们表明,在原则上,可以检测到与库仑相位相关的夹点与O $^{-2}$ -离子位移。
Magnetoelastic honeycomb fragmentation in VI$_{3}$
University of Edinburgh(爱丁堡大学);NIST Center for Neutron Research(美国国家标准与技术研究院中子研究中心);University of Maryland, College Park(马里兰大学帕克分校);ISIS Facility, Rutherford Appleton Laboratory(卢瑟福·阿普尔顿实验室 ISIS 设施);European Synchrotron Radiation Facility(欧洲同步辐射装置)
Magnetoelastic coupling and charge correlation lengths in a twin domain of Ba(Fe$_{1-x}$Co$_{x}$)$_{2}$As$_{2}$ ($x=0.047$): A high-resolution X-ray diffraction study
本文用高分辨X射线衍射方法研究了Ba(Fe $_{1-x}$ Co $_{x}$)$_{2}$ As $_{2}$(x=0.047)单晶的结构、磁性和超导电性之间的相互关系。超导态的出现与抑制\emph{T} $_\texttt{C}$周围的正交畸变有关,表现出正交性和超导性之间的竞争。高于\emph{T} $_\texttt{S}$,面内电荷相关长度随着温度的降低而增加,这可能是由顺磁四元相的电子涨落引起的。冷却后,在\emph{T} $_\texttt{S}$和\emph{T} $_\texttt{N}$观察到沿$a$($ξ_{a}$)和$b$轴($ξ_{b}$)的面内电荷相关长度的异常,表明强磁弹性耦合。面内电荷相关长度在沿和垂直于条形AFM波矢(101)$_{\rm O}$的面内分量的方向上表现出各向异性,$_{\rm O}$在\emph{T} $_\texttt{N}$附近。面外电荷关联长度的温度依赖性在\emph{T} $_\texttt{N}$处显示出单一的异常,反映了Fe-As距离和Fe局域矩之间的联系。从反相磁畴及其动态涨落的角度讨论了各向异性面内电荷关联长度$ξ_{a}$和$ξ_{b}$的来源。
Magnetic self-frustration from spontaneous structural distortion
Instituto de Física de Líquidos y Sistemas Biológicos (IFLYSIB), UNLP-CONICET(液体与生物系统物理研究所 (IFLYSIB),拉普拉塔国立大学-国家科学研究委员会);Departamento de Física, Facultad de Ciencias Exactas, Universidad Nacional de La Plata(拉普拉塔国立大学,理学院,物理系)