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arXiv 2202.08220cond-mat.str-elcond-mat.other
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电子掺杂对Ca $_{1-x}$ Y $_{x}$ MnReO $_6$磁性的增强和磁弹性耦合的抑制

Enhanced magnetism and suppressed magnetoelastic coupling induced by electron doping in Ca$_{1-x}$Y$_{x}$MnReO$_6$

A. S. Cavichini, M. T. Orlando, M. C. A. Fantini, R. Tartaglia, C. W. Galdino, F. Damay, F. Porcher, E. Granado

摘要:

Ca $_2$ MnReO $_6$双钙钛矿是具有奇异磁性的自旋-轨道辅助的Mott绝缘体,包括很大程度上非共线的Mn $^{2+}$自旋排列和这种自旋与小得多的Re $5d$磁矩之间的几乎正交耦合。在这里,研究了电子掺杂化合物Ca $_{1.7}$ Y $_{0.3}$ MnReO $_6$。中子和X-射线粉末衍射证实,几乎完整的化学秩序保持在Mn和Re网站下的Y取代在Ca网站。X射线吸收测量和Mn-O/Re-O键距的分析表明,Mn的氧化态在+2保持稳定,而Re在掺杂时减少。电子掺杂将磁有序温度从$T_c = 121$提高到$150$ K,并且还显著增强了Mn自旋的铁磁分量,但牺牲了在基础温度($T=3$ K)下的反铁磁分量。在母体化合物中观察到的$T_c$的晶格参数异常被电子掺杂抑制。讨论了Ca $_{1.7}$ Y $_{0.3}$ MnReO $_6$磁性增强和磁弹耦合抑制的可能原因。

英文摘要:

The Ca$_2$MnReO$_6$ double perovskite is a spin-orbit-assisted Mott insulator with exotic magnetic properties, including a largely non-collinear Mn$^{2+}$ spin arrangement and nearly orthogonal coupling between such spins and the much smaller Re $5d$ magnetic moments. Here, the electron-doped compound Ca$_{1.7}$Y$_{0.3}$MnReO$_6$ is investigated. Neutron and X-ray powder diffraction confirm that nearly full chemical order is maintained at the Mn and Re sites under the Y substitution at the Ca site. X-ray absorption measurements and an analysis of the Mn-O/Re-O bond distances show that the Mn oxidation state remains stable at +2 whereas Re is reduced upon doping. The electron doping increases the magnetic ordering temperature from $T_c = 121$ to $150$ K and also enhances significantly the ferromagnetic component of the Mn spins at the expense of the antiferromagnetic component at the base temperature ($T=3$ K). The lattice parameter anomalies at $T_c$ observed in the parent compound are suppressed by the electron doping. The possible reasons for the enhanced magnetism and the suppressed magnetoelastic coupling in Ca$_{1.7}$Y$_{0.3}$MnReO$_6$ are discussed.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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